diff --git a/e2e/keywords/persistentvolumeclaim.resource b/e2e/keywords/persistentvolumeclaim.resource
index 73d5b25e6..100740210 100644
--- a/e2e/keywords/persistentvolumeclaim.resource
+++ b/e2e/keywords/persistentvolumeclaim.resource
@@ -23,3 +23,12 @@ Delete persistentvolumeclaim ${claim_id}
 Delete persistentvolumeclaim for volume ${volume_id}
     ${claim_name} =    generate_name_with_suffix    volume    ${volume_id}
     delete_persistentvolumeclaim    ${claim_name}
+
+Assert persistentvolumeclaim ${claim_id} requested size remains ${size} for at least ${period} seconds
+    ${claim_name} =    generate_name_with_suffix    claim    ${claim_id}
+    FOR    ${i}    IN RANGE    ${period}
+        ${expected_size_byte} =    convert_size_to_bytes    ${size}    to_str=True
+        ${current_size_byte} =    get_claim_requested_size    ${claim_name}
+        Should Be Equal    ${current_size_byte}    ${expected_size_byte}
+        Sleep    1
+    END
diff --git a/e2e/keywords/workload.resource b/e2e/keywords/workload.resource
index 13e0926df..1c4eef61b 100644
--- a/e2e/keywords/workload.resource
+++ b/e2e/keywords/workload.resource
@@ -238,3 +238,22 @@ Expand ${workload_kind} ${workload_id} volume by ${size}
     ${new_size} =    convert_size_to_bytes    ${size}
 
     expand_workload_claim_size    ${workload_name}    ${new_size}
+
+Expand ${workload_kind} ${workload_id} volume more than storage maximum size should fail
+    ${workload_name} =   generate_name_with_suffix    ${workload_kind}    ${workload_id}
+    ${volume_name} =    get_workload_volume_name    ${workload_name}
+    ${node_name} =    get_volume_node    ${volume_name}
+    ${max_size} =    get_volume_node_disk_storage_maximum    ${volume_name}    ${node_name}
+    ${new_size} =    evaluate    ${max_size} + 1
+
+    Run Keyword And Expect Error    Failed to expand*    expand_workload_claim_size    ${workload_name}    ${new_size}    skip_retry=True
+
+Assert volume size of ${workload_kind} ${workload_id} remains ${size} for at least ${period} seconds
+    ${workload_name} =   generate_name_with_suffix    ${workload_kind}    ${workload_id}
+    ${volume_name} =    get_workload_volume_name    ${workload_name}
+    FOR    ${i}    IN RANGE    ${period}
+        ${expected_size_byte} =    convert_size_to_bytes    ${size}    to_str=True
+        ${current_size_byte} =    get_volume_size    ${volume_name}
+        Should Be Equal    ${current_size_byte}    ${expected_size_byte}
+        Sleep    1
+    END
diff --git a/e2e/libs/keywords/common_keywords.py b/e2e/libs/keywords/common_keywords.py
index 141487559..35d550d32 100644
--- a/e2e/libs/keywords/common_keywords.py
+++ b/e2e/libs/keywords/common_keywords.py
@@ -1,6 +1,7 @@
 from node import Node
 from node_exec import NodeExec
 
+from utility.utility import convert_size_to_bytes
 from utility.utility import init_k8s_api_client
 from utility.utility import generate_name_with_suffix
 
@@ -25,3 +26,8 @@ def get_node_by_index(self, node_id):
     def cleanup_node_exec(self):
         for node_name in Node().list_node_names_by_role("all"):
             NodeExec(node_name).cleanup()
+
+    def convert_size_to_bytes(self, size, to_str=False):
+        if to_str:
+            return str(convert_size_to_bytes(size))
+        return convert_size_to_bytes(size)
diff --git a/e2e/libs/keywords/persistentvolumeclaim_keywords.py b/e2e/libs/keywords/persistentvolumeclaim_keywords.py
index 912950251..9c28836d7 100644
--- a/e2e/libs/keywords/persistentvolumeclaim_keywords.py
+++ b/e2e/libs/keywords/persistentvolumeclaim_keywords.py
@@ -34,3 +34,7 @@ def expand_persistentvolumeclaim_size_by_mib(self, claim_name, size_in_mib):
 
         logging(f'Expanding persistentvolumeclaim {claim_name} by {size_in_mib} MiB')
         self.claim.set_annotation(claim_name, ANNOT_EXPANDED_SIZE, str(expanded_size))
+
+    def get_claim_requested_size(self, claim_name):
+        claim = self.claim.get(claim_name)
+        return claim.spec.resources.requests['storage']
diff --git a/e2e/libs/keywords/volume_keywords.py b/e2e/libs/keywords/volume_keywords.py
index 369be7266..860d5deb6 100644
--- a/e2e/libs/keywords/volume_keywords.py
+++ b/e2e/libs/keywords/volume_keywords.py
@@ -1,4 +1,5 @@
 import asyncio
+import json
 import time
 
 from node import Node
@@ -9,6 +10,7 @@
 from utility.constant import ANNOT_REPLICA_NAMES
 from utility.constant import LABEL_TEST
 from utility.constant import LABEL_TEST_VALUE
+from utility.constant import LONGHORN_NAMESPACE
 from utility.utility import logging
 from utility.utility import get_retry_count_and_interval
 
@@ -344,3 +346,22 @@ def get_volume_checksum(self, volume_name):
 
     def validate_volume_setting(self, volume_name, setting_name, value):
         return self.volume.validate_volume_setting(volume_name, setting_name, value)
+
+    def get_volume_size(self, volume_name):
+        volume = self.volume.get(volume_name)
+        return volume['spec']['size']
+
+    def get_volume_node_disk_storage_maximum(self, volume_name, node_name):
+        replica_list = self.replica.get(volume_name, node_name)
+        replica = replica_list[0]
+        replica_name = replica['metadata']['name']
+        node = self.node.get_node_by_name(node_name, namespace=LONGHORN_NAMESPACE)
+        for diskName in node.disks:
+            disk = node.disks[diskName]
+
+            for scheduledReplica in disk['scheduledReplica']:
+                if scheduledReplica == replica_name:
+                    logging(f"Found replica {scheduledReplica} on node {node_name} scheduled to disk {diskName}")
+                    return disk['storageMaximum']
+
+        raise Exception(f"Failed to find storageMaximum for volume {volume_name} replica {replica_name} on node {node_name}")
diff --git a/e2e/libs/node/node.py b/e2e/libs/node/node.py
index d7ed52342..7e48fe5d2 100644
--- a/e2e/libs/node/node.py
+++ b/e2e/libs/node/node.py
@@ -6,6 +6,7 @@
 from robot.libraries.BuiltIn import BuiltIn
 
 from utility.constant import DISK_BEING_SYNCING
+from utility.constant import LONGHORN_NAMESPACE
 from utility.constant import NODE_UPDATE_RETRY_INTERVAL
 from utility.utility import get_longhorn_client
 from utility.utility import get_retry_count_and_interval
@@ -99,7 +100,10 @@ def get_node_by_index(self, index, role="worker"):
         nodes = self.list_node_names_by_role(role)
         return nodes[int(index)]
 
-    def get_node_by_name(self, node_name):
+    def get_node_by_name(self, node_name, namespace="kube-system"):
+        if namespace == LONGHORN_NAMESPACE:
+            return get_longhorn_client().by_id_node(node_name)
+
         core_api = client.CoreV1Api()
         return core_api.read_node(node_name)
 
diff --git a/e2e/tests/regression/test_persistentvolumeclaim.robot b/e2e/tests/regression/test_persistentvolumeclaim.robot
new file mode 100644
index 000000000..a79ee437a
--- /dev/null
+++ b/e2e/tests/regression/test_persistentvolumeclaim.robot
@@ -0,0 +1,44 @@
+*** Settings ***
+Documentation    PersistentVolumeClaim Test Cases
+
+Test Tags    regression
+
+Resource    ../keywords/common.resource
+Resource    ../keywords/deployment.resource
+Resource    ../keywords/persistentvolumeclaim.resource
+Resource    ../keywords/setting.resource
+Resource    ../keywords/workload.resource
+
+Test Setup    Set test environment
+Test Teardown    Cleanup test resources
+
+*** Variables ***
+${LOOP_COUNT}    1
+${RETRY_COUNT}    300
+${RETRY_INTERVAL}    1
+
+*** Test Cases ***
+
+Test persistentvolumeclaim expand more than storage maximum size should fail
+    [Tags]    volume    expansion
+    [Documentation]    Verify that a PersistentVolumeClaim cannot be expanded beyond
+    ...                the storage maximum size.
+    ...
+    ...                Issue: https://github.com/longhorn/longhorn/issues/6633
+
+    Given Set setting storage-over-provisioning-percentage to 100
+    And Create persistentvolumeclaim 0 using RWX volume    storage_size=2GiB
+    And Create deployment 0 with persistentvolumeclaim 0
+    And Write 10 MB data to file data.txt in deployment 0
+
+    FOR    ${i}    IN RANGE    ${LOOP_COUNT}
+        When Expand deployment 0 volume more than storage maximum size should fail
+        Then Assert volume size of deployment 0 remains 2GiB for at least 5 seconds
+        And Assert persistentvolumeclaim 0 requested size remains 2GiB for at least 5 seconds
+        And Check deployment 0 data in file data.txt is intact
+
+        When Expand deployment 0 volume by 1 GiB
+        Then Assert persistentvolumeclaim 0 requested size remains 3GiB for at least 5 seconds
+        And Assert volume size of deployment 0 remains 3GiB for at least 5 seconds
+        And Check deployment 0 data in file data.txt is intact
+    END