diff --git a/catalog-v001.xml b/catalog-v001.xml
index 6d0fc1b..4ca5747 100644
--- a/catalog-v001.xml
+++ b/catalog-v001.xml
@@ -1,13 +1,9 @@
-
-
-
-
-
-
-
-
-
+
+
+
+
+
diff --git a/electrochemicalquantities.ttl b/electrochemicalquantities.ttl
index 6a59bc2..e16366b 100644
--- a/electrochemicalquantities.ttl
+++ b/electrochemicalquantities.ttl
@@ -11,16 +11,13 @@
@base .
rdf:type owl:Ontology ;
- owl:versionIRI ;
- owl:imports ,
- ,
- ,
- ;
+ owl:versionIRI ;
+ owl:imports ;
dcterms:abstract """Everything needed to describe fundamental quantities in electrochemistry common to all electrochemical systems.
Released under the Creative Commons license Attribution 4.0 International (CC BY 4.0)."""@en ;
dcterms:license "https://creativecommons.org/licenses/by/4.0/legalcode" ;
- owl:versionInfo "0.5.0" .
+ owl:versionInfo "0.6.0" .
#################################################################
# Annotation properties
@@ -54,6 +51,13 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
# Classes
#################################################################
+### http://emmo.info/electrochemistry#electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476
+:electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacity delivered during a discharge process"@en ;
+ skos:prefLabel "DischargeCapacity"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634
:electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
@@ -62,8 +66,11 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
### http://emmo.info/electrochemistry#electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1
:electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q658700" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reaction_rate_constant"@en ;
skos:prefLabel "ReactionRateConstant"@en .
@@ -71,7 +78,7 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
:electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-09" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte"@en ;
skos:altLabel "OhmicOvervoltage"@en ,
"OhmicPolarization"@en ;
skos:prefLabel "OhmicOverpotential"@en .
@@ -79,26 +86,29 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte."@en ;
+ owl:annotatedTarget "part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_05012606_b93d_4016_bbc7_8a927efdf723
+:electrochemistry_05012606_b93d_4016_bbc7_8a927efdf723 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of the negative electrode and the capacity of the positive electrode in a cell"@en ;
+ skos:altLabel "NToPRatio"@en ;
+ skos:prefLabel "NPRatio"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e
:electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_96f39f77_44dc_491b_8fa7_30d887fe0890 ;
- skos:prefLabel "ExternalSurfaceArea"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_061fd188_0552_4a53_8eb3_845aacc1bb5d
-:electrochemistry_061fd188_0552_4a53_8eb3_845aacc1bb5d rdf:type owl:Class ;
- owl:equivalentClass [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_23b579e1_8088_45b5_9975_064014026c42 ;
- owl:hasValue "T+2 L-2 M0 I+1 Θ0 N0 J0"
- ] ;
- rdfs:subClassOf emmo:EMMO_9895a1b4_f0a5_4167_ac5e_97db40b8bfcc ;
- skos:prefLabel "ElectricChargeCapacityPerAreaDimension"@en .
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1379273" ;
+ emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Surface_area"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a measure of the total area that the surface of a solid object occupies"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Surface_area"@en ;
+ skos:prefLabel "SurfaceArea"@en .
### http://emmo.info/electrochemistry#electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764
@@ -124,24 +134,27 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
:electrochemistry_0853b072_3b80_4864_8147_24ce35407ade rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-07" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an electrochemical reduction reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an electrochemical reduction reaction"@en ;
skos:altLabel "CathodicPolarization"@en ;
skos:prefLabel "CathodicOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_0853b072_3b80_4864_8147_24ce35407ade ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "electrode polarization associated with an electrochemical reduction reaction."@en ;
+ owl:annotatedTarget "electrode polarization associated with an electrochemical reduction reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### http://emmo.info/electrochemistry#electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef
:electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In CCCV methods, the cell voltage at which the constant current mode switches to constant voltage mode."@en ;
- emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "The imposed constant voltage is often the same value as the voltage change limit."@en ;
+ rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
+ owl:someValuesFrom emmo:EMMO_6837b106_7220_4ec6_b7c9_d549d6163672
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a control limit placed on the rate of change of the cell voltage, dV/dt."@en ;
+ skos:altLabel "dV/dt"@en ;
skos:prefLabel "VoltageChangeLimit"@en .
@@ -152,7 +165,7 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The magnitude of the voltage step in step voltammetry and related techniques."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the magnitude of the voltage step in step voltammetry and related techniques"@en ;
skos:prefLabel "StepSignalVoltage"@en .
@@ -160,32 +173,31 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
:electrochemistry_0c9655c6_6b0b_4819_a219_f286ad196fa9 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_ffb73b1e_5786_43e4_a964_cb32ac7affb7 ;
- rdfs:comment "Inverse of InternalResistance."@en ;
+ rdfs:comment "inverse of internal resistance"@en ;
skos:prefLabel "InternalConductance"@en .
-### http://emmo.info/electrochemistry#electrochemistry_0ffa4bda_8a52_471a_a59d_f27cf8caecbb
-:electrochemistry_0ffa4bda_8a52_471a_a59d_f27cf8caecbb rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
- skos:prefLabel "TransportEfficiency"@en .
+### http://emmo.info/electrochemistry#electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45
+:electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacity delivered during a charge process"@en ;
+ skos:prefLabel "ChargeCapacity"@en .
### http://emmo.info/electrochemistry#electrochemistry_10eb778d_da60_4832_a355_4ee74baea650
:electrochemistry_10eb778d_da60_4832_a355_4ee74baea650 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom emmo:EMMO_d5f3e0e5_fc7d_4e64_86ad_555e74aaff84
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Half the peak-to-peak amplitude of a sinusoidal alternating current."@en ;
+ emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "half the peak-to-peak amplitude of a sinusoidal alternating current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.A00310" ;
skos:prefLabel "AmplitudeOfAlternatingCurrent"@en .
### http://emmo.info/electrochemistry#electrochemistry_129926b6_fc30_441d_b359_29b44c988514
:electrochemistry_129926b6_fc30_441d_b359_29b44c988514 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ;
+ rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
+ emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q759643" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The electrode electric potential range between which the substance is neither oxidized nor reduced."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_window"@en ;
skos:altLabel "ElectrochemicalStabilityWindow"@en ;
@@ -195,7 +207,7 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
### http://emmo.info/electrochemistry#electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0
:electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.P04791"@en ;
rdfs:comment "The selectivity coefficient is determined by means of the potential difference of the ion- selective electrode in mixed solutions of the primary ion, A, and interfering ion, B (Fixed Interference Method) or, less desirably, in separate solutions of A and B (Separate Solution Method). The activities of the primary ion, A, and the interfering ion, B, at which K is determined should always be specified, as the value of K is defined by a modified Nikolsky-Eisenman equation. The smaller the value of K , the A,B greater the electrode’s preference for the primary ion, A."@en ;
skos:altLabel "SelectivityCoefficient"@en ,
@@ -203,6 +215,13 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
"SelectivityFactor"@en ;
skos:prefLabel "PotentiometricSelectivityCoefficient"@en .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd
:electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd rdf:type owl:Class ;
@@ -212,23 +231,24 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_f6070071_d054_4b17_9d2d_f446f7147d0f
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The electrochemical potential is the chemical potential of an ion in the presence of an electric potential."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q62525" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the electrochemical potential is the chemical potential of an ion in the presence of an electric potential"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/E01945" ;
- rdfs:comment "In quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy."@en ;
+ rdfs:comment "in quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy"@en ;
skos:prefLabel "ElectrochemicalPotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The electrochemical potential is the chemical potential of an ion in the presence of an electric potential."@en ;
+ owl:annotatedTarget "the electrochemical potential is the chemical potential of an ion in the presence of an electric potential"@en ;
dcterms:source "Atkins and DePaula, Aktins' Physical Chemistry, 8th ed., p.952"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "In quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy."@en ;
+ owl:annotatedTarget "in quantum mechanical terms, electrochemical potential is defined as the energy level of the electron orbitals in the species that have a 50 percent probability of occupancy"@en ;
dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004."
] .
@@ -236,14 +256,14 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
### http://emmo.info/electrochemistry#electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b
:electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Algebraic sum of faradaic currents flowing through an electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "algebraic sum of faradaic currents flowing through an electrode"@en ;
rdfs:comment "I"@en ;
skos:prefLabel "NetFaradaicCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Algebraic sum of faradaic currents flowing through an electrode."@en ;
+ owl:annotatedTarget "algebraic sum of faradaic currents flowing through an electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -266,7 +286,8 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
### http://emmo.info/electrochemistry#electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90
:electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1224527" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Diffusion_current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/D01722"@en ;
rdfs:comment "Diffusion current is governed by Fick’s Laws of diffusion. It is the principle on which many electroana- lytical methods are based, because the current is proportional to the bulk concentration of the diffusing species. I_{d} = z*F*A*D*\\grad(c)_{x=0}, where z is the electron number of an electrochemical reaction, F the Faraday constant, A the electrode surface area, D the diffusion coefficient of electroactive substance, and (∂c/∂x)x=0 the gradient of the amount concentration at the electrode surface position x = 0."@en ,
@@ -276,7 +297,7 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
+ owl:annotatedTarget "faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -285,14 +306,14 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
:electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_3789d3c5_77f4_456e_b7ed_40e670f47e52 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Rotational frequency of a rotating component in a rotating disk electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "rotational frequency of a rotating component in a rotating disk electrode"@en ;
emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "The rotating component can be the main rotating disk or a secondary ring as used in rotating ring disk electrodes."@en ;
skos:prefLabel "RotatingDiskSpeed"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Rotational frequency of a rotating component in a rotating disk electrode."@en ;
+ owl:annotatedTarget "rotational frequency of a rotating component in a rotating disk electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -330,13 +351,11 @@ and t* through mathematical models, provided that the long-time potential- deter
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-02" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Overpotential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/O04358" ;
- rdfs:comment "Deviation of the potential of an electrode from its equilibrium value required to cause a given current to flow through the electrode."@en ,
- "Difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential."@en ,
- "Overpotential is positive for oxidation reactions and negative for reduction reactions."@en ,
- "Overpotential is the extra potential, in relation to the equilibrium value, required to cause a given electric current to flow through the electrode."@en ;
+ rdfs:comment "difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential"@en ,
+ "overpotential is positive for oxidation reactions and negative for reduction reactions"@en ;
skos:altLabel "ElectrodePolarization"@en ,
"Overvoltage"@en ,
"PolarizationPotential"@en ;
@@ -345,14 +364,14 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction."@en ;
+ owl:annotatedTarget "electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential."@en ;
+ owl:annotatedTarget "difference between the electrode potential with current flow, and the electrode potential without current flow, i.e. the equilibrium potential"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -360,21 +379,32 @@ and t* through mathematical models, provided that the long-time potential- deter
### http://emmo.info/electrochemistry#electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30
:electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
- emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
+ emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
+ owl:someValuesFrom emmo:EMMO_4dbe2b16_3e84_4049_898d_eb89bcc925a2
+ ] ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-19" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a battery, cell, electrode, or active material by its mass."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a cell or battery [ or electrode or active material ] by its mass."@en ;
rdfs:comment "Can also be applied to electrodes."@en ;
skos:altLabel "GravimetricCapacity"@en ,
"SpecificChargeCapacity"@en ,
"SpecificElectricChargeCapacity"@en ;
skos:prefLabel "SpecificCapacity"@en .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "quotient of the capacity of a cell or battery [ or electrode or active material ] by its mass."@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6
:electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current that accompanies the adsorption of a species."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current that accompanies the adsorption of a species"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00159"@en ;
rdfs:comment "I_{ads}"@en ,
"The terms “adsorption current” and “limiting adsorption current” should not be applied to faradaic cur- rents that have been increased or decreased by adding a non-electroactive surfactant to a solution con- taining an electroactive substance, nor to currents resulting from the effect of adsorption or desorption on double-layer currents."@en ;
@@ -383,7 +413,7 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric current that accompanies the adsorption of a species."@en ;
+ owl:annotatedTarget "electric current that accompanies the adsorption of a species"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -397,9 +427,9 @@ and t* through mathematical models, provided that the long-time potential- deter
### http://emmo.info/electrochemistry#electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb
:electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Component of electric current due to transport of ions in the electric field between the electrodes."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of electric current due to transport of ions in the electric field between the electrodes"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/M03921"@en ;
rdfs:comment "I_{m}"@en ,
"The sign convention regarding current is such that the migration current is positive for the oxida- tion of a cation or the reduction of an anion and is negative for the reduction of a cation or for the oxidation of an anion. Hence, the migration current may either increase or decrease the total current observed. The migration current approaches zero as the transport number of the electroactive sub- stance is decreased by increasing the concentration of supporting electrolyte, and hence the conduc- tivity of the solution."@en ;
@@ -408,27 +438,60 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Component of electric current due to transport of ions in the electric field between the electrodes."@en ;
+ owl:annotatedTarget "component of electric current due to transport of ions in the electric field between the electrodes"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc
:electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_cde4368c_1d4d_4c94_8548_604749523c6d ;
+ owl:disjointWith :electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q6063658" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a measure of a substance's tendency towards ionic conduction"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Ionic_conductivity_(solid_state)"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.I03175"@en ;
skos:prefLabel "IonicConductivity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_25e20915_c35d_4bee_ad31_736235a79780
+:electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-25" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[an indicator of the] electric current at which a battery is discharged"@en ;
+ rdfs:comment "in practice, the term CRate is often used to mean DRate"@en ,
+ "the discharge rate is calculated as the rated capacity divided by the corresponding discharge time which results in an electric current"@en ,
+ "the quantity DRate is not used for energy-decoupled batteries like Redox Flox batteries"@en ;
+ rdfs:seeAlso "CRate"@en ;
+ skos:altLabel "DischargeRate"@en ;
+ skos:prefLabel "DRate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "[an indicator of the] electric current at which a battery is discharged"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_25e20915_c35d_4bee_ad31_736235a79780 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the discharge rate is calculated as the rated capacity divided by the corresponding discharge time which results in an electric current"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278
:electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom :electrochemistry_38ee287e_ff33_49b7_8841_bfac8eff5d49
+ owl:someValuesFrom emmo:EMMO_6837b106_7220_4ec6_b7c9_d549d6163672
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The rate of change of applied potential with time."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the rate of change of applied potential with time"@en ;
skos:altLabel "PotentialSweepRate"@en ,
"ScanRate"@en ,
"SweepRate"@en ;
@@ -437,15 +500,33 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The rate of change of applied potential with time."@en ;
+ owl:annotatedTarget "the rate of change of applied potential with time"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af
+:electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-12" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "sum of the absolute values of the potential differences resulting from anodic and cathodic polarizations of an electrochemical cell"@en ;
+ skos:altLabel "CellPolarizationPotential"@en ;
+ skos:prefLabel "CellPolarisationPotential"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "sum of the absolute values of the potential differences resulting from anodic and cathodic polarizations of an electrochemical cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa
:electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
+ skos:altLabel "RestingDuration"@en ,
+ "the duration during which an electrochemical device is kept at open-circuit conditions"@en ;
skos:prefLabel "RestingTime"@en .
@@ -454,34 +535,14 @@ and t* through mathematical models, provided that the long-time potential- deter
rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
:electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In electrochemical measurements, the voltage of an electrochemical cell to which a voltage signal is superimposed."@en ;
- emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "In EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage."@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "in EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage"@en ;
+ rdfs:seeAlso "ElectrochemicalImpedanceSpectroscopy" ;
skos:prefLabel "BaselineCellVoltage"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a ;
owl:annotatedProperty emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a ;
- owl:annotatedTarget "In EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage."@en ;
- dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
- ] .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_26c84165_e6e3_47f6_8433_e04e755a4751
-:electrochemistry_26c84165_e6e3_47f6_8433_e04e755a4751 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q124164" ;
- emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Alternating_current"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current having a sinusoidal wave form that changes direction during a cycle."@en ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Alternating_current"@en ;
- emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00252"@en ;
- rdfs:comment "The amplitude of an alternating current is half the peak-to-peak difference of the sinusoidal current."@en ;
- skos:altLabel "AC"@en ;
- skos:prefLabel "AlternatingCurrent"@en .
-
-[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_26c84165_e6e3_47f6_8433_e04e755a4751 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric current having a sinusoidal wave form that changes direction during a cycle."@en ;
+ owl:annotatedTarget "in EIS, an alternating voltage signal is superimposed to a baseline voltage, which can be the open circuit potential or a fixed cell voltage"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -493,14 +554,14 @@ and t* through mathematical models, provided that the long-time potential- deter
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time"@en ;
rdfs:comment "In practice, appropriate correction for the double-layer charging current is needed."@en ;
skos:prefLabel "QuarterTransitionTimePotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time."@en ;
+ owl:annotatedTarget "electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
] .
@@ -509,6 +570,7 @@ and t* through mathematical models, provided that the long-time potential- deter
:electrochemistry_27b3799c_250c_4332_8b71_7992c4a7bb05 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_d4f7d378_5e3b_468a_baa1_a7e98358cda7 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time of a measurement relative to the start of the test (t = 0)"@en ;
skos:prefLabel "TestTime"@en .
@@ -516,8 +578,9 @@ and t* through mathematical models, provided that the long-time potential- deter
:electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5434687" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Faradaic_current"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current that results from the electrooxidation or electroreduction of an electroactive substance."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current that results from the electrooxidation or electroreduction of an electroactive substance"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faradaic_current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/F02321"@en ;
rdfs:comment "Current that is produced by other processes, for example by diffusion of charged species, is termed ‘non- faradaic current’."@en ,
@@ -527,16 +590,24 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric current that results from the electrooxidation or electroreduction of an electroactive substance."@en ;
+ owl:annotatedTarget "electric current that results from the electrooxidation or electroreduction of an electroactive substance"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_2ab7af60_da58_4243_b3bc_cbb2155cac53
+:electrochemistry_2ab7af60_da58_4243_b3bc_cbb2155cac53 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_46376e5d_9627_4514_9881_9e62083625c3 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "energy delivered by a deviced under some specific charge conditions"@en ;
+ skos:prefLabel "ChargeEnergy"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d
:electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.H02722"@en ;
rdfs:comment "E1/2 is used in techniques providing a sigmoidal wave-shaped current including DC voltammetry/polarography, normal pulse voltammetry, hydrodynamic voltammetry, and tast polarography."@en ,
"For quasi-reversible and irreversible electrode reactions, the value of E1/2 is also affected by the rate constant of the charge transfer reaction, the difference being greater than that caused by different diffusion coefficients."@en ,
"The quarter-wave potential, Ep/4, the three-quarter-wave potential, Ep3/4 , etc., may be similarly defined."@en ;
@@ -545,7 +616,7 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current."@en ;
+ owl:annotatedTarget "electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -561,7 +632,7 @@ and t* through mathematical models, provided that the long-time potential- deter
:electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Component of an electric current that is associated with the presence of an analyate in square-wave voltammetry."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of an electric current that is associated with the presence of an analyate in square-wave voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/S05897"@en ;
rdfs:comment "I_{SW}"@en ,
"The component may be faradaic (if the analyte is electroactive) or non-faradaic (if the analyte is surface-active). The simultaneous occurrence of both effects is quite common."@en ;
@@ -570,18 +641,27 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Component of an electric current that is associated with the presence of an analyate in square-wave voltammetry."@en ;
+ owl:annotatedTarget "component of an electric current that is associated with the presence of an analyate in square-wave voltammetry"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_33e6986c_b35a_4cae_9a94_acb23248065c
+:electrochemistry_33e6986c_b35a_4cae_9a94_acb23248065c rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_dd4a7f3e_ef56_466c_ac1a_d2716b5f87ec ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a target quantity in a control system"@en ;
+ skos:altLabel "ControlledQuantity"@en ,
+ "SetQuantity"@en ;
+ skos:prefLabel "ControlProperty"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d
:electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_762ba55f_9b56_4c31_865f_cff2e7d0a94b ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
+ rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The magnitude of a current pulse applied to an electrochemical cell during pulsed potentiometry and related techniques."@en ;
- skos:prefLabel "PulseMagnitudeCurrent"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the magnitude of a current pulse applied to an electrochemical cell during pulsed potentiometry and related techniques"@en ;
+ skos:altLabel "PulseMagnitudeCurrent"@en ;
+ skos:prefLabel "MagnitudeOfCurrentPulse"@en .
### http://emmo.info/electrochemistry#electrochemistry_37b24a94_cae0_4d7a_9519_9f7692dec607
@@ -594,7 +674,7 @@ and t* through mathematical models, provided that the long-time potential- deter
:electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Typical examples of imposed potential programmes in dynamic voltammetric techniques resulting in peak-shaped responses are linear-scan voltammetry, cyclic voltammetry, ac voltammetry, differential pulse voltammetry, square-wave voltammetry, stripping voltammetry, and derivative techniques."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/P04457"@en ;
rdfs:comment "I_{p}"@en ,
@@ -604,27 +684,26 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "In dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve."@en ;
+ owl:annotatedTarget "in dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
-### http://emmo.info/electrochemistry#electrochemistry_38ee287e_ff33_49b7_8841_bfac8eff5d49
-:electrochemistry_38ee287e_ff33_49b7_8841_bfac8eff5d49 rdf:type owl:Class ;
- owl:equivalentClass [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_23b579e1_8088_45b5_9975_064014026c42 ;
- owl:hasValue "T-4 L+2 M+1 I-1 Θ0 N0 J0"
- ] ;
- rdfs:subClassOf emmo:EMMO_9895a1b4_f0a5_4167_ac5e_97db40b8bfcc ;
- skos:prefLabel "ElectricPotentialPerTimeDimension"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e
:electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_affe07e4_e9bc_4852_86c6_69e26182a17f ;
skos:prefLabel "AmbientThermodynamicTemperature"@en .
+### http://emmo.info/electrochemistry#electrochemistry_3b938708_e7e4_4ac0_a959_9c04306302e7
+:electrochemistry_3b938708_e7e4_4ac0_a959_9c04306302e7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_43003c86_9d15_433b_9789_ee2940920656 ;
+ owl:disjointWith :electrochemistry_f9e1c862_c510_4b11_9141_bc91045df817 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "thickness of the coating before any additional treatment is applied"@en ;
+ skos:prefLabel "CoatingThickness"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28
:electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
@@ -644,7 +723,7 @@ and t* through mathematical models, provided that the long-time potential- deter
:electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.P04947"@en ;
rdfs:comment "The pulse duration includes the sampling interval."@en ;
skos:prefLabel "PulseDuration"@en .
@@ -652,30 +731,56 @@ and t* through mathematical models, provided that the long-time potential- deter
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques."@en ;
+ owl:annotatedTarget "time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
] .
+### http://emmo.info/electrochemistry#electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c
+:electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_c1c8ac3c_8a1c_4777_8e0b_14c1f9f9b0c6 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in particle size distribution measurements, the mass-median-diameter, considered to be the average particle size by mass"@en ;
+ skos:prefLabel "ParticleSizeD50"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b
:electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- skos:prefLabel "MaxPulseDischargeCurrent"@en .
+ rdfs:subClassOf :electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d ,
+ :electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum current approved for pulse discharge of an electrochemical device"@en ;
+ skos:prefLabel "MaximumPulseDischargeCurrent"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_46376e5d_9627_4514_9881_9e62083625c3
+:electrochemistry_46376e5d_9627_4514_9881_9e62083625c3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
+ emmo:EMMO_31ec09ba_1713_42cb_83c7_b38bf6f9ced2 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-21"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "amount of energy that can be stored in a device under specific conditions"@en ;
+ skos:altLabel "BatteryEnergy"@en ;
+ skos:prefLabel "EnergyStorageCapability"@en .
### http://emmo.info/electrochemistry#electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e
:electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_d5be1faf_0c56_4f5a_9b78_581e6dee949f ;
+ rdfs:subClassOf :electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum amount concentration of a species in a phase, either imposed or naturally occurring"@en ;
skos:prefLabel "MaximumConcentration"@en .
+### http://emmo.info/electrochemistry#electrochemistry_4747c51d_86ab_4684_a4fb_b05f5c405ea3
+:electrochemistry_4747c51d_86ab_4684_a4fb_b05f5c405ea3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the minimum allowable temperature"@en ;
+ skos:prefLabel "MiniumumTemperature"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd
:electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_96f39f77_44dc_491b_8fa7_30d887fe0890 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Area of electrode - solution interface."@en ;
+ rdfs:subClassOf :electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e ,
+ :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "area of electrode - solution interface."@en ;
rdfs:comment "A"@en ,
"""The geometric area, A_{geom} , is the interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces.
@@ -685,7 +790,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Area of electrode - solution interface."@en ;
+ owl:annotatedTarget "area of electrode - solution interface."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -697,12 +802,19 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
skos:prefLabel "NumberOfCellsConnectedInParallel"@en .
+### http://emmo.info/electrochemistry#electrochemistry_4882cf2f_aab7_4a3a_a103_7f56b55fbed3
+:electrochemistry_4882cf2f_aab7_4a3a_a103_7f56b55fbed3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a cell or battery [ or electrode or active material ] obtained during a charge process by its mass."@en ;
+ skos:prefLabel "SpecificChargeCapacity"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47
:electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_900e357f_2ee3_425a_a0b6_322661117787 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-35" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ability of a cell or battery to retain capacity on open circuit under specified conditions."@en ;
- rdfs:comment "See also SelfDischarge"@en ;
+ rdfs:seeAlso "SelfDischarge"@en ;
skos:altLabel "CapacityRetention"@en ;
skos:prefLabel "ChargeRetention"@en .
@@ -721,38 +833,74 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
skos:prefLabel "ElectrochemicalTransportQuantity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b
+:electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the quotient of the energy of an energy-storage device or system and its volume"@en ;
+ skos:altLabel "EnergyDensity"@en ;
+ skos:prefLabel "EnergyDensityOfStorage"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be
:electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The time that elapses between the instants at which two successive drops of liquid metal are detached from the tip of the capillary."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the time that elapses between the instants at which two successive drops of liquid metal are detached from the tip of the capillary."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.D01862"@en ;
skos:prefLabel "DropTimeInPolarography"@en .
-### http://emmo.info/electrochemistry#electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc
-:electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
- skos:prefLabel "SetCurrent"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d
:electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
+ emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-10" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltage between the terminals of an electrochemical cell."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltage between the terminals of an electrochemical cell"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.A00424"@en ;
+ rdfs:comment "difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell"@en ;
+ skos:altLabel "AppliedPotential"@en ;
skos:prefLabel "CellVoltage"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Voltage between the terminals of an electrochemical cell."@en ;
+ owl:annotatedTarget "voltage between the terminals of an electrochemical cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a
+:electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-46" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[an indicator of the] electric current at which a battery is charged towards the end of charge"@en ;
+ rdfs:comment "the quantity CRate is not used for energy-decoupled batteries like Redox Flox batteries"@en ;
+ skos:altLabel "FinishingChargeRate"@en ;
+ skos:prefLabel "FinishingCRate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "[an indicator of the] electric current at which a battery is charged towards the end of charge"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_520995f8_ec9c_4b3c_bb64_2cd691947379
+:electrochemistry_520995f8_ec9c_4b3c_bb64_2cd691947379 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_06448f64_8db6_4304_8b2c_e785dba82044 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "density after calendering"@en ;
+ skos:prefLabel "CalenderedDensity"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2
:electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
@@ -776,58 +924,53 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_52ac73c7_763c_4fda_93cd_a2db9dfc2dab rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Time interval during which the current is measured in pulse voltammetry."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "time interval during which the current is measured in pulse voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.S05465"@en ;
skos:prefLabel "SamplingInterval"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_52ac73c7_763c_4fda_93cd_a2db9dfc2dab ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Time interval during which the current is measured in pulse voltammetry."@en ;
+ owl:annotatedTarget "time interval during which the current is measured in pulse voltammetry"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
:electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648 ;
+ rdfs:subClassOf :electrochemistry_5ebeea80_af22_456b_9087_78c2a8465c58 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-30" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Specified voltage of a battery at which the battery discharge is terminated."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "minimum voltage limit at which an applied excitation is altered or terminated"@en ;
+ rdfs:comment "specified voltage of a battery at which the battery discharge is terminated."@en ;
skos:altLabel "CutOffVoltage"@en ,
"DischargeCutoffVoltage"@en ,
"EndOfDischargeVoltage"@en ,
"EndPointVoltage"@en ,
+ "EndVoltage"@en ,
"FinalVoltage"@en ,
- "LowerVoltageLimit" ;
- skos:prefLabel "LowerCutoffVoltage"@en .
+ "LowerCutoffVoltage"@en ;
+ skos:prefLabel "LowerVoltageLimit" .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Specified voltage of a battery at which the battery discharge is terminated."@en ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "specified voltage of a battery at which the battery discharge is terminated."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_54e8cef6_b4cb_4560_947a_50811fa0f177
-:electrochemistry_54e8cef6_b4cb_4560_947a_50811fa0f177 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_f1a51559_aa3d_43a0_9327_918039f0dfed ;
- skos:prefLabel "ElectrolyteVolume"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_565c0b10_70fe_441a_b76a_b9a8e08ca7b7
:electrochemistry_565c0b10_70fe_441a_b76a_b9a8e08ca7b7 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-06" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an electrochemical oxidation reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an electrochemical oxidation reaction"@en ;
skos:altLabel "AnodicPolarization"@en ;
skos:prefLabel "AnodicOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_565c0b10_70fe_441a_b76a_b9a8e08ca7b7 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "electrode polarization associated with an electrochemical oxidation reaction."@en ;
+ owl:annotatedTarget "electrode polarization associated with an electrochemical oxidation reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -837,33 +980,47 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-07" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction."@en ;
- skos:altLabel "CoulombicEfficiency"@en ,
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction"@en ;
+ skos:altLabel "CurrentEfficiency"@en ,
"FaradayEfficiency"@en ;
- skos:prefLabel "CurrentEfficiency"@en .
+ skos:prefLabel "CoulombicEfficiency"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_5696453c_9da7_41e2_bbda_603c1b90a8fc ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction."@en ;
+ owl:annotatedTarget "fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_578dca29_729c_4131_8e37_a187472b1c37
-:electrochemistry_578dca29_729c_4131_8e37_a187472b1c37 rdf:type owl:Class ;
- owl:equivalentClass [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_23b579e1_8088_45b5_9975_064014026c42 ;
- owl:hasValue "T+2 L0 M0 I+1 Θ0 N0 J0"
- ] ;
- rdfs:subClassOf emmo:EMMO_9895a1b4_f0a5_4167_ac5e_97db40b8bfcc ;
- skos:prefLabel "ElectricChargeCapacityDimension"@en .
+### http://emmo.info/electrochemistry#electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8
+:electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_ba882f34_0d71_4e4f_9d92_0c076c633a2c ;
+ skos:altLabel "CycleIndex"@en ;
+ skos:prefLabel "CycleNumber"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113
+:electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe ,
+ emmo:EMMO_d5be1faf_0c56_4f5a_9b78_581e6dee949f ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "limit on the amount concentration of a species in a phase, either imposed or naturally occurring"@en ;
+ skos:prefLabel "ConcentrationLimit"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_5ebeea80_af22_456b_9087_78c2a8465c58
+:electrochemistry_5ebeea80_af22_456b_9087_78c2a8465c58 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe ,
+ emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "limit on the voltage of an electrical system"@en ;
+ skos:prefLabel "VoltageLimit"@en .
### http://emmo.info/electrochemistry#electrochemistry_5fb7a03f_d6dd_47ee_9317_0629681c7d00
:electrochemistry_5fb7a03f_d6dd_47ee_9317_0629681c7d00 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/L03534"@en ;
rdfs:comment "I_{d,lim}"@en ;
skos:altLabel "LimitingDiffusionCurrent"@en ;
@@ -872,16 +1029,16 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_5fb7a03f_d6dd_47ee_9317_0629681c7d00 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion."@en ;
+ owl:annotatedTarget "diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_601ff226_59b9_460b_90f5_2593450d96fa
:electrochemistry_601ff226_59b9_460b_90f5_2593450d96fa rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.M03825"@en ;
skos:altLabel "DonnanPotential"@en ,
"MembraneElectromotiveForce"@en ;
@@ -890,7 +1047,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_601ff226_59b9_460b_90f5_2593450d96fa ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane."@en ;
+ owl:annotatedTarget "electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -920,19 +1077,34 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
### http://emmo.info/electrochemistry#electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce
:electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- rdfs:comment "Electric current flowing to or from an electrochemical cell."@en ;
+ rdfs:comment "electric current flowing to or from an electrochemical cell."@en ;
skos:prefLabel "CellCurrent"@en .
+### http://emmo.info/electrochemistry#electrochemistry_639b844a_e801_436b_985d_28926129ead6
+:electrochemistry_639b844a_e801_436b_985d_28926129ead6 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-31"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "suitable approximate value of the voltage used to designate or identify a cell, a battery or an electrochemical system"@en ;
+ skos:prefLabel "NominalVoltage"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_639b844a_e801_436b_985d_28926129ead6 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "suitable approximate value of the voltage used to designate or identify a cell, a battery or an electrochemical system"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_63a8f9d2_0cf6_484d_b996_2e5c3f0a3c73
:electrochemistry_63a8f9d2_0cf6_484d_b996_2e5c3f0a3c73 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom :electrochemistry_6e7c2081_284f_48f5_88fb_7d517243d4fa
+ owl:someValuesFrom emmo:EMMO_183f6fac_8543_44e0_bd59_434aa7054f4c
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Amount of a chemical modifier at an electrode surface per unit area."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "amount of a chemical modifier at an electrode surface per unit area"@en ;
rdfs:comment "The total coverage may be distinguished from coverage that is electrochemically reactive or accessible on some given timescale."@en ;
skos:altLabel "ElectrodeCoverage"@en ;
skos:prefLabel "ElectrodeCoverageDensity"@en .
@@ -940,7 +1112,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_63a8f9d2_0cf6_484d_b996_2e5c3f0a3c73 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Amount of a chemical modifier at an electrode surface per unit area."@en ;
+ owl:annotatedTarget "amount of a chemical modifier at an electrode surface per unit area"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -949,7 +1121,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_666f0b69_9c74_49a3_80b3_96a188332462 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_852b4ab8_fc29_4749_a8c7_b92d4fca7d5a ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The higher end of the interval of frequencies tested in impedimetry and related techniques."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the higher end of the interval of frequencies tested in impedimetry and related techniques"@en ;
skos:prefLabel "UpperFrequencyLimit"@en .
@@ -957,28 +1129,27 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The magnitude of the current step in chronopotentiometry and related techniques."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the magnitude of the current step in chronopotentiometry and related techniques"@en ;
skos:prefLabel "StepSignalCurrent"@en .
+### http://emmo.info/electrochemistry#electrochemistry_6d981c04_3ace_4f1b_b0f8_770776cceb6f
+:electrochemistry_6d981c04_3ace_4f1b_b0f8_770776cceb6f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_ba882f34_0d71_4e4f_9d92_0c076c633a2c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the total number of cycles carried out on a specific device under a given set of conditions"@en ;
+ skos:prefLabel "TotalNumberOfCycles"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
:electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f ;
+ rdfs:subClassOf :electrochemistry_5ebeea80_af22_456b_9087_78c2a8465c58 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-55" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltage attained at the end of a charging step, at a specified constant current ."@en ;
- emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "Term used in the context of primary and secondary cells and batteries."@en ;
- skos:altLabel "EndOfChargeVoltage"@en ;
- skos:prefLabel "UpperCutoffVoltage"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_6e7c2081_284f_48f5_88fb_7d517243d4fa
-:electrochemistry_6e7c2081_284f_48f5_88fb_7d517243d4fa rdf:type owl:Class ;
- owl:equivalentClass [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_23b579e1_8088_45b5_9975_064014026c42 ;
- owl:hasValue "T0 L-2 M0 I0 Θ0 N+1 J0"
- ] ;
- rdfs:subClassOf emmo:EMMO_9895a1b4_f0a5_4167_ac5e_97db40b8bfcc ;
- skos:prefLabel "AmountPerAreaDimension"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "maximum voltage limit at which an applied excitation is altered or terminated"@en ;
+ emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "term used in the context of primary and secondary cells and batteries"@en ;
+ skos:altLabel "EndOfChargeVoltage"@en ,
+ "UpperCutoffVoltage"@en ;
+ skos:prefLabel "UpperVoltageLimit"@en .
### http://emmo.info/electrochemistry#electrochemistry_71f10616_15eb_4dc4_bc8d_ffaac3838af2
@@ -989,17 +1160,47 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
### http://emmo.info/electrochemistry#electrochemistry_74861991_7da2_4e0f_b6c1_b16713f538bf
:electrochemistry_74861991_7da2_4e0f_b6c1_b16713f538bf rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
+ rdfs:subClassOf :electrochemistry_c7b26177_21bf_4787_b656_8e78edf27f88 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-29"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided"@en ;
skos:altLabel "InitialClosedCircuitVoltage"@en ;
skos:prefLabel "InitialDischargeVoltage"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_74861991_7da2_4e0f_b6c1_b16713f538bf ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided."@en ;
+ owl:annotatedTarget "discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114
+:electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe ,
+ emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "limit on the electric current of an electrical system"@en ;
+ skos:prefLabel "CurrentLimit"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_75c28dc8_3d7d_4b6e_861e_6c8b1ad7d644
+:electrochemistry_75c28dc8_3d7d_4b6e_861e_6c8b1ad7d644 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-26" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "maximum current which should be delivered by a cell or battery into an external circuit with zero electric resistance, or an external circuit which depresses the cell or battery voltage to approximately zero volt"@en ;
+ rdfs:comment "zero electric resistance is a hypothetical condition and in practice the short-circuit current is the peak current flowing in a circuit of very low resistance compared to the internal resistance of the battery"@en ;
+ skos:prefLabel "ShortCircuitCurrent"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_75c28dc8_3d7d_4b6e_861e_6c8b1ad7d644 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "maximum current which should be delivered by a cell or battery into an external circuit with zero electric resistance, or an external circuit which depresses the cell or battery voltage to approximately zero volt"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_75c28dc8_3d7d_4b6e_861e_6c8b1ad7d644 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "zero electric resistance is a hypothetical condition and in practice the short-circuit current is the peak current flowing in a circuit of very low resistance compared to the internal resistance of the battery"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1008,7 +1209,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_762ba55f_9b56_4c31_865f_cff2e7d0a94b rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_dd4a7f3e_ef56_466c_ac1a_d2716b5f87ec ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=702-03-03" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A single value, for instance a mean, root mean square or peak value characterizing the aggregate instantaneous values of a unidirectional pulse with respect to the common initial and final value."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a single value, for instance a mean, root mean square or peak value characterizing the aggregate instantaneous values of a unidirectional pulse with respect to the common initial and final value"@en ;
skos:prefLabel "PulseMagnitude"@en .
@@ -1017,13 +1218,13 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_7c8007b0_58a7_4486_bf1c_4772852caca0 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-13" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte"@en ;
skos:prefLabel "CurrentDensityLimit"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_76e7e556_f47e_47e2_b2ef_67aeed09c63e ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte."@en ;
+ owl:annotatedTarget "maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1032,41 +1233,66 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_77f9d496_555e_4ae2_ae80_f297ef8335ca rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_f2ca6dd0_0e5f_4392_a92d_cafdae6cfc95 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Fundamental physical constant representing molar elementary charge."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q192819" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "fundamental physical constant representing molar elementary charge"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faraday_constant"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.F02325"@en ;
skos:prefLabel "FaradayConstant"@en .
+### http://emmo.info/electrochemistry#electrochemistry_79198264_cdf5_4fc3_8bcf_e5140a52547a
+:electrochemistry_79198264_cdf5_4fc3_8bcf_e5140a52547a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
+ emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-53" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ratio of the electric energy provided from a secondary battery [ or electrochemical device ] during discharge to the electric energy supplied to the battery during the preceding charge"@en ;
+ skos:prefLabel "EnergyEfficiency"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_79198264_cdf5_4fc3_8bcf_e5140a52547a ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "ratio of the electric energy provided from a secondary battery [ or electrochemical device ] during discharge to the electric energy supplied to the battery during the preceding charge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_791c1915_a791_4450_acd8_7f94764743b5
:electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom :electrochemistry_578dca29_729c_4131_8e37_a187472b1c37
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Amount of electric charge that can be stored."@en ;
- skos:altLabel "Capacity"@en ,
- "ChargeCapacity"@en ;
- skos:prefLabel "ElectricChargeCapacity"@en .
+ emmo:EMMO_1604f495_328a_4f28_9962_f4cc210739dd ,
+ emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-14" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric charge which a cell or battery can deliver under specified conditions"@en ;
+ rdfs:comment "the SI unit for electric charge is the coulomb (1 C = 1 A·s) but in practice, capacity is usually expressed in ampere hours (A·h)"@en ;
+ skos:altLabel "ChargeCapacity"@en ,
+ "ElectricChargeCapacity"@en ,
+ "StorageCapacity"@en ;
+ skos:prefLabel "Capacity"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "electric charge which a cell or battery can deliver under specified conditions"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the SI unit for electric charge is the coulomb (1 C = 1 A·s) but in practice, capacity is usually expressed in ampere hours (A·h)"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600
:electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current applied to a battery during its charge."@en ;
+ rdfs:subClassOf :electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce ,
+ :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
+ owl:disjointWith :electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current applied to a battery during its charge"@en ;
skos:prefLabel "ChargingCurrent"@en .
-### http://emmo.info/electrochemistry#electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648
-:electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Minimum cell voltage limit at which an applied signal is reversed or terminated."@en ;
- skos:prefLabel "LowerVoltageLimit"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_7f381c19_cf07_47a8_ab10_0b14d46901e8
:electrochemistry_7f381c19_cf07_47a8_ab10_0b14d46901e8 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
@@ -1077,14 +1303,14 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
:electrochemistry_7fa406b0_512a_4d59_9e0c_5d8aba0103ae rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-05"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Part of the electrode polarization arising from a charge-transfer step of the electrode reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from a charge-transfer step of the electrode reaction"@en ;
skos:altLabel "ActivationPolarization"@en ;
skos:prefLabel "ActivationOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_7fa406b0_512a_4d59_9e0c_5d8aba0103ae ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Part of the electrode polarization arising from a charge-transfer step of the electrode reaction."@en ;
+ owl:annotatedTarget "part of the electrode polarization arising from a charge-transfer step of the electrode reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1094,7 +1320,7 @@ The real (true) area, A_{real}, takes into account non-idealities of the interfa
rdfs:subClassOf :electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-13" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Standard_electrode_potential" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Equilibrium electrode potential of an electrode under standard conditions."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "equilibrium electrode potential of an electrode under standard conditions"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/S05912"@en ;
rdfs:comment """E° is related to the standard Gibbs Energy of the electrode reaction, Δr
G° or ΔrG , written as a reduction with respect to that of the standard hydrogen electrode (SHE) E° = −ΔrG°/zF."""@en ,
@@ -1106,7 +1332,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_7fc10197_41d9_4c1e_a107_928f03eb2d36 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Equilibrium electrode potential of an electrode under standard conditions."@en ;
+ owl:annotatedTarget "equilibrium electrode potential of an electrode under standard conditions"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1126,24 +1352,64 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_0972cb08_48bd_4524_ac03_8a2e7f30f02f
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ElectrochemicalPotential per mole."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical potential per mole."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/E01945" ;
rdfs:comment "Of a substance in a specified phase, the partial molar Gibbs energy of the substance at the specified electric potential."@en ;
skos:prefLabel "MolarElectrochemicalPotential"@en .
-### http://emmo.info/electrochemistry#electrochemistry_8427071b_3a01_44b8_9090_5ae0d98675b5
-:electrochemistry_8427071b_3a01_44b8_9090_5ae0d98675b5 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
- skos:prefLabel "SetVoltage"@en .
+### http://emmo.info/electrochemistry#electrochemistry_8177eae6_1631_430d_99f2_942669bcb784
+:electrochemistry_8177eae6_1631_430d_99f2_942669bcb784 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
+ emmo:EMMO_d5be1faf_0c56_4f5a_9b78_581e6dee949f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-16" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the amount concentration of some ionic species in a given volume of solution"@en ;
+ skos:prefLabel "IonConcentration"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae
+:electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe ,
+ emmo:EMMO_66bc9029_f473_45ff_bab9_c3509ff37a22 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "limit on the temperature of a system"@en ;
+ skos:prefLabel "TemperatureLimit"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_83928dce_9746_4452_a9f9_da4366a20ca4
+:electrochemistry_83928dce_9746_4452_a9f9_da4366a20ca4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_900e357f_2ee3_425a_a0b6_322661117787 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-31" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ability of a cell or battery to contain its electrolyte under specified mechanical and environmental conditions"@en ;
+ skos:prefLabel "ElectrolyteContainment"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_83928dce_9746_4452_a9f9_da4366a20ca4 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "ability of a cell or battery to contain its electrolyte under specified mechanical and environmental conditions"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_83fbc038_0c2e_4d04_91d7_cdf30f8a5535
+:electrochemistry_83fbc038_0c2e_4d04_91d7_cdf30f8a5535 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_900e357f_2ee3_425a_a0b6_322661117787 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-38" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[a sign that] qualifies a cell or a battery having the shape of a parallelepiped whose faces are rectangular"@en ;
+ skos:prefLabel "Prismatic"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_83fbc038_0c2e_4d04_91d7_cdf30f8a5535 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "[a sign that] qualifies a cell or a battery having the shape of a parallelepiped whose faces are rectangular"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_85e39686_9658_4c74_bb91_a935704c174a
:electrochemistry_85e39686_9658_4c74_bb91_a935704c174a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The duration between two consecutive steps in a staircase signal."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the duration between two consecutive steps in a staircase signal"@en ;
emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "Typically, the duration is defined between the onset of one step and the onset of the next step."@en ;
skos:prefLabel "StepDuration"@en .
@@ -1154,55 +1420,25 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
skos:prefLabel "MinimumStoichiometry"@en .
-### http://emmo.info/electrochemistry#electrochemistry_870c5c54_0764_454b_b43c_35cefd00d42c
-:electrochemistry_870c5c54_0764_454b_b43c_35cefd00d42c rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_d5be1faf_0c56_4f5a_9b78_581e6dee949f ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The set concentration."@en ;
- skos:prefLabel "NominalConcentration"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7
-:electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Direct_current"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ElectricCurrent that flows in a constant direction, i.e. a current with a constant sign."@en ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Direct_current"@en ;
- emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/D01767"@en ;
- rdfs:comment "I_{DC}"@en ,
- "The term ‘direct current’ should be used where there is ambiguity concerning the constancy of direction of current. See alternating current."@en ;
- skos:altLabel "DC"@en ;
- skos:prefLabel "DirectCurrent"@en .
-
-[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "ElectricCurrent that flows in a constant direction, i.e. a current with a constant sign."@en ;
- dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
- ] .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f
-:electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Maximum cell voltage limit at which an applied signal is reversed or terminated."@en ;
- skos:prefLabel "UpperVoltageLimit"@en .
+### http://emmo.info/electrochemistry#electrochemistry_884650fd_6cc6_4ec6_8264_c18fbe6b90ee
+:electrochemistry_884650fd_6cc6_4ec6_8264_c18fbe6b90ee rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a cell or battery [ or electrode or active material ] obtained during a discharge process by its mass."@en ;
+ skos:prefLabel "SpecificDischargeCapacity"@en .
### http://emmo.info/electrochemistry#electrochemistry_8de9735b_374a_4a0f_b29f_71a50794cf94
:electrochemistry_8de9735b_374a_4a0f_b29f_71a50794cf94 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-04" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from crystal nucleation and growth phenomena."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from crystal nucleation and growth phenomena"@en ;
skos:altLabel "CrystalizationPolarization"@en ;
skos:prefLabel "CrystalizationOverpotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_8de9735b_374a_4a0f_b29f_71a50794cf94 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "part of the electrode polarization arising from crystal nucleation and growth phenomena."@en ;
+ owl:annotatedTarget "part of the electrode polarization arising from crystal nucleation and growth phenomena"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1226,7 +1462,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_8f4b90ef_fea4_47c9_99f5_a9b3290a505d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential at which a material undergoes an oxidation or reduction decomposition."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential at which a material undergoes an oxidation or reduction decomposition"@en ;
skos:prefLabel "ElectrochemicalStabilityLimit"@en .
@@ -1245,7 +1481,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
### http://emmo.info/electrochemistry#electrochemistry_98b6e9d7_d5df_46a5_87dd_79642b8b2e4b
:electrochemistry_98b6e9d7_d5df_46a5_87dd_79642b8b2e4b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/K03399"@en ;
rdfs:comment "The kinetic current is partially or entirely controlled by the rate of the chemical reaction. This reaction may be heterogeneous, occurring at an electrode-solution interface (surface reaction), or it may be homo- geneous, occurring at some distance from the interface (bulk reaction)."@en ;
skos:prefLabel "KineticCurrent"@en .
@@ -1253,16 +1489,34 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_98b6e9d7_d5df_46a5_87dd_79642b8b2e4b ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed."@en ;
+ owl:annotatedTarget "faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_9b3b4668_0795_4a35_9965_2af383497a26
+:electrochemistry_9b3b4668_0795_4a35_9965_2af383497a26 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-15"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacity value of a battery [or electrochemical device] determined under specified conditions and declared by the manufacturer"@en ;
+ skos:prefLabel "RatedCapacity"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_9b3b4668_0795_4a35_9965_2af383497a26 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "capacity value of a battery [or electrochemical device] determined under specified conditions and declared by the manufacturer"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_9bf40017_3f58_4030_ada7_cb37a3dfda2d
:electrochemistry_9bf40017_3f58_4030_ada7_cb37a3dfda2d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_e88f75d6_9a17_4cfc_bdf7_43d7cea5a9a1 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Impetance associated with a power source."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q2527701" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-15-04" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "impedance of a linear circuit's Thévenin representation"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Internal_resistance"@en ;
rdfs:comment "According to to Thévenin's theorem can any linear electric curcuit be replaced with a voltage source in series with an impedance. This impedance is for historical reasons termed \"internal resistance\"."@en ,
"For batteries, it the internal resistance the resistance of the cell."@en ;
skos:prefLabel "InternalResistance"@en .
@@ -1273,8 +1527,10 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
owl:equivalentClass emmo:EMMO_5c78b424_087b_4e31_8c91_6422f1be1e86 ;
rdfs:subClassOf :electrochemistry_2d896559_eee3_447c_9759_87c854a4266a ,
:electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1812203" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-32" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Open-circuit_voltage"@en ;
rdfs:comment "In the case of a reversible electrode system, the OCP is also referred to as the equilibrium electrode potential. Otherwise, it is called the rest potential, or the corrosion potential, depending on the system being studied."@en ,
"voltage of a cell or battery when the discharge current is zero." ;
skos:altLabel "OpenCircuitPotential"@en ;
@@ -1283,7 +1539,14 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell."@en ;
+ owl:annotatedTarget "electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "In the case of a reversible electrode system, the OCP is also referred to as the equilibrium electrode potential. Otherwise, it is called the rest potential, or the corrosion potential, depending on the system being studied."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1340,7 +1603,10 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_a17ee4e0_c81a_4a64_9ecb_9c6fa022cf4d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b ,
emmo:EMMO_9e955e04_2977_457e_a91a_bc6a541c9a9e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Molar conductivity at infinite dilution"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "molar conductivity at infinite dilution"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Molar_conductivity#Variation_of_molar_conductivity_with_dilution"@en ;
+ rdfs:seeAlso "Kohlrausch's Law"@en ,
+ "Nernst-Einstein Equation"@en ;
skos:prefLabel "LimitingMolarConductivity"@en .
@@ -1348,7 +1614,8 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_a24f8581_a5a4_41a4_bb45_d0fdd5c0d810 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Value of an electric current at an instant in time, t."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q108057717" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "value of an electric current at an instant in time"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/I03062"@en ;
rdfs:comment "I_{t}"@en ,
"The instantaneous current is usually time-dependent and may have the character of an adsorption current, catalytic current, diffusion current, double-layer current, or kinetic current, and may include a migration current. A plot of the dependence of instantaneous current on time is commonly called an “I-t curve”."@en ;
@@ -1357,7 +1624,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a24f8581_a5a4_41a4_bb45_d0fdd5c0d810 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Value of an electric current at an instant in time, t."@en ;
+ owl:annotatedTarget "value of an electric current at an instant in time"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1366,7 +1633,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_a4dfa5c1_55a9_4285_b71d_90cf6613ca31 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Charge_transfer_coefficient" ;
rdfs:comment "The cathodic transfer coefficient αc is defined as –(RT/nF)(dlnkc /dE), where kc is the electroreduction rate constant, E is the applied potential, and R, T, and F have their usual significance. This definition is equivalent to the other, -(RT/nF)(dln|jc |/dE), where jc is the cathodic current density corrected for any changes in the reactant concentration at the electrode surface with respect to its bulk value."@en ;
skos:prefLabel "ChargeTransferCoefficient"@en .
@@ -1374,7 +1641,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a4dfa5c1_55a9_4285_b71d_90cf6613ca31 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate."@en ;
+ owl:annotatedTarget "the fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate"@en ;
dcterms:source "R. Guidelli et al., “Defining the transfer coefficient in electrochemistry: An assessment (IUPAC Technical Report),” Pure Appl. Chem., vol. 86, no. 2, pp. 245–258, 2014. https://doi.org/10.1515/pac-2014-5026"
] .
@@ -1386,42 +1653,83 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
] .
+### http://emmo.info/electrochemistry#electrochemistry_a5571263_f153_448f_84a3_cd18092cf8fa
+:electrochemistry_a5571263_f153_448f_84a3_cd18092cf8fa rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q766786" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ratio of the surface area of a solid object to the volume of the object"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Surface-area-to-volume_ratio"@en ;
+ skos:altLabel "SurfaceAreaToVolumeRatio"@en ;
+ skos:prefLabel "VolumetricSurfaceArea"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a56fc557_9dea_42e6_b936_e9d62dcaf84f
:electrochemistry_a56fc557_9dea_42e6_b936_e9d62dcaf84f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/D01847"@en ;
skos:prefLabel "DoubleLayerCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a56fc557_9dea_42e6_b936_e9d62dcaf84f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface."@en ;
+ owl:annotatedTarget "non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_a5962e05_466d_46a4_8951_bea59d7326e5
+:electrochemistry_a5962e05_466d_46a4_8951_bea59d7326e5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
+ emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-39"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ratio of the electric charge discharged from a secondary battery to the electric charge provided during the preceding charge"@en ;
+ skos:prefLabel "ChargeEfficiency"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a5962e05_466d_46a4_8951_bea59d7326e5 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "ratio of the electric charge discharged from a secondary battery to the electric charge provided during the preceding charge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a7eb870c_4ef7_4ccd_85e8_4b7b726d7a2a
+:electrochemistry_a7eb870c_4ef7_4ccd_85e8_4b7b726d7a2a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the quotient of the power of an energy-storage device or system and its volume"@en ;
+ skos:prefLabel "VolumetricPowerDensityofStorage"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a82e16c3_b766_482f_be94_b8e9af37f6fc
:electrochemistry_a82e16c3_b766_482f_be94_b8e9af37f6fc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods. The electroactive area is the area calculated from experiments with model electroactive species and may be different from the real surface area in cases where not all of the surface is electrochemically active or accessible."@en ;
- rdfs:comment "A_{real}" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods"@en ;
+ rdfs:comment "A_{real}" ,
+ "the electroactive area is the area calculated from experiments with model electroactive species and may be different from the real surface area in cases where not all of the surface is electrochemically active or accessible"@en ;
skos:prefLabel "ElectrodeRealSurfaceArea"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a82e16c3_b766_482f_be94_b8e9af37f6fc ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods. The electroactive area is the area calculated from experiments with model electroactive species and may be different from the real surface area in cases where not all of the surface is electrochemically active or accessible."@en ;
+ owl:annotatedTarget "surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_a9873707_8103_4bb4_9e51_83db1e89b1bd
+:electrochemistry_a9873707_8103_4bb4_9e51_83db1e89b1bd rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the minimum amount concentration of a species in a phase, either imposed or naturally occuring"@en ;
+ skos:prefLabel "MiniumumConcentration"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_abfadc99_6e43_4d37_9b04_7fc5b0f327ae
:electrochemistry_abfadc99_6e43_4d37_9b04_7fc5b0f327ae rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_ba882f34_0d71_4e4f_9d92_0c076c633a2c ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/C00995" ;
rdfs:comment "Symbol n is commonly used when there is no risk of confusion with an amount of substance."@en ,
"The apparent number of electrons transferred, z_{app} , represents the experimentally measured number of electrons transferred between an electrode and one electroactive substance species, whose identity must be specified. When the electrooxidation or electroreduction of a substance B is accompanied by chemical processes, such as the catalyzed or induced reduction of a second substance, or a side reaction that consumes B or an intermediate, the value of z_{app} will differ from that of z."@en ;
@@ -1432,7 +1740,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_abfadc99_6e43_4d37_9b04_7fc5b0f327ae ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified."@en ;
+ owl:annotatedTarget "number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1441,6 +1749,8 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_ae782b14_88ce_4cdd_9418_12aca00be937 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
emmo:EMMO_ba882f34_0d71_4e4f_9d92_0c076c633a2c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum number of cycles achieved in an electrochemical device before reaching some end-of-life criterion"@en ;
+ rdfs:comment "a typical end-of-life criterion in the battery domain is 80% of the initial capacity of the device"@en ;
skos:altLabel "ElectrochemicalCycleLife"@en ;
skos:prefLabel "CycleLife"@en .
@@ -1448,7 +1758,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
### http://emmo.info/electrochemistry#electrochemistry_ae9882de_d6a2_4525_a84f_80947c10f1cb
:electrochemistry_ae9882de_d6a2_4525_a84f_80947c10f1cb rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.T06472"@en ;
rdfs:comment "In experimental practice, the latter is often taken to be the moment when the rate of varia- tion of the potential of the indicator electrode attains a maximum value."@en ;
skos:prefLabel "TransitionTime"@en .
@@ -1456,7 +1766,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_ae9882de_d6a2_4525_a84f_80947c10f1cb ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "In chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero."@en ;
+ owl:annotatedTarget "in chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1471,7 +1781,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
### http://emmo.info/electrochemistry#electrochemistry_b21de1ef_6c15_4d63_b320_c9b96fbf186f
:electrochemistry_b21de1ef_6c15_4d63_b320_c9b96fbf186f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction"@en ;
rdfs:comment "E^{\\circ '}"@en ,
"E_{eq} = E^{\\circ '} - (R*T / (z*F)) * \\sum_i{\\nu_i * ln(c_i/c^{circ})}"@en ,
"It is E°′ which is calculated in electrochemical experiments when the concentrations of the various species are known, but their activities are not. Its value depends on the composi- tion of the electrolyte solution. The argument of ln is dimensionless, while the concentration ci is normalized through division by the standard concentration, usually c° = 1 mol dm^{−3} for soluble species."@en ;
@@ -1481,16 +1791,23 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b21de1ef_6c15_4d63_b320_c9b96fbf186f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction."@en ;
+ owl:annotatedTarget "equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe
+:electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a limit quantity in a control system"@en ;
+ skos:prefLabel "LimitQuantity"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b66d6553_6136_4754_902a_707e414210c2
:electrochemistry_b66d6553_6136_4754_902a_707e414210c2 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_852b4ab8_fc29_4749_a8c7_b92d4fca7d5a ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The lower end of the interval of frequencies tested in impedimetry and related techniques."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the lower end of the interval of frequencies tested in impedimetry and related techniques"@en ;
skos:prefLabel "LowerFrequencyLimit"@en .
@@ -1506,35 +1823,41 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_b92e382f_5109_4f60_ab5e_c89d340419a9 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_32dcd601_47c7_4028_b7fa_5e972ae57f12 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "radius of a particle"@en ;
skos:prefLabel "ParticleRadius"@en .
### http://emmo.info/electrochemistry#electrochemistry_ba7ac581_0e13_4815_b888_013c378932f5
:electrochemistry_ba7ac581_0e13_4815_b888_013c378932f5 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- skos:prefLabel "MaxContinuousDischargeCurrent"@en .
+ rdfs:subClassOf :electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum current approved for continuous discharge for a given electrochemical device"@en ;
+ skos:prefLabel "MaximumContinuousDischargeCurrent"@en .
### http://emmo.info/electrochemistry#electrochemistry_bad1b6f4_1b26_40e2_b552_6d53873e3973
:electrochemistry_bad1b6f4_1b26_40e2_b552_6d53873e3973 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The area of the electrode material that is accessible to the electrolyte that is used for charge transfer and/or storage."@en ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-09" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the area of the electrode material that is accessible to the electrolyte that is used for charge transfer and/or storage"@en ;
skos:altLabel "EASA"@en ,
- "ECSA"@en ;
+ "ECSA"@en ,
+ "ElectrochemicalActiveSurfaceArea"@en ;
skos:prefLabel "ElectrochemicallyActiveSurfaceArea"@en .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_bad1b6f4_1b26_40e2_b552_6d53873e3973 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "the area of the electrode material that is accessible to the electrolyte that is used for charge transfer and/or storage"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_bcb33f7e_5573_4bc2_b636_4ea313a9dd3a
:electrochemistry_bcb33f7e_5573_4bc2_b636_4ea313a9dd3a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
- emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom :electrochemistry_061fd188_0552_4a53_8eb3_845aacc1bb5d
- ] ;
+ emmo:EMMO_2946d40b_24a1_47fa_8176_e3f79bb45064 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-20" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Quotient of the capacity of a battery cell or battery by its plane area."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of the capacity of a battery cell or battery by its plane area."@en ;
rdfs:comment "Can also be applied to electrodes."@en ;
skos:altLabel "ArealCapacity"@en ;
skos:prefLabel "AreicCapacity"@en .
@@ -1542,15 +1865,16 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_bcb33f7e_5573_4bc2_b636_4ea313a9dd3a ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Quotient of the capacity of a battery cell or battery by its plane area."@en ;
+ owl:annotatedTarget "quotient of the capacity of a battery cell or battery by its plane area."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### http://emmo.info/electrochemistry#electrochemistry_c39b2498_783e_48e1_9814_6164bd99823c
:electrochemistry_c39b2498_783e_48e1_9814_6164bd99823c rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation."@en ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation"@en ;
rdfs:comment "Because the working potential range is a function of a specific electrode/electrolyte system, only approximate ranges can be given for generic systems."@en ,
"The working potential range is usually limited by the stability of the electrolyte, itself affected by the catalytic properties of the electrode, or by the stability of the electrode."@en ;
skos:prefLabel "WorkingPotentialRange"@en .
@@ -1558,7 +1882,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c39b2498_783e_48e1_9814_6164bd99823c ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation."@en ;
+ owl:annotatedTarget "range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1567,7 +1891,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
:electrochemistry_c4d551db_db17_4c33_92e6_aec71638afbc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "For dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "for dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.H02720"@en ;
rdfs:comment "The quarter-peak potential, Ep/4, the three-quarter-peak potential, Ep3/4, etc., may be similarly defined."@en ,
"This term is used in techniques providing peak-shaped responses (linear scan voltammetry, cyclic voltammetry, AC voltammetry, differential pulse voltammetry, square-wave voltam- metry, stripping voltammetry, and derivative techniques)."@en ;
@@ -1576,7 +1900,7 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c4d551db_db17_4c33_92e6_aec71638afbc ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "For dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current."@en ;
+ owl:annotatedTarget "for dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1584,14 +1908,15 @@ G° or ΔrG , written as a reduction with respect to that of the standard hydrog
### http://emmo.info/electrochemistry#electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5
:electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Quantities that control electroanalytical measurements."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quantities that control electroanalytical techniques"@en ;
skos:prefLabel "ElectrochemicalControlQuantity"@en .
### http://emmo.info/electrochemistry#electrochemistry_c55bcb85_b7b8_4e67_8a78_9a42fe25b6cf
:electrochemistry_c55bcb85_b7b8_4e67_8a78_9a42fe25b6cf rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.C00889"@en ;
rdfs:comment "I_{cat}"@en ,
"""In either of the two following situations, the current increase is termed a catalytic current:
@@ -1608,57 +1933,109 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c55bcb85_b7b8_4e67_8a78_9a42fe25b6cf ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions."@en ;
+ owl:annotatedTarget "faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_c762a928_5a74_46fd_9929_4ac2d7a3a8d7
+:electrochemistry_c762a928_5a74_46fd_9929_4ac2d7a3a8d7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the quotient of the power of an energy-storage device or system and its mass"@en ;
+ skos:prefLabel "SpecificPowerOfStorage"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c7b26177_21bf_4787_b656_8e78edf27f88
+:electrochemistry_c7b26177_21bf_4787_b656_8e78edf27f88 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltage between the terminals of a cell or battery when being discharged"@en ;
+ dcterms:source "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-28"@en ;
+ skos:altLabel "ClosedCircuitVoltage"@en ;
+ skos:prefLabel "DischargeVoltage"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c7b26177_21bf_4787_b656_8e78edf27f88 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "voltage between the terminals of a cell or battery when being discharged"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_c955c089_6ee1_41a2_95fc_d534c5cfd3d5
:electrochemistry_c955c089_6ee1_41a2_95fc_d534c5cfd3d5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_afea89af_ef16_4bdb_99d5_f3b2f4c85a6c ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Mass of active material in an electrode per unit electrode area."@en ;
- skos:altLabel "ActiveElectrochemicalMaterialLoading"@en ;
- skos:prefLabel "ActiveMaterialLoading"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "mass of a material per unit area"@en ;
+ skos:prefLabel "MassLoading"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ca36cbf3_1fed_4b88_9177_b4e16ad00cf7
+:electrochemistry_ca36cbf3_1fed_4b88_9177_b4e16ad00cf7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_46376e5d_9627_4514_9881_9e62083625c3 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "energy delivered by a deviced under some specific discharge conditions"@en ;
+ skos:prefLabel "DischargeEnergy"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cc519a19_b8d5_4e3f_b893_3a884888ad79
+:electrochemistry_cc519a19_b8d5_4e3f_b893_3a884888ad79 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum allowable temperature"@en ;
+ skos:prefLabel "MaximumTemperature"@en .
### http://emmo.info/electrochemistry#electrochemistry_ccde24bb_790a_40ca_a06e_cea156a61031
:electrochemistry_ccde24bb_790a_40ca_a06e_cea156a61031 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The common value (i0) of the anodic and cathodic partial currents when the reaction is at equilibrium."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the common value (i0) of the anodic and cathodic partial currents when the reaction is at equilibrium"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/E02238" ;
rdfs:comment "For an electrode at equilibrium at which only one reaction is significant i = 0. When more than one reaction is significant at a given electrode, subscripts to i0 may be used to distinguish exchange currents. i is not usually zero when only one of these reactions is at equilibrium."@en ,
"i0 = ia = - ic"@en ;
skos:prefLabel "ExchangeCurrent"@en .
-### http://emmo.info/electrochemistry#electrochemistry_ce4126c1_a7a8_41ce_aff0_5bfb91d2ecea
-:electrochemistry_ce4126c1_a7a8_41ce_aff0_5bfb91d2ecea rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_f1a51559_aa3d_43a0_9327_918039f0dfed ;
- rdfs:comment "The volume of an electrochemical device, as determined by its outer dimensions."@en ;
- skos:prefLabel "CellVolume"@en .
+### http://emmo.info/electrochemistry#electrochemistry_ccdfed06_6d24_47e4_98af_ce3ffe7bd09e
+:electrochemistry_ccdfed06_6d24_47e4_98af_ce3ffe7bd09e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
+ emmo:EMMO_e218c625_6a39_47a9_8d08_a2ef41c152a9 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the quotient of the energy of an energy-storage device or system and its mass"@en ;
+ skos:altLabel "SpecificEnergy"@en ;
+ skos:prefLabel "SpecificEnergyOfStorage"@en .
### http://emmo.info/electrochemistry#electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744
:electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_cde4368c_1d4d_4c94_8548_604749523c6d ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measure of a substance's tendency towards electronic conduction"@en ;
skos:prefLabel "ElectronicConductivity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_cf54e7c1_f359_4715_b61d_0350b890d597
+:electrochemistry_cf54e7c1_f359_4715_b61d_0350b890d597 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
+ owl:someValuesFrom emmo:EMMO_4817e479_e401_437e_a49b_54540b93d2a1
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q622205" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-10" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "total surface of a solid per mass"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Specific_surface_area"@en ;
+ skos:prefLabel "SpecificSurfaceArea"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_d47985f1_6bd7_4c4f_894f_13a6cab38bb5
:electrochemistry_d47985f1_6bd7_4c4f_894f_13a6cab38bb5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-16" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions"@en ;
skos:prefLabel "ResidualCapacity"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_d47985f1_6bd7_4c4f_894f_13a6cab38bb5 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions."@en ;
+ owl:annotatedTarget "electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1666,7 +2043,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
### http://emmo.info/electrochemistry#electrochemistry_d5ac8868_d318_4065_aa23_72140ae888ae
:electrochemistry_d5ac8868_d318_4065_aa23_72140ae888ae rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/L03532"@en ;
rdfs:comment "A limiting current is reached when the overpotential is sufficiently large that the faradaic current is deter- mined solely by the ability to supply electroactive species by mass transport. A limiting current is there- fore independent of applied potential over a corresponding finite potential range. A limiting current may have the character of an adsorption, catalytic, diffusion, or kinetic current, and may include a migration current."@en ;
skos:prefLabel "LimitingCurrent"@en .
@@ -1674,30 +2051,33 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_d5ac8868_d318_4065_aa23_72140ae888ae ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion."@en ;
+ owl:annotatedTarget "faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_d5dc0c1d_0926_4268_89f0_4519a326eabc
:electrochemistry_d5dc0c1d_0926_4268_89f0_4519a326eabc rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- skos:prefLabel "MaxPulseDischargeTime"@en .
+ rdfs:subClassOf :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 ,
+ :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the maximum duration of a pulse discharge for a given electrochemical device"@en ;
+ skos:prefLabel "MaximumPulseDischargeDuration"@en .
### http://emmo.info/electrochemistry#electrochemistry_d78b696d_9832_4352_a264_28a2ea7d82e4
:electrochemistry_d78b696d_9832_4352_a264_28a2ea7d82e4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_ba882f34_0d71_4e4f_9d92_0c076c633a2c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "number describing the step in a protocol"@en ;
skos:prefLabel "StepIndex"@en .
### http://emmo.info/electrochemistry#electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544
:electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b ;
+ rdfs:subClassOf :electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b ,
+ :electrochemistry_f509645f_eb27_470e_9112_7ab828ed40d3 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-12" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reversal_potential"@en ;
rdfs:comment "Eeq is related to the standard electrode potential by the Nernst equation."@en ,
"Temperature and activities of relevant species must be specified."@en ,
@@ -1710,7 +2090,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established."@en ;
+ owl:annotatedTarget "potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1728,18 +2108,56 @@ In either case, the magnitude of the catalytic current depends on the applied po
skos:prefLabel "ReferenceThermodynamicTemperature"@en .
+### http://emmo.info/electrochemistry#electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee
+:electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_faab3f84_e475_4a46_af9c_7d249f0b9aef ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-45" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "[an indicator of the] electric current at which a secondary cell or battery is charged"@en ;
+ rdfs:comment "in practice, the term CRate is often used to mean DRate"@en ,
+ "the charge rate is expressed as the reference current It = Cr/n where Cr is the rated capacity declared by the manufacturer and n is the time base in hours for which the rated capacity is declared"@en ,
+ "the quantity CRate is not used for energy-decoupled batteries like Redox Flox batteries"@en ;
+ rdfs:seeAlso "DRate"@en ;
+ skos:altLabel "ChargeRate"@en ;
+ skos:prefLabel "CRate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "[an indicator of the] electric current at which a secondary cell or battery is charged"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the charge rate is expressed as the reference current It = Cr/n where Cr is the rated capacity declared by the manufacturer and n is the time base in hours for which the rated capacity is declared"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_e2514bf9_d012_4990_b68b_6f37443f18f6
+:electrochemistry_e2514bf9_d012_4990_b68b_6f37443f18f6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3394849" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-02" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "rate at which a chemical reaction takes place"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reaction_rate"@en ;
+ skos:prefLabel "ReactionRate"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e38f11d0_a16f_4fe8_8ec5_3fe4493b7759
:electrochemistry_e38f11d0_a16f_4fe8_8ec5_3fe4493b7759 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-20" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential difference between the rigid layer and the diffuse layer of a double layer."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential difference between the rigid layer and the diffuse layer of a double layer"@en ;
skos:prefLabel "DiffuseLayerPotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e38f11d0_a16f_4fe8_8ec5_3fe4493b7759 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential difference between the rigid layer and the diffuse layer of a double layer."@en ;
+ owl:annotatedTarget "electric potential difference between the rigid layer and the diffuse layer of a double layer"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1751,7 +2169,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode potential of the working electrode at which the peak current is attained."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode potential of the working electrode at which the peak current is attained"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.P04464"@en ;
rdfs:comment "This term is used in dynamic voltammetric techniques providing a peak-shaped current response (linear-sweep voltammetry, triangular-wave voltammetry, cyclic voltammetry, AC voltammetry, differential pulse voltammetry, square-wave voltammetry, stripping voltamme- try and derivative techniques)."@en ;
skos:prefLabel "PeakPotential"@en .
@@ -1759,23 +2177,23 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e4a221e0_afc9_4464_91d4_e0c8ecdf79e8 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode potential of the working electrode at which the peak current is attained."@en ;
- rdfs:comment "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
+ owl:annotatedTarget "electrode potential of the working electrode at which the peak current is attained"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109."
] .
### http://emmo.info/electrochemistry#electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f
:electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
+ rdfs:subClassOf :electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce ,
+ :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-24"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric current delivered by a battery during its discharge."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current delivered by a battery during its discharge"@en ;
skos:prefLabel "DischargeCurrent"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric current delivered by a battery during its discharge."@en ;
+ owl:annotatedTarget "electric current delivered by a battery during its discharge"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1797,20 +2215,27 @@ In either case, the magnitude of the catalytic current depends on the applied po
] .
-### http://emmo.info/electrochemistry#electrochemistry_e8e41092_cc75_4952_bc54_af1a72d19fcd
-:electrochemistry_e8e41092_cc75_4952_bc54_af1a72d19fcd rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ,
- :electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electric charge capacity measured under a given set of experimental conditions."@en ;
- skos:altLabel "MeasuredElectricChargeCapacity"@en ;
- skos:prefLabel "MeasuredCapacity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_e8ec76bf_2a60_4982_8cde_02dfbd2e626f
+:electrochemistry_e8ec76bf_2a60_4982_8cde_02dfbd2e626f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-47" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "duration, under specific conditions, at the end of which a battery [ or electrochemical device ] has retained the ability to perform a specified function"@en ;
+ skos:altLabel "StorageLife"@en ;
+ skos:prefLabel "ShelfLife"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_e8ec76bf_2a60_4982_8cde_02dfbd2e626f ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "duration, under specific conditions, at the end of which a battery [ or electrochemical device ] has retained the ability to perform a specified function"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_e9fd9ef9_adfe_46cb_b2f9_4558468a25e7
:electrochemistry_e9fd9ef9_adfe_46cb_b2f9_4558468a25e7 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_21745019_2830_4395_bca7_15ddfd266673 ,
emmo:EMMO_7c8007b0_58a7_4486_bf1c_4772852caca0 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Defined by j0 = i0/A, where i0 is the exchange current of the electrode reaction and A is usually taken as the geometric area of the electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "defined by j0 = i0/A, where i0 is the exchange current of the electrode reaction and A is usually taken as the geometric area of the electrode"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Exchange_current_density" ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/M03777" ;
skos:altLabel "MeanExchangeCurrentDensity"@en ;
@@ -1821,24 +2246,24 @@ In either case, the magnitude of the catalytic current depends on the applied po
:electrochemistry_ecb6dfdf_bd3d_4339_8a1c_d32abbef30ba rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Duration of the sampling interval in pulse voltammetry."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "duration of the sampling interval in pulse voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.S05467"@en ;
skos:prefLabel "SamplingTime"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_ecb6dfdf_bd3d_4339_8a1c_d32abbef30ba ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Duration of the sampling interval in pulse voltammetry."@en ;
+ owl:annotatedTarget "duration of the sampling interval in pulse voltammetry"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_f046d602_22ea_4f9b_9101_319f510d39f0
:electrochemistry_f046d602_22ea_4f9b_9101_319f510d39f0 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
- emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "The rate of change of an applied current with time."@en ,
- "Used in linear potentiometry and related techniques, where a linearly-changing current is imposed to a cell to measure its voltage response."@en ;
+ rdfs:subClassOf :electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce ,
+ :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The rate of change of an applied current with time."@en ;
+ emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "Used in linear potentiometry and related techniques, where a linearly-changing current is imposed to a cell to measure its voltage response."@en ;
skos:prefLabel "CurrentScanRate"@en .
@@ -1852,7 +2277,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
:electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-10"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from a chemical reaction impeding the electrode reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part of the electrode polarization arising from a chemical reaction impeding the electrode reaction"@en ;
skos:altLabel "ReactionOvervoltage"@en ,
"ReactionPolarization"@en ;
skos:prefLabel "ReactionOverpotential"@en .
@@ -1860,7 +2285,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "part of the electrode polarization arising from a chemical reaction impeding the electrode reaction."@en ;
+ owl:annotatedTarget "part of the electrode polarization arising from a chemical reaction impeding the electrode reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1870,25 +2295,25 @@ In either case, the magnitude of the catalytic current depends on the applied po
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-11" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential at an electrode, reported as the difference in potential relative to a reference electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential at an electrode, reported as the difference in potential relative to a reference electrode"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrode_potential" ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/E01956" ;
- rdfs:comment "Cell source voltage when the electrodes of the electrochemical cell are a reference electrode and the electrode in question."@en ,
- "E, U"@en ,
- "The absolute value of the electrode potential cannot be measured, so E is always reported relative to the potential of a reference electrode, e.g. that of a standard hydrogen electrode (SHE)."@en ;
+ rdfs:comment "E, U"@en ,
+ "The absolute value of the electrode potential cannot be measured, so E is always reported relative to the potential of a reference electrode, e.g. that of a standard hydrogen electrode (SHE)."@en ,
+ "cell source voltage when the electrodes of the electrochemical cell are a reference electrode and the electrode in question."@en ;
skos:prefLabel "ElectrodePotential"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f509645f_eb27_470e_9112_7ab828ed40d3 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential at an electrode, reported as the difference in potential relative to a reference electrode."@en ;
+ owl:annotatedTarget "electric potential at an electrode, reported as the difference in potential relative to a reference electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f509645f_eb27_470e_9112_7ab828ed40d3 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Cell source voltage when the electrodes of the electrochemical cell are a reference electrode and the electrode in question."@en ;
+ owl:annotatedTarget "cell source voltage when the electrodes of the electrochemical cell are a reference electrode and the electrode in question."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1898,6 +2323,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
rdfs:subClassOf :electrochemistry_9bf40017_3f58_4030_ada7_cb37a3dfda2d ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-36" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quotient of change of voltage of a battery by the corresponding change in discharge current under specified conditions."@en ;
+ rdfs:comment "internal apparent resistance is expressed in ohms"@en ;
skos:prefLabel "InternalApparentResistance"@en .
[ rdf:type owl:Axiom ;
@@ -1907,36 +2333,32 @@ In either case, the magnitude of the catalytic current depends on the applied po
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-
-### http://emmo.info/electrochemistry#electrochemistry_fa01b7ce_c398_45f7_be8b_31a6f6533767
-:electrochemistry_fa01b7ce_c398_45f7_be8b_31a6f6533767 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
- :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell."@en ;
- rdfs:comment "Single electrode potentials relative to hypothetical standards, such as vacuum zero, are not experimentally accessible."@en ,
- "The applied potential is divided into a) two electrode potentials, each of which is the dif- ference of potential existing between the bulk of the solution and the interior of the con- ducting material of the electrode, b) an IR or ohmic potential drop through the solution of resistance R at electric current I, and c) another ohmic potential drop through each elec- trode and its metallic leads."@en ;
- skos:altLabel "Voltage"@en ;
- skos:prefLabel "AppliedPotential"@en .
-
[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_fa01b7ce_c398_45f7_be8b_31a6f6533767 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell."@en ;
- dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ owl:annotatedSource :electrochemistry_f94678d6_1386_48fc_8e54_024921924401 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "internal apparent resistance is expressed in ohms"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_f9e1c862_c510_4b11_9141_bc91045df817
+:electrochemistry_f9e1c862_c510_4b11_9141_bc91045df817 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "thickness of the coating after a calendering process"@en ;
+ skos:prefLabel "CalenderedCoatingThickness"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_fa7790d6_07bb_4b0f_9965_55966828f5f3
:electrochemistry_fa7790d6_07bb_4b0f_9965_55966828f5f3 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces"@en ;
rdfs:comment "A_{geom}"@en ;
skos:prefLabel "ElectrodeGeometricSurfaceArea"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fa7790d6_07bb_4b0f_9965_55966828f5f3 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces."@en ;
+ owl:annotatedTarget "the interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1945,7 +2367,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
:electrochemistry_ff7797ed_9ef7_40d0_872b_2c215cd54578 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.I03304"@en ;
rdfs:comment "The specification of the ISE and outer reference electrode must be described."@en ,
"When an isothermal cell is used with identical internal and external reference electrodes, the isopotential point is the activity of sensed ions for which zero net membrane potential difference is measured, e.g., sensed ion activity is the same in the inner and outer (test) solution. Slopes of calibration plots for different cell temperatures are different, but inter- sect at a common activity point. Cells with temperature gradients are not recommended."@en ;
@@ -1954,7 +2376,7 @@ In either case, the magnitude of the catalytic current depends on the applied po
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_ff7797ed_9ef7_40d0_872b_2c215cd54578 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature."@en ;
+ owl:annotatedTarget "electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -1963,14 +2385,11 @@ In either case, the magnitude of the catalytic current depends on the applied po
### https://emmo.info/electrochemistry#electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc
rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_762ba55f_9b56_4c31_865f_cff2e7d0a94b ,
- :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
- ] ;
+ rdfs:subClassOf :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d ,
+ :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The magnitude of a voltage pulse applied to an electrochemical cell during pulsed amperometry and related techniques."@en ;
- skos:prefLabel "PulseMagnitudePotential"@en .
+ skos:altLabel "PulseMagnitudePotential"@en ;
+ skos:prefLabel "MagnitudeOfPotentialPulse"@en .
### https://emmo.info/electrochemistry#electrochemistry_68059d94_4c21_4065_b329_07faeebc7e87
@@ -1996,11 +2415,8 @@ In either case, the magnitude of the catalytic current depends on the applied po
### https://emmo.info/electrochemistry#electrochemistry_f591a444_89d6_4093_836d_7d53895edce4
rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_bed1d005_b04e_4a90_94cf_02bc678a8569 ;
- owl:someValuesFrom emmo:EMMO_2e7e5796_4a80_4d73_bb84_f31138446c0c
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Half of the peak-to-peak amplitude of a periodic voltage perturbation within a single time period, with respect to a reference potential value."@en ;
+ emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "half of the peak-to-peak amplitude of a periodic voltage perturbation within a single time period, with respect to a reference potential value"@en ;
emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "This term should denote half of the peak-to-peak amplitude. Peak-to-peak and r.m.s. amplitudes should be so specified."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.A00311" ;
rdfs:comment "For Electrochemical Impedance Spectroscopy, the Peak Potential Amplitude is usually small, (normally 5 to 10 mV)."@en ;
diff --git a/electrochemistry.ttl b/electrochemistry.ttl
index 9711d01..fb5569a 100644
--- a/electrochemistry.ttl
+++ b/electrochemistry.ttl
@@ -11,9 +11,8 @@
@base .
rdf:type owl:Ontology ;
- owl:versionIRI ;
- owl:imports ,
- ;
+ owl:versionIRI ;
+ owl:imports ;
dcterms:abstract """Everything needed to describe fundamental concepts in electrochemistry common to all electrochemical systems.
Released under the Creative Commons license Attribution 4.0 International (CC BY 4.0)."""@en ;
@@ -30,7 +29,7 @@ email: simon.clark@sintef.no
Jesper Friis
SINTEF Industry
email: jesper.friis@sintef.no"""@en ;
- owl:versionInfo "0.5.0" .
+ owl:versionInfo "0.6.0" .
#################################################################
# Annotation properties
@@ -108,6 +107,14 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
skos:prefLabel "hasElectrolyte"@en .
+### http://emmo.info/electrochemistry#electrochemistry_3dcfe33d_6825_43c0_a798_68e871a68d39
+:electrochemistry_3dcfe33d_6825_43c0_a798_68e871a68d39 rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ rdfs:domain :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ rdfs:range :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 ;
+ skos:prefLabel "hasCase"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241
:electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241 rdf:type owl:ObjectProperty ;
rdfs:subPropertyOf emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
@@ -135,7 +142,7 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
### http://emmo.info/electrochemistry#electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee
:electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee rdf:type owl:ObjectProperty ;
rdfs:subPropertyOf emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
- rdfs:domain :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ rdfs:domain :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
rdfs:range :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261 ;
skos:prefLabel "hasActiveMaterial"@en .
@@ -148,10 +155,6 @@ skos:prefLabel rdf:type owl:AnnotationProperty .
skos:prefLabel "hasPositiveElectrode"@en .
-### http://emmo.info/emmo#EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5
-emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 rdf:type owl:ObjectProperty .
-
-
### http://emmo.info/emmo#EMMO_17e27c22_37e1_468c_9dd7_95e137f73e7f
emmo:EMMO_17e27c22_37e1_468c_9dd7_95e137f73e7f rdf:type owl:ObjectProperty .
@@ -180,6 +183,10 @@ emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 rdf:type owl:ObjectProperty .
emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec rdf:type owl:ObjectProperty .
+### http://emmo.info/emmo#EMMO_e1097637_70d2_4895_973f_2396f04fa204
+emmo:EMMO_e1097637_70d2_4895_973f_2396f04fa204 rdf:type owl:ObjectProperty .
+
+
### http://emmo.info/emmo#EMMO_e3850f08_8e79_454b_9d83_c517cab42857
emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 rdf:type owl:ObjectProperty .
@@ -192,36 +199,59 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
# Classes
#################################################################
-### http://emmo.info/electrochemistry#electrochemistry_008201ec_1e44_47a9_bc50_644ed07489ea
-:electrochemistry_008201ec_1e44_47a9_bc50_644ed07489ea rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
+### http://emmo.info/electrochemistry#electrochemistry_01260656_ac32_472e_9513_a607366538ec
+:electrochemistry_01260656_ac32_472e_9513_a607366538ec rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
] ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
- owl:someValuesFrom emmo:EMMO_ed4af7ae_63a2_497e_bb88_2309619ea405
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_d16eec87_c646_4566_bda6_7d3357cda061
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Gravimetry in which the material to be weighed is obtained by electrochemical reaction."@en ;
- emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
- rdfs:comment "The electrolysis can be performed by controlling current or electrode potential or, in the simple two-electrode arrangement, controlling the potential difference between the two electrodes."@en ,
- "When the precipitate has a known stoichiometric composition, electrogravimetry is a primary reference measurement procedure [VIM 2.8] not requiring calibration with a stand- ard for a quantity of the same kind (i.e. amount of substance)."@en ;
- skos:prefLabel "Electrogravimetry"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_01260656_ac32_472e_9513_a607366538ec
-:electrochemistry_01260656_ac32_472e_9513_a607366538ec rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q917260"@en ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-16"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Formation of compounds that reduces the conductivity at the surface of an electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "formation of compounds that reduces the conductivity at the surface of an electrode"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Passivation_(chemistry)"@en ;
+ skos:altLabel "Passivation"@en ;
skos:prefLabel "ElectrodePassivation"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_01260656_ac32_472e_9513_a607366538ec ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Formation of compounds that reduces the conductivity at the surface of an electrode."@en ;
+ owl:annotatedTarget "formation of compounds that reduces the conductivity at the surface of an electrode"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_027d437e_3bbf_4eda_940b_e509f8d2b993
+:electrochemistry_027d437e_3bbf_4eda_940b_e509f8d2b993 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 4.8 mm and a height of 1.6 mm"@en ;
+ skos:prefLabel "R416"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_028069a2_4e03_409e_8af2_4c8df32b5c5e
+:electrochemistry_028069a2_4e03_409e_8af2_4c8df32b5c5e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 5.4 mm"@en ;
+ skos:altLabel "R48" ;
+ skos:prefLabel "R754"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_02aefb7a_d6ce_4b6e_b854_f7b3d641f670
+:electrochemistry_02aefb7a_d6ce_4b6e_b854_f7b3d641f670 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-37" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "accelerated charge applied at greater than normal values of electric currents or of voltages (for a particular design) during a short time interval"@en ;
+ skos:altLabel "FastCharge"@en ;
+ skos:prefLabel "BoostCharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_02aefb7a_d6ce_4b6e_b854_f7b3d641f670 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "accelerated charge applied at greater than normal values of electric currents or of voltages (for a particular design) during a short time interval"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -245,9 +275,12 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which a square-wave potential waveform is superimposed on an underlying linearly varying potential ramp or staircase ramp. The current is sampled just before the end of the forward- going pulse and of the backward-going pulse and the difference of the two sampled currents is plotted versus the applied potential of the potential or staircase ramp. The square-wave voltammogram is peak- shaped."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q4016323" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which a square-wave potential waveform is superimposed on an underlying linearly varying potential ramp or staircase ramp"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Squarewave_voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Most instruments show plots of the current at the end of the forward-going pulse and of the backward-going pulse vs. the potential, as well as their difference. This can give valuable information on the kinetics of the electrode reaction and the electrode process."@en ,
+ "The current is sampled just before the end of the forward- going pulse and of the backward-going pulse and the difference of the two sampled currents is plotted versus the applied potential of the potential or staircase ramp. The square-wave voltammogram is peak-shaped"@en ,
"The sensitivity of SWV depends on the reversibility of the electrode reaction of the analyte."@en ;
skos:altLabel "OSWV"@en ,
"OsteryoungSquareWaveVoltammetry"@en ,
@@ -255,11 +288,50 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
skos:prefLabel "SquareWaveVoltammetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_0471ec77_91bc_4a78_be31_b6af613e5966
+:electrochemistry_0471ec77_91bc_4a78_be31_b6af613e5966 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_314d0bd5_67ed_437e_a609_36d46147cea7 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-11" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "insertion or removal of electrons into or from ions to obtain particles having zero electric charge"@en ;
+ skos:altLabel "Neutralization"@en ;
+ skos:prefLabel "Neutralisation"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_0471ec77_91bc_4a78_be31_b6af613e5966 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "insertion or removal of electrons into or from ions to obtain particles having zero electric charge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_04f28ce3_251d_429e_aa85_ab3eb45bbcd2
+:electrochemistry_04f28ce3_251d_429e_aa85_ab3eb45bbcd2 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-54" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "unstable condition arising during constant voltage charge in which the rate of heat dissipation capability, causing a continuous temperature increase with resulting further charge current increase, which can lead to the destruction of the battery"@en ;
+ rdfs:comment "in lithium batteries thermal runaway may cause melting of lithium"@en ;
+ skos:prefLabel "ThermalRunaway"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_04f28ce3_251d_429e_aa85_ab3eb45bbcd2 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "unstable condition arising during constant voltage charge in which the rate of heat dissipation capability, causing a continuous temperature increase with resulting further charge current increase, which can lead to the destruction of the battery"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_04f28ce3_251d_429e_aa85_ab3eb45bbcd2 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "in lithium batteries thermal runaway may cause melting of lithium"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_0508a114_544a_4f54_a7de_9b947fb4b618
:electrochemistry_0508a114_544a_4f54_a7de_9b947fb4b618 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
owl:disjointWith :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ;
- emmo:EMMO_70fe84ff_99b6_4206_a9fc_9a8931836d84 "A solid electrolyte is a solid material where the predominant charge carriers are ions."@en ;
+ emmo:EMMO_70fe84ff_99b6_4206_a9fc_9a8931836d84 "a solid electrolyte is a solid material where the predominant charge carriers are ions."@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "NASICON (Na Super Ionic Conductor), which has the general formula Na1+xZr2P3-xSix O12 , 0 < x < 3."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Fast_ion_conductor"@en ;
skos:altLabel "FastIonConductor"@en ,
@@ -269,25 +341,89 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_0508a114_544a_4f54_a7de_9b947fb4b618 ;
owl:annotatedProperty emmo:EMMO_70fe84ff_99b6_4206_a9fc_9a8931836d84 ;
- owl:annotatedTarget "A solid electrolyte is a solid material where the predominant charge carriers are ions."@en ;
+ owl:annotatedTarget "a solid electrolyte is a solid material where the predominant charge carriers are ions."@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63
+:electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode made of glassy carbon material with an intertwined graphitic ribbon structure, formed by pyrolysis of a resol precursor at temperatures up to 3000 °C"@en ;
+ rdfs:comment "extremely resistant to many chemicals, impermeable to gases and liquids, and has good electrical conductivity, high hardness and strength, and biocompatibility"@en ,
+ "glassy carbon combines glass-like mechanical characteristics with physical properties similar to graphite, owing to its “graphene ribbon” structure"@en ,
+ "one of the most frequently used working electrodes"@en ;
+ skos:altLabel "GCE"@en ;
+ skos:prefLabel "GlassyCarbonElectrode"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "electrode made of glassy carbon material with an intertwined graphitic ribbon structure, formed by pyrolysis of a resol precursor at temperatures up to 3000 °C"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "extremely resistant to many chemicals, impermeable to gases and liquids, and has good electrical conductivity, high hardness and strength, and biocompatibility"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "glassy carbon combines glass-like mechanical characteristics with physical properties similar to graphite, owing to its “graphene ribbon” structure"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "one of the most frequently used working electrodes"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_0689e6fc_cda7_4e04_b1eb_41459a0a4736
+:electrochemistry_0689e6fc_cda7_4e04_b1eb_41459a0a4736 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 2.5 mm"@en ;
+ skos:prefLabel "R2325"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc
:electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
- owl:someValuesFrom :electrochemistry_825a749f_dd07_46fb_947c_db286440911e
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
- owl:someValuesFrom :electrochemistry_cf596ea1_c313_4fe1_bd7f_c18afc8a24e3
+ owl:someValuesFrom :electrochemistry_825a749f_dd07_46fb_947c_db286440911e
] ;
owl:disjointWith :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-23" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "operation during which an electrochemical cell supplies electric energy as the result of chemical changes within the cell"@en ;
+ rdfs:comment "the opposite of a charging process"@en ;
skos:altLabel "ElectrochemicalDischarging"@en ;
- skos:prefLabel "DischargingProcess" .
+ skos:prefLabel "Discharge" .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "operation during which an electrochemical cell supplies electric energy as the result of chemical changes within the cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_06db7d9e_d224_4360_b926_734f0349d396
+:electrochemistry_06db7d9e_d224_4360_b926_734f0349d396 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 2.6 mm"@en ;
+ skos:altLabel "R59" ;
+ skos:prefLabel "R726"@en .
### http://emmo.info/electrochemistry#electrochemistry_07ad0aff_ab59_442d_9c0a_7f8c5cba8982
@@ -298,25 +434,53 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom emmo:EMMO_79a02de5_b884_4eab_bc18_f67997d597a2
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Measurement principle in which the complex electric impedance of a system is measured, usually as a function of a small amplitude sinusoidal electrode potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement principle in which the complex electric impedance of a system is measured, usually as a function of a small amplitude sinusoidal electrode potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
skos:prefLabel "Impedimetry"@en .
### http://emmo.info/electrochemistry#electrochemistry_0838f0b6_ca9a_4f76_9770_ca964617bf1b
:electrochemistry_0838f0b6_ca9a_4f76_9770_ca964617bf1b rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36 ,
+ rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
+ owl:someValuesFrom :electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
+ owl:someValuesFrom :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f
+ ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
owl:someValuesFrom :electrochemistry_cb3c0663_5962_4b79_8e72_1e8242af3977
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical method that measures the voltage response of an electrochemical cell under galvanostatic conditions to short interruptions in the current"@en ;
skos:altLabel "IntermittentCurrentInterruptionMethod"@en ;
skos:prefLabel "ICI"@en .
+### http://emmo.info/electrochemistry#electrochemistry_098690e3_9010_437e_8042_cee1656efa9b
+:electrochemistry_098690e3_9010_437e_8042_cee1656efa9b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_3ac62305_acd6_4312_9e31_4f824bd2530d
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_4c62d334_a124_40b3_9fd1_fe713d01a6af
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended lithium nickel manganese cobalt oxide (NMC) and lithium cobalt oxide (LCO) active materials"@en ;
+ skos:altLabel "NMCLCOElectrode"@en ;
+ skos:prefLabel "LithiumNickelManganeseCobaltOxideLithiumCobaltOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_09a7f560_9ddf_4c32_b067_b213eca5b0a1
:electrochemistry_09a7f560_9ddf_4c32_b067_b213eca5b0a1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1570182" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a covering on the surface of an object"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Coating"@en ;
skos:prefLabel "Coating"@en .
@@ -331,17 +495,49 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
skos:prefLabel "ElectrochemicalDegradationPhenomenon"@en .
+### http://emmo.info/electrochemistry#electrochemistry_0a5038d4_24af_4ea8_8d56_a156faeb98e2
+:electrochemistry_0a5038d4_24af_4ea8_8d56_a156faeb98e2 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 2.1 mm"@en ;
+ skos:altLabel "R63" ;
+ skos:prefLabel "R521"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
:electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
- owl:someValuesFrom :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77
+ owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
+ owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_3dcfe33d_6825_43c0_a798_68e871a68d39 ;
+ owl:someValuesFrom :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_5d299271_3f68_494f_ab96_3db9acdd3138 ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_8e9cf965_9f92_46e8_b678_b50410ce3616 ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A device whose primary function is facilitating the conversion between chemical and electrical energy."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a device whose primary function is facilitating the conversion between chemical and electrical energy."@en ;
+ rdfs:comment "an electrochemical device contains at least one electrochemical cell plus the apparati required to make it work as a practical device (e.g. terminals, container, etc.)"@en ;
skos:prefLabel "ElectrochemicalDevice"@en .
+### http://emmo.info/electrochemistry#electrochemistry_0afe79ed_dc0d_4b3e_88fa_ae0c7b1e88b5
+:electrochemistry_0afe79ed_dc0d_4b3e_88fa_ae0c7b1e88b5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_88b6445a_0445_483f_88f4_6b910e901c08
+ ] ;
+ rdfs:comment "metal electrode in which the active material is potassium"@en ;
+ skos:prefLabel "PotassiumMetalElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f
:electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ,
@@ -349,20 +545,28 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve"@en ;
skos:prefLabel "AbrasiveStrippingVoltammetry"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve."@en ;
+ owl:annotatedTarget "electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve"@en ;
dcterms:source "Scholz F, Nitschke L, Henrion G (1989) Naturwiss 76:71;"
] .
+### http://emmo.info/electrochemistry#electrochemistry_0c09df01_b251_4f75_b6e3_2578ba1a10c9
+:electrochemistry_0c09df01_b251_4f75_b6e3_2578ba1a10c9 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ skos:altLabel "R41" ,
+ "a coin case with a nominal diameter of 7.9 mm and a height of 3.6 mm"@en ;
+ skos:prefLabel "R736"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_0cc8f231_0ce5_467e_9c76_29b2c80349ad
:electrochemistry_0cc8f231_0ce5_467e_9c76_29b2c80349ad rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ,
+ rdfs:subClassOf :electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
owl:someValuesFrom :electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6
@@ -371,31 +575,23 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
owl:someValuesFrom :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a two-step charging process in which a constant current is applied until a set upper cutoff voltage is reached and then the cell is potentiostatically held at that voltage until the current falls below some set threshhold value"@en ;
skos:altLabel "CCCV"@en ;
- skos:prefLabel "ConstantCurrentConstantVoltageCharging"@en .
+ skos:prefLabel "ConstantCurrentConstantVoltageCharge"@en .
### http://emmo.info/electrochemistry#electrochemistry_0d9ba00d_04bc_4bdc_85af_3380694f6f68
:electrochemistry_0d9ba00d_04bc_4bdc_85af_3380694f6f68 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A practical hydrogen electrode whose potential depends on the pH of the solution"@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q900576" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a practical hydrogen electrode whose potential depends on the pH of the solution"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reversible_hydrogen_electrode"@en ;
skos:prefLabel "ReversibleHydrogenElectrode"@en .
-### http://emmo.info/electrochemistry#electrochemistry_0ec0ab2d_173d_4207_a53c_e550471af872
-:electrochemistry_0ec0ab2d_173d_4207_a53c_e550471af872 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "ChronoMethodsHighSpeed"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
:electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
- owl:someValuesFrom :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261
- ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_5ceab41b_2aea_4041_9e9c_a243f7562cee ;
owl:someValuesFrom :electrochemistry_9c73aff8_1c82_4116_a6be_78e21982b69d
@@ -403,16 +599,13 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_8785be5a_2493_4b12_8f39_31907ab11748 ;
owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty [ owl:inverseOf emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a
- ] ;
- owl:someValuesFrom :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914
] ;
owl:disjointWith :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-03"@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q176140" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-03"@en ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-21" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrode"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electronically conductive part in electric contact with a medium of lower electronic conductivity and intended to perform one or more of the functions of emitting charge carriers to or receiving charge carriers from that medium or to establish an electric field in that medium."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electronically conductive part in electric contact with a medium of lower electronic conductivity and intended to perform one or more of the functions of emitting charge carriers to or receiving charge carriers from that medium or to establish an electric field in that medium"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrode"@en ;
rdfs:comment "Alternative definition: Half-cell consisting of at least one electron conductor and at least one ionic conductor (electrolyte). - Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019)"@en ,
"Electron conductor in an electrochemical cell connected to the external circuit."@en ,
@@ -424,8 +617,8 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electronically conductive part in electric contact with a medium of lower electronic conductivity and intended to perform one or more of the functions of emitting charge carriers to or receiving charge carriers from that medium or to establish an electric field in that medium."@en ;
- dcterms:source "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-01-02"
+ owl:annotatedTarget "electronically conductive part in electric contact with a medium of lower electronic conductivity and intended to perform one or more of the functions of emitting charge carriers to or receiving charge carriers from that medium or to establish an electric field in that medium"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
@@ -436,6 +629,21 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
] .
+### http://emmo.info/electrochemistry#electrochemistry_0f827b54_370d_4c63_99a6_80f13b24e55e
+:electrochemistry_0f827b54_370d_4c63_99a6_80f13b24e55e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-51"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "evolution of gas resulting from electrolysis of the water in the electrolyte of a cell"@en ;
+ skos:prefLabel "GassingOfACell"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_0f827b54_370d_4c63_99a6_80f13b24e55e ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "evolution of gas resulting from electrolysis of the water in the electrolyte of a cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1
:electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ,
@@ -443,94 +651,100 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Analytical methods in which electrochemical processes or phenomena are the core of the measurement principle involving electrochemical cells providing qualitative and quantitative responses."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "analytical methods in which electrochemical processes or phenomena are the core of the measurement principle involving electrochemical cells providing qualitative and quantitative responses."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"^^xsd:anyURI ;
skos:prefLabel "ElectroanalyticalTechnique"@en .
+### http://emmo.info/electrochemistry#electrochemistry_103c9e6c_9c26_430a_9fb9_f4f041e970b0
+:electrochemistry_103c9e6c_9c26_430a_9fb9_f4f041e970b0 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SodiumMetatitanateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_10a91aba_da41_4309_a926_ddc0f285c2c1
+:electrochemistry_10a91aba_da41_4309_a926_ddc0f285c2c1 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:altLabel "RuO2Electrode"@en ;
+ skos:prefLabel "RutheniumOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_113e0469_8ae0_407f_892d_4b988f8d8a08
:electrochemistry_113e0469_8ae0_407f_892d_4b988f8d8a08 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
+ rdfs:subClassOf :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q25304247" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-09"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their temperatures."@en ;
- skos:altLabel "ThermogalvanicCell"@en ;
- skos:prefLabel "Thermocell"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their temperatures."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Thermogalvanic_cell"@en ;
+ skos:altLabel "Thermocell"@en ;
+ skos:prefLabel "ThermogalvanicCell"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_113e0469_8ae0_407f_892d_4b988f8d8a08 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their temperatures."@en ;
+ owl:annotatedTarget "electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their temperatures."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### http://emmo.info/electrochemistry#electrochemistry_1152ae6b_8b57_4d99_912e_40c6a29342fb
:electrochemistry_1152ae6b_8b57_4d99_912e_40c6a29342fb rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_579eed46_6918_4275_9a70_dfd0409ab418 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q."@en ;
+ rdfs:subClassOf emmo:EMMO_9c32fd69_f480_4130_83b3_fb25d9face14 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faraday%27s_laws_of_electrolysis#First_law"@en ;
+ skos:altLabel "FaradaysLaw" ,
+ "FaradaysLawOfElectrolysis" ;
skos:prefLabel "FaradaysFirstLawOfElectrolysis"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1152ae6b_8b57_4d99_912e_40c6a29342fb ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q."@en ;
+ owl:annotatedTarget "mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_11579b47_cbf8_45ac_aed3_343ea533b346
+:electrochemistry_11579b47_cbf8_45ac_aed3_343ea533b346 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 3.0 mm"@en ;
+ skos:prefLabel "R2330"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_11895d59_3f97_4bad_badf_1a90f2347c2a
:electrochemistry_11895d59_3f97_4bad_badf_1a90f2347c2a rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
- owl:someValuesFrom :electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
- owl:someValuesFrom :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f
- ] ,
+ rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
owl:someValuesFrom :electrochemistry_cb3c0663_5962_4b79_8e72_1e8242af3977
] ,
[ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom emmo:EMMO_90e59882_4592_4036_a75d_5fbefb22dc80
+ owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
+ owl:someValuesFrom
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120906986" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical method that applies current pulses to an electrochemical cell at rest and measures the voltage response"@en ;
skos:altLabel "GalvanostaticIntermittentTitrationTechnique"@en ;
skos:prefLabel "GITT"@en .
-### http://emmo.info/electrochemistry#electrochemistry_1340dd0b_98cd_4e6a_bd77_1907e0fd57b0
-:electrochemistry_1340dd0b_98cd_4e6a_bd77_1907e0fd57b0 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_21205421_5783_4d3e_81e5_10c5d894a88a ,
- [ rdf:type owl:Restriction ;
- owl:onProperty [ owl:inverseOf emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a
- ] ;
- owl:someValuesFrom :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914
- ] ;
- skos:prefLabel "ElectroactiveMolecularEntity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_11a774f3_d20a_4741_bd81_cae53230bd0c
+:electrochemistry_11a774f3_d20a_4741_bd81_cae53230bd0c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "ProtonInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_11e9f765_4fea_456b_bd8e_4624b9c752ae
+:electrochemistry_11e9f765_4fea_456b_bd8e_4624b9c752ae rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 24.5 mm and a height of 3.0 mm"@en ;
+ skos:prefLabel "R2430"@en .
### http://emmo.info/electrochemistry#electrochemistry_1355816f_a2b5_4800_8001_fc888f5d6b1b
:electrochemistry_1355816f_a2b5_4800_8001_fc888f5d6b1b rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
+ owl:disjointWith :electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=313-01-03" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "instrument intended to measure the value of a voltage."@en ;
skos:prefLabel "Voltmeter"@en .
@@ -543,11 +757,25 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
] .
+### http://emmo.info/electrochemistry#electrochemistry_14377ecb_5ead_431e_831e_159d622bd0ea
+:electrochemistry_14377ecb_5ead_431e_831e_159d622bd0ea rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ owl:disjointWith :electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614 ;
+ skos:prefLabel "RectangularElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_14d0358f_f65d_44f9_8b85_40b38f17c4ed
:electrochemistry_14d0358f_f65d_44f9_8b85_40b38f17c4ed rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ;
+ rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
+ :electrochemistry_32ab2ea8_6263_42a8_8682_2fe0343f8bea ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q902953" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-14"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "method of electroanalytical chemistry used to separate by electrolyse ions of a substance and to derive the amount of this substance from the increase in mass of an electrode."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrogravimetry"@en ;
skos:prefLabel "Electrogravimetry"@en .
[ rdf:type owl:Axiom ;
@@ -579,29 +807,26 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
### http://emmo.info/electrochemistry#electrochemistry_158ae038_c64b_4cc0_aa56_650475490705
:electrochemistry_158ae038_c64b_4cc0_aa56_650475490705 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_a8e42b90_7838_460c_8f27_7b5d4238b7a4
- ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom :electrochemistry_f693b744_930c_42ac_8e6f_627b22c6da3f
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of electric current"@en ;
skos:prefLabel "ElectricCurrentMeasurement"@en .
### http://emmo.info/electrochemistry#electrochemistry_15b852b5_19cc_49ab_849f_7df6175fb2be
:electrochemistry_15b852b5_19cc_49ab_849f_7df6175fb2be rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ;
+ rdfs:subClassOf :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-18"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrolyte on the cathode side of an electrochemical cell that is divided into compartments."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrolyte on the cathode side of an electrochemical cell that is divided into compartments."@en ;
rdfs:comment "Electrolyte solution in the cathodic compartment of an electrolysis cell or galvanic cell, i.e., in that part of the cell where the cathode is placed."@en ;
skos:prefLabel "Catholyte"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_15b852b5_19cc_49ab_849f_7df6175fb2be ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrolyte on the cathode side of an electrochemical cell that is divided into compartments."@en ;
+ owl:annotatedTarget "electrolyte on the cathode side of an electrochemical cell that is divided into compartments."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -613,6 +838,14 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
] .
+### http://emmo.info/electrochemistry#electrochemistry_15ec346a_6d3c_4161_95e1_9cf889965f85
+:electrochemistry_15ec346a_6d3c_4161_95e1_9cf889965f85 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 2.1 mm"@en ;
+ skos:altLabel "R60" ;
+ skos:prefLabel "R621"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_180878b5_8de8_4dd8_b881_1d0bebe326d4
:electrochemistry_180878b5_8de8_4dd8_b881_1d0bebe326d4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 ,
@@ -620,7 +853,7 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
owl:onProperty ;
owl:someValuesFrom :electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Coulometry at an imposed, constant current in the electrochemical cell."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "coulometry at an imposed, constant current in the electrochemical cell"@en ;
rdfs:comment "Direct coulometry at controlled current is usually carried out in convective mass transfer mode. The end-point of the electrolysis, at which the current is stopped, must be determined either from the inflection point in the E–t curve or by using visual or objective end-point indi- cation, similar to volumetric methods. The total electric charge is calculated as the product of the constant current and time of electrolysis or can be measured directly using a coulometer."@en ,
"The advantage of this method is that the electric charge consumed during the electrode reaction is directly proportional to the electrolysis time. Care must be taken to avoid the potential region where another electrode reaction may occur."@en ;
skos:prefLabel "DirectCoulometryAtControlledCurrent"@en .
@@ -628,20 +861,8 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
### http://emmo.info/electrochemistry#electrochemistry_183a2337_c35f_4b74_8d9a_08c74d89bedc
:electrochemistry_183a2337_c35f_4b74_8d9a_08c74d89bedc rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Hydrodynamic voltammetry using a a rotating disc electrode, where the limiting current is described by the Levich equation."@en ;
+ rdfs:subClassOf :electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "hydrodynamic voltammetry using a a rotating disc electrode, where the limiting current is described by the Levich equation"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
skos:prefLabel "VoltammetryAtARotatingDiskElectrode"@en .
@@ -650,13 +871,14 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
:electrochemistry_187326b9_1089_4122_8e7e_1a0bcba210a1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-18"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode polarization associated with a cathodic reaction."@en ;
- skos:prefLabel "CathodicPolarization"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with a cathodic reaction"@en ;
+ skos:altLabel "CathodicPolarization"@en ;
+ skos:prefLabel "CathodicPolarisation"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_187326b9_1089_4122_8e7e_1a0bcba210a1 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode polarization associated with a cathodic reaction."@en ;
+ owl:annotatedTarget "electrode polarization associated with a cathodic reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -668,21 +890,100 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
skos:prefLabel "ElectrochemicalPhenomenon"@en .
+### http://emmo.info/electrochemistry#electrochemistry_1a2eb6db_c927_4039_aea0_8dfab060fd27
+:electrochemistry_1a2eb6db_c927_4039_aea0_8dfab060fd27 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-18" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "ridges in the bottom of the case which support the plate pack (electrode stack) and thus create a space which allows the active material detached from the plates (electrodes) to settle without causing a short-circuit between the plates (electrodes)"@en ;
+ skos:prefLabel "Mudrib"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_1a2eb6db_c927_4039_aea0_8dfab060fd27 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "ridges in the bottom of the case which support the plate pack (electrode stack) and thus create a space which allows the active material detached from the plates (electrodes) to settle without causing a short-circuit between the plates (electrodes)"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_1a7fb32a_743f_4aa6_ac5a_ff7a2ba29dce
:electrochemistry_1a7fb32a_743f_4aa6_ac5a_ff7a2ba29dce rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_008201ec_1e44_47a9_bc50_644ed07489ea ;
+ rdfs:subClassOf :electrochemistry_14d0358f_f65d_44f9_8b85_40b38f17c4ed ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrogravimetry using an electrochemical quartz crystal microbalance."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The change of mass is, for rigid deposits, linearly proportional to the change of the reso- nance frequency of the quartz crystal, according to the Sauerbrey equation. For non- rigid deposits, corrections must be made."@en ;
skos:prefLabel "ElectrochemicalPiezoelectricMicrogravimetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8
+:electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ owl:disjointWith :electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-14" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "container for the plate pack or packs and electrolyte of a cell or cells made of a material impervious to the electrolyte"@en ;
+ skos:altLabel "Container"@en ,
+ "Housing"@en ;
+ skos:prefLabel "Case"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "container for the plate pack or packs and electrolyte of a cell or cells made of a material impervious to the electrolyte"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_1c0c8f43_7349_4646_94e3_c36727c5c2e3
+:electrochemistry_1c0c8f43_7349_4646_94e3_c36727c5c2e3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ;
+ skos:prefLabel "Seawater"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_1c6cef85_811f_45d0_a0fd_2bc2d9369ea4
+:electrochemistry_1c6cef85_811f_45d0_a0fd_2bc2d9369ea4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "AluminiumInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_1d0f15cb_d6b5_4c27_89ca_fe78adc1ce5b
+:electrochemistry_1d0f15cb_d6b5_4c27_89ca_fe78adc1ce5b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_aa8e9cc4_5f66_4307_b1c8_26fac7653a90
+ ] ;
+ skos:altLabel "LFPElectrode"@en ;
+ skos:prefLabel "LithiumIronPhosphateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_1d5377a7_9f2b_4fdf_958a_7eeadce158d6
+:electrochemistry_1d5377a7_9f2b_4fdf_958a_7eeadce158d6 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_ec7464a9_d99d_45f8_965b_4e9230ea8356 ;
+ skos:prefLabel "Foil"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf
+:electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ owl:disjointWith :electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-15"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part used to close the case normally having holes for filling, topping-up, gas escape, terminals, etc."@en ;
+ skos:prefLabel "CellLid"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "part used to close the case normally having holes for filling, topping-up, gas escape, terminals, etc."@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_1e72986e_e19f_4c24_8663_cadd4318bd72
:electrochemistry_1e72986e_e19f_4c24_8663_cadd4318bd72 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_54ee6b5e_5261_44a8_86eb_5717e7fdb9d0 ,
emmo:EMMO_bd8db028_aec2_4a44_ad93_1a9f8270f72c ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q182527" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Chemical_equation"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The symbolic representation of a chemical reaction in the form of symbols and formulae, wherein the reactant entities are given on the left-hand side and the product entities on the right-hand side."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the symbolic representation of a chemical reaction in the form of symbols and formulae, wherein the reactant entities are given on the left-hand side and the product entities on the right-hand side"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Chemical_equation"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.C01034"@en ;
skos:altLabel "ChemicalEquation"@en ,
@@ -692,7 +993,7 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1e72986e_e19f_4c24_8663_cadd4318bd72 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The symbolic representation of a chemical reaction in the form of symbols and formulae, wherein the reactant entities are given on the left-hand side and the product entities on the right-hand side."@en ;
+ owl:annotatedTarget "the symbolic representation of a chemical reaction in the form of symbols and formulae, wherein the reactant entities are given on the left-hand side and the product entities on the right-hand side"@en ;
dcterms:source "IUPAC. Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook."
] .
@@ -700,7 +1001,7 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
### http://emmo.info/electrochemistry#electrochemistry_1fc5642c_b7b2_43bf_ad20_f96001db8800
:electrochemistry_1fc5642c_b7b2_43bf_ad20_f96001db8800 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrolyte solution, the ions of which are electroinactive in the range of applied potential being studied, and whose ionic strength (and, therefore, contribution to the overall conductivity) is usually much greater than the concentration of an electroactive substance to be dissolved in it."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrolyte solution, the ions of which are electroinactive in the range of applied potential being studied, and whose ionic strength (and, therefore, contribution to the overall conductivity) is usually much greater than the concentration of an electroactive substance to be dissolved in it."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Supporting_electrolyte"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/S06149"@en ;
skos:altLabel "BaseElectrolyte" ,
@@ -711,7 +1012,7 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_1fc5642c_b7b2_43bf_ad20_f96001db8800 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrolyte solution, the ions of which are electroinactive in the range of applied potential being studied, and whose ionic strength (and, therefore, contribution to the overall conductivity) is usually much greater than the concentration of an electroactive substance to be dissolved in it."@en ;
+ owl:annotatedTarget "electrolyte solution, the ions of which are electroinactive in the range of applied potential being studied, and whose ionic strength (and, therefore, contribution to the overall conductivity) is usually much greater than the concentration of an electroactive substance to be dissolved in it."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -719,10 +1020,11 @@ emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d rdf:type owl:ObjectProperty .
### http://emmo.info/electrochemistry#electrochemistry_212af058_3bbb_419f_a9c6_90ba9ebb3706
:electrochemistry_212af058_3bbb_419f_a9c6_90ba9ebb3706 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907411" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-06-07" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A good electron conductor support designed to transfer electrons from the external circuit to the active materials of the cell."@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a """Copper foil
Aluminum foil"""@en ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Current_collector"@en ;
skos:altLabel "ElectrodeCurrentCollector"@en ;
skos:prefLabel "CurrentCollector"@en .
@@ -734,20 +1036,28 @@ Aluminum foil"""@en ;
] .
+### http://emmo.info/electrochemistry#electrochemistry_21eef598_0799_4cb1_b2d5_6e072a8579a3
+:electrochemistry_21eef598_0799_4cb1_b2d5_6e072a8579a3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 3.6 mm"@en ;
+ skos:altLabel "R42" ;
+ skos:prefLabel "R1136"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_225cb9b8_d413_451e_9e36_fb6d1344b16e
:electrochemistry_225cb9b8_d413_451e_9e36_fb6d1344b16e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8
+ owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648
+ owl:someValuesFrom :electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f
+ owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
@@ -766,8 +1076,9 @@ Aluminum foil"""@en ;
### http://emmo.info/electrochemistry#electrochemistry_22725105_c941_4b14_a4a2_fcb627958607
:electrochemistry_22725105_c941_4b14_a4a2_fcb627958607 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Instrument which controls the electric current between the working electrode and the auxiliary electrode."@en ;
+ rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5519411" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "instrument which controls the electric current between the working electrode and the auxiliary electrode"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Galvanostat"@en ;
skos:altLabel "Amperostat"@en ;
skos:prefLabel "Galvanostat"@en .
@@ -775,55 +1086,159 @@ Aluminum foil"""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_22725105_c941_4b14_a4a2_fcb627958607 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Instrument which controls the electric current between the working electrode and the auxiliary electrode."@en ;
+ owl:annotatedTarget "instrument which controls the electric current between the working electrode and the auxiliary electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_23b30468_be7b_45a9_bc11_a8219bc3ab8b
+:electrochemistry_23b30468_be7b_45a9_bc11_a8219bc3ab8b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous mixture of ammonium chloride and zinc chloride"@en ;
+ skos:prefLabel "LeclancheElectrolyte"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_245c9442_ca1d_4070_a624_182b92d30b10
+:electrochemistry_245c9442_ca1d_4070_a624_182b92d30b10 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "ZincInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_25d01d13_3ca5_4619_98c1_8ebbd01ad794
+:electrochemistry_25d01d13_3ca5_4619_98c1_8ebbd01ad794 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_22522299_4091_4d1f_82a2_3890492df6db ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-48" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "service test with an uninterrupted discharge"@en ;
+ skos:prefLabel "ContinuousServiceTest"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_25d01d13_3ca5_4619_98c1_8ebbd01ad794 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "service test with an uninterrupted discharge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_26a0dc36_8171_4a84_88dd_0f5dd7cb2d20
+:electrochemistry_26a0dc36_8171_4a84_88dd_0f5dd7cb2d20 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ;
+ skos:prefLabel "AqueousPotassiumHydroxideSolution"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_26b19a7c_59ca_4e1b_8fb9_ba061c22531e
+:electrochemistry_26b19a7c_59ca_4e1b_8fb9_ba061c22531e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_0993cbab_ff7f_4ec3_8a6c_cd67497d54d9
+ ] ;
+ skos:altLabel "metal electrode in which the active material is copper"@en ;
+ skos:prefLabel "CopperElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62
:electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
:electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1 ,
:electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_c4bace1d_4db0_4cd3_87e9_18122bae2840 ;
+ owl:someValuesFrom
+ ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q904093" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-11" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement principle in which the electrode potential of a working electrode is controlled and the electric current measured."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "techniques based on the measurement of current as a function of controlled time-dependent applied potential"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Voltammetry" ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The current vs. potential (I-E) curve is called a voltammogram."@en ;
skos:prefLabel "Voltammetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_27662d03_1bcf_4393_a239_32e31b760839
+:electrochemistry_27662d03_1bcf_4393_a239_32e31b760839 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-08" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "finished assembly of the positive and negative plate (electrode) groups with interleaved separators and terminals or intercell connectors"@en ;
+ skos:altLabel "PlatePack"@en ;
+ skos:prefLabel "ElectrodeStack"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_27662d03_1bcf_4393_a239_32e31b760839 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "finished assembly of the positive and negative plate (electrode) groups with interleaved separators and terminals or intercell connectors"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_279ecc9f_bfbc_4108_ae40_3c1c0f735e60
:electrochemistry_279ecc9f_bfbc_4108_ae40_3c1c0f735e60 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
+ rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "analyzes the output signal of a stimulated system"@en ;
+ rdfs:comment "based on the Fourier Transform analysis"@en ;
skos:altLabel "FRA"@en ,
"FrequencyResponseAnalyzer"@en ;
skos:prefLabel "FrequencyResponseAnalyser"@en .
+### http://emmo.info/electrochemistry#electrochemistry_27a81a51_e8d7_42fb_834f_0d068fa45d89
+:electrochemistry_27a81a51_e8d7_42fb_834f_0d068fa45d89 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_2031516a_2be7_48e8_9af7_7e1270e308fe ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-14" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "solution which has the same concentration of a solute as one that is in equilibrium with undissolved solute at specified values of the temperature and pressure" ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.S05471"@en ;
+ skos:prefLabel "SaturatedSolution"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_27a81a51_e8d7_42fb_834f_0d068fa45d89 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "solution which has the same concentration of a solute as one that is in equilibrium with undissolved solute at specified values of the temperature and pressure" ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_28213033_4c74_441c_81c4_a0cad05f9eb6
:electrochemistry_28213033_4c74_441c_81c4_a0cad05f9eb6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-17"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode polarization associated with an anodic reaction."@en ;
- skos:prefLabel "AnodicPolarization"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode polarization associated with an anodic reaction"@en ;
+ skos:altLabel "AnodicPolarization"@en ;
+ skos:prefLabel "AnodicPolarisation"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_28213033_4c74_441c_81c4_a0cad05f9eb6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode polarization associated with an anodic reaction."@en ;
+ owl:annotatedTarget "electrode polarization associated with an anodic reaction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_296b95b0_c4cb_45db_a8ca_f638379870c4
+:electrochemistry_296b95b0_c4cb_45db_a8ca_f638379870c4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 12.5 mm and a height of 2.0 mm"@en ;
+ skos:prefLabel "R1220"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_2a177462_ff01_4b83_ab9f_032e93c9ec69
+:electrochemistry_2a177462_ff01_4b83_ab9f_032e93c9ec69 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_59168cd9_e3af_4345_96e9_88a80afd3d16
+ ] ;
+ rdfs:comment "metal electrode in which the active material is magnesium"@en ;
+ skos:prefLabel "MagnesiumElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_2a40b878_7d09_49db_91b2_d0ee30192284
:electrochemistry_2a40b878_7d09_49db_91b2_d0ee30192284 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "For solutions in protic solvents, the universal reference electrode for which, under standard conditions, the standard electrode potential (H+ / H2) is zero at all temperatures."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q898559" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "for solutions in protic solvents, the universal reference electrode for which, under standard conditions, the standard electrode potential (H+ / H2) is zero at all temperatures"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Standard_hydrogen_electrode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/S05917"@en ;
rdfs:comment "Potential of a platinum electrode in a theoretical ideal solution (the current standard for zero potential for all temperatures)"@en ;
@@ -833,15 +1248,24 @@ Aluminum foil"""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2a40b878_7d09_49db_91b2_d0ee30192284 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "For solutions in protic solvents, the universal reference electrode for which, under standard conditions, the standard electrode potential (H+ / H2) is zero at all temperatures."@en ;
+ owl:annotatedTarget "for solutions in protic solvents, the universal reference electrode for which, under standard conditions, the standard electrode potential (H+ / H2) is zero at all temperatures"@en ;
dcterms:source "IUPAC. Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook."
] .
### http://emmo.info/electrochemistry#electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d
:electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
+ rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_24c71baf_6db6_48b9_86c8_8c70cf36db0c ;
+ owl:someValuesFrom :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q904857" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a double layer of charges exists at the interface between two conducting media: One side carries a positive excess charge, which is balanced by a negative excess of equal magnitude on the other side."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Double_layer_(surface_science)"@en ;
+ skos:altLabel "DL"@en ,
+ "EDL"@en ,
+ "ElectricalDoubleLayer"@en ;
skos:prefLabel "DoubleLayer"@en .
[ rdf:type owl:Axiom ;
@@ -854,8 +1278,13 @@ Aluminum foil"""@en ;
### http://emmo.info/electrochemistry#electrochemistry_2d32a81a_2148_41bd_84fb_467aa8de4a8f
:electrochemistry_2d32a81a_2148_41bd_84fb_467aa8de4a8f rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Foil, wire, disc, or mesh electrode made of platinum, which is the most commonly used metallic working electrode in electrochemistry."@en ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_25f6ff4c_53ad_4837_97c4_aa6f06099bb5
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q20851363" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "foil, wire, disc, or mesh electrode made of platinum, which is the most commonly used metallic working electrode in electrochemistry"@en ;
rdfs:comment "Pt has a very small overpotential for hydrogen evolution, which determines the negative potential limit in protic solvents. Pt adsorbs hydrogen, resulting in hydrogen adsorption/desorption waves. However, the positive potential limit in polar aprotic solvents free of oxygen and water is higher than that for any other commonly used electrode materials. In the presence of water and/or oxygen, Pt forms a film of oxide (and/or chemisorbed oxygen), resulting in potentially interfering waves or peaks."@en ;
skos:altLabel "PtElectrode"@en ;
skos:prefLabel "PlatinumElectrode"@en .
@@ -863,47 +1292,66 @@ Aluminum foil"""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2d32a81a_2148_41bd_84fb_467aa8de4a8f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Foil, wire, disc, or mesh electrode made of platinum, which is the most commonly used metallic working electrode in electrochemistry."@en ;
+ owl:annotatedTarget "foil, wire, disc, or mesh electrode made of platinum, which is the most commonly used metallic working electrode in electrochemistry"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_2dea31c2_5061_4464_ab76_5336bef23629
+:electrochemistry_2dea31c2_5061_4464_ab76_5336bef23629 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_5d73661e_e710_4844_ab9b_a85b7e68576a ;
+ owl:someValuesFrom emmo:EMMO_66bc9029_f473_45ff_bab9_c3509ff37a22
+ ] ;
+ skos:prefLabel "CelsiusTemperatureMeasurementResult"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8
:electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-04"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An interfacial reaction that necessarily involves a charge-transfer step."@en ,
- "Electrochemical reaction involving the transfer of electrons between electrolyte and electrode."@en ;
- rdfs:comment "The electrode (or interfacial) reaction involves all the processes (chemical reaction, structural reorganization, adsorption) accompanying the charge transfer step."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical reaction involving the transfer of electrons between electrolyte and electrode"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.E01960"@en ;
+ rdfs:comment "An interfacial reaction that necessarily involves a charge-transfer step."@en ,
+ "The electrode (or interfacial) reaction involves all the processes (chemical reaction, structural reorganization, adsorption) accompanying the charge transfer step."@en ;
skos:prefLabel "ElectrodeReaction"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "An interfacial reaction that necessarily involves a charge-transfer step."@en ;
- dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
+ owl:annotatedTarget "electrochemical reaction involving the transfer of electrons between electrolyte and electrode"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ;
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- owl:annotatedTarget "Electrochemical reaction involving the transfer of electrons between electrolyte and electrode."@en ;
- dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "An interfacial reaction that necessarily involves a charge-transfer step."@en ;
+ dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
### http://emmo.info/electrochemistry#electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d
:electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q2698605" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-15"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Accumulation or depletion of electric charges at an electrode, resulting in a difference between the electrode potential with current flow, and the potential without current flow or equilibrium electrode potential."@en ;
- skos:altLabel "ElectrodePolarizationProcess"@en ;
- skos:prefLabel "ElectrodePolarization"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "accumulation or depletion of electric charges at an electrode, resulting in a difference between the electrode potential with current flow, and the potential without current flow or equilibrium electrode potential"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Polarization_(electrochemistry)"@en ;
+ skos:altLabel "ElectrodePolarization"@en ,
+ "Polarisation"@en ,
+ "Polarization"@en ;
+ skos:prefLabel "ElectrodePolarisation"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Accumulation or depletion of electric charges at an electrode, resulting in a difference between the electrode potential with current flow, and the potential without current flow or equilibrium electrode potential."@en ;
+ owl:annotatedTarget "accumulation or depletion of electric charges at an electrode, resulting in a difference between the electrode potential with current flow, and the potential without current flow or equilibrium electrode potential"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -921,14 +1369,15 @@ Aluminum foil"""@en ;
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648
+ owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f
+ owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1147647" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Cyclic_voltammetry"^^xsd:anyURI ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which the electric current is recorded as the electrode potential is varied with time cycli- cally between two potential limits, normally at a constant scan rate."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which the electric current is recorded as the electrode potential is varied with time cycli- cally between two potential limits, normally at a constant scan rate"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Cyclic_voltammetry"^^xsd:anyURI ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Cyclic voltammetry is frequently used for the investigation of mechanisms of electrochemi- cal/electrode reactions. The current-potential curve may be modelled to obtain reaction mechanisms and electrochemical parameters."@en ,
@@ -939,11 +1388,110 @@ Aluminum foil"""@en ;
skos:prefLabel "CyclicVoltammetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_2fd5964b_0c65_4413_8b8c_849639e6d1e7
+:electrochemistry_2fd5964b_0c65_4413_8b8c_849639e6d1e7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d53259a7_0d9c_48b9_a6c1_4418169df303
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended silicon oxide and graphite active materials"@en ;
+ skos:prefLabel "SiliconOxideGraphiteElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_30c8fb1b_3c75_49f5_9395_c15dfaf71b12
+:electrochemistry_30c8fb1b_3c75_49f5_9395_c15dfaf71b12 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 1.6 mm"@en ;
+ rdfs:comment "often used in wrist watches"@en ;
+ skos:prefLabel "R2016"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_31b7ac6a_b1eb_45e7_a075_b6063080c949
+:electrochemistry_31b7ac6a_b1eb_45e7_a075_b6063080c949 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 2.1 mm"@en ;
+ skos:altLabel "R55" ;
+ skos:prefLabel "R1121"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_31e8052d_bede_43c6_8b41_d51bb24c9489
+:electrochemistry_31e8052d_bede_43c6_8b41_d51bb24c9489 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_4920de95_3a48_4669_b762_5a0b5232b52f
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_4d09ddc4_7e71_4712_afab_b33d8df38983
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_efaca8db_a3e0_4188_9c9b_ed0037966725
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a time series of electrical quantities"@en ;
+ skos:prefLabel "TimeseriesElectricalDataset"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_3279f575_1c62_4bf2_a6e8_de4c7ff36f8e
+:electrochemistry_3279f575_1c62_4bf2_a6e8_de4c7ff36f8e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 2.1 mm"@en ;
+ skos:altLabel "R58" ;
+ skos:prefLabel "R721"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_328c6e36_3706_4d92_abae_432fa3adb2a0
+:electrochemistry_328c6e36_3706_4d92_abae_432fa3adb2a0 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-13" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "internal component used to reduce the amount of electrolyte loss due to electrolyte spray being carried in the gas and/or by electrolyte movement"@en ;
+ rdfs:comment "a cell baffle has a second function in protecting the plate pack from damage by objects inserted through the filling hole"@en ;
+ skos:prefLabel "CellBaffle"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_328c6e36_3706_4d92_abae_432fa3adb2a0 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "internal component used to reduce the amount of electrolyte loss due to electrolyte spray being carried in the gas and/or by electrolyte movement"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_328c6e36_3706_4d92_abae_432fa3adb2a0 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "a cell baffle has a second function in protecting the plate pack from damage by objects inserted through the filling hole"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_32ab2ea8_6263_42a8_8682_2fe0343f8bea
+:electrochemistry_32ab2ea8_6263_42a8_8682_2fe0343f8bea rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
+ owl:someValuesFrom emmo:EMMO_ed4af7ae_63a2_497e_bb88_2309619ea405
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q192414" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "quantitative determination of a chemical species based on its mass"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Gravimetric_analysis" ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/G02694"@en ;
+ skos:altLabel "GravimetricMethod"@en ;
+ skos:prefLabel "GravimetricAnalysis"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0
:electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-17"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "In an electrochemical cell, device made of insulating material permeable to the ions of the electrolyte and prohibiting totally or partially the mixing of the substances on both sides."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1718181" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-17"@en ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-11" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "in an electrochemical cell, device made of insulating material permeable to the ions of the electrolyte and prohibiting totally or partially the mixing of the substances on both sides."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Separator_(electricity)"@en ;
rdfs:comment "Membranes and diaphragms are special forms of electrochemical separators."@en ;
skos:altLabel "ElectrochemicalSeparator"@en ;
skos:prefLabel "Separator"@en .
@@ -951,26 +1499,105 @@ Aluminum foil"""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "In an electrochemical cell, device made of insulating material permeable to the ions of the electrolyte and prohibiting totally or partially the mixing of the substances on both sides."@en ;
+ owl:annotatedTarget "in an electrochemical cell, device made of insulating material permeable to the ions of the electrolyte and prohibiting totally or partially the mixing of the substances on both sides."@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_334b3acd_e35d_4d5a_b8b5_6d13cbebbc57
+:electrochemistry_334b3acd_e35d_4d5a_b8b5_6d13cbebbc57 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 ;
+ skos:prefLabel "SulfuricAcidSolution"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_339e1ba1_2006_4f22_aac4_3ce75edf1088
+:electrochemistry_339e1ba1_2006_4f22_aac4_3ce75edf1088 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_db74b6b7_09fc_40db_a7d5_6eb86b69192a
+ ] ;
+ skos:altLabel "FTOElectrode"@en ;
+ skos:prefLabel "FluorineDopedTinOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_344ed3a6_481a_499f_afef_631f1cece9ef
+:electrochemistry_344ed3a6_481a_499f_afef_631f1cece9ef rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_7dc738d6_74f2_489e_ae84_a6dbdf627f2e
+ ] ;
+ skos:altLabel "NiOOHElectrode"@en ,
+ "NickelOxyhydroxideElectrode"@en ;
+ skos:prefLabel "NickelOxideHydroxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_34bc54e3_de4c_41f8_8d3a_d77c951ee23a
+:electrochemistry_34bc54e3_de4c_41f8_8d3a_d77c951ee23a rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_4f226cf3_6d02_4d35_8566_a9e641bc6ff3 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q190136" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-07" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "needle-like or tree-like formation of crystalline growth formed during deposition of a material"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Dendrite_(crystal)"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.D01588"@en ;
+ skos:prefLabel "Dendrite"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_34bc54e3_de4c_41f8_8d3a_d77c951ee23a ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "needle-like or tree-like formation of crystalline growth formed during deposition of a material"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_34cb7ea7_2436_46e0_806e_a3c7835ae228
+:electrochemistry_34cb7ea7_2436_46e0_806e_a3c7835ae228 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 1.65 mm"@en ;
+ skos:altLabel "R67" ;
+ skos:prefLabel "R716"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5
:electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
owl:disjointWith :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q175233" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Cathode"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "by convention, cell electrode at which, a reduction reaction occurs"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Cathode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/C00905"@en ;
- rdfs:comment "The concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes."@en ;
+ rdfs:comment "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction"@en ,
+ "the cathode is the positive electrode during discharge and the negative electrode during charge"@en ,
+ "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ;
skos:prefLabel "Cathode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction."@en ;
+ owl:annotatedTarget "by convention, cell electrode at which, a reduction reaction occurs"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the cathode is the positive electrode during discharge and the negative electrode during charge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -978,24 +1605,40 @@ Aluminum foil"""@en ;
### http://emmo.info/electrochemistry#electrochemistry_3663991d-9319-4f7a-922b-f0e428b58801
:electrochemistry_3663991d-9319-4f7a-922b-f0e428b58801 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix. At a given time, there may be a large range of reaction rates within the pores. The distribution of these rates will depend on physical structure, conductivity of the matrix and of the electrolyte, and on parameters characterizing the electrode processes themselves."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix."@en ;
skos:prefLabel "PorousElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_3663991d-9319-4f7a-922b-f0e428b58801 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix. At a given time, there may be a large range of reaction rates within the pores. The distribution of these rates will depend on physical structure, conductivity of the matrix and of the electrolyte, and on parameters characterizing the electrode processes themselves."@en ;
+ owl:annotatedTarget "porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix."@en ;
dcterms:references "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004."
] .
+### http://emmo.info/electrochemistry#electrochemistry_36e05f2f_d279_4816_b5ae_6bb4cef02736
+:electrochemistry_36e05f2f_d279_4816_b5ae_6bb4cef02736 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 12.5 mm and a height of 1.6 mm"@en ;
+ skos:prefLabel "R1216"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_38755e67_9d3b_4a82_bd8d_ef40a70379c1
:electrochemistry_38755e67_9d3b_4a82_bd8d_ef40a70379c1 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
owl:disjointWith :electrochemistry_9b6853e7_3412_463d_b5a9_82c14acebf7d ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a tank for holding anolyte"@en ;
+ rdfs:comment "usually used in a flow cell system"@en ;
skos:prefLabel "AnolyteTank"@en .
+### http://emmo.info/electrochemistry#electrochemistry_387e1e59_e511_4acb_b5ec_fa7360ec7557
+:electrochemistry_387e1e59_e511_4acb_b5ec_fa7360ec7557 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ skos:altLabel "a coin case with a nominal diameter of 9.5 mm and a height of 2.7 mm"@en ;
+ skos:prefLabel "R927"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_39536efc_22a6_4f39_b0c2_e8b845a36278
:electrochemistry_39536efc_22a6_4f39_b0c2_e8b845a36278 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 ,
@@ -1007,7 +1650,7 @@ Aluminum foil"""@en ;
owl:onProperty ;
owl:someValuesFrom :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Coulometry at a preselected constant potential of the working electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "coulometry at a preselected constant potential of the working electrode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Direct coulometry at controlled potential is usually carried out in convective mass trans- fer mode using a large surface working electrode. Reference and auxiliary electrodes are placed in separate compartments. The total electric charge is obtained by integration of the I–t curve or can be measured directly using a coulometer."@en ,
"""In principle, the end point at which I = 0, i.e. when the concentration of species under study becomes zero, can be reached only at infinite time. However, in practice, the electrolysis is stopped when the current has decayed to a few percent of the initial value and the charge passed at infinite time is calculated from a plot of charge Q(t) against time t. For a simple system under diffusion control Qt= Q∞[1 − exp(−DAt/Vδ)], where Q∞ = limt→∞Q(t) is the total
@@ -1015,10 +1658,35 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "DirectCoulometryAtControlledPotential"@en .
+### http://emmo.info/electrochemistry#electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37
+:electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "a round-type case with a height that is less than the diameter"@en ;
+ skos:altLabel "ButtonCase"@en ;
+ skos:prefLabel "CoinCase"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_399b10cd_8a2e_47be_96b8_295890bd2460
+:electrochemistry_399b10cd_8a2e_47be_96b8_295890bd2460 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d071c9d0_1358_4d9f_9690_53b7d69e025c
+ ] ;
+ skos:prefLabel "RhodiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_39c6f5a0_5dc8_4112_b432_b9fece568ca2
+:electrochemistry_39c6f5a0_5dc8_4112_b432_b9fece568ca2 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.5 mm and a height of 3.0 mm"@en ;
+ skos:prefLabel "R1130"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_3a77b5e7_9646_4154_bf8f_5f798989e5f3
:electrochemistry_3a77b5e7_9646_4154_bf8f_5f798989e5f3 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A working electrode in the shape of a ring used in a rotating ring disk electrode (RRDE)."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a working electrode in the shape of a ring used in a rotating ring disk electrode (RRDE)."@en ;
skos:altLabel "RingElectrode"@en ;
skos:prefLabel "AnnularWorkingElectrode"@en .
@@ -1030,7 +1698,8 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the amount of an accumulated species is measured by voltammetry. The measured electric current in step 2 is related to the concentration of analyte in the solution by calibration."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the amount of an accumulated species is measured by voltammetry. The measured electric current in step 2 is related to the concentration of analyte in the solution by calibration."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_stripping_analysis"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Anodic stripping voltammetry (ASV) was historically used to measure concentrations of metal ions in solution using cathodic accumulation with mercury to form an amalgam. Due to the toxicity of mercury and its compounds, inductively coupled plasma optical emission spectrometry and inductively coupled plasma mass spectrometry have frequently replaced ASV at mercury electrodes in the laboratory, often sacrificing the probing of speciation and lability in complex matrices. Mercury has now been replaced by non-toxic bismuth or anti- mony as films on a solid electrode support (such as glassy carbon) with equally good sensi- tivity and detection limits."@en ,
"Because the accumulation (pre-concentration) step can be prolonged, increasing the amount of material at the electrode, stripping voltammetry is able to measure very small concentrations of analyte."@en ,
@@ -1059,7 +1728,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which potential pulses of amplitude increasing by a constant increment and with a pulse width of 2 to 200 ms are superimposed on a constant initial potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which potential pulses of amplitude increasing by a constant increment and with a pulse width of 2 to 200 ms are superimposed on a constant initial potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Normal pulse polarography is NPV in which a dropping mercury electrode is used as the working electrode. A pulse is applied just before the mechanically enforced end of the drop. The pulse width is usually 10 to 20 % of the drop time. The drop dislodgment is synchro- nized with current sampling, which is carried out just before the end of the pulse, as in NPV."@en ,
"Sigmoidal wave-shaped voltammograms are obtained."@en ,
@@ -1077,14 +1746,77 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "ElectrochemicalRelation"@en .
+### http://emmo.info/electrochemistry#electrochemistry_3e6a7d5f_3700_46b3_b1b8_f34e37e6f931
+:electrochemistry_3e6a7d5f_3700_46b3_b1b8_f34e37e6f931 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_bbfa82dc_68a0_4d0b_a3f0_735cbbc19cf2
+ ] ;
+ skos:prefLabel "IridiumElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6
:electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ,
:electrochemistry_f07be701_9d6a_415b_ac6d_63202297a7a1 ;
owl:disjointWith :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-49" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "charge during which the voltage is maintained at a constant value regardless of charge current or temperature"@en ;
skos:altLabel "FloatCharging"@en ,
"PotentiostaticCharging"@en ;
- skos:prefLabel "ConstantVoltageCharging"@en .
+ skos:prefLabel "ConstantVoltageCharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "charge during which the voltage is maintained at a constant value regardless of charge current or temperature"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_3f67016b_32b9_4419_a3f8_a5ffb5e92538
+:electrochemistry_3f67016b_32b9_4419_a3f8_a5ffb5e92538 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ;
+ skos:prefLabel "AqueousAmmoniumChlorideSolution"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089
+:electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-30" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "gradual and slow spreading of an electrolyte film on the external surface of a cell or battery"@en ;
+ rdfs:comment "electrolyte creep is sometimes indicated by the presence of a visible solid deposit or wet spots"@en ;
+ skos:prefLabel "ElectrolyteCreep"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "gradual and slow spreading of an electrolyte film on the external surface of a cell or battery"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "electrolyte creep is sometimes indicated by the presence of a visible solid deposit or wet spots"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc
+:electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-22" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "conductive part of a device, electric circuit or electric network, provided for connecting that device, electric circuit or electric network to one or more external conductors"@en ;
+ skos:prefLabel "Terminal"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "conductive part of a device, electric circuit or electric network, provided for connecting that device, electric circuit or electric network to one or more external conductors"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_3f9b2956_1465_4fe0_b0df_5e4784dac3b6
@@ -1094,9 +1826,18 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_17e27c22_37e1_468c_9dd7_95e137f73e7f ;
owl:someValuesFrom :electrochemistry_1355816f_a2b5_4800_8001_fc888f5d6b1b
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system for measuring electric potential"@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "a digital voltmeter connected to a computer"@en ;
skos:prefLabel "ElectricPotentialMeasuringSystem"@en .
+### http://emmo.info/electrochemistry#electrochemistry_3fdc81d5_eef3_4408_a6e4_3c51c5b1c8dc
+:electrochemistry_3fdc81d5_eef3_4408_a6e4_3c51c5b1c8dc rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:altLabel "WO3Electrode"@en ;
+ skos:prefLabel "TungstenOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_3fe63496_6d87_427a_b2aa_4555bc31ee1a
:electrochemistry_3fe63496_6d87_427a_b2aa_4555bc31ee1a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
@@ -1104,7 +1845,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement principle based on measurement of current at a controlled applied potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "techniques based on measurement of current at a constant controlled potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Amperometry can be distinguished from voltammetry by the parameter being controlled (electrode potential E) and the parameter being measured (electrode current I which is usually a function of time – see chronoamperometry)."@en ,
"In a non-stirred solution, a diffusion-limited current is usually measured, which is propor-tional to the concentration of an electroactive analyte."@en ,
@@ -1113,38 +1854,68 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "Amperometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_400cb3e0_27b5_4d9a_be80_f86ad2757763
+:electrochemistry_400cb3e0_27b5_4d9a_be80_f86ad2757763 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 5.0 mm"@en ;
+ skos:prefLabel "R2050"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_402598d9_0eea_405d_b0d0_3b8b79deba6f
:electrochemistry_402598d9_0eea_405d_b0d0_3b8b79deba6f rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0a0de817_addc_46a5_8ba2_255d48cdf366 ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ] ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "solid electrolyte interphase (SEI) growth"@en ;
skos:prefLabel "InterphaseGrowth"@en .
### http://emmo.info/electrochemistry#electrochemistry_403c300e_09b9_400b_943b_04e82a3cfb56
:electrochemistry_403c300e_09b9_400b_943b_04e82a3cfb56 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_3663991d-9319-4f7a-922b-f0e428b58801 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A porous electrode which is coated onto a non-porous substrate, typically a metallic foil current collector."@en ;
+ rdfs:subClassOf :electrochemistry_09a7f560_9ddf_4c32_b067_b213eca5b0a1 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a porous electrode which is coated onto a non-porous substrate, typically a metallic foil current collector."@en ;
skos:prefLabel "PorousElectrodeCoating"@en .
-### http://emmo.info/electrochemistry#electrochemistry_40e3bde2_77d6_4251_9781_8f6e6fa7a160
-:electrochemistry_40e3bde2_77d6_4251_9781_8f6e6fa7a160 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical experiments (usually potentiostatic) where the applied constant or linearly changed potential is superimposed by an alternating (sinusoidal) potential signal of small magnitude."@en ;
- skos:prefLabel "ACTechniques"@en .
-
-[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_40e3bde2_77d6_4251_9781_8f6e6fa7a160 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical experiments (usually potentiostatic) where the applied constant or linearly changed potential is superimposed by an alternating (sinusoidal) potential signal of small magnitude."@en ;
- dcterms:source "Bard AJ, Faulkner LR (2001) Electrochemical methods, 2nd edn. Wiley, New York, chap 10, pp 368"
- ] .
+### http://emmo.info/electrochemistry#electrochemistry_4143b1c2_2d21_419e_af45_247d4c78ce7e
+:electrochemistry_4143b1c2_2d21_419e_af45_247d4c78ce7e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SiliconOxideElectrode"@en .
### http://emmo.info/electrochemistry#electrochemistry_418c59bd_dc9d_438b_bc7c_494fbd1bb4f8
:electrochemistry_418c59bd_dc9d_438b_bc7c_494fbd1bb4f8 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrode that is coated on only one side of the current collector."@en ;
- skos:prefLabel "SingleSidedElectrode"@en .
+ rdfs:subClassOf :electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that is coated on only one side of the current collector"@en ;
+ skos:prefLabel "SingleCoatedElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_41ddf723_245f_4ce8_b9b1_7d9b3b9eea7d
+:electrochemistry_41ddf723_245f_4ce8_b9b1_7d9b3b9eea7d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f3e7979a_e3ef_450a_8762_7d8778afe478
+ ] ;
+ skos:altLabel "LNMOElectrode"@en ;
+ skos:prefLabel "LithiumNickelManganeseOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603
+:electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a rigid prismatic case that is described by characteristic length, width, and height"@en ;
+ skos:prefLabel "PrismaticCase"@en .
### http://emmo.info/electrochemistry#electrochemistry_43ce1a7e_8056_40cb_bdbd_4ce991af1821
@@ -1155,7 +1926,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom emmo:EMMO_0ee5779e_d798_4ee5_9bfe_c392d5bea112
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement principle based on the measurement of the dielectric constant of a sample resulting from the orientation of particles (molecules or ions) that have a dipole moment in an electric field."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical measurement principle based on the measurement of the dielectric constant of a sample resulting from the orientation of particles (molecules or ions) that have a dipole moment in an electric field"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Dielectrometric titrations use dielectrometry for the end-point detection."@en ,
"The method is used to monitor the purity of dielectrics, for example to detect small amounts of moisture."@en ;
@@ -1164,24 +1935,35 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330
:electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ rdfs:subClassOf :electrochemistry_e3d3d21c_cb9a_498c_bdb0_63c964f0d3c6 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1418367" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-27" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Self-discharge"@en ;
rdfs:seeAlso "ChargeRetention"@en ;
skos:prefLabel "SelfDischarge"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit."@en ;
+ owl:annotatedTarget "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_468df5e8_f7b0_4761_96e9_1a83cc11027d
-:electrochemistry_468df5e8_f7b0_4761_96e9_1a83cc11027d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "PotentiostaticChronoamperometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_457a8f92_0a19_4773_8114_a42edff32248
+:electrochemistry_457a8f92_0a19_4773_8114_a42edff32248 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-04" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "assembly of plates of the same polarity electrically connected together"@en ;
+ skos:prefLabel "PlateGroup"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_457a8f92_0a19_4773_8114_a42edff32248 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "assembly of plates of the same polarity electrically connected together"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1
@@ -1190,29 +1972,196 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "VoltageControlledProcess"@en .
-### http://emmo.info/electrochemistry#electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc
-:electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc rdf:type owl:Class .
+### http://emmo.info/electrochemistry#electrochemistry_46ac0fd3_2b8e_40aa_bf5d_19cf1dd39052
+:electrochemistry_46ac0fd3_2b8e_40aa_bf5d_19cf1dd39052 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d6031563_07c3_4cf7_852e_474dce2acc1c
+ ] ;
+ skos:prefLabel "StrontiumElectrode"@en .
-### http://emmo.info/electrochemistry#electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e
-:electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-03" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "situation in which a material in a given environment undergoes negligible electrochemical corrosion."@en ;
- emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "cathodic protection"@en ;
- skos:prefLabel "ElectrochemicalImmunity"@en .
+### http://emmo.info/electrochemistry#electrochemistry_47346d85_b9be_4480_8993_6307b1c58fcd
+:electrochemistry_47346d85_b9be_4480_8993_6307b1c58fcd rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_c109ca45_08c7_4436_a818_a9c575785e2f
+ ] ;
+ skos:altLabel "metal electrode in which the active material is lithium"@en ;
+ skos:prefLabel "LithiumElectrode"@en .
-[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "situation in which a material in a given environment undergoes negligible electrochemical corrosion."@en ;
- dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+
+### http://emmo.info/electrochemistry#electrochemistry_4839708a_3864_47eb_b719_373ff8874c61
+:electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 ,
+ :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode consisting of two metal oxide active materials"@en ;
+ skos:prefLabel "BimetallicOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_48e380c3_0441_4761_a80f_3e448cb2f0ba
+:electrochemistry_48e380c3_0441_4761_a80f_3e448cb2f0ba rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_3ac62305_acd6_4312_9e31_4f824bd2530d
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_e8fafdc8_6cd3_4dd0_9630_10ca8e3f1827
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended lithium nickel manganese cobalt oxide (NMC) and lithium manganese oxide (LMO) active materials"@en ;
+ skos:altLabel "NMCLMOElectrode"@en ;
+ skos:prefLabel "LithiumNickelMananeseCobaltOxideLithiumManganeseOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4920de95_3a48_4669_b762_5a0b5232b52f
+:electrochemistry_4920de95_3a48_4669_b762_5a0b5232b52f rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vector containing at least two values for the quantity electric current"@en ;
+ skos:prefLabel "ElectricCurrentVector"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_49263a32_eca6_4644_8144_0d3b14c26d0a
+:electrochemistry_49263a32_eca6_4644_8144_0d3b14c26d0a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_c4bace1d_4db0_4cd3_87e9_18122bae2840 ;
+ owl:someValuesFrom emmo:EMMO_2031516a_2be7_48e8_9af7_7e1270e308fe
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
+ owl:someValuesFrom :electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty ;
+ owl:someValuesFrom
+ ] ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-04" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "mixing of a substance into another substance with formation of one new homogeneous substance"@en ;
+ rdfs:comment "the result of the dissolution of one or more solutes into a solvent is a solution"@en ;
+ skos:prefLabel "Dissolution"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_49263a32_eca6_4644_8144_0d3b14c26d0a ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "mixing of a substance into another substance with formation of one new homogeneous substance"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb
+:electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_5d73661e_e710_4844_ab9b_a85b7e68576a ;
+ owl:someValuesFrom emmo:EMMO_d4f7d378_5e3b_468a_baa1_a7e98358cda7
+ ] ;
+ skos:prefLabel "TimeMeasurementResult"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4977521c_0438_4659_bc81_1c77fae836bb
+:electrochemistry_4977521c_0438_4659_bc81_1c77fae836bb rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
+ skos:prefLabel "ThionylChlorideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_49909cd1_44f4_41b4_877a_82a52845a5cb
+:electrochemistry_49909cd1_44f4_41b4_877a_82a52845a5cb rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-10" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of a cell made of insulating material intended to maintain the spacing between plates of opposite polarity or between the plate pack and the case"@en ;
+ skos:prefLabel "Spacer"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_49909cd1_44f4_41b4_877a_82a52845a5cb ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "component of a cell made of insulating material intended to maintain the spacing between plates of opposite polarity or between the plate pack and the case"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4a13e538_4c08_4ba9_8ebc_98a866208e01
+:electrochemistry_4a13e538_4c08_4ba9_8ebc_98a866208e01 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_97439fbb_155f_433d_9edd_d510cd491f24
+ ] ;
+ skos:prefLabel "SodiumNickelPhosphateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903
+:electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-13" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cell container which is usually metallic and typically, but not exclusively, cylindrical"@en ;
+ skos:prefLabel "CellCan"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cell container which is usually metallic and typically, but not exclusively, cylindrical"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e
+:electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-03" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "situation in which a material in a given environment undergoes negligible electrochemical corrosion."@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "cathodic protection"@en ;
+ skos:prefLabel "ElectrochemicalImmunity"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "situation in which a material in a given environment undergoes negligible electrochemical corrosion."@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_4bdd6359_1422_4c50_ac0c_5d8042dd65fc
+:electrochemistry_4bdd6359_1422_4c50_ac0c_5d8042dd65fc rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a model for the double layer that includes the action of the solvent on the surface"@en ;
+ rdfs:comment "proposed by John Bockris, M. A. V. Devanathan, and Klaus Mueller in 1963"@en ;
+ skos:altLabel "BDM"@en ;
+ skos:prefLabel "BockrisDevanathanMuellerModel"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4c3ee364_829b_41a4_b895_ca4a041efb2a
+:electrochemistry_4c3ee364_829b_41a4_b895_ca4a041efb2a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "LithiumInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4d09ddc4_7e71_4712_afab_b33d8df38983
+:electrochemistry_4d09ddc4_7e71_4712_afab_b33d8df38983 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vector containing at least two values for the quantity voltage"@en ;
+ skos:prefLabel "VoltageVector"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_4d6f7f50_b343_4bd6_8612_2b8521a99c9b
:electrochemistry_4d6f7f50_b343_4bd6_8612_2b8521a99c9b rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q100318565" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-15" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "increasing the rate of an electrode reaction by adding specific material to the electrode."@en ;
skos:prefLabel "Electrocatalysis"@en .
@@ -1227,15 +2176,17 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_4df84ec1_8a1a_4770_963f_bf48009bd043
:electrochemistry_4df84ec1_8a1a_4770_963f_bf48009bd043 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The electrochemical dissolution of a material to soluble species."@en ;
+ rdfs:subClassOf :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ,
+ :electrochemistry_49263a32_eca6_4644_8144_0d3b14c26d0a ;
+ owl:disjointWith :electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the electrochemical dissolution of a material to soluble species"@en ;
rdfs:comment "It can be regarded as the reversal of electrodeposition."@en ;
skos:prefLabel "Electrodissolution"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_4df84ec1_8a1a_4770_963f_bf48009bd043 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The electrochemical dissolution of a material to soluble species."@en ;
+ owl:annotatedTarget "the electrochemical dissolution of a material to soluble species"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
@@ -1243,18 +2194,35 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_4e02d727_07fe_41fd_886c_041317342086
:electrochemistry_4e02d727_07fe_41fd_886c_041317342086 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrolyte consisting of anions and cations with equal absolute charge numbers."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrolyte consisting of anions and cations with equal absolute charge numbers."@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "KCl (1:1), MgSO4 (2:2)" ;
skos:prefLabel "BinaryElectrolyte"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_4e02d727_07fe_41fd_886c_041317342086 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "An electrolyte consisting of anions and cations with equal absolute charge numbers."@en ;
+ owl:annotatedTarget "an electrolyte consisting of anions and cations with equal absolute charge numbers."@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
+### http://emmo.info/electrochemistry#electrochemistry_4edb47d6_107c_40a2_be7c_6b26e9d296da
+:electrochemistry_4edb47d6_107c_40a2_be7c_6b26e9d296da rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SodiumManganeseHexacyanoferrateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_4f2348dd_d9ea_4448_af8c_a4a38f3d04b4
+:electrochemistry_4f2348dd_d9ea_4448_af8c_a4a38f3d04b4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_8069b9ca_4639_49c6_b182_fedff62869a1
+ ] ;
+ rdfs:comment "metal electrode in which the active material is calcium"@en ;
+ skos:prefLabel "CalciumMetalElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2
:electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_fcae603e_aa6e_4940_9fa1_9f0909cabf3b ;
@@ -1263,10 +2231,57 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "ElectrochemicalInterface"@en .
+### http://emmo.info/electrochemistry#electrochemistry_502a98a3_ce47_421f_8e0a_016ed171c900
+:electrochemistry_502a98a3_ce47_421f_8e0a_016ed171c900 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_c5582dae_ccff_4fbe_adaa_078091054640
+ ] ;
+ skos:prefLabel "SodiumIronPhosphateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_510e4061_c4fa_49aa_a052_23ad56098eda
+:electrochemistry_510e4061_c4fa_49aa_a052_23ad56098eda rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_df038b95_6c39_4fce_8c16_237057a08c0b
+ ] ;
+ skos:prefLabel "ChromiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528
+:electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:minQualifiedCardinality "2"^^xsd:nonNegativeInteger ;
+ owl:onClass emmo:EMMO_df96cbb6_b5ee_4222_8eab_b3675df24bea
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an active electrode with a blend of two or more active materials"@en ;
+ skos:prefLabel "BlendedActiveElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_522f0c0b_cf33_4328_af71_12e38dae6798
+:electrochemistry_522f0c0b_cf33_4328_af71_12e38dae6798 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-25" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "accessible conductive part provided for the connection of an external electric circuit to the positive electrode of the cell"@en ;
+ skos:prefLabel "PositiveTerminal"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_522f0c0b_cf33_4328_af71_12e38dae6798 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "accessible conductive part provided for the connection of an external electric circuit to the positive electrode of the cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_52501237_0c13_4bfb_aa3a_441c6a9ae3a6
:electrochemistry_52501237_0c13_4bfb_aa3a_441c6a9ae3a6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Titration in which the titrant is generated electrochemically, either by constant current or at constant potential. The titrant reacts stoichiometrically with the analyte, the amount of which is calculated using Faraday’s laws of electrolysis from the electric charge required to reach the end-point."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "titration in which the titrant is generated electrochemically, either by constant current or at constant potential. The titrant reacts stoichiometrically with the analyte, the amount of which is calculated using Faraday’s laws of electrolysis from the electric charge required to reach the end-point"@en ;
rdfs:comment "Coulometric titrations are usually carried out in convective mass transfer mode using a large surface working electrode. The reference and auxiliary electrodes are located in sepa- rate compartments. A basic requirement is a 100 % current efficiency of titrant generation at the working electrode. End-point detection can be accomplished with potentiometry, amperometry, biamperometry, bipotentiometry, photometry, or by using a visual indicator."@en ,
"The main advantages are that titration is possible with less stable titrants, the standardi- zation of titrant is not necessary, the volume of the test solution is not changed, and the method is easily automated."@en ;
skos:prefLabel "CoulometricTitration"@en .
@@ -1279,12 +2294,9 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30
:electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc ,
- :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ;
- owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
- ] ;
+ :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ;
owl:disjointWith :electrochemistry_9865e4f9_756d_4d94_a6fd_4102ab795f9e ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a discharging process in which the current is kept at a constant value"@en ;
skos:altLabel "GalvanostaticDischarging"@en ;
skos:prefLabel "ConstantCurrentDischarging"@en .
@@ -1292,14 +2304,16 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec
:electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_4f226cf3_6d02_4d35_8566_a9e641bc6ff3 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A spatial region at the interface be-tween two bulk phases in contact, which is different chemically and physically from both phases in contact."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a spatial region at the interface between two bulk phases in contact, which is different chemically and physically from both phases in contact"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "SEI, double layer"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/I03085" ;
+ skos:altLabel "InterfacialLayer"@en ;
skos:prefLabel "Interphase"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A spatial region at the interface be-tween two bulk phases in contact, which is different chemically and physically from both phases in contact."@en ;
+ owl:annotatedTarget "a spatial region at the interface between two bulk phases in contact, which is different chemically and physically from both phases in contact"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
@@ -1313,18 +2327,27 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916
:electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q241065" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-01"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Movement of a fluid through a diaphragm, produced by application of an electric field."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "movement of a fluid through a diaphragm, produced by application of an electric field"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electro-osmosis"@en ;
skos:prefLabel "Electroosmosis"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Movement of a fluid through a diaphragm, produced by application of an electric field."@en ;
+ owl:annotatedTarget "movement of a fluid through a diaphragm, produced by application of an electric field"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_564d31be_91cb_4a8f_8369_2a55f1180499
+:electrochemistry_564d31be_91cb_4a8f_8369_2a55f1180499 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrolyte solution with an organic solvent"@en ;
+ skos:prefLabel "OrganicElectrolyte"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a
:electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 ,
@@ -1361,38 +2384,37 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_56f85b19_1384_4e88_b130_cb8e7984db83
:electrochemistry_56f85b19_1384_4e88_b130_cb8e7984db83 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrode that is coated on both sides of the current collector."@en ;
- skos:prefLabel "DoubleSidedElectrode"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_579eed46_6918_4275_9a70_dfd0409ab418
-:electrochemistry_579eed46_6918_4275_9a70_dfd0409ab418 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_9c32fd69_f480_4130_83b3_fb25d9face14 ;
- rdfs:comment "If reference is made only to ‘Faraday’s Law of electrolysis’ the first law is meant."@en ;
- skos:prefLabel "FaradaysLawsOfElectrolysis"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_58143f50_c3c1_4cba_b8eb_577282b4b026
-:electrochemistry_58143f50_c3c1_4cba_b8eb_577282b4b026 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
- owl:someValuesFrom emmo:EMMO_4f2d3939_91b1_4001_b8ab_7d19074bf845
- ] ;
- skos:prefLabel "ElectricPotentialMeasurementResult"@en .
+ rdfs:subClassOf :electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that is coated on both sides of the current collector"@en ;
+ skos:prefLabel "DoubleCoatedElectrode"@en .
### http://emmo.info/electrochemistry#electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91
:electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a separator with a porosity greater than 0"@en ;
skos:prefLabel "PorousSeparator"@en .
+### http://emmo.info/electrochemistry#electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a
+:electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom emmo:EMMO_d4f7d378_5e3b_468a_baa1_a7e98358cda7
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a vector of discrete times"@en ;
+ skos:prefLabel "TimeVector"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_598ae3d0_76e9_429c_a0e1_8694525cb574
:electrochemistry_598ae3d0_76e9_429c_a0e1_8694525cb574 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_f19ff3b4_6bfe_4c41_a2b2_9affd39c140b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3258329" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "For any electrolyte A_xB_y, the limiting molar conductivity is expressed as x times the limiting molar conductivity of A^{y+} and y times the limiting molar conductivity of B^{x-}."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Molar_conductivity#Kohlrausch's_law_of_independent_migration_of_ions"@en ;
+ rdfs:comment "proposed by Friedrich Kohlrausch between 1875-1879"@en ,
+ "valid for dilute solutions"@en ;
skos:prefLabel "KohlrauschsLaw"@en .
@@ -1403,7 +2425,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Linear scan voltammetry with slow scan rate in which a dropping mercury electrode is used as the working electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "linear scan voltammetry with slow scan rate in which a dropping mercury electrode is used as the working electrode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "If the whole scan is performed on a single growing drop, the technique should be called single drop scan voltammetry. The term polarography in this context is discouraged."@en ,
"This is the oldest variant of polarographic techniques, introduced by Jaroslav Heyrovský (1890 – 1967)."@en ,
@@ -1411,54 +2433,55 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "DCPolarography"@en .
+### http://emmo.info/electrochemistry#electrochemistry_5a7a3028_db9e_4045_ab68_054c6afc91fc
+:electrochemistry_5a7a3028_db9e_4045_ab68_054c6afc91fc rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_9c32fd69_f480_4130_83b3_fb25d9face14 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q899494" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the rate of the chemical reaction is directly proportional to the product of the activities or concentrations of the reactants"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Law_of_mass_action"@en ;
+ skos:prefLabel "LawOfMassAction"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e
:electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrode in which the actve electrochemical material is a metal."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode in which the actve electrochemical material is a metal"@en ;
+ rdfs:comment "the term metal is meant to loosely cover alkali metals, alkaline earth metals, transition metals, post-transition metals, and metalloids"@en ;
skos:prefLabel "MetalElectrode"@en .
+### http://emmo.info/electrochemistry#electrochemistry_5c0fdc09_166e_40a6_ad74_be66f0db51bc
+:electrochemistry_5c0fdc09_166e_40a6_ad74_be66f0db51bc rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_9da78aea_d436_40e2_a68f_c3dee32b825e
+ ] ;
+ skos:prefLabel "CarbonMonofluorideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1
:electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q9252431"@en ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-02"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrocapillarity"@en ;
skos:prefLabel "Electrocapillarity"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface."@en ;
+ owl:annotatedTarget "change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_5dc0c44e_6fdc_49fc_8654_b8b2d75d0d2d
-:electrochemistry_5dc0c44e_6fdc_49fc_8654_b8b2d75d0d2d rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_3f9b2956_1465_4fe0_b0df_5e4784dac3b6
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_58143f50_c3c1_4cba_b8eb_577282b4b026
- ] ;
- skos:prefLabel "ElectricPotentialMeasurement"@en .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e
-:electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Amperometry" ;
- skos:prefLabel "AmperometricProcess"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98
:electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ;
+ rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
owl:disjointWith :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An ion-transport medium that does not contain water."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an ion-transport medium that does not contain water."@en ;
skos:altLabel "NonAqueousElectrolyticSolution"@en ,
"NonAqueousSolution"@en ;
skos:prefLabel "NonAqueousElectrolyte"@en .
@@ -1466,7 +2489,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "An ion-transport medium that does not contain water."@en ;
+ owl:annotatedTarget "an ion-transport medium that does not contain water."@en ;
dcterms:source "IEEE Standard Glossary of Stationary Battery Terminology (2016), https://doi.org/10.1109/IEEESTD.2016.7552407"
] .
@@ -1474,31 +2497,60 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89
:electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
- emmo:EMMO_70fe84ff_99b6_4206_a9fc_9a8931836d84 "An electrolyte in the liquid phase."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrolyte in the liquid phase."@en ;
skos:prefLabel "LiquidElectrolyte"@en .
+### http://emmo.info/electrochemistry#electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7
+:electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-23" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cover of insulating material used to avoid electric contact with the cell or battery terminal"@en ;
+ skos:altLabel "TerminalCover"@en ;
+ skos:prefLabel "TerminalProtector"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cover of insulating material used to avoid electric contact with the cell or battery terminal"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03
:electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_579eed46_6918_4275_9a70_dfd0409ab418 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "When the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ;
- rdfs:comment "m_1/m_2 = (M_1/z_1) / (M_2/z_2)"@en ;
+ rdfs:subClassOf emmo:EMMO_9c32fd69_f480_4130_83b3_fb25d9face14 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "when the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faraday%27s_laws_of_electrolysis#Second_law"@en ;
+ rdfs:comment "m_1/m_2 = (M_1/z_1) / (M_2/z_2)" ;
skos:prefLabel "FaradaysSecondLawOfElectrolysis"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "When the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ;
+ owl:annotatedTarget "when the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_610f0bc8_557d_455b_a8ed_272d5d1813c9
+:electrochemistry_610f0bc8_557d_455b_a8ed_272d5d1813c9 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_ff5b9c8c_3fb0_4575_9ab8_23ebd9116294
+ ] ;
+ rdfs:comment "metal electrode in which the active material is lead"@en ;
+ skos:prefLabel "LeadElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878
:electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ;
owl:disjointWith :electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An aqueous electrolyte with a nominal pH greater than 7."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH greater than 7"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "KOH-H2O"@en ;
+ rdfs:comment "typical alkaline electrolytes have a pH in the range 13 < x < 15"@en ;
skos:altLabel "AlkalineAqueousElectrolyte"@en ,
"AlkalineSolution"@en ;
skos:prefLabel "AlkalineElectrolyte"@en .
@@ -1507,7 +2559,8 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_61740c42_d332_492c_8b37_90a187c7f6d9
:electrochemistry_61740c42_d332_492c_8b37_90a187c7f6d9 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_3b35e843_3132_41e3_b6df_541cd45ba880 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Stripping voltammetry in which material accumulated at the working electrode is electrochemically reduced in the stripping step."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q4016325" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "stripping voltammetry in which material accumulated at the working electrode is electrochemically reduced in the stripping step"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "A peak-shaped cathodic stripping voltammogram is obtained. Peak current depends on time of accumulation, mass transport of analyte (stirring), scan rate and mode (linear or pulse), and analyte concentration in solution."@en ;
skos:altLabel "CSV"@en ;
@@ -1532,10 +2585,25 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
] .
+### http://emmo.info/electrochemistry#electrochemistry_6235cc7c_2eee_432a_93af_47d7e05db007
+:electrochemistry_6235cc7c_2eee_432a_93af_47d7e05db007 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_5cee19d2_f916_4264_a8ed_efed13a808d2
+ ] ;
+ skos:prefLabel "HardCarbonElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_634467ad_feed_4979_adb2_877d98fe1768
:electrochemistry_634467ad_feed_4979_adb2_877d98fe1768 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Any junction between two electrolyte solutions of different composition."@en ;
+ rdfs:subClassOf :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger ;
+ owl:onClass :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "any junction between two electrolyte solutions of different composition."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/L03584"@en ;
rdfs:comment "Across such a junction there arises a potential difference, called the liquid junction potential."@en ,
"In the operational pH cell the junction is between the test, or pH standard, solution and the filling solution or the bridge solution of the reference electrode."@en ;
@@ -1545,8 +2613,9 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f
:electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q899119" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Salt_bridge"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Salt_bridge"@en ;
rdfs:comment "A typical construction is a tube of an inert material (e.g. agar agar) filled with a solution containing an electrolyte with approximately equal ion mobilities of the cation and the anion (e.g., KNO3, KCl), with the ends of the tube immersed in the electrolyte solution of the half cells."@en ;
skos:prefLabel "SaltBridge"@en .
@@ -1554,15 +2623,25 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ;
+ owl:annotatedTarget "means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_6385e07f_f40d_46b2_b998_c439950d75cb
+:electrochemistry_6385e07f_f40d_46b2_b998_c439950d75cb rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e ;
+ skos:prefLabel "WaveSpring"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b
:electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Potentiometry in which the potential is measured with time following a change in applied current."@en ;
+ rdfs:subClassOf :electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "potentiometry in which the potential is measured with time following a change in applied current"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The change in applied current is usually a step, but cyclic current reversals or linearly increasing currents are also used."@en ;
skos:prefLabel "Chronopotentiometry"@en .
@@ -1571,29 +2650,16 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685
:electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q30587730"@en ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-06"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Transport of ions in an electrolyte due to an electric field."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "transport of ions in an electrolyte due to an electric field"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_migration"@en ;
skos:prefLabel "ElectrochemicalMigration"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Transport of ions in an electrolyte due to an electric field."@en ;
- dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
- ] .
-
-
-### http://emmo.info/electrochemistry#electrochemistry_63fe114f_5803_4f2a_8d07_93d3be380e41
-:electrochemistry_63fe114f_5803_4f2a_8d07_93d3be380e41 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-13" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "method of electroanalytical chemistry in which the electric charge consumed or produced is measured and used to derive the amount-of-substance transformed."@en ;
- skos:prefLabel "Coulometry"@en .
-
-[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_63fe114f_5803_4f2a_8d07_93d3be380e41 ;
- owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "method of electroanalytical chemistry in which the electric charge consumed or produced is measured and used to derive the amount-of-substance transformed."@en ;
+ owl:annotatedTarget "transport of ions in an electrolyte due to an electric field"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1601,8 +2667,9 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65
:electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_314d0bd5_67ed_437e_a609_36d46147cea7 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1530469" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=112-04-03"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon serving as the basis of a measurement."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon serving as the basis of a measurement"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Energy absorption applied to the measurement of amount-of-substance concentration."@en ,
"Hall effect applied to the measurement of magnetic flux density."@en ,
"Thermoelectric effect applied to the measurement of temperature."@en ;
@@ -1611,11 +2678,27 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
skos:prefLabel "MeasurementPrinciple"@en .
+### http://emmo.info/electrochemistry#electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0
+:electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0 rdf:type owl:Class ;
+ rdfs:subClassOf ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-16" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material used to seal the cell lid to the case or to the terminals of a cell"@en ;
+ skos:prefLabel "LidSealingCompound"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "material used to seal the cell lid to the case or to the terminals of a cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2
:electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An aqueous electrolyte with a nominal pH values less than 7."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH values less than 7"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "HCl-H2O"@en ;
+ rdfs:comment "typical alkaline electrolytes have a pH in the range 0 < x < 4"@en ;
skos:altLabel "AcidicAqueousElectrolyte"@en ,
"AcidicSolution"@en ;
skos:prefLabel "AcidicElectrolyte"@en .
@@ -1624,7 +2707,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc
:electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode made of a solid amalgam of an appropriate metal."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode made of a solid amalgam of an appropriate metal"@en ;
rdfs:comment "Liquid and paste amalgams can also be used."@en ,
"Solid amalgam electrodes are electrochemically similar to the hanging mercury drop electrode. Their main advantages are high hydrogen overpotential (similar to liquid mercury); a wide working potential range; the simple mechanical, chemical, and electrochemical regeneration of the surface; a long lifetime; low toxicity of material (comparable with that of dental amalgams); applicability for field measurements; compatibility with flow-through systems; simple construction, without mobile parts; and easy miniaturization."@en ;
skos:altLabel "SAE"@en ;
@@ -1633,26 +2716,63 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode made of a solid amalgam of an appropriate metal."@en ;
+ owl:annotatedTarget "electrode made of a solid amalgam of an appropriate metal"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_68c1c36e_1548_4247_bae2_fe7102a2c4ff
+:electrochemistry_68c1c36e_1548_4247_bae2_fe7102a2c4ff rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm"@en ;
+ skos:altLabel "R66"@en ;
+ skos:prefLabel "R626"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_68eb5e35_5bd8_47b1_9b7f_f67224fa291e
:electrochemistry_68eb5e35_5bd8_47b1_9b7f_f67224fa291e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q863583" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material or substance that holds or draws other materials together to form a cohesive whole"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "CMC, PVDF"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Binder_(material)"@en ;
skos:altLabel "ElectrodeBinder"@en ;
skos:prefLabel "Binder"@en .
+### http://emmo.info/electrochemistry#electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e
+:electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aff732a9_238a_4734_977c_b2ba202af126 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-07" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "positive plate (electrode) which is either composed of an assembly of porous tube of perforated metal or tissue either a gauntlet with or without a central current collector spine, the active material being placed within the tubes"@en ;
+ skos:prefLabel "TubularPlate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "positive plate (electrode) which is either composed of an assembly of porous tube of perforated metal or tissue either a gauntlet with or without a central current collector spine, the active material being placed within the tubes"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_6b275583_433f_46f7_aafd_ebc9409257cc
+:electrochemistry_6b275583_433f_46f7_aafd_ebc9409257cc rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm"@en ;
+ rdfs:comment "often used in wrist watches"@en ;
+ skos:altLabel "R66" ;
+ skos:prefLabel "R626"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5
:electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ rdfs:subClassOf :electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3587619" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A disc electrode that is embedded in the centre of a cylinder which rotates in solution around the longitudinal cylinder axis."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Rotating_disk_electrode"@en ;
rdfs:comment "The current is directly proportional to the electrode area and the electrode is uniformly accessible."@en ,
"The limiting current is given by the Levich equation."@en ;
+ skos:altLabel "RDE"@en ;
skos:prefLabel "RotatingDiskElectrode"@en .
[ rdf:type owl:Axiom ;
@@ -1663,6 +2783,17 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
] .
+### http://emmo.info/electrochemistry#electrochemistry_6d0fe07e_a629_479c_ab24_2846f209bb0b
+:electrochemistry_6d0fe07e_a629_479c_ab24_2846f209bb0b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_acdb232f_8041_4e11_8a11_5db2d2baae4d
+ ] ;
+ skos:altLabel "LTOElectrode"@en ;
+ skos:prefLabel "LithiumTitanateElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
:electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 rdf:type owl:Class .
@@ -1675,7 +2806,10 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement principle in which the electric charge required to carry out a known electrochemical reaction is measured. By Faraday’s laws of electrolysis, the amount of substance is proportional to the charge."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1136979" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-13" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical measurement principle in which the electric charge required to carry out a known electrochemical reaction is measured. By Faraday’s laws of electrolysis, the amount of substance is proportional to the charge"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Coulometry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Coulometry used to measure the amount of substance is a primary reference measurement procedure [VIM 2.8] not requiring calibration with a standard for a quantity of the same kind (i.e. amount of substance)."@en ,
"The coulometric experiment can be carried out at controlled (constant) potential (see direct coulometry at controlled potential) or controlled (constant) current (see direct coulometry at controlled current)."@en ;
@@ -1685,6 +2819,7 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_6ec59f99_5f26_4a7d_9b90_b52e0f8ad190
:electrochemistry_6ec59f99_5f26_4a7d_9b90_b52e0f8ad190 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q900939" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A type of reference electrode based on the reaction between sliver and silver chloride."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Silver_chloride_electrode"@en ;
skos:prefLabel "SilverChlorideElectrode"@en .
@@ -1702,54 +2837,71 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
### http://emmo.info/electrochemistry#electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77
:electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_b9522e56_1fac_4766_97e6_428605fabd3e ,
- [ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
- owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241 ;
- owl:someValuesFrom :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241 ;
- owl:someValuesFrom :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302
- ] ;
+ owl:equivalentClass [ rdf:type owl:Class ;
+ owl:unionOf ( [ owl:intersectionOf ( [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
+ owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
+ ]
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_5d299271_3f68_494f_ab96_3db9acdd3138 ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ]
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_8e9cf965_9f92_46e8_b678_b50410ce3616 ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ]
+ ) ;
+ rdf:type owl:Class
+ ]
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:minQualifiedCardinality "2"^^xsd:nonNegativeInteger ;
+ owl:onClass :electrochemistry_9da958fc_f76d_4654_8a78_99b5f98c118c
+ ]
+ )
+ ] ;
+ rdfs:subClassOf emmo:EMMO_b9522e56_1fac_4766_97e6_428605fabd3e ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q80097" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-01"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ;
+ emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "http://dbpedia.org:8891/page/Electrochemical_cell" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_cell"@en ;
- rdfs:comment "Composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy."@en ,
- "If processes of interest occur at both the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or two working electrodes."@en ,
+ rdfs:comment "If processes of interest occur at both the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or two working electrodes."@en ,
"In electrochemistry the term “cell” is commonly qualified to describe the particular device on which electrochemical reactions take place. It is important to distinguish between the concept of an electrochemical cell (two electrodes separated by electrolyte) and an electrochemical device (a manufactured object for making practical use of an electrochemical cell, e.g. for measurement or energy storage purposes)."@en ,
- "System that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)."@en ;
+ "composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy"@en ,
+ "system that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)"@en ;
skos:prefLabel "ElectrochemicalCell"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ;
+ owl:annotatedTarget "a system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ;
dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004."
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy."@en ;
+ owl:annotatedTarget "composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "System that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)."@en ;
+ owl:annotatedTarget "system that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)"@en ;
rdfs:comment "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185
:electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries."@en ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_b3815a7f_f64a_48f6_b0ce_d0032578c699
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries"@en ;
rdfs:comment "At positive potentials, Au forms an oxide and/or chemisorbed oxygen layer, while in the presence of complexing anions, such as chloride or cyanide, it readily undergoes oxidation and dissolution, limiting its working potential range and its applications."@en ;
skos:altLabel "AuElectrode"@en ;
skos:prefLabel "GoldElectrode"@en .
@@ -1757,11 +2909,18 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries."@en ;
+ owl:annotatedTarget "foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_713200a1_952b_49e2_90b7_deba229f6bbe
+:electrochemistry_713200a1_952b_49e2_90b7_deba229f6bbe rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:altLabel "LMPElectrode"@en ;
+ skos:prefLabel "LithiumManganesePhosphateElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_729a1064_d039_4b74_9d1d_759b18a3971c
:electrochemistry_729a1064_d039_4b74_9d1d_759b18a3971c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_3fe63496_6d87_427a_b2aa_4555bc31ee1a ,
@@ -1777,12 +2936,20 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
owl:onProperty ;
owl:someValuesFrom emmo:EMMO_90e59882_4592_4036_a75d_5fbefb22dc80
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Amperometry in which the current is measured as a function of time after a change in the applied potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "amperometry in which the current is measured as a function of time after a change in the applied potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "If the potential step is from a potential at which no current flows (i.e., at which the oxidation or reduction of the electrochemically active species does not take place) to one at which the current is limited by diffusion (see diffusion-limited current), the current obeys the Cottrell equation."@en ;
+ skos:altLabel "AmperiometricDetection"@en ,
+ "AmperometricCurrentTimeCurve"@en ;
skos:prefLabel "Chronoamperometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_7393f12f_e3b9_42d6_bffb_e5613f53108f
+:electrochemistry_7393f12f_e3b9_42d6_bffb_e5613f53108f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ;
+ skos:prefLabel "AqueousZincChlorideSolution"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37
:electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b ,
@@ -1805,28 +2972,75 @@ charge passed at infinite time, D is the diffusion coefficient of the electroact
] .
+### http://emmo.info/electrochemistry#electrochemistry_74459386_875c_4303_b774_60125b599d06
+:electrochemistry_74459386_875c_4303_b774_60125b599d06 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a soft pouch case that is described by its length, width, and height"@en ;
+ skos:prefLabel "PouchCase"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c
:electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrode at which the predominant electrochemical reaction is an intercalation."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode at which the predominant electrochemical reaction is an intercalation"@en ;
skos:altLabel "IntercalationElectrode"@en ;
skos:prefLabel "InsertionElectrode"@en .
-### http://emmo.info/electrochemistry#electrochemistry_771e82be_c61d_4aad_bdcf_62ca3e68a939
-:electrochemistry_771e82be_c61d_4aad_bdcf_62ca3e68a939 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "AmperometricCurrentTimeCurve"@en .
+### http://emmo.info/electrochemistry#electrochemistry_76318e8e_c1ba_49ac_8029_a951bd9dc955
+:electrochemistry_76318e8e_c1ba_49ac_8029_a951bd9dc955 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 1.6 mm"@en ;
+ skos:altLabel "R62" ;
+ skos:prefLabel "R516"@en .
-### http://emmo.info/electrochemistry#electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29
-:electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-15"@en ;
- emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a """The standard hydrogen electrode represents the primary standard in electrochemistry. Elec- trodes of the 2nd kind, such as Ag | AgCl, Hg | Hg2
-Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous solutions containing ions Cl^{−}, SO_4^{2−}, and OH^{−}, respectively."""@en ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reference_electrode"@en ;
- emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/R05229"@en ;
+### http://emmo.info/electrochemistry#electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c
+:electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-36"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cable used for the electrical connection of the battery terminals and the load and/or the charger"@en ;
+ skos:prefLabel "OutputCable"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cable used for the electrical connection of the battery terminals and the load and/or the charger"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_76e461aa_5948_4a68_8337_284d11e0fd7d
+:electrochemistry_76e461aa_5948_4a68_8337_284d11e0fd7d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_5088ad54_b37d_4ee1_a086_d6c17e644f9a
+ ] ;
+ skos:altLabel "NiOElectrode"@en ;
+ skos:prefLabel "NickelOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_76fe8fb2_868e_48eb_95ca_fc6acd6f5fc9
+:electrochemistry_76fe8fb2_868e_48eb_95ca_fc6acd6f5fc9 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d673ceb2_3045_4e2e_8cad_56f5169b542f
+ ] ;
+ skos:altLabel "TiO2Electrode"@en ;
+ skos:prefLabel "TitaniumDioxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29
+:electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q653954" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-15"@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a """The standard hydrogen electrode represents the primary standard in electrochemistry. Elec- trodes of the 2nd kind, such as Ag | AgCl, Hg | Hg2
+Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous solutions containing ions Cl^{−}, SO_4^{2−}, and OH^{−}, respectively."""@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reference_electrode"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/R05229"@en ;
rdfs:comment "Electrode that maintains an essentially constant potential under the conditions prevailing in an electrochemical measurement, and that serves for observation, measurement, or control of the potential of the indicator or working electrode."@en ,
"Electrode with a well-defined and constant equilibrium potential with respect to which it is possible to measure or calculate electrode potentials of other electrodes by including them in an appropriate electrochemical cell."@en ,
"In potentiometry, under zero current condition, the essentially constant potential is achieved by ensuring a constant composition of solution in contact with the electrode forming a half-cell. Practical reference half-cells are generally non-polarizable electrodes of the 2nd kind (metal | insoluble salt | ion), constructed so that their electrolyte solutions serve as salt bridges to the solutions under investigation."@en ,
@@ -1852,13 +3066,13 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
:electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-19"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ;
skos:prefLabel "PhotoelectrolyticCell"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ;
+ owl:annotatedTarget "electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -1866,17 +3080,20 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5
:electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ;
- owl:someValuesFrom :electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc
- ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
owl:someValuesFrom :electrochemistry_22725105_c941_4b14_a4a2_fcb627958607
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a process in which the electric current is kept constant"@en ;
skos:prefLabel "GalvanostaticProcess"@en .
+### http://emmo.info/electrochemistry#electrochemistry_78f75a64_55b6_4243_a35e_3d279c83209b
+:electrochemistry_78f75a64_55b6_4243_a35e_3d279c83209b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 ;
+ skos:prefLabel "PhosphoricAcidSolution"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_79a8802e_8296_459a_b65d_6e5c79e1bf37
:electrochemistry_79a8802e_8296_459a_b65d_6e5c79e1bf37 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ,
@@ -1904,6 +3121,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:onProperty ;
owl:someValuesFrom :electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a cycling protocol in which an electrochemical cell is subject to alternating galvanostatic charging and discharging processes"@en ;
skos:prefLabel "GalvanostaticCycling"@en .
@@ -1911,9 +3129,12 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
:electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
:electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-14"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Material that is oxidized or reduced at an electrode in an electrochemical cell."@en ;
- rdfs:comment "If an electroactive substance B is formed, in the solution or at the electrode surface, by a chemical reaction from another substance C, the substance C should be called the precursor of B." ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907375" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-14"@en ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-33" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material that is oxidized or reduced at an electrode in an electrochemical cell"@en ;
+ rdfs:comment "in secondary cells, the active material is restored to its original state during charge"@en ,
+ "material which reacts chemically to produce electric energy when the cell discharges" ;
skos:altLabel "ActiveElectrochemicalMaterial"@en ,
"ElectrochemicallyActiveMaterial"@en ;
skos:prefLabel "ActiveMaterial"@en .
@@ -1921,42 +3142,170 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Material that is oxidized or reduced at an electrode in an electrochemical cell."@en ;
+ owl:annotatedTarget "material that is oxidized or reduced at an electrode in an electrochemical cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "in secondary cells, the active material is restored to its original state during charge"@en ;
+ rdfs:comment "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "material which reacts chemically to produce electric energy when the cell discharges" ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_7d20588b_69da_46f7_b05d_5b637f6426cb
-:electrochemistry_7d20588b_69da_46f7_b05d_5b637f6426cb rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "AmperometricDetection"@en .
+### http://emmo.info/electrochemistry#electrochemistry_79e12290_d1e5_4c41_916c_18f1e4d7fb51
+:electrochemistry_79e12290_d1e5_4c41_916c_18f1e4d7fb51 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_68c0876b_cb62_41cd_846d_95cc9d9a8733
+ ] ;
+ skos:prefLabel "SiliconElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7b811780_7251_481b_a4d3_97d437955099
+:electrochemistry_7b811780_7251_481b_a4d3_97d437955099 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_8f857eb2_7cc8_4294_954d_e69f2842c084
+ ] ;
+ skos:prefLabel "CobaltElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7b9db6b3_36f0_4b5d_acbb_9284a9054a09
+:electrochemistry_7b9db6b3_36f0_4b5d_acbb_9284a9054a09 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_9b92f5b9_a477_4267_bf68_769c995e6e83
+ ] ;
+ skos:prefLabel "IndiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7beef5fb_a406_4284_b85a_87d55cf46a0e
+:electrochemistry_7beef5fb_a406_4284_b85a_87d55cf46a0e rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_5d73661e_e710_4844_ab9b_a85b7e68576a ;
+ owl:someValuesFrom emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88
+ ] ;
+ skos:prefLabel "ElectricCurrentMeasurementResult"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7cc8b738_3462_4592_ba83_951a8d50fef7
+:electrochemistry_7cc8b738_3462_4592_ba83_951a8d50fef7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_8522bd08_3855_4e4b_bca0_30923a40de88
+ ] ;
+ skos:prefLabel "CaesiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_7f168ebc_4c78_459c_9a39_bddaa57e214c
+:electrochemistry_7f168ebc_4c78_459c_9a39_bddaa57e214c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a modification of the Stern model that considers the double layer as three regions separated by the inner Helmholtz plane and the outer Helmholtz plane"@en ;
+ rdfs:comment "proposed by D. C. Grahame in 1947"@en ;
+ skos:prefLabel "GrahameModel"@en .
### http://emmo.info/electrochemistry#electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917
:electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_17e27c22_37e1_468c_9dd7_95e137f73e7f ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
owl:someValuesFrom :electrochemistry_3a77b5e7_9646_4154_bf8f_5f798989e5f3
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5829908"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Rotating_ring-disk_electrode"@en ;
rdfs:comment "This arrangement is largely used in mechanistic studies."@en ;
+ skos:altLabel "RRDE"@en ;
skos:prefLabel "RotatingRingDiskElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)."@en ;
+ owl:annotatedTarget "a second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77
+:electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_194e367c_9783_4bf5_96d0_9ad597d48d9a ,
+ emmo:EMMO_1cba0b27_15d0_4326_933f_379d0b3565b6 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q186588" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a series of data points indexed in time order"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Time_series"@en ;
+ skos:prefLabel "TimeSeries"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e
:electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ;
+ rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_35c29eb6_f57e_48d8_85af_854f9e926e77 ;
+ owl:someValuesFrom :electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_c4bace1d_4db0_4cd3_87e9_18122bae2840 ;
+ owl:someValuesFrom :electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of time"@en ;
skos:prefLabel "TimeMeasurement"@en .
+### http://emmo.info/electrochemistry#electrochemistry_7ffe1cb6_f87e_4b4a_8ce7_c98e2a584cb1
+:electrochemistry_7ffe1cb6_f87e_4b4a_8ce7_c98e2a584cb1 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ emmo:material_99e61c41_9038_418a_b98c_ab225bd6bec1 ;
+ skos:prefLabel "RutheniumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_80fdbd63_9b7a_462b_a8cb_b50f5f6ab182
+:electrochemistry_80fdbd63_9b7a_462b_a8cb_b50f5f6ab182 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_73d4606c_7460_4a5c_9413_793bdf35753e
+ ] ;
+ skos:prefLabel "LiquidGalliumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_81833d8a_b03d_4250_be84_6385415beb01
+:electrochemistry_81833d8a_b03d_4250_be84_6385415beb01 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261
+ ] ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-34" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "blend containing a material which reacts chemically to produce electrical energy with other constituents and additives"@en ;
+ skos:prefLabel "ActiveMaterialMix"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_81833d8a_b03d_4250_be84_6385415beb01 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "blend containing a material which reacts chemically to produce electrical energy with other constituents and additives"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb
:electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 ,
@@ -1993,23 +3342,36 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_825a749f_dd07_46fb_947c_db286440911e
:electrochemistry_825a749f_dd07_46fb_947c_db286440911e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dc0c44e_6fdc_49fc_8654_b8b2d75d0d2d ,
+ rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77
+ owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of the electric potential between the terminals of an electrochemical cell"@en ;
skos:altLabel "ElectrochemicalCellVoltageMeasurement"@en ;
- skos:prefLabel "CellVoltageMeasurement"@en .
+ skos:prefLabel "VoltageMeasurement"@en .
### http://emmo.info/electrochemistry#electrochemistry_82b66bfe_ec25_417b_ba65_b631ddaaca0e
:electrochemistry_82b66bfe_ec25_417b_ba65_b631ddaaca0e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q898591" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A reference electrode based on the reaction between elemental mercury and mercury(I) chloride."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Saturated_calomel_electrode"@en ;
skos:prefLabel "SaturatedCalomelElectrode"@en .
+### http://emmo.info/electrochemistry#electrochemistry_82c70935_0aea_454b_92bf_17fb0b488012
+:electrochemistry_82c70935_0aea_454b_92bf_17fb0b488012 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_848003a2_71ee_4967_8039_354c907ec7f4
+ ] ;
+ skos:altLabel "ZnOElectrode"@en ;
+ skos:prefLabel "ZincOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_82fef384_8eec_4765_b707_5397054df594
:electrochemistry_82fef384_8eec_4765_b707_5397054df594 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
@@ -2019,6 +3381,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
] ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a material added to an electrode for the purpose of increasing its electronic conductivity."@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "carbon black"@en ;
skos:altLabel "ElectronicallyConductiveElectrodeAdditive"@en ;
skos:prefLabel "ConductiveAdditive"@en .
@@ -2042,7 +3405,9 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_83ee23b3_2f5c_4afa_b972_ac85e91d7306
:electrochemistry_83ee23b3_2f5c_4afa_b972_ac85e91d7306 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Potential of a platinum electrode in 1 M acid solution."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q115694592" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "potential of a platinum electrode in 1 M acid solution."@en ;
+ rdfs:comment "hydrogen gas at 1 atm pressures is bubbled through the acid solution"@en ;
skos:altLabel "NHE"@en ;
skos:prefLabel "NormalHydrogenElectrode"@en .
@@ -2050,33 +3415,32 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f
:electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ,
- :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ;
- owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
- ] ;
+ :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-38"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "charge during which the electric current is maintained at a constant value regardless of the battery voltage or temperature"@en ;
skos:altLabel "GalvanostaticCharging"@en ;
- skos:prefLabel "ConstantCurrentCharging"@en .
+ skos:prefLabel "ConstantCurrentCharge"@en .
-
-### http://emmo.info/electrochemistry#electrochemistry_852542de_832e_473e_b70c_1d5ec235fc33
-:electrochemistry_852542de_832e_473e_b70c_1d5ec235fc33 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "ChronoMethods"@en .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "charge during which the electric current is maintained at a constant value regardless of the battery voltage or temperature"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f
:electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ;
+ rdfs:subClassOf :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-19" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrolyte on the anode side of an electrochemical cell that is divided into compartments."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrolyte on the anode side of an electrochemical cell that is divided into compartments"@en ;
rdfs:comment "Electrolyte solution in the anodic compartment of an electrolysis cell or galvanic cell, i.e., in that part of the cell where the anode is placed."@en ;
skos:prefLabel "Anolyte"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrolyte on the anode side of an electrochemical cell that is divided into compartments."@en ;
+ owl:annotatedTarget "electrolyte on the anode side of an electrochemical cell that is divided into compartments"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -2090,14 +3454,15 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_86be0987_5e21_43ec_b975_8f679999d328
:electrochemistry_86be0987_5e21_43ec_b975_8f679999d328 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode containing two different metals (e.g. platinum and ruthenium) on its surface (e.g. to modify its electrocatalytic properties)."@en ;
+ rdfs:subClassOf :electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 ,
+ :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode containing two different metals (e.g. platinum and ruthenium) on its surface (e.g. to modify its electrocatalytic properties)"@en ;
skos:prefLabel "BimetallicElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_86be0987_5e21_43ec_b975_8f679999d328 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode containing two different metals (e.g. platinum and ruthenium) on its surface (e.g. to modify its electrocatalytic properties)."@en ;
+ owl:annotatedTarget "electrode containing two different metals (e.g. platinum and ruthenium) on its surface (e.g. to modify its electrocatalytic properties)"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -2106,7 +3471,8 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
:electrochemistry_871bc4a4_2d17_4b88_9b0f_7ab85f14afea rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
owl:disjointWith :electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode whose function is to carry the electric current flowing through the electrical circuit of an electrochemical cell, the electrochemical processes on its surface not being of interest."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1768785" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode whose function is to carry the electric current flowing through the electrical circuit of an electrochemical cell, the electrochemical processes on its surface not being of interest"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Auxiliary_electrode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00535"@en ;
rdfs:comment "An auxiliary electrode is used in any three-electrode cell, together with a working electrode and reference electrode."@en ,
@@ -2117,30 +3483,96 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_871bc4a4_2d17_4b88_9b0f_7ab85f14afea ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode whose function is to carry the electric current flowing through the electrical circuit of an electrochemical cell, the electrochemical processes on its surface not being of interest."@en ;
+ owl:annotatedTarget "electrode whose function is to carry the electric current flowing through the electrical circuit of an electrochemical cell, the electrochemical processes on its surface not being of interest"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
-### http://emmo.info/electrochemistry#electrochemistry_89ff4fa5_142f_49ec_bfe8_117a38648ed8
-:electrochemistry_89ff4fa5_142f_49ec_bfe8_117a38648ed8 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
- skos:prefLabel "MeasuringCell"@en .
+### http://emmo.info/electrochemistry#electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e
+:electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ skos:prefLabel "Spring"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_88100e2c_0f6e_4483_afbf_30029a6702c6
+:electrochemistry_88100e2c_0f6e_4483_afbf_30029a6702c6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 3.1 mm"@en ;
+ skos:prefLabel "R731"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7
+:electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 ,
+ emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q159241" ;
+ emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Direct_current"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electric current that flows in a constant direction, i.e. a current with a constant sign"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Direct_current"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/D01767"@en ;
+ rdfs:comment "I_{DC}"@en ,
+ "The term ‘direct current’ should be used where there is ambiguity concerning the constancy of direction of current. See alternating current."@en ;
+ skos:altLabel "DC"@en ;
+ skos:prefLabel "DirectCurrent"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "electric current that flows in a constant direction, i.e. a current with a constant sign"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_885ffc4d_2b29_42d6_8597_6fc879c21d60
+:electrochemistry_885ffc4d_2b29_42d6_8597_6fc879c21d60 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 3.5 mm"@en ;
+ skos:prefLabel "R2335"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_88d2d4bc_4244_4419_a260_ad099a62d580
+:electrochemistry_88d2d4bc_4244_4419_a260_ad099a62d580 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
+ skos:prefLabel "SulfurElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_8968eb7a_9a65_4286_a596_c31b998df329
+:electrochemistry_8968eb7a_9a65_4286_a596_c31b998df329 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SodiumIronHexacyanoferrateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9
+:electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_314d0bd5_67ed_437e_a609_36d46147cea7 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q36534" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a process that results in the interconversion of chemical species"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Chemical_reaction"@en ;
+ emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.C01033"@en ;
+ skos:prefLabel "ChemicalReaction"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "a process that results in the interconversion of chemical species"@en ;
+ dcterms:source "PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1096"
+ ] .
### http://emmo.info/electrochemistry#electrochemistry_8a5083b0_cd23_4f8c_99e8_b9ccd6f9f3a2
:electrochemistry_8a5083b0_cd23_4f8c_99e8_b9ccd6f9f3a2 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
+ rdfs:subClassOf :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q903563" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-08"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their ion concentrations."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their ion concentrations"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Concentration_cell"@en ;
- rdfs:comment "A concentration cell produces a voltage as it attempts to reach equilibrium, which will occur when the concentration in both cells is equal." ;
+ rdfs:comment "a concentration cell produces a voltage as it attempts to reach equilibrium, which will occur when the concentration in both cells is equal."@en ;
skos:prefLabel "ConcentrationCell"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_8a5083b0_cd23_4f8c_99e8_b9ccd6f9f3a2 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their ion concentrations."@en ;
+ owl:annotatedTarget "electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their ion concentrations"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -2148,6 +3580,8 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_8ab1e656_38ff_48e6_ab09_293d76bc9044
:electrochemistry_8ab1e656_38ff_48e6_ab09_293d76bc9044 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_2480b72b_db8d_460f_9a5f_c2912f979046 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q12385831" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "substance that increases chemical reaction speed, and which is conserved after the reaction"@en ;
skos:prefLabel "Catalyst"@en .
@@ -2158,7 +3592,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
owl:someValuesFrom :electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A gas diffusion electrode in which the gas is air."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a gas diffusion electrode in which the gas is air"@en ;
rdfs:comment "The reaction occuring in an air electrode is typically the oxygen reduction reaction (ORR)."@en ;
skos:prefLabel "AirElectrode"@en .
@@ -2166,6 +3600,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_8ba8ec72_abd0_49eb_a06f_83fe5da108f4
:electrochemistry_8ba8ec72_abd0_49eb_a06f_83fe5da108f4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_3b35e843_3132_41e3_b6df_541cd45ba880 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q939328" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Stripping voltammetry in which material accumulated at the working electrode is electrochemically oxi- dized in the stripping step."@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "A peak-shaped anodic stripping voltammogram is obtained. Peak current depends on time of accumulation, mass transport of analyte (stirring), scan rate and mode (linear or pulse), and analyte concentration in solution."@en ,
@@ -2191,7 +3626,6 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_8ca00b45_5ba6_48a0_aaf6_abd959a7238b
:electrochemistry_8ca00b45_5ba6_48a0_aaf6_abd959a7238b rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ,
- :electrochemistry_40e3bde2_77d6_4251_9781_8f6e6fa7a160 ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
owl:someValuesFrom :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278
@@ -2202,11 +3636,11 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648
+ owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
- owl:someValuesFrom :electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f
+ owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88
] ,
[ rdf:type owl:Restriction ;
owl:onProperty ;
@@ -2216,13 +3650,75 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:onProperty ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which a sinusoidal alternating potential of small amplitude (10 to 50 mV) of constant frequency (10 Hz to 100 kHz) is superimposed on a slowly and linearly varying potential ramp."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120895154" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which a sinusoidal alternating potential of small amplitude (10 to 50 mV) of constant frequency (10 Hz to 100 kHz) is superimposed on a slowly and linearly varying potential ramp"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The resulting alternating current is plotted versus imposed DC potential. The obtained AC voltammogram is peak-shaped."@en ;
skos:altLabel "ACV"@en ;
skos:prefLabel "ACVoltammetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_8d3bf304_78e4_4e99_abe1_6ab429e44ed1
+:electrochemistry_8d3bf304_78e4_4e99_abe1_6ab429e44ed1 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-17"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cell which remains closed and does not release either gas or liquid when operated within the limits specified by the manufacturer"@en ;
+ rdfs:comment "a sealed cell may be equipped with a safety device to prevent a dangerously high internal pressure and is designed to operate during its life in its original sealed state"@en ;
+ skos:prefLabel "SealedCell"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_8d3bf304_78e4_4e99_abe1_6ab429e44ed1 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cell which remains closed and does not release either gas or liquid when operated within the limits specified by the manufacturer"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_8d3bf304_78e4_4e99_abe1_6ab429e44ed1 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "a sealed cell may be equipped with a safety device to prevent a dangerously high internal pressure and is designed to operate during its life in its original sealed state"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_900d95fb_863d_4142_a96d_369fb39e2639
+:electrochemistry_900d95fb_863d_4142_a96d_369fb39e2639 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ owl:disjointWith :electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1326992" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-04"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "capacitor consisting of a metallic plate as first conductor, a very thin oxide film formed on the metal as the dielectric and an electrolyte as second conductor"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrolytic_capacitor"@en ;
+ skos:prefLabel "ElectrolyticCapacitor"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_900d95fb_863d_4142_a96d_369fb39e2639 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "capacitor consisting of a metallic plate as first conductor, a very thin oxide film formed on the metal as the dielectric and an electrolyte as second conductor"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_90103be0_9096_4f98_89c7_b5db01197858
+:electrochemistry_90103be0_9096_4f98_89c7_b5db01197858 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "CalciumInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9017b8b9_e21e_4961_a3c1_c0aeef3fe795
+:electrochemistry_9017b8b9_e21e_4961_a3c1_c0aeef3fe795 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 2.0 mm"@en ;
+ skos:prefLabel "R2020"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9109b3f6_112b_456d_ae45_b82c271c656b
+:electrochemistry_9109b3f6_112b_456d_ae45_b82c271c656b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:altLabel "LMFPElectrode"@en ;
+ skos:prefLabel "LithiumManganeseIronPhosphateElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5
:electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ;
@@ -2235,52 +3731,186 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
owl:someValuesFrom :electrochemistry_212af058_3bbb_419f_a9c6_90ba9ebb3706
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_403c300e_09b9_400b_943b_04e82a3cfb56
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode which consists of an active material coating on one or more sides a current collector substrate."@en ;
- skos:prefLabel "CoatedElectrode"@en .
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-02"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cell electrode consisting of a current collector and active material"@en ;
+ skos:prefLabel "Plate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cell electrode consisting of a current collector and active material"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
-### http://emmo.info/electrochemistry#electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d
-:electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
- owl:someValuesFrom :electrochemistry_15b852b5_19cc_49ab_849f_7df6175fb2be
- ] ,
+### http://emmo.info/electrochemistry#electrochemistry_94209cd8_f68f_40e6_ac70_cfb97a16e593
+:electrochemistry_94209cd8_f68f_40e6_ac70_cfb97a16e593 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 1.3 mm"@en ;
+ skos:prefLabel "R512"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_94497aca_52a0_48e3_9b76_157b050e35b3
+:electrochemistry_94497aca_52a0_48e3_9b76_157b050e35b3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 3.2 mm"@en ;
+ rdfs:comment "very common case for lithim metal cells"@en ;
+ skos:prefLabel "R2032"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_952c8c3a_df21_4dd1_8d8c_380e43dc8c78
+:electrochemistry_952c8c3a_df21_4dd1_8d8c_380e43dc8c78 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
[ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
- owl:someValuesFrom :electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_8f7dd877_5ad0_48f1_bbec_84153d8215f4
] ;
+ skos:prefLabel "AluminiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d
+:electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrochemical cell in which the active materials are flowed through the cell from an external source"@en ;
skos:altLabel "ElectrochemicalFlowCell"@en ;
skos:prefLabel "FlowCell"@en .
+### http://emmo.info/electrochemistry#electrochemistry_96309fa9_e157_48fe_9fda_41003860a3c0
+:electrochemistry_96309fa9_e157_48fe_9fda_41003860a3c0 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q755961" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-18"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "chemiluminescence produced in electrode reactions"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemiluminescence"@en ;
+ skos:altLabel "ECL"@en ,
+ "ElectrogeneratedChemiluminescence"@en ;
+ skos:prefLabel "Electrochemiluminescence"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_96309fa9_e157_48fe_9fda_41003860a3c0 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "chemiluminescence produced in electrode reactions"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_9865e4f9_756d_4d94_a6fd_4102ab795f9e
:electrochemistry_9865e4f9_756d_4d94_a6fd_4102ab795f9e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc ,
:electrochemistry_f07be701_9d6a_415b_ac6d_63202297a7a1 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a discharging process in which the voltage between the terminals of the electrochemical cell is kept at a constant value"@en ;
skos:altLabel "PotentiostaticDischarging"@en ;
- skos:prefLabel "ConstantVoltageDischarging"@en .
+ skos:prefLabel "ConstantVoltageDischarge"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_98d5101e_cd11_4a0d_b856_6fcd8aad132e
+:electrochemistry_98d5101e_cd11_4a0d_b856_6fcd8aad132e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e ;
+ skos:prefLabel "BellevilleWasher"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_990d19b8_672a_4219_a2b3_0a25bfa13f69
+:electrochemistry_990d19b8_672a_4219_a2b3_0a25bfa13f69 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-40" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "extended charge to ensure an equal state of charge of all cells in a battery"@en ;
+ skos:prefLabel "EqualizationCharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_990d19b8_672a_4219_a2b3_0a25bfa13f69 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "extended charge to ensure an equal state of charge of all cells in a battery"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_99475d6c_304c_4d6b_9eca_fbc42f768be5
+:electrochemistry_99475d6c_304c_4d6b_9eca_fbc42f768be5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 30.0 mm and a height of 3.2 mm"@en ;
+ skos:prefLabel "R3032"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_99bdbd45_c3ea_4fb9_ae50_ed1ab6bb1dff
+:electrochemistry_99bdbd45_c3ea_4fb9_ae50_ed1ab6bb1dff rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical method that measures the voltage drop of a cell resulting from a square wave current load"@en ;
+ skos:altLabel "HybridPulsePowerCharacterisation"@en ,
+ "HybridPulsePowerCharacterization"@en ;
+ skos:prefLabel "HPPC"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9a23f61b_fef0_40f8_84f9_2057f90f6a95
+:electrochemistry_9a23f61b_fef0_40f8_84f9_2057f90f6a95 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.3 mm and a height of 3.2 mm"@en ;
+ rdfs:comment "8 of these in series are used to form an A23 battery"@en ,
+ "rarely used independently"@en ;
+ skos:prefLabel "R932"@en .
### http://emmo.info/electrochemistry#electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc
:electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:EMMO_df96cbb6_b5ee_4222_8eab_b3675df24bea
+ ] ;
owl:disjointWith :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ;
- skos:altLabel "ReactiveElectrode" ;
- skos:prefLabel "NonInertElectrode"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode which is chemically altered by the electrode reaction"@en ;
+ rdfs:comment "the opposite of an inert electrode"@en ;
+ skos:altLabel "NonInertElectrode"@en ,
+ "ReactiveElectrode" ;
+ skos:prefLabel "ActiveElectrode"@en .
### http://emmo.info/electrochemistry#electrochemistry_9b6853e7_3412_463d_b5a9_82c14acebf7d
:electrochemistry_9b6853e7_3412_463d_b5a9_82c14acebf7d rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a tank for holding catholyte"@en ;
+ rdfs:comment "usually used in a flow cell system"@en ;
skos:prefLabel "CatholyteTank"@en .
+### http://emmo.info/electrochemistry#electrochemistry_9bc02662_9799_4593_906d_638a841d7352
+:electrochemistry_9bc02662_9799_4593_906d_638a841d7352 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a structural representation of the double layer that states that the accumulation of electric charge on the surface of the electrode is balanced by a layer of ions in the electrolyte"@en ;
+ rdfs:comment "proposed by Hermann von Helmholtz in 1853"@en ,
+ "the first model for the double layer"@en ;
+ skos:prefLabel "HelmholtzModel"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9c0e683b_40d7_4786_b31f_910dd68b2ea8
+:electrochemistry_9c0e683b_40d7_4786_b31f_910dd68b2ea8 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 1.2 mm"@en ;
+ skos:prefLabel "R2012"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_9c73aff8_1c82_4116_a6be_78e21982b69d
:electrochemistry_9c73aff8_1c82_4116_a6be_78e21982b69d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-05"@en ;
+ rdfs:subClassOf :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
+ ] ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-05"@en ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-26"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "interface between an electrolyte and an electrode where an electrode reaction takes place."@en ;
skos:altLabel "ActiveSurfaceOfAnElectrode"@en ;
skos:prefLabel "ElectrodeElectrolyteInterface"@en .
@@ -2293,19 +3923,22 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] .
+### http://emmo.info/electrochemistry#electrochemistry_9ceffffd_b918_48c2_aad9_5db16fa6149d
+:electrochemistry_9ceffffd_b918_48c2_aad9_5db16fa6149d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 2.5 mm"@en ;
+ rdfs:comment "often used in wrist watches and automobile remotes"@en ;
+ skos:prefLabel "R2025"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_9d7e5fea_a49a_4a19_a8de_8e24c60e420c
:electrochemistry_9d7e5fea_a49a_4a19_a8de_8e24c60e420c rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_ad6c76cf_b400_423e_820f_cf0c4e77f455
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_affe07e4_e9bc_4852_86c6_69e26182a17f
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An equation relating the limiting molar conductivity Λ_m^0 (see Kohlrausch's law) to the ionic diffusion coefficients."@en ;
+ rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q9325636" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an equation relating the limiting molar conductivity Λ_m^0 to the ionic diffusion coefficients."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Einstein_relation_(kinetic_theory)#Nernst%E2%80%93Einstein_equation"@en ;
rdfs:comment "\\Lambda_m^0 = (F^2/(R*T)) * (v_{+} * z_{+}^2 * D_{+} + v_{–} * z_{–}^2 * D_{–})"@en ;
+ rdfs:seeAlso "KohlrauschsLaw"@en ;
skos:prefLabel "NernstEinsteinEquation"@en .
@@ -2313,39 +3946,93 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
:electrochemistry_9da958fc_f76d_4654_8a78_99b5f98c118c rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_b9522e56_1fac_4766_97e6_428605fabd3e ,
[ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
] ,
[ rdf:type owl:Restriction ;
- owl:onProperty :electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241 ;
- owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger ;
+ owl:onClass :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A system comprising one electrode in contact with an ionic conductor."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q903509" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system comprising one electrode in contact with an ionic conductor."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Half-cell"@en ;
- skos:altLabel "ElectrochemicalHalfCell" ;
- skos:prefLabel "HalfCell"@en .
+ skos:altLabel "HalfCell"@en ;
+ skos:prefLabel "ElectrochemicalHalfCell"@en .
-### http://emmo.info/electrochemistry#electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275
-:electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A non-polarizable electrode is an electrode that holds its potential essentially constant by efficiently allowing electric current to pass. This is a desirable characteristic for a reference electrode."@en ;
- skos:prefLabel "NonPolarizableElectrode"@en .
+### http://emmo.info/electrochemistry#electrochemistry_9e24d403_8531_416e_a9ec_d1ec5508bcb1
+:electrochemistry_9e24d403_8531_416e_a9ec_d1ec5508bcb1 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_0bdf0bb9_41fc_455d_af11_a249e24acdf6
+ ] ;
+ skos:prefLabel "SodiumCobaltPhosphateElectrode"@en .
-[ rdf:type owl:Axiom ;
+
+### http://emmo.info/electrochemistry#electrochemistry_9ee6e728_e8f5_4b36_a045_d63da69dfc85
+:electrochemistry_9ee6e728_e8f5_4b36_a045_d63da69dfc85 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-44" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "continued charging of a fully charged secondary cell or battery"@en ;
+ rdfs:comment "overcharge is also the act of charging beyond a certain limit specified by the manufacturer"@en ;
+ skos:prefLabel "Overcharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_9ee6e728_e8f5_4b36_a045_d63da69dfc85 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "continued charging of a fully charged secondary cell or battery"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_9ee6e728_e8f5_4b36_a045_d63da69dfc85 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "overcharge is also the act of charging beyond a certain limit specified by the manufacturer"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9f1ffb54_4403_4541_98c1_3a821c6d060f
+:electrochemistry_9f1ffb54_4403_4541_98c1_3a821c6d060f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the process of applying a current pulse"@en ;
+ skos:prefLabel "CurrentPulse"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275
+:electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that holds its potential essentially constant by efficiently allowing electric current to pass"@en ;
+ rdfs:comment "this is a desirable characteristic for a reference electrode" ;
+ skos:prefLabel "NonPolarizableElectrode"@en .
+
+[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A non-polarizable electrode is an electrode that holds its potential essentially constant by efficiently allowing electric current to pass. This is a desirable characteristic for a reference electrode."@en ;
+ owl:annotatedTarget "an electrode that holds its potential essentially constant by efficiently allowing electric current to pass"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29
+:electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q6557456" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that uses a liquid metal"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Liquid_metal_electrode"@en ;
+ rdfs:comment "they can be used in electrocapillarity, voltammetry, and impedance measurements"@en ;
+ skos:prefLabel "LiquidMetalElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0
:electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-09"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode reaction in which oxidation occurs at the anode."@en ;
- rdfs:comment "An electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode reaction in which oxidation occurs at the anode"@en ;
+ rdfs:comment "an electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate"@en ,
+ "electrode reaction involving an electrochemical oxidation"@en ;
skos:altLabel "Electrooxidation"@en ,
"ElectrooxidationReaction"@en ;
skos:prefLabel "AnodicReaction"@en .
@@ -2353,17 +4040,24 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode reaction in which oxidation occurs at the anode."@en ;
+ owl:annotatedTarget "electrode reaction in which oxidation occurs at the anode"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "An electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate."@en ;
+ owl:annotatedTarget "an electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "electrode reaction involving an electrochemical oxidation"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_a05e7945_c942_45cf_812c_c9a595d15888
:electrochemistry_a05e7945_c942_45cf_812c_c9a595d15888 rdf:type owl:Class ;
@@ -2379,24 +4073,83 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543
:electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907475" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-08"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction"@en ;
rdfs:comment "Noble metals, mercury, and carbon are typically used as (nearly) inert electrodes."@en ;
skos:prefLabel "InertElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction."@en ;
+ owl:annotatedTarget "electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069
+:electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-20"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "partial or complete external covering of a cell"@en ;
+ rdfs:comment "a jacket may be made of metal (insulated from the cell terminals), plastic, paper or other suitable material"@en ;
+ skos:prefLabel "Jacket"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "partial or complete external covering of a cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "a jacket may be made of metal (insulated from the cell terminals), plastic, paper or other suitable material"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_a10ede13_c895_4f56_a728_b1aab512b31b
+:electrochemistry_a10ede13_c895_4f56_a728_b1aab512b31b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_9c9ceee7_2470_4d05_89e7_28fb93108e38
+ ] ;
+ rdfs:comment "metal electrode in which the active material is tin"@en ;
+ skos:prefLabel "TinElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c
+:electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-03"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plate in which the active material is applied as a paste to a conductive current collector"@en ;
+ skos:altLabel "CoatedElectrode"@en ;
+ skos:prefLabel "PastedPlate"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "plate in which the active material is applied as a paste to a conductive current collector"@en ;
+ rdfs:comment "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a277e420_2483_44d5_a2bc_4e421dea231a
+:electrochemistry_a277e420_2483_44d5_a2bc_4e421dea231a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 2.6 mm"@en ;
+ skos:altLabel "R57" ;
+ skos:prefLabel "R926"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a2b92d2e_4431_411e_8da5_a4c08bac2c0e
:electrochemistry_a2b92d2e_4431_411e_8da5_a4c08bac2c0e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-17"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Process inside an electrolytic cell used to coat a conductive object with a layer of a material."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "process inside an electrolytic cell used to coat a conductive object with a layer of a material"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electroplating"@en ;
rdfs:comment "The process of depositing a usually thin layer of metal upon a usually metallic substrate (or any other conductor, e.g. graphite), in order to improve the appearance, and/or to change the surface properties of the substrate."@en ;
skos:altLabel "Galvanizing"@en ;
@@ -2405,7 +4158,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a2b92d2e_4431_411e_8da5_a4c08bac2c0e ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Process inside an electrolytic cell used to coat a conductive object with a layer of a material."@en ;
+ owl:annotatedTarget "process inside an electrolytic cell used to coat a conductive object with a layer of a material"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -2417,11 +4170,47 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] .
+### http://emmo.info/electrochemistry#electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a
+:electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-12" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of a cell which permits the flow of gas in one direction only"@en ;
+ rdfs:comment "a valve has a characteristic venting or opening and closing pressure"@en ;
+ skos:prefLabel "Valve"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "component of a cell which permits the flow of gas in one direction only"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "a valve has a characteristic venting or opening and closing pressure"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a3745142_b97a_4e19_b7ed_03599f56e81d
+:electrochemistry_a3745142_b97a_4e19_b7ed_03599f56e81d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_2a540939_3908_4f85_92f9_c46da7d4e9cb
+ ] ;
+ skos:prefLabel "SilverOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841
:electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_8ab1e656_38ff_48e6_ab09_293d76bc9044 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5357962" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-16" ;
+ emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrocatalyst"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material that can cause electrocatalysis."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrocatalyst"@en ;
skos:prefLabel "Electrocatalyst"@en .
[ rdf:type owl:Axiom ;
@@ -2434,8 +4223,13 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e
:electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver."@en ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_e1e6ff98_0725_4d27_ab21_2ca5a95371f0
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q20851418" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver"@en ;
rdfs:comment "Ag electrodes were first used in potentiometry for the determination of Cl−, Br−, I−, as well as for Ag+ ions, to which they are sensitive."@en ;
skos:altLabel "AgElectrode"@en ;
skos:prefLabel "SilverElectrode"@en .
@@ -2443,84 +4237,100 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver."@en ;
+ owl:annotatedTarget "electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_a4e7c3d6_45bd_402a_962f_5d4b88af84ff
+:electrochemistry_a4e7c3d6_45bd_402a_962f_5d4b88af84ff rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 24.5 mm and a height of 1.2 mm"@en ;
+ skos:prefLabel "R2412"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914
:electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 rdf:type owl:Class ;
- owl:equivalentClass [ rdf:type owl:Class ;
- owl:unionOf ( :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0
- :electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6
- )
- ] ;
rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom emmo:EMMO_8043d3c6_a4c1_4089_ba34_9744e28e5b3d
- ] ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-01"@en ,
+ :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120892494" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-01" ,
"https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-01" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A chemical reaction in an electrolyte involving a transfer of electrons between chemical components or between chemical components and an electrode."@en ;
- rdfs:comment "Any process either caused or accompanied by the passage of an electric current and involving in most cases the transfer of electrons between two substances."@en ,
- "Electrochemical reactions occur at electrochemical interfaces."@en ,
- "The electrode reaction can also involve other chemical reactions including subreactions on a cell electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a chemical reaction in an electrolyte involving a transfer of electrons between chemical components or between chemical components and an electrode"@en ;
+ rdfs:comment "any process either caused or accompanied by the passage of an electric current and involving in most cases the transfer of electrons between two substances"@en ,
+ "electrochemical reactions occur at electrochemical interfaces"@en ,
+ "the electrode reaction can also involve other chemical reactions including subreactions on a cell electrode"@en ;
skos:altLabel "ChargeTransferReaction"@en ;
skos:prefLabel "ElectrochemicalReaction"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A chemical reaction in an electrolyte involving a transfer of electrons between chemical components or between chemical components and an electrode."@en ;
+ owl:annotatedTarget "a chemical reaction in an electrolyte involving a transfer of electrons between chemical components or between chemical components and an electrode"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Any process either caused or accompanied by the passage of an electric current and involving in most cases the transfer of electrons between two substances."@en ;
+ owl:annotatedTarget "any process either caused or accompanied by the passage of an electric current and involving in most cases the transfer of electrons between two substances"@en ;
dcterms:source "Bockris, J. O'M. and Despić, . Aleksandar R. (2011, December 15). Electrochemical reaction. Encyclopedia Britannica. https://www.britannica.com/science/electrochemical-reaction"
] .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the electrode reaction can also involve other chemical reactions including subreactions on a cell electrode"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
-### http://emmo.info/electrochemistry#electrochemistry_a8e42b90_7838_460c_8f27_7b5d4238b7a4
-:electrochemistry_a8e42b90_7838_460c_8f27_7b5d4238b7a4 rdf:type owl:Class ;
+### http://emmo.info/electrochemistry#electrochemistry_a76072fe_ca6e_48ad_8b4a_ab98a2bc9abb
+:electrochemistry_a76072fe_ca6e_48ad_8b4a_ab98a2bc9abb rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
- owl:someValuesFrom emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88
+ owl:onProperty emmo:EMMO_5d73661e_e710_4844_ab9b_a85b7e68576a ;
+ owl:someValuesFrom emmo:EMMO_17b031fb_4695_49b6_bb69_189ec63df3ee
] ;
- skos:prefLabel "ElectricCurrentMeasurementResult"@en .
+ skos:prefLabel "VoltageMeasurementResult"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a87d4b9d_ba91_4549_aed4_508d1160c0c0
+:electrochemistry_a87d4b9d_ba91_4549_aed4_508d1160c0c0 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 24.5 mm and a height of 7.7 mm"@en ;
+ skos:prefLabel "R2477"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614
+:electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ skos:prefLabel "RoundElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_a8edd38f_f8a5_41fb_9fc7_48f1866fd699
+:electrochemistry_a8edd38f_f8a5_41fb_9fc7_48f1866fd699 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_250fa43e_1f26_4ed8_b787_91a2325a8e7b
+ ] ;
+ skos:altLabel "CupricOxideElectrode"@en ;
+ skos:prefLabel "CopperOxideElectrode"@en .
### http://emmo.info/electrochemistry#electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f
:electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
- owl:someValuesFrom :electrochemistry_825a749f_dd07_46fb_947c_db286440911e
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
- owl:someValuesFrom :electrochemistry_cf596ea1_c313_4fe1_bd7f_c18afc8a24e3
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q11388109" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-27" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "operation during which a secondary cell or battery is supplied with electric energy from an external circuit which results in chemical changes within the cell and thus the storage of energy as chemical energy."@en ;
skos:altLabel "ElectrochemicalCharging"@en ;
- skos:prefLabel "ChargingProcess"@en .
+ skos:prefLabel "Charge"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
@@ -2541,6 +4351,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:onProperty ;
owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q620700" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which the current is recorded as the electrode potential is varied linearly with time."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Linear_sweep_voltammetry"^^xsd:anyURI ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
@@ -2555,7 +4366,7 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_a9fc3f77_e48e_4bce_b118_044d608722f6
:electrochemistry_a9fc3f77_e48e_4bce_b118_044d608722f6 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
+ rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Measuring instrument for electric current that controls the potential difference between a working electrode and a reference electrode and measures the electric current between a working electrode and an auxiliary electrode."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Potentiostat"@en ;
skos:prefLabel "Potentiostat"@en .
@@ -2568,6 +4379,44 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] .
+### http://emmo.info/electrochemistry#electrochemistry_aa5ed981_c11b_4c4f_b1fd_8c432e009484
+:electrochemistry_aa5ed981_c11b_4c4f_b1fd_8c432e009484 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "describes the double layer as divided into two parts separated by the Stern plane, located about one hydrated ion radius from the electrode surface"@en ;
+ rdfs:comment "proposed by Otto Stern in 1924"@en ;
+ skos:prefLabel "SternModel"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_aaafc5d6_050a_4c51_b1ca_db5839aad4de
+:electrochemistry_aaafc5d6_050a_4c51_b1ca_db5839aad4de rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 24.5 mm and a height of 5.0 mm"@en ;
+ skos:prefLabel "R2450"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69
+:electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-48"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "charging method applied to a secondary battery using two levels of charge rate with feedback control to initiate the changeover from a high to a low charge rate"@en ;
+ skos:prefLabel "TwoStepCharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "charging method applied to a secondary battery using two levels of charge rate with feedback control to initiate the changeover from a high to a low charge rate"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_abffe8cd_14d3_4437_84e6_5dfc61b057e8
+:electrochemistry_abffe8cd_14d3_4437_84e6_5dfc61b057e8 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 4.2 mm"@en ;
+ skos:altLabel "R43" ;
+ skos:prefLabel "R1142"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_ac6c2371_995a_4fcb_89a2_15cb6615741e
:electrochemistry_ac6c2371_995a_4fcb_89a2_15cb6615741e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ,
@@ -2578,15 +4427,8 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_e3850f08_8e79_454b_9d83_c517cab42857 ;
owl:someValuesFrom :electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a cycling protocol in which an electrochemical cell is first put through a CCCV charging process followed by a constant current discharge process"@en ;
skos:prefLabel "CCCVCycling"@en .
@@ -2595,8 +4437,9 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
rdfs:subClassOf emmo:EMMO_d7788d1a_020d_4c78_85a1_13563fcec168 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-19" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "model representing the structure of an electrolyte at an electrode-electrolyte interface by a rigid layer formed by the charge carriers on the surface of the electrode and a diffuse layer formed by mobile ions in the electrolyte."@en ;
- skos:altLabel "ElectricalDoubleLayer"@en ,
- "ElectricalPolarizationLayer"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Double_layer_(surface_science)"@en ;
+ skos:altLabel "ElectricalDoubleLayerModel"@en ,
+ "ElectricalPolarizationLayerModel"@en ;
skos:prefLabel "DoubleLayerModel"@en .
[ rdf:type owl:Axiom ;
@@ -2607,16 +4450,76 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] .
+### http://emmo.info/electrochemistry#electrochemistry_acdeaa89_0e99_4941_8821_d5dea3d34912
+:electrochemistry_acdeaa89_0e99_4941_8821_d5dea3d34912 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-50"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "constant voltage charge where the electric current is limited to a predetermined value"@en ;
+ skos:prefLabel "ModifiedConstantVoltageCharge"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_acdeaa89_0e99_4941_8821_d5dea3d34912 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "constant voltage charge where the electric current is limited to a predetermined value"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e
+:electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-11" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vent of special design which provides protection against the propagation of a flame front from or into the interior of a secondary cell"@en ;
+ rdfs:comment "this flame front may originate from a spark or an external naked flame igniting combustible electrolysis gas"@en ;
+ skos:prefLabel "FlameArrestorVent"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "vent of special design which provides protection against the propagation of a flame front from or into the interior of a secondary cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "this flame front may originate from a spark or an external naked flame igniting combustible electrolysis gas"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_af92a3ae_e870_4676_9ae7_cda277b1e6e1
+:electrochemistry_af92a3ae_e870_4676_9ae7_cda277b1e6e1 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 5.4 mm"@en ;
+ skos:prefLabel "R2354"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_aff732a9_238a_4734_977c_b2ba202af126
:electrochemistry_aff732a9_238a_4734_977c_b2ba202af126 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907518" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=151-13-05" ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-06" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "for a device having two electrodes, that electrode having the higher electric potential"@en ;
+ rdfs:comment "by convention, a reduction reaction occurs during discharge"@en ;
+ skos:altLabel "PositivePlate"@en ;
skos:prefLabel "PositiveElectrode"@en .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_aff732a9_238a_4734_977c_b2ba202af126 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "by convention, a reduction reaction occurs during discharge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1
:electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ rdfs:subClassOf :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5037987" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode of a composite of carbon powder and a pasting liquid (including mineral oil, Nujol, bromoform, bromonaphthalene)."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Carbon_paste_electrode"@en ;
rdfs:comment "The CPE was first described by Adams in 1958. A CPE is typically housed in a Teflon holder, contacted by a conductive wire (occasionally a piston is used to renew the surface by extrusion of the used paste). Problems are long-term stability of the paste and that the binder can influence its properties."@en ,
"These electrodes can easily be chemically modified by the incorporation of reagents (electrocatalysts, redox mediators, complexation agents, enzymes, etc.) and by the attachment of micro- or nanoparticles to prepare electrochemical sensors for analytical applications."@en ;
skos:altLabel "CPE"@en ;
@@ -2630,31 +4533,29 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
] .
+### http://emmo.info/electrochemistry#electrochemistry_b1cf9fee_2164_4f95_8204_90f717373a8a
+:electrochemistry_b1cf9fee_2164_4f95_8204_90f717373a8a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "a round-type case with a height that is greater than or equal to the diameter"@en ;
+ skos:prefLabel "CylindricalCase"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f
:electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Membrane constituted of two or more structural planes of non-identical morphologies."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120965018" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "membrane constituted of two or more structural planes of non-identical morphologies"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.AT06862" ;
skos:prefLabel "AsymmetricMembrane"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Membrane constituted of two or more structural planes of non-identical morphologies."@en ;
+ owl:annotatedTarget "membrane constituted of two or more structural planes of non-identical morphologies"@en ;
dcterms:source "IUPAC. Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook."
] .
-### http://emmo.info/electrochemistry#electrochemistry_b2e7fd5d_6eec_41a7_a621_51aff19c3114
-:electrochemistry_b2e7fd5d_6eec_41a7_a621_51aff19c3114 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
- owl:someValuesFrom emmo:EMMO_0adabf6f_7404_44cb_9f65_32d83d8101a3
- ] ;
- skos:prefLabel "TimeMeasurementResult"@en .
-
-
### http://emmo.info/electrochemistry#electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e
:electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
@@ -2663,17 +4564,42 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom emmo:EMMO_cde4368c_1d4d_4c94_8548_604749523c6d
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Measurement principle in which the electric conductivity of a solution is measured."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q901180" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement principle in which the electric conductivity of a solution is measured"@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Monitoring of the purity of deionized water."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Conductometry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The conductivity of a solution depends on the concentration and nature of ions present."@en ;
skos:prefLabel "Conductometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90
+:electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q189673" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-08" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "process where molecules split up into ions due to being dissolved"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Dissociation_(chemistry)"@en ;
+ skos:prefLabel "Dissociation"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "process where molecules split up into ions due to being dissolved"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2
:electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry in which small potential pulses (constant height 10 to 100 mV, constant width 10 to 100 ms) are superimposed onto a linearly varying potential or onto a staircase potential ramp. The current is sampled just before the onset of the pulse (e.g. 10 to 20 ms) and for the same sampling time just before the end of the pulse. The difference between the two sampled currents is plotted versus the potential applied before the pulse. Thus, a differential pulse voltammogram is peak-shaped."@en ;
+ rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5275361" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which small potential pulses (constant height 10 to 100 mV, constant width 10 to 100 ms) are superimposed onto a linearly varying potential or onto a staircase potential ramp. The current is sampled just before the onset of the pulse (e.g. 10 to 20 ms) and for the same sampling time just before the end of the pulse. The difference between the two sampled currents is plotted versus the potential applied before the pulse. Thus, a differential pulse voltammogram is peak-shaped"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Differential_pulse_voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Differential pulse polarography is differential pulse voltammetry in which a dropping mercury electrode is used as the working electrode. A pulse is applied before the mechani- cally enforced end of the drop and the current is sampled twice: just before the onset of the pulse and just before its end. The pulse width is usually 10 to 20 % of the drop life. The drop dislodgement is synchronized with current sampling, which is carried out as in DPV."@en ,
"The ratio of faradaic current to charging current is enhanced and the negative influence of charging current is partially eliminated in the same way as in normal pulse voltammetry (NPV). Moreover, subtraction of the charging current sampled before the application of the pulse further decreases its negative influence. Due to the more enhanced signal (faradaic current) to noise (charging current) ratio, the limit of detection is lower than with NPV."@en ,
@@ -2682,10 +4608,29 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
skos:prefLabel "DifferentialPulseVoltammetry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_b3eb8c65_5644_45e3_9e17_0be6277c7962
+:electrochemistry_b3eb8c65_5644_45e3_9e17_0be6277c7962 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_3ac62305_acd6_4312_9e31_4f824bd2530d
+ ] ;
+ skos:altLabel "NMCElectrode"@en ;
+ skos:prefLabel "LithiumNickelManganeseCobaltOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_b442217f_02f6_4991_aadf_22d81369223c
+:electrochemistry_b442217f_02f6_4991_aadf_22d81369223c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 3.1 mm"@en ;
+ skos:altLabel "R54" ;
+ skos:prefLabel "R1131"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b5039bc8_f595_4797_908a_7e86131fbde4
:electrochemistry_b5039bc8_f595_4797_908a_7e86131fbde4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential. The time between changes in potential in step 2 is related to the concentration of analyte in the solution."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential. The time between changes in potential in step 2 is related to the concentration of analyte in the solution"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Historically for the analysis of metal ions, mercury ions were added to the test solution to form a mercury amalgam when reduced. Alternatively, an HMDE or MFE was used and the oxidizing agent added after amalgam formation. However, the toxicity of mercury and its compounds have all but precluded the present-day use of mercury."@en ,
"The accumulation is similar to that used in stripping voltammetry."@en ,
@@ -2696,8 +4641,8 @@ Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous s
### http://emmo.info/electrochemistry#electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686
:electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An electrochemical cell for conductivity measurements."@en ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrochemical cell for conductivity measurements"@en ;
rdfs:comment """Formed, in theory, by two 1 cm2 reversible electrodes spaced 1 cm apart, providing a uniform distribution of electrical field. In practice, however, a number
of other configurations are used."""@en ;
skos:prefLabel "ConductivityCell"@en .
@@ -2705,33 +4650,79 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "An electrochemical cell for conductivity measurements."@en ;
+ owl:annotatedTarget "an electrochemical cell for conductivity measurements"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: http://doi.org/10.1007/978-3-642-29551-5"
] .
+### http://emmo.info/electrochemistry#electrochemistry_b56a95e6_eea5_4a58_99aa_045fd28e75d3
+:electrochemistry_b56a95e6_eea5_4a58_99aa_045fd28e75d3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 2.7 mm"@en ;
+ skos:altLabel "R64" ;
+ skos:prefLabel "R527"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_b5e91259_cd97_4ed6_9ab2_4b18ef68a35a
+:electrochemistry_b5e91259_cd97_4ed6_9ab2_4b18ef68a35a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "LithiumVanadiumOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82
:electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_ceaaf9f7_fd11_424b_8fda_9afa186af186 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A constituent in an electrochemical system."@en ;
+ rdfs:comment "a constituent is essential to the functioning of the system and cannot be replaced by a comparable thing without altering the behaviour of the system" ;
skos:prefLabel "ElectrochemicalConstituent"@en .
### http://emmo.info/electrochemistry#electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302
:electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-27" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Anode"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "by convention, cell electrode at which an oxidation reaction occurs"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Anode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00370"@en ;
- rdfs:comment "At an anode, electrons are produced in a galvanic cell or extracted in an electrolytic cell."@en ,
- "The concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes."@en ;
+ rdfs:comment "at an anode, electrons are produced in a galvanic cell or extracted in an electrolytic cell"@en ,
+ "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation"@en ,
+ "the anode is the negative electrode during discharge and the positive electrode during charge"@en ,
+ "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ;
skos:prefLabel "Anode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation."@en ;
+ owl:annotatedTarget "by convention, cell electrode at which an oxidation reaction occurs"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "at an anode, electrons are produced in a galvanic cell or extracted in an electrolytic cell"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the anode is the negative electrode during discharge and the positive electrode during charge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -2739,7 +4730,8 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_b76a778f_253f_4210_a67f_fb6444d0de26
:electrochemistry_b76a778f_253f_4210_a67f_fb6444d0de26 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Mercury electrode formed by sequence of mercury drops falling from a small aperture."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q962292" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "mercury electrode formed by sequence of mercury drops falling from a small aperture"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Dropping_mercury_electrode"@en ;
rdfs:comment "Other kinds of mercury drop electrodes are the static mercury drop electrode (SMDE), in which a drop is held at constant radius before being mechanically knocked off, and the hanging mercury drop elec- trode (HMDE), in which the whole experiment is performed on a single drop of mercury."@en ,
"The DME was introduced by Jaroslav Heyrovský (1890 – 1967). A drop is renewed every few seconds. Many metals amalgamate with mercury so that in the analysis of metal ions in aqueous solution the DME maintains a fresh surface throughout."@en ;
@@ -2749,53 +4741,106 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b76a778f_253f_4210_a67f_fb6444d0de26 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Mercury electrode formed by sequence of mercury drops falling from a small aperture."@en ;
+ owl:annotatedTarget "mercury electrode formed by sequence of mercury drops falling from a small aperture"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_b79d4f9e_5727_4895_8d7f_5fc18d83eb90
+:electrochemistry_b79d4f9e_5727_4895_8d7f_5fc18d83eb90 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_f47611a2_e081_47f0_b287_3fda5f706154 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-07" ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-13" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an unwanted side reaction"@en ;
+ rdfs:comment "in a galvanic cell, parasitic reactions may cause inefficiencies or loss of performance"@en ;
+ skos:prefLabel "ParasiticReaction"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b79d4f9e_5727_4895_8d7f_5fc18d83eb90 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "an unwanted side reaction"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b79d4f9e_5727_4895_8d7f_5fc18d83eb90 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "in a galvanic cell, parasitic reactions may cause inefficiencies or loss of performance"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a
:electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ,
emmo:EMMO_5cb107ba_7daa_46dd_8f9f_da22a6eac676 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120906632" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Aqueous_solution"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An ion-transport medium, which may be immobilized, in which water is the solvent."@en ;
- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Aqueous_solution"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an ion-transport medium, which may be immobilized, in which water is the solvent."@en ;
skos:altLabel "AqueousElectrolyticSolution"@en ;
skos:prefLabel "AqueousElectrolyte"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "An ion-transport medium, which may be immobilized, in which water is the solvent."@en ;
+ owl:annotatedTarget "an ion-transport medium, which may be immobilized, in which water is the solvent."@en ;
dcterms:source "IEEE Standard Glossary of Stationary Battery Terminology (2016), https://doi.org/10.1109/IEEESTD.2016.7552407"
] .
-### http://emmo.info/electrochemistry#electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66
-:electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-03"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Device that stores electrical energy using a double layer in an electrochemical cell."@en ;
- skos:altLabel "Supercapacitor"@en ;
- skos:prefLabel "ElectrochemicalCapacitor"@en .
+### http://emmo.info/electrochemistry#electrochemistry_b851c7e9_60bf_4d3d_abe1_8d08d3d85124
+:electrochemistry_b851c7e9_60bf_4d3d_abe1_8d08d3d85124 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-24" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "accessible conductive part provided for the connection of an external electric circuit to the negative electrode of the cell"@en ;
+ skos:prefLabel "NegativeTerminal"@en .
[ rdf:type owl:Axiom ;
- owl:annotatedSource :electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66 ;
+ owl:annotatedSource :electrochemistry_b851c7e9_60bf_4d3d_abe1_8d08d3d85124 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Device that stores electrical energy using a double layer in an electrochemical cell."@en ;
+ owl:annotatedTarget "accessible conductive part provided for the connection of an external electric circuit to the negative electrode of the cell"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
-### http://emmo.info/electrochemistry#electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74
-:electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ,
+### http://emmo.info/electrochemistry#electrochemistry_b8dc138f_8024_4f15_8350_192425d23a4d
+:electrochemistry_b8dc138f_8024_4f15_8350_192425d23a4d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f92b3948_72a5_4662_acf7_5d8dd64e85de
+ ] ;
+ skos:altLabel "metal electrode in which the active material is nickel"@en ;
+ skos:prefLabel "NickelElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66
+:electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f ;
+ owl:disjointWith :electrochemistry_ca0527c1_f682_4eea_aca5_f3ae66a9ddce ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Device that stores electrical energy using a double layer in an electrochemical cell."@en ;
+ rdfs:comment "stores energy electrostatically in the Helmholtz Layer"@en ;
+ skos:altLabel "DoubleLayerCapacitor"@en ,
+ "EDLC"@en ,
+ "ElectrochemicalCapacitor"@en ;
+ skos:prefLabel "ElectrochemicalDoubleLayerCapacitor"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "Device that stores electrical energy using a double layer in an electrochemical cell."@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74
+:electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ,
[ rdf:type owl:Restriction ;
owl:onProperty :electrochemistry_5eb197ea_0c3e_4ea2_8392_81152ee91515 ;
- owl:someValuesFrom :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29
+ owl:someValuesFrom :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical cell with a working electrode, reference electrode, and auxiliary electrode."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell with a working electrode, reference electrode, and auxiliary electrode"@en ;
rdfs:comment "A potentiostat can be used to maintain a potential difference between the working and ref- erence electrodes."@en ,
"Electric current flows between the working and auxiliary electrodes. Electrode potential may be measured between the working and reference electrodes."@en ;
skos:altLabel "ThreeElectrodeElectrochemicalCell" ;
@@ -2804,11 +4849,34 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical cell with a working electrode, reference electrode, and auxiliary electrode."@en ;
+ owl:annotatedTarget "electrochemical cell with a working electrode, reference electrode, and auxiliary electrode"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_bb2faf17_b819_4876_b17f_fa82917cf85d
+:electrochemistry_bb2faf17_b819_4876_b17f_fa82917cf85d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 7.9 mm and a height of 1.3 mm"@en ;
+ skos:prefLabel "R712"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_bb710d71_98fa_48a1_85bc_d8f1ef2200da
+:electrochemistry_bb710d71_98fa_48a1_85bc_d8f1ef2200da rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_aa8e9cc4_5f66_4307_b1c8_26fac7653a90
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f3e7979a_e3ef_450a_8762_7d8778afe478
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended lithium nickel manganese oxide (LNMO) and lithium iron phosphate (LFP) active materials"@en ;
+ skos:altLabel "LNMOLFPElectrode"@en ;
+ skos:prefLabel "LithiumNickelManganeseOxideLithiumIronPhosphateElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215
:electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_3663991d-9319-4f7a-922b-f0e428b58801 ,
@@ -2817,7 +4885,9 @@ of other configurations are used."""@en ;
owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
owl:someValuesFrom :electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A type of electrode specifically designed for gaseous reactants or products or both."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q909759" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-02" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a type of electrode specifically designed for gaseous reactants or products or both"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Gas_diffusion_electrode"@en ;
rdfs:comment "A gas diffusion electrode usually comprises one or more porous layers, like the gas diffusion layer and the catalyst layer."@en ,
"Gas diffusion electrodes can be gas diffusion anodes or gas diffusion cathodes."@en ,
@@ -2828,7 +4898,22 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A type of electrode specifically designed for gaseous reactants or products or both."@en ;
+ owl:annotatedTarget "a type of electrode specifically designed for gaseous reactants or products or both"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_bbc77932_643b_4603_a4e8_970ef06a76ad
+:electrochemistry_bbc77932_643b_4603_a4e8_970ef06a76ad rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-19"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "part which insures insulation between the plate (electrode) edges and adjacent plates (electrodes) and the container side walls"@en ;
+ skos:prefLabel "EdgeInsulator"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_bbc77932_643b_4603_a4e8_970ef06a76ad ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "part which insures insulation between the plate (electrode) edges and adjacent plates (electrodes) and the container side walls"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -2836,24 +4921,30 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_bd33779c_6f40_4354_ab5d_f6c17396414d
:electrochemistry_bd33779c_6f40_4354_ab5d_f6c17396414d rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q180253"@en ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-05"@en ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Fuel_cell"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Galvanic cell that transforms chemical energy from continuously supplied reactants to electric energy by an electrochemical process."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "galvanic cell that transforms chemical energy from continuously supplied reactants to electric energy by an electrochemical process."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Fuel_cell"@en ;
skos:prefLabel "FuelCell"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_bd33779c_6f40_4354_ab5d_f6c17396414d ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Galvanic cell that transforms chemical energy from continuously supplied reactants to electric energy by an electrochemical process."@en ;
+ owl:annotatedTarget "galvanic cell that transforms chemical energy from continuously supplied reactants to electric energy by an electrochemical process."@en ;
rdfs:comment "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
### http://emmo.info/electrochemistry#electrochemistry_bea04148_10d9_4eda_9cd5_8f609d7e9ff8
:electrochemistry_bea04148_10d9_4eda_9cd5_8f609d7e9ff8 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ;
- skos:prefLabel "TemperatureMeasurement"@en .
+ rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_c4bace1d_4db0_4cd3_87e9_18122bae2840 ;
+ owl:someValuesFrom :electrochemistry_2dea31c2_5061_4464_ab76_5336bef23629
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of temperature"@en ;
+ skos:prefLabel "CelsiusTemperatureMeasurement"@en .
### http://emmo.info/electrochemistry#electrochemistry_bed5b5f9_b89d_45e3_a8c2_81b70ae21847
@@ -2877,20 +4968,67 @@ of other configurations are used."""@en ;
skos:prefLabel "StrippingChronopotentiometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_c05692eb_ae92_4e03_b355_f259f9089cb8
+:electrochemistry_c05692eb_ae92_4e03_b355_f259f9089cb8 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-52" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "device used to assist in the measurement of the level of electrolyte in a cell"@en ;
+ skos:prefLabel "ElectrolyteLevelIndicator"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c05692eb_ae92_4e03_b355_f259f9089cb8 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "device used to assist in the measurement of the level of electrolyte in a cell"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c14ae9b3_e4ba_4129_a7b6_afd2d4571de6
+:electrochemistry_c14ae9b3_e4ba_4129_a7b6_afd2d4571de6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-01" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "permanently sealed gas tight cell without pressure release device"@en ;
+ skos:prefLabel "HermeticallySealedCell"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c14ae9b3_e4ba_4129_a7b6_afd2d4571de6 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "permanently sealed gas tight cell without pressure release device"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c183f697_8995_477c_9ccd_5c12d98e3633
+:electrochemistry_c183f697_8995_477c_9ccd_5c12d98e3633 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "PotassiumInsertionElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_c2024587_3237_474e_8df9_91d10db2df47
:electrochemistry_c2024587_3237_474e_8df9_91d10db2df47 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode whose potential changes with an applied potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode whose potential changes with an applied potential"@en ;
skos:prefLabel "PolarizableElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c2024587_3237_474e_8df9_91d10db2df47 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode whose potential changes with an applied potential."@en ;
+ owl:annotatedTarget "electrode whose potential changes with an applied potential"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_c231227b_f318_4e59_ad90_6e91072903ed
+:electrochemistry_c231227b_f318_4e59_ad90_6e91072903ed rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_e8fafdc8_6cd3_4dd0_9630_10ca8e3f1827
+ ] ;
+ skos:altLabel "LMOElectrode"@en ;
+ skos:prefLabel "LithiumManganeseOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_c3f4b34a_0e2c_46f3_baab_4ebd2682d26f
:electrochemistry_c3f4b34a_0e2c_46f3_baab_4ebd2682d26f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ;
@@ -2912,14 +5050,126 @@ of other configurations are used."""@en ;
:electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-16"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Platinized platinum electrode saturated by a stream of pure gaseous hydrogen."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "platinized platinum electrode saturated by a stream of pure gaseous hydrogen"@en ;
rdfs:comment "A platinized platinum electrode consists of a platinum rod covered by compact platinum powder called platinum black."@en ;
skos:prefLabel "HydrogenElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Platinized platinum electrode saturated by a stream of pure gaseous hydrogen."@en ;
+ owl:annotatedTarget "platinized platinum electrode saturated by a stream of pure gaseous hydrogen"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c55ec02c_b727_4df1_97ce_91d7bb5d5e91
+:electrochemistry_c55ec02c_b727_4df1_97ce_91d7bb5d5e91 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-32" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "unplanned escape of electrolyte, gas or other material from a cell or battery"@en ;
+ skos:prefLabel "Leakage"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c55ec02c_b727_4df1_97ce_91d7bb5d5e91 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "unplanned escape of electrolyte, gas or other material from a cell or battery"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c5f51531_1452_4654_82e5_0505491c2c7d
+:electrochemistry_c5f51531_1452_4654_82e5_0505491c2c7d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SodiumTitaniumOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c5fd7b61_40f1_4225_a173_5caa3c5f4773
+:electrochemistry_c5fd7b61_40f1_4225_a173_5caa3c5f4773 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_859210f4_f4ac_445d_841c_74e3fbe74c3e
+ ] ;
+ skos:prefLabel "TungstenElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c610d869_cc03_44f0_b40d_ca86e945b9c9
+:electrochemistry_c610d869_cc03_44f0_b40d_ca86e945b9c9 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-16" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cell from which electrolyte cannot escape regardless of its orientation"@en ;
+ rdfs:comment "some vented cells or batteries are designed so as to be non-spillable when operated within the limits specified by the manufacturer"@en ;
+ skos:prefLabel "NonSpillableCell"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c610d869_cc03_44f0_b40d_ca86e945b9c9 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "cell from which electrolyte cannot escape regardless of its orientation"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c610d869_cc03_44f0_b40d_ca86e945b9c9 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "some vented cells or batteries are designed so as to be non-spillable when operated within the limits specified by the manufacturer"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c63baed9_48dd_4b5c_9e8c_03011010ffb6
+:electrochemistry_c63baed9_48dd_4b5c_9e8c_03011010ffb6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_2a87ca10_fc6a_4d61_b48c_d9790a566ee3
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_db74b6b7_09fc_40db_a7d5_6eb86b69192a
+ ] ;
+ skos:altLabel "ITO"@en ;
+ skos:prefLabel "IndiumTinOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c831d963_629a_41ab_850f_97fb6841b739
+:electrochemistry_c831d963_629a_41ab_850f_97fb6841b739 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d53259a7_0d9c_48b9_a6c1_4418169df303
+ ] ;
+ skos:prefLabel "GraphiteElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c91164b8_5e56_4c94_bad1_d7ada576b0e7
+:electrochemistry_c91164b8_5e56_4c94_bad1_d7ada576b0e7 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_22522299_4091_4d1f_82a2_3890492df6db ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-45" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "test carried out to measure the loss of capacity, open-circuit voltage, short-circuit current or other quantities after storage under specified conditions"@en ;
+ skos:prefLabel "StorageTest"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c91164b8_5e56_4c94_bad1_d7ada576b0e7 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "test carried out to measure the loss of capacity, open-circuit voltage, short-circuit current or other quantities after storage under specified conditions"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_c936bfbe_7a0c_4185_a317_db1ce2c3c38c
+:electrochemistry_c936bfbe_7a0c_4185_a317_db1ce2c3c38c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e ,
+ :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "electrochemical immunity produced by an appropriate cathodic polarization."@en ,
+ "https://www.wikidata.org/wiki/Q15152527" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-05" ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Cathodic_protection"@en ;
+ skos:prefLabel "CathodicProtection"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c936bfbe_7a0c_4185_a317_db1ce2c3c38c ;
+ owl:annotatedProperty emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 ;
+ owl:annotatedTarget "electrochemical immunity produced by an appropriate cathodic polarization."@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -2927,94 +5177,220 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_c94c041b_8ea6_43e7_85cc_d2bce7785b4c
:electrochemistry_c94c041b_8ea6_43e7_85cc_d2bce7785b4c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=151-13-04" ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "for a device having two electrodes, that electrode having the lower electric potential."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907506" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=151-13-04" ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-05" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "for a device having two electrodes, that electrode having the lower electric potential"@en ;
+ rdfs:comment "by convention, an oxidation reaction occurs during discharge"@en ;
+ skos:altLabel "NegativePlate"@en ;
skos:prefLabel "NegativeElectrode"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_c94c041b_8ea6_43e7_85cc_d2bce7785b4c ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "for a device having two electrodes, that electrode having the lower electric potential."@en ;
+ owl:annotatedTarget "for a device having two electrodes, that electrode having the lower electric potential"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_c94c041b_8ea6_43e7_85cc_d2bce7785b4c ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "by convention, an oxidation reaction occurs during discharge"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ca0527c1_f682_4eea_aca5_f3ae66a9ddce
+:electrochemistry_ca0527c1_f682_4eea_aca5_f3ae66a9ddce rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q7254569" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a type of supercapacitor that uses metal oxide or conducting polymer electrodes with a high amount of electrochemical pseudocapacitance additional to the double-layer capacitance"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Pseudocapacitor"@en ;
+ rdfs:comment "stores energy electrochemically via Faradaic mechanisms"@en ;
+ skos:prefLabel "ElectrochemicalPseudocapacitor"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ca48d41c_f5ea_4bf8_84ce_2d67fd9dad98
+:electrochemistry_ca48d41c_f5ea_4bf8_84ce_2d67fd9dad98 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vector containing at least two values for the quantity cycle number"@en ;
+ skos:prefLabel "CycleNumberVector"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ca4d9efc_70be_441e_b358_d927aa4c36c4
+:electrochemistry_ca4d9efc_70be_441e_b358_d927aa4c36c4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_dcdbdbed_2e20_40d1_a7a5_5761de7f0618
+ ] ;
+ skos:altLabel "MnO2Electrode"@en ;
+ skos:prefLabel "ManganeseDioxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cab66388_3feb_4101_82bc_f4441f0b60e3
+:electrochemistry_cab66388_3feb_4101_82bc_f4441f0b60e3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_c28a0967_ed23_48cc_a14e_a651d75a19db
+ ] ;
+ skos:altLabel "LNOElectrode"@en ;
+ skos:prefLabel "LithiumNickelOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cb223440_51bd_4f16_a536_96ec408e7de4
+:electrochemistry_cb223440_51bd_4f16_a536_96ec408e7de4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ;
+ skos:prefLabel "FormationCycling"@en .
+
### http://emmo.info/electrochemistry#electrochemistry_cb3c0663_5962_4b79_8e72_1e8242af3977
:electrochemistry_cb3c0663_5962_4b79_8e72_1e8242af3977 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ;
- owl:someValuesFrom :electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef
- ] ,
+ :electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6 ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
owl:someValuesFrom :electrochemistry_825a749f_dd07_46fb_947c_db286440911e
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
- owl:someValuesFrom :electrochemistry_cf596ea1_c313_4fe1_bd7f_c18afc8a24e3
] ;
skos:altLabel "OCVHold"@en ;
skos:prefLabel "OpenCircuitHold"@en .
-### http://emmo.info/electrochemistry#electrochemistry_cf596ea1_c313_4fe1_bd7f_c18afc8a24e3
-:electrochemistry_cf596ea1_c313_4fe1_bd7f_c18afc8a24e3 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_158ae038_c64b_4cc0_aa56_650475490705 ,
+### http://emmo.info/electrochemistry#electrochemistry_cba03815_eaa8_493d_b9e4_52856b57fde6
+:electrochemistry_cba03815_eaa8_493d_b9e4_52856b57fde6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
- owl:someValuesFrom :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f7525766_90cf_43e9_8932_7cb3b14f676f
] ;
- skos:prefLabel "CellCurrentMeasurement"@en .
+ skos:altLabel "IrO2Electrode"@en ;
+ skos:prefLabel "IridiumOxideElectrode"@en .
-### http://emmo.info/electrochemistry#electrochemistry_d1042a12_e4be_4992_86cb_59420ef4e05c
-:electrochemistry_d1042a12_e4be_4992_86cb_59420ef4e05c rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
+### http://emmo.info/electrochemistry#electrochemistry_cc0468a2_1851_4d3d_92a6_b4059db0c056
+:electrochemistry_cc0468a2_1851_4d3d_92a6_b4059db0c056 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
[ rdf:type owl:Restriction ;
- owl:onProperty [ owl:inverseOf emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a
- ] ;
- owl:someValuesFrom :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_b01771a9_218a_4b01_b20f_4021cfa0b7d5
] ;
+ skos:prefLabel "SodiumManganesePhosphateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cc1f854a_ba6c_436e_bd18_c8b9159bbf52
+:electrochemistry_cc1f854a_ba6c_436e_bd18_c8b9159bbf52 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-23" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component fitted into the filling hole of a cell with a provision of allowing the venting of electrolysis gas from the cell¨"@en ;
+ skos:prefLabel "VentCap"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_cc1f854a_ba6c_436e_bd18_c8b9159bbf52 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "component fitted into the filling hole of a cell with a provision of allowing the venting of electrolysis gas from the cell¨"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cc4e178c_bc1f_4502_b6c2_33f304ef6bab
+:electrochemistry_cc4e178c_bc1f_4502_b6c2_33f304ef6bab rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_89fd13e8_8061_41da_83f4_634144116425
+ ] ;
+ skos:prefLabel "IronElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ce4352a7_f0b1_4f27_9184_6deebf8bbe96
+:electrochemistry_ce4352a7_f0b1_4f27_9184_6deebf8bbe96 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 15.8 mm and a height of 11.1 mm"@en ;
+ skos:altLabel "R52"@en ;
+ skos:prefLabel "R1511"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cf6eebea_24f6_48d2_8389_65eba0393762
+:electrochemistry_cf6eebea_24f6_48d2_8389_65eba0393762 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 2.6 mm"@en ;
+ skos:altLabel "R56" ;
+ skos:prefLabel "R1126"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_cff80dd5_19a9_4357_8fb9_410a978153e2
+:electrochemistry_cff80dd5_19a9_4357_8fb9_410a978153e2 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ;
+ skos:prefLabel "SodiumTitaniumPhosphateElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d0a26dc2_fde9_4a11_ac26_7c18499d28a5
+:electrochemistry_d0a26dc2_fde9_4a11_ac26_7c18499d28a5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_9bd78e1c_a4dc_41b6_8013_adb51df1ffdc
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "metal electrode in which the active material is zinc"@en ;
+ skos:prefLabel "ZincElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d1042a12_e4be_4992_86cb_59420ef4e05c
+:electrochemistry_d1042a12_e4be_4992_86cb_59420ef4e05c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q865807" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a generic denomination of particles or quasiparticles responsible for electric charge transport."@en ;
emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "electron, hole, ion"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Charge_carrier"@en ;
skos:prefLabel "ChargeCarrier"@en .
### http://emmo.info/electrochemistry#electrochemistry_d11b0e66_c35b_4da7_80a1_037ce89b77fb
:electrochemistry_d11b0e66_c35b_4da7_80a1_037ce89b77fb rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 ;
+ rdfs:subClassOf :electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a separator is composed of a mass of intermeshed glass fibers."@en ;
+ skos:altLabel "FibreglassSeparator"@en ;
skos:prefLabel "GlassFibreSeparator"@en .
### http://emmo.info/electrochemistry#electrochemistry_d16eec87_c646_4566_bda6_7d3357cda061
:electrochemistry_d16eec87_c646_4566_bda6_7d3357cda061 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An interfacial layer of an electrode surface, that causes the electrode to become passivated."@en ;
+ rdfs:subClassOf :electrochemistry_09a7f560_9ddf_4c32_b067_b213eca5b0a1 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an interfacial layer of an electrode surface, that causes the electrode to become passivated"@en ;
skos:prefLabel "PassivationLayer"@en .
-### http://emmo.info/electrochemistry#electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672
-:electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_07ad0aff_ab59_442d_9c0a_7f8c5cba8982 ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_666f0b69_9c74_49a3_80b3_96a188332462
- ] ,
+### http://emmo.info/electrochemistry#electrochemistry_d2726dd5_69f0_4cb1_bd3c_4c48813e57e7
+:electrochemistry_d2726dd5_69f0_4cb1_bd3c_4c48813e57e7 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ,
[ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom :electrochemistry_b66d6553_6136_4754_902a_707e414210c2
- ] ,
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_c728b6b9_449a_45ff_b5ae_6b7968708f0d
+ ] ;
+ skos:prefLabel "IronDisulfideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d2f6f1a6_4dee_4c5e_9a69_32b9fe990d2f
+:electrochemistry_d2f6f1a6_4dee_4c5e_9a69_32b9fe990d2f rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_1cba0b27_15d0_4326_933f_379d0b3565b6 ,
[ rdf:type owl:Restriction ;
- owl:onProperty ;
- owl:someValuesFrom
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_ca48d41c_f5ea_4bf8_84ce_2d67fd9dad98
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a series of data points indexed in cycle order"@en ;
+ skos:prefLabel "CycleDomainMatrix"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672
+:electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_07ad0aff_ab59_442d_9c0a_7f8c5cba8982 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3492904"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Impedimetric sensors are based on measurement of a concentration-dependent parameter taken from analysis of the respective electrochemical impedance spectra, or from the impedance magnitudes at a chosen fixed frequency."@en ,
"The sinusoidal current response lags behind the sinusoidal voltage perturbation by a phase angle φ. Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. Complex plane plots are the more commonly used for electrochemical sensors."@en ;
@@ -3025,6 +5401,10 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69
:electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
+ ] ,
[ rdf:type owl:Restriction ;
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
owl:someValuesFrom :electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc
@@ -3033,10 +5413,15 @@ of other configurations are used."""@en ;
owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
owl:someValuesFrom :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f
] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5074261" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-28" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "set of operations that is carried out on a secondary cell or battery and is repeated regularly in the same sequence."@en ;
- skos:altLabel "ElectrochemicalCycling"@en ;
- skos:prefLabel "CyclingProcess"@en .
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Charge_cycle"@en ;
+ rdfs:comment "in a secondary battery these operations may consist of a sequence of a discharge followed by a charge or a charge followed by a discharge under specified conditions"@en ,
+ "this sequence may include rest periods"@en ;
+ skos:altLabel "ChargeCycle"@en ,
+ "ElectrochemicalCycling"@en ;
+ skos:prefLabel "Cycling"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ;
@@ -3045,19 +5430,27 @@ of other configurations are used."""@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "in a secondary battery these operations may consist of a sequence of a discharge followed by a charge or a charge followed by a discharge under specified conditions"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "this sequence may include rest periods"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_d48ea516_5cac_4f86_bc88_21b6276c0938
:electrochemistry_d48ea516_5cac_4f86_bc88_21b6276c0938 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_ad6c76cf_b400_423e_820f_cf0c4e77f455
- ] ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_affe07e4_e9bc_4852_86c6_69e26182a17f
- ] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The standard phenomenological model for electrode kinetics, describing the relation between the electrode current from an electrochemical charge-transfer reaction and the surface overpotential of the electrode."@en ;
+ rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q903846" ;
+ emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Butler%E2%80%93Volmer_equation"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a phenomenological model for electrode kinetics, describing the relation between the electrode current from an electrochemical charge-transfer reaction and the surface overpotential of the electrode"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Butler%E2%80%93Volmer_equation"@en ;
rdfs:comment "i = i0 * (exp(alpha*n*F*eta/(R*T)) – exp(-(1-alpha)*n*F*eta/(R*T)))" ;
skos:altLabel "ButlerVolmerApproximation"@en ,
@@ -3080,10 +5473,93 @@ of other configurations are used."""@en ;
] .
+### http://emmo.info/electrochemistry#electrochemistry_d5f67a0c_ed56_479d_9b68_6003142f98b0
+:electrochemistry_d5f67a0c_ed56_479d_9b68_6003142f98b0 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 16.0 mm and a height of 1.6 mm"@en ;
+ skos:prefLabel "R1616"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d61deb36_b397_4811_bf7a_66d8e4578c6e
+:electrochemistry_d61deb36_b397_4811_bf7a_66d8e4578c6e rdf:type owl:Class ;
+ rdfs:subClassOf ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "alternating current consistent with a sinusoidal waveform"@en ;
+ skos:prefLabel "SinusoidalCurrentWaveform"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d67a0921_15e4_4c73_804e_97b2d66452b8
+:electrochemistry_d67a0921_15e4_4c73_804e_97b2d66452b8 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 3.6 mm"@en ;
+ skos:altLabel "R45" ;
+ skos:prefLabel "R936"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00
+:electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-37" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "conductor of electricity used for carrying current between components in an electric circuit"@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "a connector electrically joins two cells, or a terminal of a cell to a terminal of the battery, or a terminal of the battery to an exterior circuit and also to auxiliary devices"@en ;
+ skos:prefLabel "Connector"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "conductor of electricity used for carrying current between components in an electric circuit"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00 ;
+ owl:annotatedProperty emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a ;
+ owl:annotatedTarget "a connector electrically joins two cells, or a terminal of a cell to a terminal of the battery, or a terminal of the battery to an exterior circuit and also to auxiliary devices"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d90221a0_0da7_4876_9cac_0e943e445f6f
+:electrochemistry_d90221a0_0da7_4876_9cac_0e943e445f6f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f8d50782_11fa_4188_ba55_d043d2eb597d
+ ] ;
+ skos:prefLabel "TitaniumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b
+:electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-09" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "assembly of one positive plate, one negative plate and the associated separator if any"@en ;
+ skos:altLabel "PlatePair"@en ;
+ skos:prefLabel "ElectrodePair"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "assembly of one positive plate, one negative plate and the associated separator if any"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_d936c767_1530_419c_93f4_59e08f0d702c
+:electrochemistry_d936c767_1530_419c_93f4_59e08f0d702c rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "SodiumInsertionElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166
:electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Voltammetry with forced flow of the solution towards the electrode surface."@en ;
+ rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q17028237" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry with forced flow of the solution towards the electrode surface"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Hydrodynamic_voltammetry"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "A linear potential scan, at sufficiently slow scan rates so as to ensure a steady state response, is usually applied."@en ,
"Mass transport of a redox species enhanced by convection in this way results in a greater electric current. Convective mass transfer occurs up to the diffusion-limiting layer, within which the mass transfer is controlled by diffusion. Electroactive substance depletion outside the diffusion layer is annulled by convective mass transfer, which results in steady- state sigmoidal wave-shaped current-potential curves."@en ,
@@ -3091,31 +5567,76 @@ of other configurations are used."""@en ;
skos:prefLabel "HydrodynamicVoltammetry"@en .
-### http://emmo.info/electrochemistry#electrochemistry_db4f8776_0d92_4641_9202_2591d1624328
-:electrochemistry_db4f8776_0d92_4641_9202_2591d1624328 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "ConstantPotentialChronoamperometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_d9888f1f_2226_4ce3_9cb3_91fd9bd1bf22
+:electrochemistry_d9888f1f_2226_4ce3_9cb3_91fd9bd1bf22 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ;
+ skos:prefLabel "MagnesiumInsertionElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_dac5067c_e6f2_4fca_a915_5b7b918ca1c4
+:electrochemistry_dac5067c_e6f2_4fca_a915_5b7b918ca1c4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 10.8 mm"@en ;
+ skos:prefLabel "R11108"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_dc019f3f_e5f3_4eeb_bab9_a845a02223a0
+:electrochemistry_dc019f3f_e5f3_4eeb_bab9_a845a02223a0 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 1.65 mm"@en ;
+ skos:altLabel "R65" ;
+ skos:prefLabel "R616"@en .
### http://emmo.info/electrochemistry#electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c
:electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An aqueous electrolyte with a nominal pH value between 6 and 8."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH value between 4 and 10."@en ;
+ rdfs:comment "this covers the pH domain typically described as \"weakly acidic\", \"neutral\", and \"weakly alkaline\""@en ;
skos:altLabel "NearNeutralAqueousElectrolyte"@en ,
"NearNeutralSolution"@en ;
skos:prefLabel "NearNeutralElectrolyte"@en .
-### http://emmo.info/electrochemistry#electrochemistry_dded0f27_75da_4a62_ba5e_22050089b726
-:electrochemistry_dded0f27_75da_4a62_ba5e_22050089b726 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "PotentiostaticDCMeasurement"@en .
+### http://emmo.info/electrochemistry#electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f
+:electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q754523" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-03"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "type of capacitor characterized by high capacitance, high specific and volumetric energy density, and low voltage limits"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Supercapacitor"@en ;
+ skos:prefLabel "Supercapacitor"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_dd4c5ffa_6228_41d8_8a44_a40a2b22723e
+:electrochemistry_dd4c5ffa_6228_41d8_8a44_a40a2b22723e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_90f71119_f476_4033_b6ee_6342680322e5
+ ] ;
+ skos:prefLabel "CadmiumElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_df4dd678_9642_47c9_84dd_4bb09f369f53
+:electrochemistry_df4dd678_9642_47c9_84dd_4bb09f369f53 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_a16a1bae_7844_42fd_bb6d_979195d6c933
+ ] ;
+ rdfs:comment "metal electrode in which the active material is sodium"@en ;
+ skos:prefLabel "SodiumElectrode"@en .
### http://emmo.info/electrochemistry#electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff
:electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Liquid metal electrode used in polarography."@en ;
+ rdfs:subClassOf :electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_dc5fb846_1824_40f8_9834_81f118aa1c2d
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "liquid metal electrode used in polarography"@en ;
rdfs:comment "A mercury film electrode (MFE) or thin mercury film electrode (TMFE) is formed by coating a conducting substrate, usually glassy carbon, with a layer of mercury (thin film, amalgam, or array of microdrops), often by electrodeposition from a solution containing Hg(II). The electrode area is normally in the range of 0.1 to 0.5 cm2 and mercury film thickness typically ranges from 10 to 1000 nm, producing a film of large surface area-to-volume ratio that results in a high analyte pre-concentration during the deposition step of anodic stripping voltammetry. Compared to an HMDE, the MFE provides high sensitivity and resolution; however, it is somewhat less reproducible and more prone to interferences from intermetallic formation and surface-active substances."@en ,
"Liquid mercury is an ideal electrode material for negative potentials because of its high overpotential for hydrogen evolution (electrochemical reduction of hydroxonium cations from solution). However, mercury is readily oxidized, particularly in the presence of anions that form complexes or that pre- cipitate with Hg(I) or Hg(II) ions, and thus it is not suitable for use at positive potentials. The use of liquid mercury has largely been discontinued because of concerns about the toxicity of the element and its compounds."@en ;
skos:altLabel "HgElectrode"@en ;
@@ -3124,17 +5645,25 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Liquid metal electrode used in polarography."@en ;
+ owl:annotatedTarget "liquid metal electrode used in polarography"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_e0869e7a_36fe_4e33_9843_a5dc19fcb488
+:electrochemistry_e0869e7a_36fe_4e33_9843_a5dc19fcb488 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 15.5 mm and a height of 6.0 mm"@en ;
+ skos:prefLabel "R9"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f
:electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q209440" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-02"@en ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Galvanic_cell"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Galvanic_cell"@en ;
rdfs:comment "An electrochemical cell that spontaneously produces work."@en ,
"Electrochemical cell intended to produce electric energy."@en ;
@@ -3143,7 +5672,7 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ;
+ owl:annotatedTarget "electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -3165,26 +5694,90 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc
:electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-09"@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q64403" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-09" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrolysis"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Method of separating and neutralizing ions by an electric current in an electrolytic cell."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "method of separating and neutralizing ions by an electric current in an electrolytic cell"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrolysis"@en ;
skos:prefLabel "Electrolysis"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Method of separating and neutralizing ions by an electric current in an electrolytic cell."@en ;
+ owl:annotatedTarget "method of separating and neutralizing ions by an electric current in an electrolytic cell"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+### http://emmo.info/electrochemistry#electrochemistry_e2c91edd_dd01_4309_9735_6fe5280261d4
+:electrochemistry_e2c91edd_dd01_4309_9735_6fe5280261d4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215 ;
+ skos:prefLabel "OxygenElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e3d3d21c_cb9a_498c_bdb0_63c964f0d3c6
:electrochemistry_e3d3d21c_cb9a_498c_bdb0_63c964f0d3c6 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0a0de817_addc_46a5_8ba2_255d48cdf366 ;
+ rdfs:subClassOf :electrochemistry_0a0de817_addc_46a5_8ba2_255d48cdf366 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df
+ ] ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q16851742" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a degradation phenomena in electrochemical devices in which the practicaclly achieveable capacity of the cell is less than the measured capacity at the beginning of life."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Capacity_loss"@en ;
+ skos:altLabel "CapacityLoss"@en ;
skos:prefLabel "CapacityFade"@en .
+### http://emmo.info/electrochemistry#electrochemistry_e3f6eacc_f661_404e_ac16_45d2fa1f5d89
+:electrochemistry_e3f6eacc_f661_404e_ac16_45d2fa1f5d89 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q288224" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=521-02-82" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an interphase formed when two materials with different chemical potentials are brought in contact with each other, and the atoms or electrons are unable to migrate to establish local charge neutrality"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Depletion_region"@en ;
+ skos:altLabel "DepletionLayer"@en ,
+ "DepletionRegion"@en ,
+ "DepletionZone"@en ,
+ "JunctionRegion"@en ,
+ "SpaceChargeRegion"@en ;
+ skos:prefLabel "SpaceChargeLayer"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5
+:electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ;
+ skos:prefLabel "MetalOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_e73cb0b7_e2af_4c1a_b05b_503df25a8bf5
+:electrochemistry_e73cb0b7_e2af_4c1a_b05b_503df25a8bf5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 10.0 mm and a height of 2.5 mm"@en ;
+ skos:prefLabel "R1025"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_e84e691a_df58_465c_9771_7a7fe2212ed5
+:electrochemistry_e84e691a_df58_465c_9771_7a7fe2212ed5 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ;
+ skos:prefLabel "AqueousLithiumHydroxideSolution"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_e8c39ecc_29d1_4172_996e_d5b05dc88015
+:electrochemistry_e8c39ecc_29d1_4172_996e_d5b05dc88015 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_68c0876b_cb62_41cd_846d_95cc9d9a8733
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_d53259a7_0d9c_48b9_a6c1_4418169df303
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended silicon and graphite active materials"@en ;
+ skos:prefLabel "SiliconGraphiteElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6
:electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ,
@@ -3193,19 +5786,32 @@ of other configurations are used."""@en ;
owl:onProperty emmo:EMMO_fd689787_31b0_41cf_bf03_0d69af76469d ;
owl:someValuesFrom
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical measurement principle where the potential difference between an indicator electrode and a reference electrode is measured."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q900632" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-12" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "techniques based on the measurement of potential at controlled current (constant or equal to zero)"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "For measurements using ion-selective electrodes, the measurement is made under equi- librium conditions what means that the macroscopic electric current is zero and the con- centrations of all species are uniform throughout the solution. The indicator electrode is in direct contact with the analyte solution, whereas the reference electrode is usually separated from the analyte solution by a salt bridge. The potential difference between the indicator and reference electrodes is normally directly proportional to the logarithm of the activity (concentration) of the analyte in the solution (Nernst equation). See also ion selec- tive electrode."@en ,
"Method of electroanalytical chemistry based on measurement of an electrode potential."@en ;
skos:prefLabel "Potentiometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_e8d9e091_a56d_4a24_a305_d1bac55cfce3
+:electrochemistry_e8d9e091_a56d_4a24_a305_d1bac55cfce3 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_0139937b_2724_4864_84fb_f14bcfb83538
+ ] ;
+ skos:prefLabel "SodiumManganeseOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4
:electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q2608426" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-06"@en ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrolytic_cell"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrochemical cell intended to produce chemical reactions."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell intended to produce chemical reactions"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrolytic_cell"@en ;
rdfs:comment "An electrochemical cell that requires input of work to drive the reaction."@en ,
"Electrochemical cell in which electrical energy is converted into chemical energy."@en ;
@@ -3214,7 +5820,7 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrochemical cell intended to produce chemical reactions."@en ;
+ owl:annotatedTarget "electrochemical cell intended to produce chemical reactions"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
@@ -3233,10 +5839,26 @@ of other configurations are used."""@en ;
] .
+### http://emmo.info/electrochemistry#electrochemistry_e94f6d42_35e4_4f9f_bb74_5e0628bbd454
+:electrochemistry_e94f6d42_35e4_4f9f_bb74_5e0628bbd454 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603 ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-18"@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "case with multiple separate cell compartments"@en ;
+ skos:prefLabel "MonoblocContainer"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_e94f6d42_35e4_4f9f_bb74_5e0628bbd454 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "case with multiple separate cell compartments"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_e9639083_e9c5_4d0a_97e8_be1e139c179f
:electrochemistry_e9639083_e9c5_4d0a_97e8_be1e139c179f rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Titration in which the electric conductivity of a solution is measured as a function of the amount of titrant added."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q11778221" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "titration in which the electric conductivity of a solution is measured as a function of the amount of titrant added"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "The equivalence-point is obtained as the intersection of linear parts of the conductance G, versus titrant volume V, curve (see"@en ,
"The method can be used for deeply coloured or turbid solutions. Acid-base and precipita- tion reactions are most frequently used."@en ,
@@ -3244,6 +5866,45 @@ of other configurations are used."""@en ;
skos:prefLabel "ConductometricTitration"@en .
+### http://emmo.info/electrochemistry#electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82
+:electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom :electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a case that is described by its diameter and height"@en ;
+ skos:prefLabel "RoundCase"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_eb09ca25_90c9_4b55_9165_76fbf7fb5a46
+:electrochemistry_eb09ca25_90c9_4b55_9165_76fbf7fb5a46 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_334b7617_34d5_4cb4_9e03_cde9ff19183d
+ ] ;
+ skos:prefLabel "BismuthElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_eb1c9aa3_ad4f_4f2a_80f6_d6c8a8bc0d9a
+:electrochemistry_eb1c9aa3_ad4f_4f2a_80f6_d6c8a8bc0d9a rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 2.1 mm"@en ;
+ skos:altLabel "R69" ;
+ skos:prefLabel "R921"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ebd01982_6b0c_48e7_90ef_7b7342009449
+:electrochemistry_ebd01982_6b0c_48e7_90ef_7b7342009449 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ;
+ skos:prefLabel "AqueousSodiumHydroxideSolution"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755
:electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_68390bfb_e307_479d_8f78_d66d8773cb1d ;
@@ -3251,10 +5912,34 @@ of other configurations are used."""@en ;
skos:prefLabel "ElectrochemicalMaterial"@en .
+### http://emmo.info/electrochemistry#electrochemistry_ebf314c7_81ad_4d77_9da4_b454520fda0e
+:electrochemistry_ebf314c7_81ad_4d77_9da4_b454520fda0e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 1.6 mm"@en ;
+ skos:altLabel "R68" ;
+ skos:prefLabel "R916"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ec1dce8b_bb46_41a9_b532_6bed381aa557
+:electrochemistry_ec1dce8b_bb46_41a9_b532_6bed381aa557 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-14" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "secondary cell having a cover provided with an opening through which products of electrolysis and evaporation are allowed to escape freely from the cell to the atmosphere"@en ;
+ skos:prefLabel "VentedCell"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_ec1dce8b_bb46_41a9_b532_6bed381aa557 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "secondary cell having a cover provided with an opening through which products of electrolysis and evaporation are allowed to escape freely from the cell to the atmosphere"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_ec6f3d6f_bdf5_418f_9314_3ef2ff528103
:electrochemistry_ec6f3d6f_bdf5_418f_9314_3ef2ff528103 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Development of a carbon paste electrode that is screen printed using a carbon/polymer mixture of suitable composition."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907443" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "development of a carbon paste electrode that is screen printed using a carbon/polymer mixture of suitable composition"@en ;
rdfs:comment "These electrodes can easily be chemically modified by the incorporation of reagents (electrocatalysts, redox mediators, complexation agents, enzymes, etc.) and by the attachment of micro- or nanoparticles to prepare electrochemical sensors for analytical applications."@en ,
"Typical composition of a carbon ink expressed as mass fractions is graphite powder 60 % and polystyrene 40 %."@en ;
skos:prefLabel "CarbonInkElectrode"@en .
@@ -3262,23 +5947,51 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_ec6f3d6f_bdf5_418f_9314_3ef2ff528103 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Development of a carbon paste electrode that is screen printed using a carbon/polymer mixture of suitable composition."@en ;
+ owl:annotatedTarget "development of a carbon paste electrode that is screen printed using a carbon/polymer mixture of suitable composition"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
### http://emmo.info/electrochemistry#electrochemistry_ecf136cb_2584_4cb1_98b7_2d2b3d22e40d
:electrochemistry_ecf136cb_2584_4cb1_98b7_2d2b3d22e40d rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An interfacial layer that forms between an electrode phase and and electrolyte phase, due to the decomposition of the electrolyte."@en ;
- emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "Although the definition could apply to any electrode, it is conventionally used to describe interfacial layers that form on the anode of an electrochemical cell."@en ;
+ rdfs:subClassOf :electrochemistry_d16eec87_c646_4566_bda6_7d3357cda061 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an interfacial layer that forms between an electrode phase and and electrolyte phase, due to the decomposition of the electrolyte"@en ;
+ emmo:EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f "although the definition could apply to any electrode, it is conventionally used to describe interfacial layers that form on the anode of an electrochemical cell."@en ;
skos:altLabel "SEI"@en ;
skos:prefLabel "SolidElectrolyteInterphase"@en .
+### http://emmo.info/electrochemistry#electrochemistry_ee0278fb_932d_48cd_a20a_c1b89b29d68b
+:electrochemistry_ee0278fb_932d_48cd_a20a_c1b89b29d68b rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_cdd18f0c_e7b3_4d09_b3dd_c09fe4b1adba
+ ] ;
+ skos:prefLabel "SodiumCobaltOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_ee479886_6805_4018_95e1_500185e44215
+:electrochemistry_ee479886_6805_4018_95e1_500185e44215 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_ec7464a9_d99d_45f8_965b_4e9230ea8356 ;
+ skos:prefLabel "Powder"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_efaca8db_a3e0_4188_9c9b_ed0037966725
+:electrochemistry_efaca8db_a3e0_4188_9c9b_ed0037966725 rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ;
+ owl:someValuesFrom emmo:EMMO_66bc9029_f473_45ff_bab9_c3509ff37a22
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vector containing at least two values for the quantity celsius temperature"@en ;
+ skos:prefLabel "CelsiusTemperatureVector"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_efc4f7ab_850d_443c_a17f_184983021f96
:electrochemistry_efc4f7ab_850d_443c_a17f_184983021f96 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q302489" ;
emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-39" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "arrangement of cells or batteries wherein all the positive terminals and all the negative terminals, respectively, are connected together."@en ;
skos:prefLabel "ParallelConnection"@en .
@@ -3303,37 +6016,117 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085
:electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "The process of forming a film or a bulk material using an electrochemical process where the electrons are supplied by an external power supply."@en ;
+ rdfs:subClassOf :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ,
+ :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the process of forming a film or a bulk material using an electrochemical process where the electrons are supplied by an external power supply"@en ;
skos:prefLabel "Electrodeposition"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "The process of forming a film or a bulk material using an electrochemical process where the electrons are supplied by an external power supply."@en ;
+ owl:annotatedTarget "the process of forming a film or a bulk material using an electrochemical process where the electrons are supplied by an external power supply"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
+### http://emmo.info/electrochemistry#electrochemistry_f19d3b4f_d59b_4a92_a547_54a6f59cc9b4
+:electrochemistry_f19d3b4f_d59b_4a92_a547_54a6f59cc9b4 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_cd17ca33_ae3d_4738_8930_547673bf6c1f
+ ] ;
+ skos:altLabel "NCAElectrode"@en ;
+ skos:prefLabel "LithiumNickelCobaltAluminumOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_f1c7eacb_9f21_4100_925c_3974f266e06f
:electrochemistry_f1c7eacb_9f21_4100_925c_3974f266e06f rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a membrane composed of two layers, typically with different chemical properties or functional roles."@en ;
+ rdfs:subClassOf :electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an asymmetric membrane composed of two layers, typically with different chemical properties or functional roles"@en ;
skos:prefLabel "BilayerMembrane"@en .
+### http://emmo.info/electrochemistry#electrochemistry_f2cf71c1_f2d7_4131_82e0_2701cdecea55
+:electrochemistry_f2cf71c1_f2d7_4131_82e0_2701cdecea55 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 16.0 mm and a height of 3.2 mm"@en ;
+ skos:prefLabel "R1632"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_f330680b_347e_45b3_9113_5ce09d18d60b
+:electrochemistry_f330680b_347e_45b3_9113_5ce09d18d60b rdf:type owl:Class ;
+ rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty [ owl:inverseOf emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec
+ ] ;
+ owl:someValuesFrom :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8
+ ] ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-41" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "vent of special design which allows to release gas from a cell in order to avoid excessive internal pressure and thereby to preclude rupture or explosion of the cell container"@en ;
+ skos:prefLabel "PressureReliefVent"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_f330680b_347e_45b3_9113_5ce09d18d60b ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "vent of special design which allows to release gas from a cell in order to avoid excessive internal pressure and thereby to preclude rupture or explosion of the cell container"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_f47611a2_e081_47f0_b287_3fda5f706154
+:electrochemistry_f47611a2_e081_47f0_b287_3fda5f706154 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q22117434" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-06" ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-13" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "chemical reaction which occurs in addition to the main process"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Side_reaction"@en ;
+ skos:altLabel "SecondaryReaction"@en ;
+ skos:prefLabel "SideReaction"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_f47611a2_e081_47f0_b287_3fda5f706154 ;
+ owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
+ owl:annotatedTarget "chemical reaction which occurs in addition to the main process"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+
### http://emmo.info/electrochemistry#electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4
:electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 rdf:type owl:Class ;
- rdfs:subClassOf emmo:EMMO_bafc17b5_9be4_4823_8bbe_ab4e90b6738c ;
+ rdfs:subClassOf emmo:EMMO_bafc17b5_9be4_4823_8bbe_ab4e90b6738c ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_c4bace1d_4db0_4cd3_87e9_18122bae2840 ;
+ owl:someValuesFrom :electrochemistry_31e8052d_bede_43c6_8b41_d51bb24c9489
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
+ owl:someValuesFrom :electrochemistry_158ae038_c64b_4cc0_aa56_650475490705
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
+ owl:someValuesFrom :electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
+ owl:someValuesFrom :electrochemistry_825a749f_dd07_46fb_947c_db286440911e
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_d43af210_f854_4432_a891_ce3022e3b558 ;
+ owl:someValuesFrom :electrochemistry_bea04148_10d9_4eda_9cd5_8f609d7e9ff8
+ ] ;
skos:prefLabel "ElectrochemicalMethod"@en .
### http://emmo.info/electrochemistry#electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6
:electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-10"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode reaction in which reduction occurs at the cathode."@en ;
- rdfs:comment "Electrode reaction, where the energy of electrons in the working electrode is higher than the LUMO orbital of the substrate."@en ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-10"@en ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-12" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode reaction in which reduction occurs at the cathode"@en ;
+ rdfs:comment "electrode reaction involving an electrochemical reduction"@en ,
+ "electrode reaction, where the energy of electrons in the working electrode is higher than the LUMO orbital of the substrate"@en ;
skos:altLabel "Electroreduction"@en ,
"ElectroreductionReaction"@en ;
skos:prefLabel "CathodicReaction"@en .
@@ -3341,14 +6134,21 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode reaction in which reduction occurs at the cathode."@en ;
+ owl:annotatedTarget "electrode reaction in which reduction occurs at the cathode"@en ;
+ dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
+ ] .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "electrode reaction involving an electrochemical reduction"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Electrode reaction, where the energy of electrons in the working electrode is higher than the LUMO orbital of the substrate."@en ;
+ owl:annotatedTarget "electrode reaction, where the energy of electrons in the working electrode is higher than the LUMO orbital of the substrate"@en ;
dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5"
] .
@@ -3356,12 +6156,37 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_f54474fc_5d07_474b_97ae_f5d0349363b4
:electrochemistry_f54474fc_5d07_474b_97ae_f5d0349363b4 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a flow cell that uses one or more electroactive components deposited as a solid layer"@en ;
skos:prefLabel "HybridFlowCell"@en .
+### http://emmo.info/electrochemistry#electrochemistry_f57a7dac_2ec2_4d51_b697_01a844c4467f
+:electrochemistry_f57a7dac_2ec2_4d51_b697_01a844c4467f rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "considers the effects of specific adsorbed ions in the double layer"@en ;
+ rdfs:comment "proposed by Sergio Trasatti and Giovanni Buzzanca in 1971"@en ;
+ skos:prefLabel "TrasattiBuzzancaModel"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_f6223121_7df5_42f8_902c_d26fa2fc4f04
+:electrochemistry_f6223121_7df5_42f8_902c_d26fa2fc4f04 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_4126ee09_b9c6_4694_bf33_0d8970e05f72
+ ] ;
+ skos:altLabel "PbOElectrode"@en ;
+ skos:prefLabel "LeadOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_f6341d7d_7620_48f5_97b2_99b55c349169
:electrochemistry_f6341d7d_7620_48f5_97b2_99b55c349169 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_0a0de817_addc_46a5_8ba2_255d48cdf366 ;
+ rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ;
+ owl:someValuesFrom :electrochemistry_79d1b273-58cd-4be6-a250-434817f7c261
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a degradation mechanism in electrochemical cells in which fractures in the active material particles increase cell resistance."@en ;
skos:prefLabel "ActiveMaterialParticleCracking"@en .
@@ -3372,13 +6197,16 @@ of other configurations are used."""@en ;
owl:onProperty emmo:EMMO_17e27c22_37e1_468c_9dd7_95e137f73e7f ;
owl:someValuesFrom :electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940
] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system for measuing electric current"@en ;
+ emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "a digital coulometer connected to a computer"@en ;
skos:prefLabel "ElectricCurrentMeasuringSystem"@en .
### http://emmo.info/electrochemistry#electrochemistry_f6fcd255_248d_4603_b128_04dab960a676
:electrochemistry_f6fcd255_248d_4603_b128_04dab960a676 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907462" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/I03006"@en ;
rdfs:comment "If processes of interest occur both at the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or working electrodes."@en ,
"This term is typically used in potentiometry."@en ;
@@ -3387,17 +6215,36 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_f6fcd255_248d_4603_b128_04dab960a676 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement."@en ;
+ owl:annotatedTarget "electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
+### http://emmo.info/electrochemistry#electrochemistry_f7e253da_b12e_40b0_ba51_8cb039839ab6
+:electrochemistry_f7e253da_b12e_40b0_ba51_8cb039839ab6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 12.05 mm and a height of 2.5 mm"@en ;
+ skos:prefLabel "R1225"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_f8e0d532_cf44_403c_9188_e00ee161a3c1
:electrochemistry_f8e0d532_cf44_403c_9188_e00ee161a3c1 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_ecf136cb_2584_4cb1_98b7_2d2b3d22e40d ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a type of solid electrolyte interface that forms on the surface of the electrode designated as the \"cathode\" or positive electrode"@en ;
+ rdfs:comment "used to distinguish the interphase on the cathode surface from that on the anode, which is typically called the solid electrolyte interphase (SEI)"@en ;
skos:prefLabel "CathodeElectrolyteInterphase"@en .
+### http://emmo.info/electrochemistry#electrochemistry_f8f81b27_1d6c_42d8_a7e9_5a2534102562
+:electrochemistry_f8f81b27_1d6c_42d8_a7e9_5a2534102562 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_68f9b85e_340f_46ec_96da_ebb6bd62f5fd
+ ] ;
+ skos:prefLabel "SodiumChromiumOxideElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_f91c9ae3_42b8_4efa_9b67_a406d162d3b5
:electrochemistry_f91c9ae3_42b8_4efa_9b67_a406d162d3b5 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 ,
@@ -3413,63 +6260,103 @@ of other configurations are used."""@en ;
owl:onProperty ;
owl:someValuesFrom :electrochemistry_85e39686_9658_4c74_bb91_a935704c174a
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Direct coulometry at controlled potential in which the electric charge passed after the application of a potential step perturbation is measured as a function of time (Q-t curve)."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "direct coulometry at controlled potential in which the electric charge passed after the application of a potential step perturbation is measured as a function of time (Q-t curve)"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ;
rdfs:comment "Chronocoulometry provides the same information that is provided by chronoamperometry, since it is based on the integration of the I-t curve. Nevertheless, chronocoulometry offers important experimental advantages, such as (i) the measured signal usually increases with time and hence the later parts of the transient can be detected more accurately, (ii) a better signal-to-noise ratio can be achieved, and (iii) other contributions to overall charge passed as a function of time can be discriminated from those due to the diffusion of electroactive substances."@en ;
skos:prefLabel "Chronocoulometry"@en .
+### http://emmo.info/electrochemistry#electrochemistry_f9e2e676_5cd1_4e22_a776_af45838d4027
+:electrochemistry_f9e2e676_5cd1_4e22_a776_af45838d4027 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ;
+ skos:prefLabel "AqueousAmmoniaSolution"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_f9f056bb_a38b_43bd_a6bd_99d618431f4d
+:electrochemistry_f9f056bb_a38b_43bd_a6bd_99d618431f4d rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_f96ceacb_2808_4c4d_925c_d28086c8a2e1
+ ] ;
+ skos:prefLabel "PalladiumElectrode"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de
:electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ,
emmo:EMMO_4b3e2374_52a1_4420_8e3f_3ae6b9bf7dff ;
- rdfs:comment "A liquid electrolyte that consists of solutes dissolved in a solvent."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a liquid electrolyte that consists of solutes dissolved in a solvent"@en ;
skos:altLabel "ElectrolyticSolution"@en ;
skos:prefLabel "ElectrolyteSolution"@en .
+### http://emmo.info/electrochemistry#electrochemistry_fa54f95d_b49e_43b5_84c3_35520d0fb2f6
+:electrochemistry_fa54f95d_b49e_43b5_84c3_35520d0fb2f6 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an extension of the Helmholtz model that describes the distribution of ions as a function of distance from the electrode surface to the bulk of the electroylte"@en ;
+ rdfs:comment "this model fails for highly charged double layers"@en ;
+ skos:prefLabel "GouyChapmanModel"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_fab4bd12_c4ed_417a_92a3_bcb109000d82
+:electrochemistry_fab4bd12_c4ed_417a_92a3_bcb109000d82 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 4.0 mm"@en ;
+ skos:prefLabel "R2040"@en .
+
+
### http://emmo.info/electrochemistry#electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59
:electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ,
:electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 ;
- emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-02"@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q162908" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-02" ,
+ "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-29" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrolyte"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A material in which the mobile species are ions and free movement of electrons is blocked." ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a material in which the mobile species are ions and free movement of electrons is blocked."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrolyte"@en ;
- rdfs:comment """1. Conducting medium in which the flow of electric current is accompanied by the movement of ions.
-2. Substance that provides ions on dissolution in a solvent or on melting."""@en ,
- "A solid electrolyte is a solid material where the predominant charge carriers are ions. For example: NASICON (Na Super Ionic Conductor), which has the general formula Na1+xZr2P3-xSix O12 , 0 < x < 3."@en ,
+ rdfs:comment "A solid electrolyte is a solid material where the predominant charge carriers are ions. For example: NASICON (Na Super Ionic Conductor), which has the general formula Na1+xZr2P3-xSix O12 , 0 < x < 3."@en ,
"An ionic liquid is an electrolyte composed of a salt that is liquid below 100 °C. Ionic liquids have found uses in electrochemical analysis, because their unconventional properties include a negligible vapor pressure, a high thermal and electrochemical stability, and exceptional dissolution properties for both organic and inorganic chemical species."@en ,
- "Liquid or solid substance containing mobile ions that render it conductive."@en ;
+ "conducting medium in which the flow of electric current is accompanied by the movement of ions"@en ,
+ "liquid or solid substance containing mobile ions that render it conductive"@en ,
+ "substance that provides ions on dissolution in a solvent or on melting"@en ;
skos:prefLabel "Electrolyte"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "A material in which the mobile species are ions and free movement of electrons is blocked." ;
+ owl:annotatedTarget "a material in which the mobile species are ions and free movement of electrons is blocked."@en ;
dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004."
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget """1. Conducting medium in which the flow of electric current is accompanied by the movement of ions.
-2. Substance that provides ions on dissolution in a solvent or on melting."""@en ;
+ owl:annotatedTarget "conducting medium in which the flow of electric current is accompanied by the movement of ions"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
owl:annotatedProperty rdfs:comment ;
- owl:annotatedTarget "Liquid or solid substance containing mobile ions that render it conductive."@en ;
+ owl:annotatedTarget "liquid or solid substance containing mobile ions that render it conductive"@en ;
dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org"
] .
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ;
+ owl:annotatedProperty rdfs:comment ;
+ owl:annotatedTarget "substance that provides ions on dissolution in a solvent or on melting"@en ;
+ dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
+ ] .
+
### http://emmo.info/electrochemistry#electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35
:electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_0f007072-a8dd-4798-b865-1bf9363be627 ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode at which one or more electroactive substances undergo reaction in the solution being investigated."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q477099" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode at which one or more electroactive substances undergo reaction in the solution being investigated"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Working_electrode"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/W06686"@en ;
rdfs:comment "If processes of interest occur both at the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or working electrodes."@en ,
@@ -3480,7 +6367,7 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Electrode at which one or more electroactive substances undergo reaction in the solution being investigated."@en ;
+ owl:annotatedTarget "electrode at which one or more electroactive substances undergo reaction in the solution being investigated"@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
@@ -3488,8 +6375,9 @@ of other configurations are used."""@en ;
### http://emmo.info/electrochemistry#electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940
:electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q905539" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Voltmeter"@en ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Voltameter"@en ;
rdfs:comment "Modern instruments for measuring trace water by Karl Fischer titration use the passage of a measured charge to produce iodine from iodide solution. They are known as Karl Fischer coulometers"@en ,
"The silver coulometer is a primary reference measurement procedure [VIM 2.8] for charge and current. By weighing the mass of silver deposited in a known time at constant current, the charge and current are calculated from Faraday’s laws of electrolysis"@en ;
@@ -3499,28 +6387,41 @@ of other configurations are used."""@en ;
[ rdf:type owl:Axiom ;
owl:annotatedSource :electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ;
+ owl:annotatedTarget "measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ;
dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109"
] .
-### http://emmo.info/electrochemistry#electrochemistry_fe333444_1f07_4d67_afcf_05dbd292b9b3
-:electrochemistry_fe333444_1f07_4d67_afcf_05dbd292b9b3 rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_5dd49895_0489_4324_89fe_862a71f3eb1e ;
- skos:prefLabel "PotentiostaticPolarization"@en .
+### http://emmo.info/electrochemistry#electrochemistry_fbf40756_3265_4468_bcdb_88d162afc539
+:electrochemistry_fbf40756_3265_4468_bcdb_88d162afc539 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 2.0 mm"@en ;
+ skos:prefLabel "R2320"@en .
-### http://emmo.info/electrochemistry#electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e
-:electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e rdf:type owl:Class ;
- rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ,
- [ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_ad6c76cf_b400_423e_820f_cf0c4e77f455
- ] ,
+### http://emmo.info/electrochemistry#electrochemistry_fd7caf39_0a43_4fbf_958e_a62067aa9007
+:electrochemistry_fd7caf39_0a43_4fbf_958e_a62067aa9007 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ,
[ rdf:type owl:Restriction ;
- owl:onProperty emmo:EMMO_b2282816_b7a3_44c6_b2cb_3feff1ceb7fe ;
- owl:someValuesFrom emmo:EMMO_affe07e4_e9bc_4852_86c6_69e26182a17f
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_4c62d334_a124_40b3_9fd1_fe713d01a6af
] ;
+ skos:altLabel "LCOElectrode"@en ;
+ skos:prefLabel "LithiumCobaltOxideElectrode"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_fe054d02_41c7_40e9_8206_3440ab6a67b2
+:electrochemistry_fe054d02_41c7_40e9_8206_3440ab6a67b2 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 5.4 mm"@en ;
+ skos:altLabel "R44" ;
+ skos:prefLabel "R1154"@en .
+
+
+### http://emmo.info/electrochemistry#electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e
+:electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q751124" ;
emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Nernst_equation"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An equation that relates the reduction potential of an electrochemical reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation."@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Nernst_equation" ;
@@ -3529,10 +6430,28 @@ of other configurations are used."""@en ;
skos:prefLabel "NernstEquation"@en .
+### http://emmo.info/electrochemistry#electrochemistry_fffc3dad_6946_4c32_a9d3_f5f311339881
+:electrochemistry_fffc3dad_6946_4c32_a9d3_f5f311339881 rdf:type owl:Class ;
+ rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_aa8e9cc4_5f66_4307_b1c8_26fac7653a90
+ ] ,
+ [ rdf:type owl:Restriction ;
+ owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ;
+ owl:someValuesFrom emmo:material_e8fafdc8_6cd3_4dd0_9630_10ca8e3f1827
+ ] ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended lithium manganese oxide (LMO) and lithium iron phosphate (LFP) active materials"@en ;
+ skos:altLabel "LMOLFPElectrode"@en ;
+ skos:prefLabel "LithiumManganeseOxideLithiumIronPhosphateElectrode"@en .
+
+
### http://emmo.info/emmo#EMMO_a2a68924_b759_4ba4_a25d_126021569fb9
emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
rdfs:subClassOf :electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q176088" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A general term which refers to a continuous layer, usually consisting of a semi-permeable material, with controlled permeability covering a structure, such as carbon or an inert metal, or separating two electrolyte solutions."@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Membrane"@en ;
emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.M03823" ;
skos:prefLabel "Membrane"@en .
@@ -3615,17 +6534,24 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_40ca9548_910a_48b6_9a26_f94095d349cd
rdf:type owl:Class ;
rdfs:subClassOf ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5163647" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=131-11-22" ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Signal consisting of a constant electric current."@en ;
- skos:altLabel "DC"@en ;
- skos:prefLabel "ConstantCurrentSignal"@en .
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Constant_current" ;
+ skos:altLabel "ConstantCurrentSignal"@en ,
+ "DC"@en ;
+ skos:prefLabel "DirectCurrent"@en .
### https://emmo.info/electrochemistry#electrochemistry_46676855_68b0_4096_ac6c_35400111d46d
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plot of the time-dependent amount of electric charge passed through an electrochemical system due to the application of a electric potential."@en ;
- skos:altLabel "QtCurve"@en ;
- skos:prefLabel "ChargeTimeCurve"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plot of the time-dependent amount of electric charge passed through an electrochemical system due to the application of a electric potential"@en ;
+ skos:altLabel "ChargeTimeCurve"@en ,
+ "ElectricChargeTimeCurve"@en ,
+ "ElectricChargeTimePlot"@en ,
+ "QtCurve"@en ;
+ skos:prefLabel "ChargeTimePlot"@en .
### https://emmo.info/electrochemistry#electrochemistry_58a20764_c339_4856_983a_05092b5282e8
@@ -3649,7 +6575,8 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_712c791a_d593_4732_af73_493f7bc50999
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Rapid, transient change in the amplitude of an electric current, from a baseline value to a higer or lower value, followed by a rapid return to the baseline value."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q114979515" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "rapid, transient change in the amplitude of an electric current, from a baseline value to a higer or lower value, followed by a rapid return to the baseline value."@en ;
skos:prefLabel "CurrentPulse"@en .
@@ -3692,19 +6619,23 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_a2b01d05_b472_4cf5_b388_e0914db56324
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested in an impedimetry measurement."@en ;
- skos:altLabel "ComplexPlanePlot"@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1333343" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested in an impedimetry measurement"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Nyquist_stability_criterion#Nyquist_plot"@en ;
+ skos:altLabel "ComplexPlanePlot"@en ,
+ "NyquistDiagram"@en ;
skos:prefLabel "NyquistPlot"@en .
### https://emmo.info/electrochemistry#electrochemistry_a53d6dee_1547_4854_a311_805b4d557298
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Periodic current where the amplitude alternates at a steady frequency between fixed minimum and maximum values, with the same duration at minimum and maximum."@en ;
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q124164" ;
+ emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=131-11-24" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "periodic current where the amplitude alternates at a steady frequency between fixed minimum and maximum values, with the same duration at minimum and maximum"@en ;
emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Alternating_current"@en ;
- skos:altLabel "AC"@en ,
- "AlternatingCurrent"@en ;
- skos:prefLabel "SinusoidalCurrentWaveform"@en .
+ skos:altLabel "AC"@en ;
+ skos:prefLabel "AlternatingCurrent"@en .
### https://emmo.info/electrochemistry#electrochemistry_b49e2355_392f_4e83_b630_7ff4581d767b
@@ -3718,13 +6649,14 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_b99cff7f_b13f_4075_aa88_62c04f8daacc
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plot of the dependence of instantaneous current on time."@en ;
- skos:prefLabel "CurrentTimeCurve"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plot of the dependence of instantaneous current on time"@en ;
+ skos:altLabel "CurrentTimeCurve"@en ;
+ skos:prefLabel "CurrentTimePlot"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Plot of the dependence of instantaneous current on time."@en ;
+ owl:annotatedTarget "plot of the dependence of instantaneous current on time"@en ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 """Pingarrón, José M., et al. \"Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019).\" Pure and Applied Chemistry
92.4 (2020): 641-694. DOI: https://doi.org/10.1515/pac-2018-0109"""
] .
@@ -3741,14 +6673,16 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
owl:onProperty emmo:EMMO_3446e167_c576_49d6_846c_215bb8878a55 ;
owl:someValuesFrom emmo:EMMO_c995ae70_3b84_4ebb_bcfc_69e6a281bb88
] ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plot of current versus applied potential (I-E) for a given system."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plot of current versus applied potential (I-E) for a given system"@en ;
rdfs:comment "The curve is sigmoidal in hydrodynamic voltammetry, voltammetry at microelectrodes and polarography, or peak-shaped in ac voltammetry, differential pulse voltammetry, square- wave voltammetry, stripping voltammetry, and derivative techniques."@en ;
- skos:prefLabel "CurrentPotentialCurve"@en .
+ skos:altLabel "CurrentPotentialCurve"@en ,
+ "ElectricCurrentPotentialCurve"@en ;
+ skos:prefLabel "CurrentPotentialPlot"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Plot of current versus applied potential (I-E) for a given system."@en ;
+ owl:annotatedTarget "plot of current versus applied potential (I-E) for a given system"@en ;
dcterms:source """Pingarrón, José M., et al. \"Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019).\" Pure and Applied Chemistry
92.4 (2020): 641-694. DOI: https://doi.org/10.1515/pac-2018-0109"""
] .
@@ -3757,13 +6691,14 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_bbae1ef4_0a95_4e7d_9932_1bf939129eef
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Current-potential curve in a voltammetry experiment."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "current-potential curve in a voltammetry experiment"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Voltammetry#Voltammograms"@en ;
skos:prefLabel "Voltammogram"@en .
[ rdf:type owl:Axiom ;
owl:annotatedSource ;
owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ;
- owl:annotatedTarget "Current-potential curve in a voltammetry experiment."@en ;
+ owl:annotatedTarget "current-potential curve in a voltammetry experiment"@en ;
dcterms:source """Pingarrón, José M., et al. \"Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019).\" Pure and Applied Chemistry
92.4 (2020): 641-694. DOI: https://doi.org/10.1515/pac-2018-0109"""
] .
@@ -3779,8 +6714,11 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_cd7d24a5_db31_4d76_97d9_367c809f099e
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plot of the time-dependence of instantaneous potential following a change in applied current."@en ;
- skos:prefLabel "PotentialTimeCurve"@en .
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plot of the time-dependence of instantaneous electric potential following a change in applied current"@en ;
+ skos:altLabel "ElectricPotentialTimeCurve"@en ,
+ "ElectricPotentialTimePlot"@en ,
+ "PotentialTimeCurve"@en ;
+ skos:prefLabel "PotentialTimePlot"@en .
### https://emmo.info/electrochemistry#electrochemistry_d359386f_ae2d_4ad4_9616_464e2111b67d
@@ -3795,15 +6733,17 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
rdfs:subClassOf emmo:EMMO_eb7de1a1_c30e_4f0d_94c6_fe70414d7e61 ;
emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Graphical representation of a dataset resulting from the measurement of the response of an electrochemical system."@en ;
rdfs:comment "Shows the relationship between two or more electrochemical variables."@en ;
- skos:prefLabel "ElectrochemicalCurve"@en .
+ skos:prefLabel "ElectrochemicalPlot"@en .
### https://emmo.info/electrochemistry#electrochemistry_e0b57b09_68ee_4687_a901_bfb599421972
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency at all the frequencies tested in an impedimetry measurement."@en ;
- skos:altLabel "BodePlot"@en ;
- skos:prefLabel "BodeDiagram"@en .
+ emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q245627" ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency at all the frequencies tested in an impedimetry measurement"@en ;
+ emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Bode_plot"@en ;
+ skos:altLabel "BodeDiagram"@en ;
+ skos:prefLabel "BodePlot"@en .
### https://emmo.info/electrochemistry#electrochemistry_f9af8440_3629_4558_a944_9dfaf3dfd7ec
@@ -3816,13 +6756,15 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
### https://emmo.info/electrochemistry#electrochemistry_fa774456_718a_4a28_ba6a_6f828887c510
rdf:type owl:Class ;
rdfs:subClassOf ;
- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Signal where an electric current is varied linearly from an initial current, tipically 0 A."@en ;
+ emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "signal where an electric current is varied linearly from an initial current, typically 0 A"@en ;
skos:prefLabel "LinearCurrentRamp"@en .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+ ] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
@@ -3830,25 +6772,28 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+ ] .
+
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
@@ -3869,19 +6814,19 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
@@ -3893,19 +6838,22 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+ ] .
+
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
@@ -3914,25 +6862,31 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+ ] .
+
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+ ] .
+
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
@@ -3941,13 +6895,13 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
@@ -3962,10 +6916,7 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
- ] .
-
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
@@ -3974,10 +6925,10 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
@@ -3992,13 +6943,16 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+ ] .
+
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
@@ -4016,9 +6970,6 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
- ] .
-
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
@@ -4031,25 +6982,22 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
- ] .
-
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
@@ -4070,10 +7018,10 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
@@ -4085,61 +7033,46 @@ emmo:EMMO_a2a68924_b759_4ba4_a25d_126021569fb9 rdf:type owl:Class ;
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
- ] .
-
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
- ] .
-
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
- ] .
-
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
- ] .
-
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
- ] .
-
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "4"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
-[ owl:qualifiedCardinality "1"^^xsd:nonNegativeInteger
+[ owl:qualifiedCardinality "2"^^xsd:nonNegativeInteger
] .
### Generated by the OWL API (version 4.5.9.2019-02-01T07:24:44Z) https://github.com/owlcs/owlapi
diff --git a/emmo-concepts.ttl b/emmo-concepts.ttl
deleted file mode 100644
index 3ec4309..0000000
--- a/emmo-concepts.ttl
+++ /dev/null
@@ -1,24 +0,0 @@
-@prefix : .
-@prefix owl: .
-@prefix rdf: .
-@prefix xml: .
-@prefix xsd: .
-@prefix rdfs: .
-@base .
-
- rdf:type owl:Ontology ;
- owl:versionIRI ;
- owl:imports .
-
-#################################################################
-# Annotation properties
-#################################################################
-
-### http://emmo.info/emmo#EMMO_aaef5da2_829f_40da_b3f8_468ccc47bb11
- rdf:type owl:AnnotationProperty ;
- "A symbol in Latex markup language that represents the entity."@en ;
- "latexLabel"@en ;
- rdfs:subPropertyOf rdfs:label .
-
-
-### Generated by the OWL API (version 4.5.9.2019-02-01T07:24:44Z) https://github.com/owlcs/owlapi
diff --git a/inferred_version/electrochemicalquantities-inferred.ttl b/inferred_version/electrochemicalquantities-inferred.ttl
new file mode 100644
index 0000000..6e97611
--- /dev/null
+++ b/inferred_version/electrochemicalquantities-inferred.ttl
@@ -0,0 +1,43205 @@
+@prefix : .
+@prefix owl: .
+@prefix rdf: .
+@prefix xml: .
+@prefix xsd: .
+@prefix rdfs: .
+@base .
+
+ rdf:type owl:Ontology ;
+ owl:versionIRI ;
+ """Emanuele Ghedini
+University of Bologna (IT)
+email: emanuele.ghedini@unibo.it"""@en ,
+ """Gerhard Goldbeck
+Goldbeck Consulting Ltd (UK)
+email: gerhard@goldbeck-consulting.com"""@en ,
+ "emmo@emmc.eu" ;
+ "The EMMO requires FacT++ reasoner plugin in order to visualize all inferences and class hierarchy (ctrl+R hotkey in Protege)."@en ,
+ "This ontology is generated with EMMOntoPy using data from the ASE Python package."@en ,
+ "You can contact EMMO Authors via emmo@emmc.eu"@en ;
+ ""@en ,
+ """Defines physical quantities in the International System of Quantities (ISQ). ISQ was made an official ISO standard in 2009 and is defined in the ISO/IEC 80000 standard.
+
+ISQ underlines the SI system and defines physical quanties that are measured with SI units.
+
+ISQ has 7 base quantities and many derived quantities defined in terms of the 7 base quantities.
+
+The number of derived quantities not closed and may increase based on the need by domain ontologies."""@en ,
+ """Defines properties as the result of an observation process. Observation is a semiotic process that stimulate an interpretant within the interpreter who communicates the perception result to other interpreters through a sign, which is the property.
+
+Hence, properties creates a link between the holistic and the perceptual perspectives.
+
+Subclasses of property are subclasses that spesialise the type of observation process."""@en ,
+ """Defines the formal language of metrology, including theoretical and practical aspects of measurements.
+
+This module is based on the International vocabulary of metrology (VIM) as well as the ISO/IEC 80000 standard."""@en ,
+ """Defines the holistic perspective which include process and the role of its participants.
+
+Processes are 4D object's that unfolds in time in a way that has a meaning to the ontologist with participants who's role is assigned by the ontologist."""@en ,
+ """Defines the perceptual perspective, which categorises real world objects according to how they are percieved by an user as a recognisable pattern in space or time.
+
+The perceptual module includes formal languages, pictures, geometry, mathematics and sounds. Phenomenic objects can be used in a semiotic process as signs."""@en ,
+ """Defines the perceptual perspective, which which categorises real world objects according to how they are percieved by an user as a recognisable pattern in space or time.
+
+The perceptual module includes formal languages, pictures, geometry, mathematics and sounds. Phenomenic objects can be used in a semiotic process as signs."""@en ,
+ """Defines the reductionistic perspective, which uses the fundamental non-transitive parthood relation, called direct parthood, to provide a powerful granularity description of multiscale real world objects. EMMO can in principle represents the Universe with direct parthood relations as a direct rooted tree up to its elementary constituents.
+
+In addition to direct parthood, the reductionistic module defines 'State' as a tesselation of spatial direct parts with no change of granularity or cardinality and 'Existent' as a tesselation of temporal direct parts."""@en ,
+ "Defines the root of the physicalistic perspective that introduces the concept of real world objects that have a meaning for the ontologist under an applied physics perspective."@en ,
+ "Describes manufacturing processes with engineered participants. The module also provides a root for engineered materials."@en ,
+ """Elementary Multiperspective Material Ontology (EMMO)
+
+EMMO is a multidisciplinary effort to develop a standard representational framework (the ontology) based on current materials modelling knowledge, including physical sciences, analytical philosophy and information and communication technologies.
+
+It provides the connection between the physical world, materials characterisation world and materials modelling world.
+
+EMMO is released under a Creative Commons license Attribution 4.0 International (CC BY 4.0)."""@en ,
+ """Everything needed to describe fundamental quantities in electrochemistry common to all electrochemical systems.
+
+Released under the Creative Commons license Attribution 4.0 International (CC BY 4.0)."""@en ,
+ """Introduces the fundamental mereocausal (and mereotopological) concepts of EMMO and their relations with the real world entities that they represent. EMMO uses mereocausality as the ground for all the subsequent ontology modules.
+The concept of causal connection is used to define the first distinction between ontology entities namely the item and collections. Items are causally self-connected objects, while collections are causally disconnected.
+Quantum mereology is based on the concept of quantum entity. This module introduces also the fundamental mereotopological relations used to distinguish between space and time dimensions, making spacetime emerge from underlying network of causal relations between quantum entities."""@en ,
+ "The 'noncoherentsiunits' module contains non-coherent SI derived units. This include ."@en ,
+ """The EMMO perspectives level ontology is a container for the EMMO perspectives level ontologies.
+
+The perspectives level ontologies act as roots for extending the EMMO towards specific application domains. They describe the world from different perspectives, including
+ - physicalistic
+ - holistic
+ - reductionistic
+ - perceptual
+ - data
+ - semiotic
+ - persistence"""@en ,
+ "The chemistry module populates the physicalistic perspective with materials subclasses categorised according to modern applied chemistry."@en ,
+ "The domain module is a container that imports some common domain extensions of EMMO perspectives. The intension is to provide examples for developers of EMMO-based domain ontologies."@en ,
+ "The materials module populates the physicalistic perspective with materials subclasses categorised according to modern applied physical sciences."@en ,
+ "The math module defines the formal language of mathematics. Mathematical objects represents graphical objects based on graphical symbols arranged according the rules of math."@en ,
+ "The models module defines models as semiotic signs that stands for an object by resembling or imitating it, in shape or by sharing a similar logical structure."@en ,
+ "The module 'coherentsiunits' contain coherent derived SI units. For each physical dimensionality there exists one and only one coherent derived SI unit. Examples of such units are m/s, Pa·m, etc..."@en ,
+ "The module 'prefixedsiunits' contains prefixed SI units, like km, ms, MPa, etc..."@en ,
+ "The module 'siacceptedunits' include non-SI units that are accepted for use with the SI units as well as derived units constructed from SI and SI-accepted units."@en ,
+ """The module 'sidimensionalunits' defines SI dimensional unit classes. These classes provide a categorisation of all units according to their SI physical dimensions.
+
+This module provides a connection between physical quantities defined in the 'isq' modules and the units defined in the 'siunits' and 'unitsextension' modules."""@en ,
+ """The module 'siunits' defines the 7 base units and 22 derived units as well as the metric prefixes specified in the SI system.
+
+All additional derived units, SI-based or not, goes into the 'units-extension' module."""@en ,
+ "The periodic table domain ontology provide a simple reference implementation of all atoms in the periodic table with a few selected conventional properties. It is ment as both an example for other domain ontologies as well as a useful assert by itself. Periodic table is released under the Creative Commons Attribution 4.0 International license (CC BY 4.0)."@en ,
+ """The perspective module provides the practical implementation of the EMMO pluralistic approach for which the only objective categorization is provided by the Universe individual and all the Quantum individuals.
+
+Between these two extremes, there are several subjective ways to categorize real world objects, each one provide under a 'Perspective' subclass."""@en ,
+ """The semiotics module is based on the semiotic theory by Charles S. Peirce. It introduces the triadic semiotic process, called semiosis, with its participants an 'object' that is represented by a 'sign' producing another sign, the 'interpretant' and finally the 'interpreter' who connects the 'object', 'sign' and 'interpretant'.
+
+The role of abstract objects are in EMMO fulfilled by semiotic objects, i.e. real world objects (e.g. symbol or sign) that stand for other real world objects that are to be interpreted by an agent. These symbols appear in actions (semiotic processes) meant to communicate meaning by establishing relationships between symbols (signs)."""@en ;
+ "Access, DE" ,
+ "Adham Hashibon, Fraunhofer IWM (DE)" ,
+ "Adham Hashibon, Fraunhofer IWM, DE" ,
+ "Adham Hashibon, University College of London, UK"@en ,
+ "Anne de Baas, Goldbeck Consulting Ltd, UK"@en ,
+ "Frabcesca L. Bleken, SINTEF (NO)" ,
+ "Francesca L. Bleken, SINTEF (NO)" ,
+ "Francesca Lønstad Bleken, SINTEF, NO"@en ,
+ "Francesco A. Zaccarini, University of Bologna (IT)" ,
+ "Francesco Zaccarini, University of Bologna, IT"@en ,
+ "Fraunhofer IWM, DE" ,
+ "Georg Schmitz, Access (DE)" ,
+ "Georg Schmitz, Access, DE" ,
+ "Georg Schmitz, Access, DE"@en ,
+ "Gerhard Goldbeck, Boldbeck Consulting Ltd (UK)" ,
+ "Gerhard Goldbeck, Goldbeck Consulting Ltd (UK)" ,
+ "Gerhard Goldbeck, Goldbeck Consulting Ltd, UK"@en ,
+ "Goldbeck Consulting Ltd (UK)" ,
+ "Ilaria Maria Paponetti, University of Bologna (IT)" ,
+ "Jesper Friis, SINTEF, NO" ,
+ "Jesper Friis, SINTEF, NO"@en ,
+ "Michael Noeske, FRAUNHOFER IFAM, DE"@en ,
+ "SINTEF, NO" ,
+ "Sebastiano Moruzzi, University of Bologna, IT"@en ,
+ "Simon Clark, SINTEF (NO)" ,
+ "University of Bologna, IT" ;
+ "Adham Hashibon" ,
+ "Emanuele Ghedini" ,
+ "Emanuele Ghedini, University of Bologna (IT)" ,
+ "Emanuele Ghedini, University of Bologna, IT" ,
+ "Emanuele Ghedini, University of Bologna, IT"@en ,
+ "Francesca Lønstad Bleken, SINTEF, NO"@en ,
+ "Georg Schmitz" ,
+ "Gerhard Goldbeck" ,
+ "Gerhard Goldbeck, Goldbeck Consulting Ltd (UK)" ,
+ "Jesper Friis" ,
+ "Jesper Friis, SINTEF (NO)" ,
+ "Jesper Friis, SINTEF, NO"@en ;
+ "https://creativecommons.org/licenses/by/4.0/legalcode" ,
+ "https://creativecommons.org/licenses/by/4.0/legalcode"@en ;
+ "EMMC ASBL" ,
+ "EMMC ASBL"@en ,
+ """EMMC ASBL
+European Materials Modelling Council
+Silversquare Stéphanie
+Avenue Louise 54
+1050 Brussels
+CBE no: 0731 621 312
+contact@emmc.eu"""@en ;
+ "Chemistry"@en ,
+ "Distinctional"@en ,
+ "Domain"@en ,
+ "EMMO perspectives-level ontology"@en ,
+ "Elementary Multiperspective Material Ontology"@en ,
+ "Elementary Multiperspective Material Ontology (EMMO)"@en ,
+ "Holistic"@en ,
+ "Information"@en ,
+ "International System of Quantities (ISQ)"@en ,
+ "Manufacturing"@en ,
+ "Materials"@en ,
+ "Math"@en ,
+ "Mereocausality"@en ,
+ "Metrology"@en ,
+ "Models"@en ,
+ "Perceptual"@en ,
+ "Periodic table"@en ,
+ "Persholistic"@en ,
+ "Persistence"@en ,
+ "Perspective"@en ,
+ "Physicalistic"@en ,
+ "Properties"@en ,
+ "Reductionistic"@en ,
+ "SI dimensional units"@en ,
+ "SI units"@en ,
+ "Semiotics"@en ,
+ "Symbolic"@en ,
+ "Units extension"@en ;
+ rdfs:comment """Contacts:
+Gerhard Goldbeck
+Goldbeck Consulting Ltd (UK)
+email: gerhard@goldbeck-consulting.com
+
+Emanuele Ghedini
+University of Bologna (IT)
+email: emanuele.ghedini@unibo.it"""@en ,
+ "Contacts: emmo@emmc.eu"@en ,
+ """Note: this file has automatically been populated with dimensional units from QUDT.
+
+We kindly acknowledge NIST for reusing their content, including the physical dimensionality of units."""@en ,
+ """Note: this file has automatically been populated with dimensional units from QUDT.
+
+We kindly acknowledge NIST for reusing their content, including the selection of units, their elucidations and conversion multiplier."""@en ,
+ """Note: this file has automatically been populated with units from QUDT.
+
+We kindly acknowledge NIST for reusing their content, including the selection of units, their elucidations and conversion multiplier."""@en ,
+ "The EMMO requires FaCT++ reasoner plugin in order to visualize all inferences and class hierarchy (ctrl+R hotkey in Protege)."@en ,
+ "The EMMO requires FacT++ reasoner plugin in order to visualize all inferences and class hierarchy (ctrl+R hotkey in Protege)."@en ,
+ "The EMMO should be reasoned in order to visualize all inferences and class hierarchy in Protege (ctrl+R hotkey). It is tested with both the HermiT (preferred) and FacT++ reasoners."@en ,
+ "The EMMO should be reasoned with HermiT to visualize all inferences and class hierarchy (ctrl+R hotkey in Protege)."@en ;
+ owl:versionInfo "0.6.0" ,
+ "1.0.0-beta5" ,
+ "1.0.0-beta5"@en ;
+ "https://github.com/emmo-repo/EMMO/raw/master/doc/emmo-logo.png" .
+
+#################################################################
+# Annotation properties
+#################################################################
+
+### http://emmo.info/emmo#EMMO_0b1cbe60_d380_4787_b92e_be26bdacf2c2
+ rdf:type owl:AnnotationProperty ;
+ "The UN/CEFACT Recommendation 20 provides three character alphabetic and alphanumeric codes for representing units of measurement for length, area, volume/capacity, mass (weight), time, and other quantities used in international trade. The codes are intended for use in manual and/or automated systems for the exchange of information between participants in international trade."@en ;
+ "uneceCommonCode"@en .
+
+
+### http://emmo.info/emmo#EMMO_1246b120_abbe_4840_b0f8_3e4348b24a17
+ rdf:type owl:AnnotationProperty ;
+ "A person or organisation acting as a contact point for enquiries about the ontology resource"@en ;
+ "The annotation should include an email address."@en ;
+ "contact"@en .
+
+
+### http://emmo.info/emmo#EMMO_1f1b164d_ec6a_4faa_8d5e_88bda62316cc
+ rdf:type owl:AnnotationProperty ;
+ "URL to corresponing entity in QUDT."@en ;
+ rdfs:seeAlso "http://www.qudt.org/2.1/catalog/qudt-catalog.html"@en ;
+ "qudtReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_209ba1b3_149f_4ff0_b672_941610eafd72
+ rdf:type owl:AnnotationProperty ;
+ "IRI to corresponding concept in the Ontology of units of Measure."@en ;
+ rdfs:seeAlso "https://enterpriseintegrationlab.github.io/icity/OM/doc/index-en.html" ,
+ "https://github.com/HajoRijgersberg/OM" ;
+ "omReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54
+ rdf:type owl:AnnotationProperty ;
+ "URL corresponding to entry in Wikidata."@en ;
+ rdfs:seeAlso "https://www.wikidata.org/" ;
+ "wikidataReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_31252f35_c767_4b97_a877_1235076c3e13
+ rdf:type owl:AnnotationProperty ;
+ "The conceptualisation annotation is a comment that helps the reader to understand how the world has been conceptualised by the ontology authors."@en ;
+ "A conceptualisation is the preliminary step behind each theory, preceding each logical formalisation. The readers approaching an ontology entity should first read the conceptualisation annotation to clearly understand \"what we are talking about\" and the accompanying terminology, and then read the elucidation."@en ,
+ "An elucidation can provide references to external knowledge sources (i.e. ISO, Goldbook, RoMM)."@en ;
+ "conceptualisation"@en .
+
+
+### http://emmo.info/emmo#EMMO_33ae2d07_5526_4555_a0b4_8f4c031b5652
+ rdf:type owl:AnnotationProperty ;
+ "Unified Code for Units of Measure (UCUM)."@en ;
+ "The Unified Code for Units of Measure (UCUM) is a code system intended to include all units of measures being contemporarily used in international science, engineering, and business. The purpose is to facilitate unambiguous electronic communication of quantities together with their units."@en ;
+ rdfs:seeAlso "https://ucum.org/"^^xsd:anyURI ;
+ "ucumCode"@en .
+
+
+### http://emmo.info/emmo#EMMO_371f5265_fa29_4081_b722_2c530b1fdddb
+ rdf:type owl:AnnotationProperty ;
+ "Pubchem URI for a compound or substance ID."@en ;
+ "pubChemReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_3aa37f92_8dc5_4ee4_8438_e41e6ae20c62
+ rdf:type owl:AnnotationProperty ;
+ "ISO9000Reference"@en .
+
+
+### http://emmo.info/emmo#EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f
+ rdf:type owl:AnnotationProperty ;
+ "URL for the entry in the International Electrotechnical Vocabulary (IEV)."@en ;
+ rdfs:seeAlso "https://www.electropedia.org/" ;
+ "IEVReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25
+ rdf:type owl:AnnotationProperty ;
+ "URL to corresponding dpbedia entry."@en ;
+ rdfs:seeAlso "https://wiki.dbpedia.org/" ;
+ "dbpediaReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_705f27ae_954c_4f13_98aa_18473fc52b25
+ rdf:type owl:AnnotationProperty ;
+ "The etymology annotation explains the origin of a word and the historical development of its meaning."@en ;
+ "Definitions are usually taken from Wiktionary."@en ,
+ "The etymology annotation is usually applied to rdfs:label entities, to better understand the connection between a label and the concept it concisely represents."@en ;
+ "etymology"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource ;
+ owl:annotatedProperty ;
+ owl:annotatedTarget "Definitions are usually taken from Wiktionary."@en ;
+ rdfs:seeAlso "https://en.wiktionary.org/wiki/Wiktionary"@en
+ ] .
+
+
+### http://emmo.info/emmo#EMMO_70fe84ff_99b6_4206_a9fc_9a8931836d84
+ rdf:type owl:AnnotationProperty ;
+ "Precise and univocal description of an ontological entity in the framework of an axiomatic system."@en ;
+ "A definition univocally determines a OWL entity using necessary and sufficient conditions referring to other OWL entities."@en ;
+ "definition"@en .
+
+
+### http://emmo.info/emmo#EMMO_7f1dec83_d85e_4e1b_b7bd_c9442d4f5a64
+ rdf:type owl:AnnotationProperty ;
+ "The standard symbol for a unit."@en ;
+ "A unit symbol may be a symbolic construct (e.g. km) or a symbol (e.g. m)."@en ;
+ "unitSymbol"@en .
+
+
+### http://emmo.info/emmo#EMMO_8de5d5bf_db1c_40ac_b698_095ba3b18578
+ rdf:type owl:AnnotationProperty ;
+ "Corresponding item number in ISO 80 000."@en ;
+ "3-1.1 (ISO80000 reference to length)"@en ;
+ rdfs:seeAlso "https://www.iso.org/obp/ui/#iso:std:iso:80000:-1:ed-1:v1:en"@en ;
+ "ISO80000Reference"@en .
+
+
+### http://emmo.info/emmo#EMMO_964568dd_64d2_454b_a12f_ac389f1c5e7f
+ rdf:type owl:AnnotationProperty ;
+ "ISO14040Reference"@en .
+
+
+### http://emmo.info/emmo#EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9
+ rdf:type owl:AnnotationProperty ;
+ "Short enlightening explanation aimed to facilitate the user in drawing the connection (interpretation) between a OWL entity and the real world object(s) for which it stands."@en ;
+ "An elucidation should address the real world entities using the concepts introduced by the conceptualisation annotation."@en ;
+ "elucidation"@en .
+
+
+### http://emmo.info/emmo#EMMO_b292d30e_4d60_43f5_9f3e_9c4e00e17a10
+ rdf:type owl:AnnotationProperty .
+
+
+### http://emmo.info/emmo#EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a
+ rdf:type owl:AnnotationProperty ;
+ "Illustrative example of how the entity is used."@en ;
+ "example"@en .
+
+
+### http://emmo.info/emmo#EMMO_b8c10b72_7cc1_4e82_b4ab_728faf504919
+ rdf:type owl:AnnotationProperty ;
+ "Corresponds to the molecular formula of the compound."@en ;
+ "molecularFormula"@en .
+
+
+### http://emmo.info/emmo#EMMO_bb49844b_45d7_4f0d_8cae_8e552cbc20d6
+ rdf:type owl:AnnotationProperty ;
+ "quantity value (term in VIM that corresponds to Quantity in EMMO)"@en ;
+ "The term in the International vocabulary of metrology (VIM) (JCGM 200:2008) that corresponds to the annotated term in EMMO."@en ;
+ rdfs:seeAlso "https://www.bipm.org/documents/20126/2071204/JCGM_200_2012.pdf"^^xsd:anyURI ;
+ "VIMTerm"@en .
+
+
+### http://emmo.info/emmo#EMMO_c6e77b51_681b_4d04_b20d_a08f2b977470
+ rdf:type owl:AnnotationProperty ;
+ "Axiom not included in the theory because of OWL 2 DL global restrictions for decidability."@en ;
+ "OWLDLRestrictedAxiom"@en .
+
+[ rdf:type owl:Axiom ;
+ owl:annotatedSource ;
+ owl:annotatedProperty ;
+ owl:annotatedTarget "Axiom not included in the theory because of OWL 2 DL global restrictions for decidability."@en ;
+ rdfs:seeAlso "https://www.w3.org/TR/2012/REC-owl2-syntax-20121211/#Global_Restrictions_on_Axioms_in_OWL_2_DL"^^xsd:anyURI
+ ] .
+
+
+### http://emmo.info/emmo#EMMO_c7b62dd7_063a_4c2a_8504_42f7264ba83f
+ rdf:type owl:AnnotationProperty ;
+ "A text that add some information about the entity."@en ;
+ "A comment can be addressed to facilitate interpretation, to suggest possible usage, to clarify the concepts behind each entity with respect to other ontological apporaches."@en ;
+ "comment"@en .
+
+
+### http://emmo.info/emmo#EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d
+ rdf:type owl:AnnotationProperty ;
+ "URL to corresponding Wikipedia entry."@en ;
+ rdfs:seeAlso "https://www.wikipedia.org/" ;
+ "wikipediaReference"@en .
+
+
+### http://emmo.info/emmo#EMMO_f652e7d2_0b33_4d10_8d0f_2f70089982ba
+ rdf:type owl:AnnotationProperty ;
+ "Corresponds to the IUPAC name of the compound."@en ;
+ "IUPACName"@en .
+
+
+### http://emmo.info/emmo#EMMO_fe015383_afb3_44a6_ae86_043628697aa2
+ rdf:type owl:AnnotationProperty ;
+ rdfs:comment "DOI to corresponding concept in IUPAC"@en ;
+ rdfs:seeAlso "https://goldbook.iupac.org/"^^xsd:anyURI ;
+ "iupacReference"@en .
+
+
+### http://emmo.info/emmo#157fdf31_6387_42be_8e72_10530519214a
+ rdf:type owl:AnnotationProperty ;
+ "A link to a graphical representation aimed to facilitate understanding of the concept, or of an annotation." ;
+ "figure"@en .
+
+
+### http://purl.org/dc/terms/abstract
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/contributor
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/creator
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/license
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/publisher
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/references
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/source
+ rdf:type owl:AnnotationProperty .
+
+
+### http://purl.org/dc/terms/title
+ rdf:type owl:AnnotationProperty .
+
+
+### http://www.w3.org/2000/01/rdf-schema#seeAlso
+rdfs:seeAlso rdfs:comment """EMMO applies the naming convension to its sub-properties of rdfs:seeAlso that their label must end with one of the following terms:
+ - 'Match': resolvable URLs to corresponding entity in another ontology
+ - 'Entry': resolvable URLs to a human readable resource describing the subject
+ - 'Ref': non-resolvable reference to a human readable resource describing the subject"""@en ,
+ "Indicate a resource that might provide additional information about the subject resource."@en .
+
+
+### http://www.w3.org/2002/07/owl#minQualifiedCardinality
+owl:minQualifiedCardinality rdf:type owl:AnnotationProperty .
+
+
+### http://www.w3.org/2002/07/owl#qualifiedCardinality
+owl:qualifiedCardinality rdf:type owl:AnnotationProperty .
+
+
+### http://www.w3.org/2004/02/skos/core#altLabel
+ rdf:type owl:AnnotationProperty .
+
+
+### http://www.w3.org/2004/02/skos/core#prefLabel
+ rdf:type owl:AnnotationProperty .
+
+
+### http://xmlns.com/foaf/0.1/logo
+ rdf:type owl:AnnotationProperty .
+
+
+#################################################################
+# Object Properties
+#################################################################
+
+### http://emmo.info/emmo#EMMO_01e5766d_dac3_4574_8a78_310de92a5c9d
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf ;
+ owl:propertyDisjointWith ;
+ "x isNotCauseOf y iff not(x isCauseOf y)"@en ;
+ rdfs:seeAlso ;
+ "isNotCauseOf"@en .
+
+
+### http://emmo.info/emmo#EMMO_057d0573_6ac0_4c27_9e3f_3c29205fd104
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf ;
+ rdfs:domain ;
+ rdfs:range ;
+ "hasDeducer"@en .
+
+
+### http://emmo.info/emmo#EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf ;
+ rdfs:range ;
+ rdfs:comment "Relates an object to a quantity describing a quantifiable property of the object obtained via a well-defined procedure."@en ;
+ "hasObjectiveProperty"@en .
+
+
+### http://emmo.info/emmo#EMMO_0b1502e2_d12f_4ff3_83b1_eeedf9382954
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf ;
+ rdfs:domain ;
+ "The relation between a process and the entity that represents how things have turned out."@en ;
+ "hasOutcome"@en .
+
+
+### http://emmo.info/emmo#EMMO_0d829933_29e3_4e61_b3d3_88e6b9d0d0ce
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf ;
+ rdfs:domain ;
+ rdfs:range ;
+ "hasDeclared"@en .
+
+
+### http://emmo.info/emmo#EMMO_0e86a108_9d4d_4582_8126_f0c527d81901
+ rdf:type owl:ObjectProperty ;
+ rdfs:subPropertyOf