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Here are 3 links for Autodesk Masterclasses that teach UI creation from within Maya:
http://area.autodesk.com/accessdenied?/masterclasses/masterclass/gdc11_class3
http://area.autodesk.com/accessdenied?/masterclasses/masterclass/class2_q4_2011
http://area.autodesk.com/accessdenied?/masterclasses/masterclass/class2_q2_2012_kristine_middlemiss
Please enjoy.
P.S. Here's another simple set of tutorials for PyQt and Maya:
http://zurbrigg.com/maya-tutorials