diff --git a/.github/workflows/doc.yml b/.github/workflows/doc.yml index d8ca830..6d12a0f 100644 --- a/.github/workflows/doc.yml +++ b/.github/workflows/doc.yml @@ -33,35 +33,35 @@ jobs: pip install Markdown==3.4.3 rdflib==6.3.2 pandoc # Add any other dependencies if needed - name: Render documentation from ttl - run: python sphinx/ttl_to_rst.py + run: python docs/ttl_to_rst.py - name: Build HTML uses: ammaraskar/sphinx-action@master with: - docs-folder: "sphinx/" + docs-folder: "docs/" pre-build-command: "apt-get update -y; apt-get install -y pandoc" - name: Create context file from ttl - run: python sphinx/ttl_to_context.py + run: python docs/ttl_to_context.py - name: Check if HTML context directory exists run: | - if [ ! -d "sphinx/_build/html/context/" ]; then + if [ ! -d "docs/_build/html/context/" ]; then echo "Creating HTML context directory" - sudo mkdir -p sphinx/_build/html/context/ + sudo mkdir -p docs/_build/html/context/ else echo "HTML context directory already exists" fi - if [ ! -d "sphinx/_build/html/version/" ]; then + if [ ! -d "docs/_build/html/version/" ]; then echo "Creating HTML versions directory" - sudo mkdir -p sphinx/_build/html/version/ + sudo mkdir -p docs/_build/html/version/ else echo "HTML version directory already exists" fi - name: Copy context file to HTML directory - run: sudo cp context/context.json sphinx/_build/html/context/ + run: sudo cp context/context.json docs/_build/html/context/ - name: Commit changes run: | @@ -78,17 +78,17 @@ jobs: run: | git fetch --tags git tag | while read TAG; do - sudo mkdir -p "sphinx/_build/html/version/$TAG" - sudo cp "electrochemistry.ttl" "sphinx/_build/html/version/$TAG/" - sudo cp "electrochemistry-inferred.ttl" "sphinx/_build/html/version/$TAG/" - sudo cp "electrochemicalquantities.ttl" "sphinx/_build/html/version/$TAG/" + sudo mkdir -p "docs/_build/html/version/$TAG" + sudo cp "electrochemistry.ttl" "docs/_build/html/version/$TAG/" + sudo cp "electrochemistry-inferred.ttl" "docs/_build/html/version/$TAG/" + sudo cp "electrochemicalquantities.ttl" "docs/_build/html/version/$TAG/" if [ -d "context" ]; then echo "Context directory exists, copying context.json to $TAG" # Make sure the context directory exists in the version-specific directory - sudo mkdir -p "sphinx/_build/html/version/$TAG/context" + sudo mkdir -p "docs/_build/html/version/$TAG/context" # Copy context.json to the tag-specific context directory - sudo cp "context/context.json" "sphinx/_build/html/version/$TAG/context" + sudo cp "context/context.json" "docs/_build/html/version/$TAG/context" else echo "No context directory found in the source directory." fi @@ -98,13 +98,13 @@ jobs: uses: actions/upload-artifact@v4 with: name: documentationHTML - path: sphinx/_build/html/ + path: docs/_build/html/ - name: Deploy uses: peaceiris/actions-gh-pages@v3 if: github.ref == 'refs/heads/master' with: github_token: ${{ secrets.GITHUB_TOKEN }} - publish_dir: sphinx/_build/html + publish_dir: docs/_build/html diff --git a/_deprecate/docs/about.html b/_deprecate/docs/about.html deleted file mode 100644 index 8707d27..0000000 --- a/_deprecate/docs/about.html +++ /dev/null @@ -1,44 +0,0 @@ - - - - - - BattINFO - - - - - - -

About Electrochemistry Domain Ontology

-

Contributors

- -

Projects

- -

License

-

The Battery Interface Domain Ontology is released under the Creative Commons Attribution 4.0 International license (CC BY 4.0).

- - - \ No newline at end of file diff --git a/_deprecate/docs/assets/about.md b/_deprecate/docs/assets/about.md deleted file mode 100644 index 3389d3f..0000000 --- a/_deprecate/docs/assets/about.md +++ /dev/null @@ -1,33 +0,0 @@ -# About Electrochemistry Domain Ontology - - -## Contributors - -* Simon Clark, SINTEF, Norway -* Eibar Flores, SINTEF, Norway -* Francesca Lønstad Bleken, SINTEF, Norway -* Jesper Friis, SINTEF, Norway -* Casper Welzel Andersen, SINTEF, Norway -* Martin Uhrin, EPFL, Switzerland -* Simon Stier, Fraunhofer, Germany -* Marek Marcinek, Warsaw University of Technology, Poland -* Anna Szczesna, Warsaw University of Technology, Poland -* Miran Gaberscek, National Institute of Chemistry, Slovenia -* Deyana Stoytcheva, ICMAB, Spain -* Rosa Palacin, ICMAB, Spain -* Ingeborg-Helene Svenum, SINTEF, Norway -* Inga Gudem Ringdalen, SINTEF, Norway -* Emanuele Farhi, SOLEIL synchrotron, France - -## Projects - -* [BIG-MAP](http://www.big-map.eu/); Grant Agreement No: 957189 BIG-MAP - -## License - -The Battery Interface Domain Ontology is released under the [Creative Commons Attribution 4.0 International](https://creativecommons.org/licenses/by/4.0/legalcode) license (CC BY 4.0). - - - - - diff --git a/_deprecate/docs/assets/banner.jpg b/_deprecate/docs/assets/banner.jpg deleted file mode 100644 index 5300d75..0000000 Binary files a/_deprecate/docs/assets/banner.jpg and /dev/null differ diff --git a/_deprecate/docs/assets/banner.svg b/_deprecate/docs/assets/banner.svg deleted file mode 100644 index 941f0cf..0000000 --- a/_deprecate/docs/assets/banner.svg +++ /dev/null @@ -1,294 +0,0 @@ - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - BattINFO - Electrochemistry Domain - - diff --git a/_deprecate/docs/assets/contribute.md b/_deprecate/docs/assets/contribute.md deleted file mode 100644 index 295935e..0000000 --- a/_deprecate/docs/assets/contribute.md +++ /dev/null @@ -1,31 +0,0 @@ -# Contributing to the ontology - -There are two ways you can contribute to the ontology. - -### Suggest minor changes on existing elements - -[Create a feature request](https://github.com/emmo-repo/domain-electrochemistry/issues/new) in a [Github Issue](https://docs.github.com/en/issues/tracking-your-work-with-issues/creating-an-issue) to suggest edits to names, defintions, references on existing classes and properties. - -### Propose additions/deletion of elements - -> **_NOTE:_** We recommend contacting some of [BattINFO](https://github.com/BIG-MAP/BattINFO) contributors in advance to discuss which additions deletions you wish to make. - -We recommend using the [forking workflow](https://www.atlassian.com/git/tutorials/comparing-workflows/forking-workflow) to contribute additions/deletions. -Fork this repository, clone the fork on your local PC, create your branch based on the existing `dev` branch (e.g. `dev_john_doe`) and work on the editions in you local copy. - -You can edit ontologes in two main ways. -One is programmatically, using for instance [EMMOntoPy](https://github.com/emmo-repo/EMMOntoPy). -The second and more common is using the interface provided by the Protégé software. -In case of the latter, [install Protégé](https://protege.stanford.edu/) and use it to open the ontology file you wish to edit. -Before adding elements, ensure Prot´égé is configured to create IRIs in the right format: - -* Open Protégé -* Go to File/Open and load the ontology file you wish to modify -* Go to File/Preferences and there go to the New Entities Tab -* Ensure you have configured the preferences as shown below: - - ![Protege config.](doc/img/protege_config_contribute.png) - Here is the "Specified IRI" for you to copy: ```https://emmo.info/electrochemistry#``` - -* Once you have made your changes, commit them to your fork and [create a pull request](https://docs.github.com/en/pull-requests/collaborating-with-pull-requests/proposing-changes-to-your-work-with-pull-requests/creating-a-pull-request). -* We will merge the request after assessing it. \ No newline at end of file diff --git a/_deprecate/docs/assets/favicon.ico b/_deprecate/docs/assets/favicon.ico deleted file mode 100644 index 5c6375d..0000000 Binary files a/_deprecate/docs/assets/favicon.ico and /dev/null differ diff --git a/_deprecate/docs/assets/images/bigmap_logo.png b/_deprecate/docs/assets/images/bigmap_logo.png deleted file mode 100644 index 122f0e5..0000000 Binary files a/_deprecate/docs/assets/images/bigmap_logo.png and /dev/null differ diff --git a/_deprecate/docs/assets/images/flag_of_europe.png b/_deprecate/docs/assets/images/flag_of_europe.png deleted file mode 100644 index 31d7460..0000000 Binary files a/_deprecate/docs/assets/images/flag_of_europe.png and /dev/null differ diff --git a/_deprecate/docs/assets/index.md b/_deprecate/docs/assets/index.md deleted file mode 100644 index 5a4a028..0000000 --- a/_deprecate/docs/assets/index.md +++ /dev/null @@ -1,21 +0,0 @@ - -| [**About**](./about.html) | [**Contribute**](./contribute.html) | [![BattINFO Github](https://badgen.net/badge/icon/github?icon=github&label)](https://github.com/emmo-repo/domain-electrochemistry) - -An electrochemistry domain ontology developed in the [BIG-MAP][2] project. -The ontology is a part of the [Battery Interface Domain Ontology (BattINFO)](https://big-map.github.io/BattINFO/). - -The ontology is based on [EMMO][1]. - -The Electrochemistry Domain ontology is a digital resource to support interoperability of electrochemical data. - -This ontology consists of a list of entities representing concepts used in electrochemistry. Each entity has a unique identifier (IRI) and is annotated with additional information, such as its preferred name ("prefLabel"), alternative names, definition, references, etc. As users link their research resources to ontology entities, they are effectively describing their resource using a common vocabulary. Resources can be datasets, documents, persons, organizations, equipment, samples... anything linked to the common vocabulary described in this ontology, becomes part of an ecosystem of Findable resources. - - -### [See list of entities](./electrochemistry.html) - - -[1]: https://github.com/emmo-repo/EMMO -[2]: https://www.big-map.eu - - - diff --git a/_deprecate/docs/contribute.html b/_deprecate/docs/contribute.html deleted file mode 100644 index b385f1f..0000000 --- a/_deprecate/docs/contribute.html +++ /dev/null @@ -1,46 +0,0 @@ - - - - - - BattINFO - - - - - - -

Contributing to the ontology

-

There are two ways you can contribute to the ontology.

-

Suggest minor changes on existing elements

-

Create a feature request in a Github Issue to suggest edits to names, defintions, references on existing classes and properties.

-

Propose additions/deletion of elements

-
-

NOTE: We recommend contacting some of BattINFO contributors in advance to discuss which additions deletions you wish to make.

-
-

We recommend using the forking workflow to contribute additions/deletions. -Fork this repository, clone the fork on your local PC, create your branch based on the existing dev branch (e.g. dev_john_doe) and work on the editions in you local copy.

-

You can edit ontologes in two main ways. -One is programmatically, using for instance EMMOntoPy. -The second and more common is using the interface provided by the Protégé software. -In case of the latter, install Protégé and use it to open the ontology file you wish to edit. -Before adding elements, ensure Prot´égé is configured to create IRIs in the right format:

- -

Protege config.
- Here is the "Specified IRI" for you to copy: https://emmo.info/electrochemistry#

- - - - \ No newline at end of file diff --git a/_deprecate/docs/css/style.css b/_deprecate/docs/css/style.css deleted file mode 100644 index f2418aa..0000000 --- a/_deprecate/docs/css/style.css +++ /dev/null @@ -1,68 +0,0 @@ -body { - font-family: Helvetica, sans-serif; - margin: 40px auto; - max-width: 800px; - padding: 0 20px; -} - -.banner { - display: flex; - flex-direction: column; - align-items: center; - margin: 0 auto; - max-width: 100%; - overflow: hidden; -} - - -h1, h2, h3 { - color: #333; -} - -h1 { - font-size: 24px; - margin-bottom: 20px; -} - -h2 { - font-size: 20px; - margin-bottom: 15px; -} - -h3 { - font-size: 18px; - margin-bottom: 10px; -} - -p { - line-height: 1.5; - text-align: justify; -} - -p.entity { - margin-bottom: -0.1em; - line-height: 1.3; - } - -a { - color: #002a57; -} - -code { - background-color: #f8f8f8; - padding: 2px 4px; - font-family: Consolas, Monaco, monospace; -} - -blockquote { - border-left: 3px solid #333; - margin: 0; - padding-left: 10px; - color: #777; -} - -hr { - border: none; - border-top: 1px solid #ccc; - margin: 20px 0; -} diff --git a/_deprecate/docs/electrochemistry.html b/_deprecate/docs/electrochemistry.html deleted file mode 100644 index 7085078..0000000 --- a/_deprecate/docs/electrochemistry.html +++ /dev/null @@ -1,704 +0,0 @@ - - - - - - BattINFO - - - - - - -

Quantities used in Electrochemistry

-

ActivationOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fa406b0_512a_4d59_9e0c_5d8aba0103ae

Elucidation: part of the electrode polarization arising from a charge-transfer step of the electrode reaction

Alternative Label(s): ActivationPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-05


-

AdsorptionCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6

Elucidation: electric current that accompanies the adsorption of a species

IUPAC Reference: https://goldbook.iupac.org/terms/view/A00159


-

AmbientThermodynamicTemperature

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e


-

AmplitudeOfAlternatingCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10eb778d_da60_4832_a355_4ee74baea650

Elucidation: half the peak-to-peak amplitude of a sinusoidal alternating current

IUPAC Reference: https://doi.org/10.1351/goldbook.A00310


-

AmplitudeOfAlternatingVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f591a444_89d6_4093_836d_7d53895edce4

Elucidation: half of the peak-to-peak amplitude of a periodic voltage perturbation within a single time period, with respect to a reference potential value

IUPAC Reference: https://doi.org/10.1351/goldbook.A00311


-

AnodicOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_565c0b10_70fe_441a_b76a_b9a8e08ca7b7

Elucidation: electrode polarization associated with an electrochemical oxidation reaction

Alternative Label(s): AnodicPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-06


-

AreicCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bcb33f7e_5573_4bc2_b636_4ea313a9dd3a

Elucidation: quotient of the capacity of a battery cell or battery by its plane area.

Alternative Label(s): ArealCapacity

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-20


-

BaselineCellVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a

Elucidation: In electrochemical measurements, the voltage of an electrochemical cell to which a voltage signal is superimposed.


-

CRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e1fd84eb_acdb_4b2c_b90c_e899d552a3ee

Elucidation: [an indicator of the] electric current at which a secondary cell or battery is charged

Alternative Label(s): ChargeRate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-45


-

CalenderedCoatingThickness

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9e1c862_c510_4b11_9141_bc91045df817

Elucidation: thickness of the coating after a calendering process


-

CalenderedDensity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_520995f8_ec9c_4b3c_bb64_2cd691947379

Elucidation: density after calendering


-

Capacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_791c1915_a791_4450_acd8_7f94764743b5

Elucidation: electric charge which a cell or battery can deliver under specified conditions

Alternative Label(s): ChargeCapacity, ElectricChargeCapacity, StorageCapacity

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-14


-

CatalyticCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c55bcb85_b7b8_4e67_8a78_9a42fe25b6cf

Elucidation: faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions

IUPAC Reference: https://doi.org/10.1351/goldbook.C00889


-

CathodicOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0853b072_3b80_4864_8147_24ce35407ade

Elucidation: electrode polarization associated with an electrochemical reduction reaction

Alternative Label(s): CathodicPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-07


-

CellCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce


-

CellPolarisationPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_265bb4d6_5eec_40f6_a3fa_59b3bd08e9af

Elucidation: sum of the absolute values of the potential differences resulting from anodic and cathodic polarizations of an electrochemical cell

Alternative Label(s): CellPolarizationPotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-12


-

CellVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d

Elucidation: voltage between the terminals of an electrochemical cell

Alternative Label(s): AppliedPotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-10

IUPAC Reference: https://doi.org/10.1351/goldbook.A00424


-

ChargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10763eb0_dbc9_4d34_bd1a_7b8996590d45

Elucidation: capacity delivered during a charge process


-

ChargeEfficiency

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a5962e05_466d_46a4_8951_bea59d7326e5

Elucidation: ratio of the electric charge discharged from a secondary battery to the electric charge provided during the preceding charge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-39


-

ChargeEnergy

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2ab7af60_da58_4243_b3bc_cbb2155cac53

Elucidation: energy delivered by a deviced under some specific charge conditions


-

ChargeRetention

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47

Elucidation: ability of a cell or battery to retain capacity on open circuit under specified conditions.

Alternative Label(s): CapacityRetention

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-35


-

ChargeTransferCoefficient

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a4dfa5c1_55a9_4285_b71d_90cf6613ca31

Elucidation: the fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate

Wikipedia Reference: https://en.wikipedia.org/wiki/Charge_transfer_coefficient


-

ChargingCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600

Elucidation: electric current applied to a battery during a charging process


-

CoatingThickness

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3b938708_e7e4_4ac0_a959_9c04306302e7

Elucidation: thickness of the coating before any additional treatment is applied


-

ConcentrationLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5eae657f_5914_4252_85c6_3fc772dea113

Elucidation: limit on the amount concentration of a species in a phase, either imposed or naturally occurring


-

ConcentrationOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9ed7210c_c4fa_467b_822d_ba12f885bdf4

Elucidation: The concentration overpotential of an electrode reaction at a given electrode current density (c.d.) is basically the difference in equilibrium potentials across the diffusion layer. More precisely, it is the potential of a reference electrode (of the same electrode reaction as the working electrode ) with the interfacial concentrations which establish themselves at c.d., relative to the potential of a similar reference electrode with the concentrations of the bulk solution. From such a measured potential difference, with c.d. flowing, one needs to subtract the ohmic potential drop prevailing between the two electrodes.

Alternative Label(s): ConcentrationPolarization, MassTransferOverpotential, MassTransferPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-08

IUPAC Reference: https://goldbook.iupac.org/terms/view/C01230

Wikipedia Reference: https://en.wikipedia.org/wiki/Overpotential#Concentration_overpotential


-

ConstantCurrentChargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_37c38b7e_9ded_481a_85fd_a467f1ee2b9f

Elucidation: the capacity obtained during constant current charging of an electrochemical device


-

ConstantCurrentChargePercentage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f073272_8925_4344_995c_a5a6dd1fcde6

Elucidation: the percentage of the total charge capacity that is obtained during a constant current charge process


-

ConstantCurrentDischargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_08833ed2_6324_411a_b34b_fe64c44cd5ef

Elucidation: the capacity obtained during constant current discharging of an electrochemical device


-

ConstantCurrentDischargePercentage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_457aed58_6e7e_42d5_9d78_b424c8d60aa3

Elucidation: the percentage of the total discharge capacity that is obtained during a constant current discharge process


-

ControlProperty

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_33e6986c_b35a_4cae_9a94_acb23248065c

Elucidation: a target quantity in a control system

Alternative Label(s): ControlledQuantity, SetQuantity


-

CoulombicEfficiency

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5696453c_9da7_41e2_bbda_603c1b90a8fc

Elucidation: fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction

Alternative Label(s): CoulombEfficiency, CurrentEfficiency, FaradayEfficiency

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-07


-

CrystalizationOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8de9735b_374a_4a0f_b29f_71a50794cf94

Elucidation: part of the electrode polarization arising from crystal nucleation and growth phenomena

Alternative Label(s): CrystalizationPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-04


-

CurrentChangeLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_71f10616_15eb_4dc4_bc8d_ffaac3838af2


-

CurrentDensityLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76e7e556_f47e_47e2_b2ef_67aeed09c63e

Elucidation: maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-13


-

CurrentLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_74de2c33_84fc_4c2f_afe1_56d169149114

Elucidation: limit on the electric current of an electrical system


-

CurrentScanRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f046d602_22ea_4f9b_9101_319f510d39f0

Elucidation: The rate of change of an applied current with time.


-

Cycle

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8

Elucidation: the number of charge-discharge cycles that an electrochemical device has experienced

Alternative Label(s): CycleIndex, CycleNumber


-

CycleLife

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ae782b14_88ce_4cdd_9418_12aca00be937

Elucidation: the maximum number of cycles achieved in an electrochemical device before reaching some end-of-life criterion

Alternative Label(s): ElectrochemicalCycleLife


-

D10ParticleSize

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b83c6435_6edf_470e_9725_538a853e08f7


-

D50ParticleSize

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c

Elucidation: in particle size distribution measurements, the mass-median-diameter, considered to be the average particle size by mass


-

D90ParticleSize

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8e943e12_ecc0_4093_899e_7226be6be7f2


-

D95ParticleSize

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_02d2d1d1_241c_429b_b4e7_31f2c3dc4835


-

DRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_25e20915_c35d_4bee_ad31_736235a79780

Elucidation: [an indicator of the] electric current at which a battery is discharged

Alternative Label(s): DischargeRate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-25


-

DiffuseLayerPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e38f11d0_a16f_4fe8_8ec5_3fe4493b7759

Elucidation: electric potential difference between the rigid layer and the diffuse layer of a double layer

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-20


-

DiffusionCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90

Elucidation: faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface.

IUPAC Reference: https://goldbook.iupac.org/terms/view/D01722

Wikipedia Reference: https://en.wikipedia.org/wiki/Diffusion_current


-

DiffusionLimitedCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5fb7a03f_d6dd_47ee_9317_0629681c7d00

Elucidation: diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion

Alternative Label(s): LimitingDiffusionCurrent

IUPAC Reference: https://goldbook.iupac.org/terms/view/L03534


-

Diffusivity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_37b24a94_cae0_4d7a_9519_9f7692dec607


-

DischargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0141b5c2_9f15_46f4_82e6_92a104faa476

Elucidation: capacity delivered during a discharge process


-

DischargeCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f

Elucidation: electric current delivered by a battery during its discharge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-24


-

DischargeEnergy

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ca36cbf3_1fed_4b88_9177_b4e16ad00cf7

Elucidation: energy delivered by a deviced under some specific discharge conditions


-

DischargeVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c7b26177_21bf_4787_b656_8e78edf27f88

Elucidation: voltage between the terminals of a cell or battery when being discharged

Alternative Label(s): ClosedCircuitVoltage


-

DoubleLayerCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a56fc557_9dea_42e6_b936_e9d62dcaf84f

Elucidation: non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface

IUPAC Reference: https://goldbook.iupac.org/terms/view/D01847


-

DropTimeInPolarography

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be

Elucidation: the time that elapses between the instants at which two successive drops of liquid metal are detached from the tip of the capillary.

IUPAC Reference: https://doi.org/10.1351/goldbook.D01862


-

ElectrochemicalControlQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5

Elucidation: quantities that control electroanalytical techniques


-

ElectrochemicalKineticQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_21745019_2830_4395_bca7_15ddfd266673

Elucidation: An ElectrochemicalQuantity that relates to the kinetics of a reaction.


-

ElectrochemicalPerformanceQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634


-

ElectrochemicalPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd

Elucidation: the electrochemical potential is the chemical potential of an ion in the presence of an electric potential

IUPAC Reference: https://goldbook.iupac.org/terms/view/E01945

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemical_potential


-

ElectrochemicalProperty

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_900e357f_2ee3_425a_a0b6_322661117787


-

ElectrochemicalQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112

Elucidation: Physical quantities defined within the domain of electrochemistry.


-

ElectrochemicalStabilityLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8f4b90ef_fea4_47c9_99f5_a9b3290a505d

Elucidation: electric potential at which a material undergoes an oxidation or reduction decomposition


-

ElectrochemicalThermodynamicQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2d896559_eee3_447c_9759_87c854a4266a

Elucidation: A thermodynamically derived ElectrochemicalQuantity.


-

ElectrochemicalTransportQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b

Elucidation: An ElectrochemicalQuantity related to the transport of mass, charge, or energy.


-

ElectrochemicalWindow

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_129926b6_fc30_441d_b359_29b44c988514

Elucidation: The electrode electric potential range between which the substance is neither oxidized nor reduced.

Alternative Label(s): ElectrochemicalStabilityWindow

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemical_window


-

ElectrochemicallyActiveSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bad1b6f4_1b26_40e2_b552_6d53873e3973

Elucidation: the area of the electrode material that is accessible to the electrolyte that is used for charge transfer and/or storage

Alternative Label(s): EASA, ECSA, ElectrochemicalActiveSurfaceArea

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-09


-

ElectrodeCoverageDensity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_63a8f9d2_0cf6_484d_b996_2e5c3f0a3c73

Elucidation: amount of a chemical modifier at an electrode surface per unit area

Alternative Label(s): ElectrodeCoverage


-

ElectrodeGeometricSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa7790d6_07bb_4b0f_9965_55966828f5f3

Elucidation: the interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces


-

ElectrodePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f509645f_eb27_470e_9112_7ab828ed40d3

Elucidation: electric potential at an electrode, reported as the difference in potential relative to a reference electrode

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-11

IUPAC Reference: https://goldbook.iupac.org/terms/view/E01956

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrode_potential


-

ElectrodeRealSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a82e16c3_b766_482f_be94_b8e9af37f6fc

Elucidation: surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods


-

ElectrodeSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd

Elucidation: area of electrode - solution interface.


-

ElectrolyteContainment

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83928dce_9746_4452_a9f9_da4366a20ca4

Elucidation: ability of a cell or battery to contain its electrolyte under specified mechanical and environmental conditions

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-31


-

ElectronNumberOfAnElectrochemicalReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_abfadc99_6e43_4d37_9b04_7fc5b0f327ae

Elucidation: number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified

Alternative Label(s): ChargeNumber, NumberOfElectronsTransferred

IUPAC Reference: https://goldbook.iupac.org/terms/view/C00995


-

ElectronicConductivity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744

Elucidation: measure of a substance's tendency towards electronic conduction


-

EnergyDensityOfStorage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b

Elucidation: the quotient of the energy of an energy-storage device or system and its volume

Alternative Label(s): EnergyDensity


-

EnergyEfficiency

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79198264_cdf5_4fc3_8bcf_e5140a52547a

Elucidation: ratio of the electric energy provided from a secondary battery [ or electrochemical device ] during discharge to the electric energy supplied to the battery during the preceding charge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-53


-

EnergyStorageCapability

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46376e5d_9627_4514_9881_9e62083625c3

Elucidation: amount of energy that can be stored in a device under specific conditions

Alternative Label(s): BatteryEnergy

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-21


-

EquilibriumElectrodePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544

Elucidation: potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established

Alternative Label(s): EquilibriumPotential, NernstPotential, ReversiblePotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-12

Wikipedia Reference: https://en.wikipedia.org/wiki/Reversal_potential


-

ExchangeCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ccde24bb_790a_40ca_a06e_cea156a61031

Elucidation: the common value (i0) of the anodic and cathodic partial currents when the reaction is at equilibrium

IUPAC Reference: https://goldbook.iupac.org/terms/view/E02238


-

ExchangeCurrentDensity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e9fd9ef9_adfe_46cb_b2f9_4558468a25e7

Elucidation: defined by j0 = i0/A, where i0 is the exchange current of the electrode reaction and A is usually taken as the geometric area of the electrode

Alternative Label(s): MeanExchangeCurrentDensity

IUPAC Reference: https://goldbook.iupac.org/terms/view/M03777

Wikipedia Reference: https://en.wikipedia.org/wiki/Exchange_current_density


-

FaradaicCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456

Elucidation: electric current that results from the electrooxidation or electroreduction of an electroactive substance

IUPAC Reference: https://goldbook.iupac.org/terms/view/F02321

Wikipedia Reference: https://en.wikipedia.org/wiki/Faradaic_current


-

FaradayConstant

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_77f9d496_555e_4ae2_ae80_f297ef8335ca

Elucidation: fundamental physical constant representing molar elementary charge

IUPAC Reference: https://doi.org/10.1351/goldbook.F02325

Wikipedia Reference: https://en.wikipedia.org/wiki/Faraday_constant


-

FinishingCRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_50674621_09ae_4f03_8ee9_3997b88c8b2a

Elucidation: [an indicator of the] electric current at which a battery is charged towards the end of charge

Alternative Label(s): FinishingChargeRate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-46


-

FormalElectrodePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b21de1ef_6c15_4d63_b320_c9b96fbf186f

Elucidation: equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction

Alternative Label(s): FormalPotential


-

HalfPeakPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c4d551db_db17_4c33_92e6_aec71638afbc

Elucidation: for dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current

IUPAC Reference: https://doi.org/10.1351/goldbook.H02720


-

HalfWavePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d

Elucidation: electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current

IUPAC Reference: https://doi.org/10.1351/goldbook.H02722


-

InitialDischargeVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_74861991_7da2_4e0f_b6c1_b16713f538bf

Elucidation: discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided

Alternative Label(s): InitialClosedCircuitVoltage

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-29


-

InititalThermodynamicTemperature

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9c9b80a4_a00b_4b91_8e17_3a7831f2bf2f


-

InstantaneousCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a24f8581_a5a4_41a4_bb45_d0fdd5c0d810

Elucidation: value of an electric current at an instant in time

IUPAC Reference: https://goldbook.iupac.org/terms/view/I03062


-

InternalApparentResistance

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f94678d6_1386_48fc_8e54_024921924401

Elucidation: quotient of change of voltage of a battery by the corresponding change in discharge current under specified conditions.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-36


-

InternalConductance

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0c9655c6_6b0b_4819_a219_f286ad196fa9


-

InternalResistance

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9bf40017_3f58_4030_ada7_cb37a3dfda2d

Elucidation: impedance of a linear circuit's Thévenin representation

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-15-04

Wikipedia Reference: https://en.wikipedia.org/wiki/Internal_resistance


-

IonConcentration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8177eae6_1631_430d_99f2_942669bcb784

Elucidation: the amount concentration of some ionic species in a given volume of solution

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-16


-

IonicConductivity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc

Elucidation: a measure of a substance's tendency towards ionic conduction

IUPAC Reference: https://doi.org/10.1351/goldbook.I03175

Wikipedia Reference: https://en.wikipedia.org/wiki/Ionic_conductivity_(solid_state)


-

IsopotentialPoint

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ff7797ed_9ef7_40d0_872b_2c215cd54578

Elucidation: electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature

IUPAC Reference: https://doi.org/10.1351/goldbook.I03304


-

KineticCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_98b6e9d7_d5df_46a5_87dd_79642b8b2e4b

Elucidation: faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed

IUPAC Reference: https://goldbook.iupac.org/terms/view/K03399


-

LimitQuantity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b395a244_3a75_4737_be38_981bfa1277fe

Elucidation: a limit quantity in a control system


-

LimitingCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5ac8868_d318_4065_aa23_72140ae888ae

Elucidation: faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion

IUPAC Reference: https://goldbook.iupac.org/terms/view/L03532


-

LimitingMolarConductivity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a17ee4e0_c81a_4a64_9ecb_9c6fa022cf4d

Elucidation: molar conductivity at infinite dilution

Wikipedia Reference: https://en.wikipedia.org/wiki/Molar_conductivity#Variation_of_molar_conductivity_with_dilution


-

LowerFrequencyLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b66d6553_6136_4754_902a_707e414210c2

Elucidation: the lower end of the interval of frequencies tested in impedimetry and related techniques


-

LowerVoltageLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9

Elucidation: minimum voltage limit at which an applied excitation is altered or terminated

Alternative Label(s): CutOffVoltage, DischargeCutoffVoltage, EndOfDischargeVoltage, EndPointVoltage, EndVoltage, FinalVoltage, LowerCutoffVoltage

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-30


-

MagnitudeOfCurrentPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d

Elucidation: the magnitude of a current pulse applied to an electrochemical cell during pulsed potentiometry and related techniques

Alternative Label(s): PulseMagnitudeCurrent


-

MagnitudeOfPotentialPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc

Elucidation: The magnitude of a voltage pulse applied to an electrochemical cell during pulsed amperometry and related techniques.

Alternative Label(s): PulseMagnitudePotential


-

MassLoading

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c955c089_6ee1_41a2_95fc_d534c5cfd3d5

Elucidation: mass of a material per unit area


-

MaximumConcentration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e

Elucidation: the maximum amount concentration of a species in a phase, either imposed or naturally occurring


-

MaximumContinuousDischargeCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ba7ac581_0e13_4815_b888_013c378932f5

Elucidation: the maximum current approved for continuous discharge for a given electrochemical device


-

MaximumPulseDischargeCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b

Elucidation: the maximum current approved for pulse discharge of an electrochemical device


-

MaximumPulseDischargeDuration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5dc0c1d_0926_4268_89f0_4519a326eabc

Elucidation: the maximum duration of a pulse discharge for a given electrochemical device


-

MaximumStoichiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_95ef8c3c_62fe_467f_b5d4_dd0cd18a7ea8


-

MaximumTemperature

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cc519a19_b8d5_4e3f_b893_3a884888ad79

Elucidation: the maximum allowable temperature


-

MembranePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_601ff226_59b9_460b_90f5_2593450d96fa

Elucidation: electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane

Alternative Label(s): DonnanPotential, MembraneElectromotiveForce

IUPAC Reference: https://doi.org/10.1351/goldbook.M03825


-

MigrationCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb

Elucidation: component of electric current due to transport of ions in the electric field between the electrodes

IUPAC Reference: https://goldbook.iupac.org/terms/view/M03921


-

MinimumStoichiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_86324806_4263_4d80_b5af_1a7be844ab5b


-

MiniumumConcentration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a9873707_8103_4bb4_9e51_83db1e89b1bd

Elucidation: the minimum amount concentration of a species in a phase, either imposed or naturally occuring


-

MiniumumTemperature

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4747c51d_86ab_4684_a4fb_b05f5c405ea3

Elucidation: the minimum allowable temperature


-

MolarElectrochemicalPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fe804b8_6126_4132_be8f_b4985d61b1f6

Elucidation: electrochemical potential per mole.

IUPAC Reference: https://goldbook.iupac.org/terms/view/E01945


-

NPRatio

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_05012606_b93d_4016_bbc7_8a927efdf723

Elucidation: quotient of the capacity of the negative electrode and the capacity of the positive electrode in a cell

Alternative Label(s): NToPRatio


-

NetFaradaicCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b

Elucidation: algebraic sum of faradaic currents flowing through an electrode


-

NominalVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_639b844a_e801_436b_985d_28926129ead6

Elucidation: suitable approximate value of the voltage used to designate or identify a cell, a battery or an electrochemical system

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-31


-

NumberOfCellsConnectedInParallel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_482173dc_7779_4f12_982c_b19f2cda2dac


-

NumberOfCellsConnectedInSeries

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9d6a52ed_a53d_4327_a391_f173677a4b1d


-

OhmicOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a

Elucidation: part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte

Alternative Label(s): OhmicOvervoltage, OhmicPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-09


-

OpenCircuitVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b

Elucidation: electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell

Alternative Label(s): OCP, OCV, OpenCircuitPotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-32

Wikipedia Reference: https://en.wikipedia.org/wiki/Open-circuit_voltage


-

Overpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6

Elucidation: electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction

Alternative Label(s): ElectrodePolarization, Overvoltage, PolarizationPotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-02

IUPAC Reference: https://goldbook.iupac.org/terms/view/O04358

Wikipedia Reference: https://en.wikipedia.org/wiki/Overpotential


-

ParticleRadius

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b92e382f_5109_4f60_ab5e_c89d340419a9

Elucidation: radius of a particle


-

PeakCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05

Elucidation: in dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve

IUPAC Reference: https://goldbook.iupac.org/terms/view/P04457


-

PeakPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e4a221e0_afc9_4464_91d4_e0c8ecdf79e8

Elucidation: electrode potential of the working electrode at which the peak current is attained

IUPAC Reference: https://doi.org/10.1351/goldbook.P04464


-

Polarity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_16a5de33_a2ca_4563_80d4_6caeb08d97ca

Elucidation: nominal property of an electrode, having values negative or positive according to the sign of the electrode potential, or neutral when the electrode potential is zero.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-14


-

PotentialScanRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278

Elucidation: the rate of change of applied potential with time

Alternative Label(s): PotentialSweepRate, ScanRate, SweepRate


-

PotentiometricSelectivityCoefficient

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0

Elucidation: parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B

Alternative Label(s): SelectivityCoefficient, SelectivityConstant, SelectivityFactor

IUPAC Reference: https://doi.org/10.1351/goldbook.P04791


-

Prismatic

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83fbc038_0c2e_4d04_91d7_cdf30f8a5535

Elucidation: [a sign that] qualifies a cell or a battery having the shape of a parallelepiped whose faces are rectangular

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-38


-

PulseDuration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56

Elucidation: time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques

IUPAC Reference: https://doi.org/10.1351/goldbook.P04947


-

PulseMagnitude

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_762ba55f_9b56_4c31_865f_cff2e7d0a94b

Elucidation: a single value, for instance a mean, root mean square or peak value characterizing the aggregate instantaneous values of a unidirectional pulse with respect to the common initial and final value

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=702-03-03


-

QuarterTransitionTimePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4

Elucidation: electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time


-

RatedCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9b3b4668_0795_4a35_9965_2af383497a26

Elucidation: capacity value of a battery [or electrochemical device] determined under specified conditions and declared by the manufacturer

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-15


-

ReactionOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e

Elucidation: part of the electrode polarization arising from a chemical reaction impeding the electrode reaction

Alternative Label(s): ReactionOvervoltage, ReactionPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-10


-

ReactionRate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e2514bf9_d012_4990_b68b_6f37443f18f6

Elucidation: rate at which a chemical reaction takes place

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-02

Wikipedia Reference: https://en.wikipedia.org/wiki/Reaction_rate


-

ReactionRateConstant

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1

Elucidation: a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants

Wikipedia Reference: https://en.wikipedia.org/wiki/Reaction_rate_constant


-

Record

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_838a927f_775e_4c6d_8e39_7865548608c2

Elucidation: an entry in a dataset, typically consisting of one line.


-

ReferenceThermodynamicTemperature

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_db40df7e_1aa5_49a7_85cb_2aa2c1c70489


-

ResidualActiveMass

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2

Elucidation: charged active material remaining in a cell following a discharge to a specified end-of-discharge voltage.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-37


-

ResidualCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d47985f1_6bd7_4c4f_894f_13a6cab38bb5

Elucidation: electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-16


-

ResidualCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764

Elucidation: Electric current that flows, at a particular value of the applied potential, in the absence of the substance whose electrode behaviour is being investigated, i.e. a "blank" solution.

Alternative Label(s): BackgroundCurrent

IUPAC Reference: https://goldbook.iupac.org/terms/view/R05311


-

ResponseTimeAtAnISE

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c

Elucidation: Duration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy.


-

RestingTime

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa

Alternative Label(s): RestingDuration, the duration during which an electrochemical device is kept at open-circuit conditions


-

RotatingDiskSpeed

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe

Elucidation: rotational frequency of a rotating component in a rotating disk electrode


-

SamplingInterval

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_52ac73c7_763c_4fda_93cd_a2db9dfc2dab

Elucidation: time interval during which the current is measured in pulse voltammetry

IUPAC Reference: https://doi.org/10.1351/goldbook.S05465


-

SamplingTime

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ecb6dfdf_bd3d_4339_8a1c_d32abbef30ba

Elucidation: duration of the sampling interval in pulse voltammetry

IUPAC Reference: https://doi.org/10.1351/goldbook.S05467


-

ShelfLife

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e8ec76bf_2a60_4982_8cde_02dfbd2e626f

Elucidation: duration, under specific conditions, at the end of which a battery [ or electrochemical device ] has retained the ability to perform a specified function

Alternative Label(s): StorageLife

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-47


-

ShortCircuitCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_75c28dc8_3d7d_4b6e_861e_6c8b1ad7d644

Elucidation: maximum current which should be delivered by a cell or battery into an external circuit with zero electric resistance, or an external circuit which depresses the cell or battery voltage to approximately zero volt

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-26


-

SignalReferencePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_68059d94_4c21_4065_b329_07faeebc7e87

Elucidation: Potential to which the magnitude of an excitation signal is compared to.

Alternative Label(s): BaselinePotential


-

SpecificCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30

Elucidation: quotient of the capacity of a cell or battery [ or electrode or active material ] by its mass.

Alternative Label(s): GravimetricCapacity, SpecificChargeCapacity, SpecificElectricChargeCapacity

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-19


-

SpecificChargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4882cf2f_aab7_4a3a_a103_7f56b55fbed3

Elucidation: quotient of the capacity of a cell or battery [ or electrode or active material ] obtained during a charge process by its mass.


-

SpecificDischargeCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_884650fd_6cc6_4ec6_8264_c18fbe6b90ee

Elucidation: quotient of the capacity of a cell or battery [ or electrode or active material ] obtained during a discharge process by its mass.


-

SpecificEnergyCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5e4490b8_c1dd_4e00_980b_c484e1bf4904

Elucidation: the specific energy of an electrochemical device obtained during a charge process


-

SpecificEnergyDischarge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9d57962c_e150_4e64_962b_8fd6a92c9234

Elucidation: the specific energy of an electrochemical device obtained during a discharge process


-

SpecificEnergyOfStorage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ccdfed06_6d24_47e4_98af_ce3ffe7bd09e

Elucidation: the quotient of the energy of an energy-storage device or system and its mass

Alternative Label(s): SpecificEnergy


-

SpecificPowerOfStorage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c762a928_5a74_46fd_9929_4ac2d7a3a8d7

Elucidation: the quotient of the power of an energy-storage device or system and its mass


-

SpecificSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cf54e7c1_f359_4715_b61d_0350b890d597

Elucidation: total surface of a solid per mass

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-10

Wikipedia Reference: https://en.wikipedia.org/wiki/Specific_surface_area


-

SquareWaveCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65

Elucidation: component of an electric current that is associated with the presence of an analyate in square-wave voltammetry

IUPAC Reference: https://goldbook.iupac.org/terms/view/S05897


-

StandardElectrodePotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fc10197_41d9_4c1e_a107_928f03eb2d36

Elucidation: equilibrium electrode potential of an electrode under standard conditions

Alternative Label(s): StandardPotential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-13

IUPAC Reference: https://goldbook.iupac.org/terms/view/S05912


-

StepDuration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_85e39686_9658_4c74_bb91_a935704c174a

Elucidation: the duration between two consecutive steps in a staircase signal


-

StepIndex

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d78b696d_9832_4352_a264_28a2ea7d82e4

Elucidation: number describing the step in a protocol


-

StepSignalCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8

Elucidation: the magnitude of the current step in chronopotentiometry and related techniques


-

StepSignalVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6

Elucidation: the magnitude of the voltage step in step voltammetry and related techniques


-

StepTime

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_80ca00f8_c891_4493_87a2_7d39b9d1e098

Elucidation: time of a measurement relative to the start of the step (t = 0)


-

Stoichiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f0667139_6428_4e3d_ac0d_08c1dd7f36ea


-

SurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e

Elucidation: a measure of the total area that the surface of a solid object occupies

Wikipedia Reference: https://en.wikipedia.org/wiki/Surface_area


-

SurfaceAreaPerVolume

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f381c19_cf07_47a8_ab10_0b14d46901e8


-

SurfaceOverpotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_60741c58_a10d_4aa6_bb68_0066a6ff8e30

Elucidation: The potential of a working electrode relative to a reference electrode of the same kinds placed in the solution adjacent to the surface of the working electrode (just outside the double layer).

Alternative Label(s): SurfacePolarization


-

TappedDensity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5ce6a328_713c_4383_ad63_26c902c30e34

Elucidation: the density of a powdered or granular material when it is subjected to tapping or mechanical vibration

Alternative Label(s): TapDensity


-

TemperatureCoefficientOfTheCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8f3ab19f_ce22_424e_a9bf_d5cedb815374

Elucidation: quotient of the change in capacity of a cell by the corresponding change in temperature.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-18


-

TemperatureCoefficientOfTheOpenCircuitVoltage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28

Elucidation: quotient of change in open-circuit voltage of a cell or battery by the corresponding change in temperature.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-33


-

TemperatureLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82fce40c_434d_4640_a3d2_e26379b6acae

Elucidation: limit on the temperature of a system


-

TestTime

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_27b3799c_250c_4332_8b71_7992c4a7bb05

Elucidation: time of a measurement relative to the start of the test (t = 0)


-

TheoreticalCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b7781ebc_90a7_4f19_997f_aed28dee1b01

Alternative Label(s): TheoreticalChargeCapacity


-

TotalNumberOfCycles

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6d981c04_3ace_4f1b_b0f8_770776cceb6f

Elucidation: the total number of cycles carried out on a specific device under a given set of conditions


-

TransitionTime

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ae9882de_d6a2_4525_a84f_80947c10f1cb

Elucidation: in chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero

IUPAC Reference: https://doi.org/10.1351/goldbook.T06472


-

UpperFrequencyLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_666f0b69_9c74_49a3_80b3_96a188332462

Elucidation: the higher end of the interval of frequencies tested in impedimetry and related techniques


-

UpperVoltageLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88

Elucidation: maximum voltage limit at which an applied excitation is altered or terminated

Alternative Label(s): EndOfChargeVoltage, UpperCutoffVoltage

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-55


-

VoltageChangeLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef

Elucidation: a control limit placed on the rate of change of the cell voltage, dV/dt.

Alternative Label(s): dV/dt


-

VoltageLimit

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5ebeea80_af22_456b_9087_78c2a8465c58

Elucidation: limit on the voltage of an electrical system


-

VolumetricCapacity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e6b63190_acac_4e78_9cba_fb2b10bbe910

Elucidation: quotient of the capacity of a cell or battery by its volume.

Alternative Label(s): VolumetricChargeCapacity, VolumetricElectricChargeCapacity

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-17


-

VolumetricPowerDensityofStorage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a7eb870c_4ef7_4ccd_85e8_4b7b726d7a2a

Elucidation: the quotient of the power of an energy-storage device or system and its volume


-

VolumetricSurfaceArea

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a5571263_f153_448f_84a3_cd18092cf8fa

Elucidation: ratio of the surface area of a solid object to the volume of the object

Alternative Label(s): SurfaceAreaToVolumeRatio

Wikipedia Reference: https://en.wikipedia.org/wiki/Surface-area-to-volume_ratio


-

WorkingPotentialRange

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c39b2498_783e_48e1_9814_6164bd99823c

Elucidation: range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation


-

Electrochemistry Concepts

-

ACVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8ca00b45_5ba6_48a0_aaf6_abd959a7238b

Elucidation: voltammetry in which a sinusoidal alternating potential of small amplitude (10 to 50 mV) of constant frequency (10 Hz to 100 kHz) is superimposed on a slowly and linearly varying potential ramp

Alternative Label(s): ACV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

ACVoltammetrySignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58a20764_c339_4856_983a_05092b5282e8

Elucidation: Sinusoidal potential waveform superimposed to a linear potential ramp.


-

AbrasiveStrippingVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f

Elucidation: electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve


-

AcidicElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2

Elucidation: an aqueous electrolyte with a nominal pH values less than 7

Alternative Label(s): AcidicAqueousElectrolyte, AcidicSolution


-

ActiveElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc

Elucidation: an electrode which is chemically altered by the electrode reaction

Alternative Label(s): NonInertElectrode, ReactiveElectrode


-

ActiveMaterial

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261

Elucidation: material that is oxidized or reduced at an electrode in an electrochemical cell

Alternative Label(s): ActiveElectrochemicalMaterial, ActiveElectrochemicalMaterial, ElectrochemicallyActiveMaterial, ElectrochemicallyActiveMaterial

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-14


-

ActiveMaterialMix

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_81833d8a_b03d_4250_be84_6385415beb01

Elucidation: blend containing a material which reacts chemically to produce electrical energy with other constituents and additives

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-34


-

ActiveMaterialParticleCracking

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6341d7d_7620_48f5_97b2_99b55c349169

Elucidation: a degradation mechanism in electrochemical cells in which fractures in the active material particles increase cell resistance.


-

AdsorptiveStrippingVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a05e7945_c942_45cf_812c_c9a595d15888

Elucidation: Stripping voltammetry involving pre-concentration by adsorption of the analyte (in contrast to electro- chemical accumulation).

Alternative Label(s): AdSV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

AirElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8b40856f_1ca2_4137_9616_7fb624671909

Elucidation: a gas diffusion electrode in which the gas is air


-

AlkalineElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878

Elucidation: an aqueous electrolyte with a nominal pH greater than 7

Alternative Label(s): AlkalineAqueousElectrolyte, AlkalineSolution


-

AlternatingCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a53d6dee_1547_4854_a311_805b4d557298

Elucidation: periodic current where the amplitude alternates at a steady frequency between fixed minimum and maximum values, with the same duration at minimum and maximum

Alternative Label(s): AC

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=131-11-24

Wikipedia Reference: https://en.wikipedia.org/wiki/Alternating_current


-

AluminiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_952c8c3a_df21_4dd1_8d8c_380e43dc8c78

Elucidation: electrode in which the active material is aluminium


-

AluminiumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1c6cef85_811f_45d0_a0fd_2bc2d9369ea4

Elucidation: an insertion electrode in which the guest molecule is aluminium


-

AmmoniaSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9e2e676_5cd1_4e22_a776_af45838d4027

Elucidation: a solution of ammonia (NH3) dissolved in water (H2O)

Alternative Label(s): AqueousAmmoniaSolution


-

AmmoniumChlorideSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f67016b_32b9_4419_a3f8_a5ffb5e92538

Elucidation: a solution of ammonium chloride (NH4Cl) dissolved in water (H2O)

Alternative Label(s): AqueousAmmoniumChlorideSolution


-

Amperometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3fe63496_6d87_427a_b2aa_4555bc31ee1a

Elucidation: techniques based on measurement of current at a constant controlled potential

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

AnnularWorkingElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3a77b5e7_9646_4154_bf8f_5f798989e5f3

Elucidation: a working electrode in the shape of a ring used in a rotating ring disk electrode (RRDE).

Alternative Label(s): RingElectrode


-

Anode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302

Elucidation: by convention, cell electrode at which an oxidation reaction occurs

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-27

IUPAC Reference: https://goldbook.iupac.org/terms/view/A00370

Wikipedia Reference: https://en.wikipedia.org/wiki/Anode


-

AnodicPolarisation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_28213033_4c74_441c_81c4_a0cad05f9eb6

Elucidation: electrode polarization associated with an anodic reaction

Alternative Label(s): AnodicPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-17


-

AnodicReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0

Elucidation: electrode reaction in which oxidation occurs at the anode

Alternative Label(s): Electrooxidation, ElectrooxidationReaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-09


-

AnodicStrippingVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8ba8ec72_abd0_49eb_a06f_83fe5da108f4

Elucidation: Stripping voltammetry in which material accumulated at the working electrode is electrochemically oxi- dized in the stripping step.

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Anolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f

Elucidation: electrolyte on the anode side of an electrochemical cell that is divided into compartments

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-19


-

AnolyteTank

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_38755e67_9d3b_4a82_bd8d_ef40a70379c1

Elucidation: a tank for holding anolyte


-

AqueousElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a

Elucidation: an ion-transport medium, which may be immobilized, in which water is the solvent.

Alternative Label(s): AqueousElectrolyticSolution


-

AsymmetricMembrane

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f

Elucidation: membrane constituted of two or more structural planes of non-identical morphologies

IUPAC Reference: https://doi.org/10.1351/goldbook.AT06862


-

BellevilleWasher

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_98d5101e_cd11_4a0d_b856_6fcd8aad132e

Elucidation: a type of spring, in the form of a conical washer


-

BilayerMembrane

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f1c7eacb_9f21_4100_925c_3974f266e06f

Elucidation: an asymmetric membrane composed of two layers, typically with different chemical properties or functional roles


-

BimetallicElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_86be0987_5e21_43ec_b975_8f679999d328

Elucidation: electrode containing two different metals (e.g. platinum and ruthenium) on its surface (e.g. to modify its electrocatalytic properties)


-

BimetallicOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4839708a_3864_47eb_b719_373ff8874c61

Elucidation: an electrode consisting of two metal oxide active materials


-

BinaryElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4e02d727_07fe_41fd_886c_041317342086

Elucidation: an electrolyte consisting of anions and cations with equal absolute charge numbers.


-

Binder

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_68eb5e35_5bd8_47b1_9b7f_f67224fa291e

Elucidation: material or substance that holds or draws other materials together to form a cohesive whole

Alternative Label(s): ElectrodeBinder

Wikipedia Reference: https://en.wikipedia.org/wiki/Binder_(material)


-

BismuthElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_eb09ca25_90c9_4b55_9165_76fbf7fb5a46

Elucidation: electrode in which the active material is bismuth


-

BlendedActiveElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528

Elucidation: an active electrode with a blend of two or more active materials


-

BockrisDevanathanMuellerModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4bdd6359_1422_4c50_ac0c_5d8042dd65fc

Elucidation: a model for the double layer that includes the action of the solvent on the surface

Alternative Label(s): BDM


-

BodePlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e0b57b09_68ee_4687_a901_bfb599421972

Elucidation: plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency at all the frequencies tested in an impedimetry measurement

Alternative Label(s): BodeDiagram

Wikipedia Reference: https://en.wikipedia.org/wiki/Bode_plot


-

BoostCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_02aefb7a_d6ce_4b6e_b854_f7b3d641f670

Elucidation: accelerated charge applied at greater than normal values of electric currents or of voltages (for a particular design) during a short time interval

Alternative Label(s): FastCharge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-37


-

ButlerVolmerEquation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d48ea516_5cac_4f86_bc88_21b6276c0938

Elucidation: a phenomenological model for electrode kinetics, describing the relation between the electrode current from an electrochemical charge-transfer reaction and the surface overpotential of the electrode

Alternative Label(s): ButlerVolmerApproximation, ErdeyGruzVolmerEquation

Wikipedia Reference: https://en.wikipedia.org/wiki/Butler%E2%80%93Volmer_equation


-

CCCVCycling

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ac6c2371_995a_4fcb_89a2_15cb6615741e

Elucidation: a cycling protocol in which an electrochemical cell is first put through a CCCV charging process followed by a constant current discharge process


-

CadmiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dd4c5ffa_6228_41d8_8a44_a40a2b22723e

Elucidation: electrode in which the active material is cadmium


-

CaesiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7cc8b738_3462_4592_ba83_951a8d50fef7

Elucidation: electrode in which the active material is caesium


-

CalciumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4f2348dd_d9ea_4448_af8c_a4a38f3d04b4


-

CalciumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_90103be0_9096_4f98_89c7_b5db01197858

Elucidation: an insertion electrode in which the guest molecule is calcium


-

CapacityFade

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e3d3d21c_cb9a_498c_bdb0_63c964f0d3c6

Elucidation: a degradation phenomena in electrochemical devices in which the practicaclly achieveable capacity of the cell is less than the measured capacity at the beginning of life.

Alternative Label(s): CapacityLoss

Wikipedia Reference: https://en.wikipedia.org/wiki/Capacity_loss


-

CarbonInkElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ec6f3d6f_bdf5_418f_9314_3ef2ff528103

Elucidation: development of a carbon paste electrode that is screen printed using a carbon/polymer mixture of suitable composition


-

CarbonMonofluorideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5c0fdc09_166e_40a6_ad74_be66f0db51bc

Elucidation: electrode in which the active material is carbon monofluoride


-

CarbonPasteElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1

Elucidation: Electrode of a composite of carbon powder and a pasting liquid (including mineral oil, Nujol, bromoform, bromonaphthalene).

Alternative Label(s): CPE

Wikipedia Reference: https://en.wikipedia.org/wiki/Carbon_paste_electrode


-

CardonDioxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_573be62a_5aae_4984_9a51_7c50845493df

Elucidation: a gas diffusion electrode in which the active material is carbon dioxide (CO2)


-

Case

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8

Elucidation: container for the plate pack or packs and electrolyte of a cell or cells made of a material impervious to the electrolyte

Alternative Label(s): Container, Housing

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-14


-

Catalyst

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8ab1e656_38ff_48e6_ab09_293d76bc9044

Elucidation: substance that increases chemical reaction speed, and which is conserved after the reaction


-

Cathode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5

Elucidation: by convention, cell electrode at which, a reduction reaction occurs

IUPAC Reference: https://goldbook.iupac.org/terms/view/C00905

Wikipedia Reference: https://en.wikipedia.org/wiki/Cathode


-

CathodeElectrolyteInterphase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f8e0d532_cf44_403c_9188_e00ee161a3c1

Elucidation: a type of solid electrolyte interface that forms on the surface of the electrode designated as the "cathode" or positive electrode


-

CathodicPolarisation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_187326b9_1089_4122_8e7e_1a0bcba210a1

Elucidation: electrode polarization associated with a cathodic reaction

Alternative Label(s): CathodicPolarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-18


-

CathodicProtection

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c936bfbe_7a0c_4185_a317_db1ce2c3c38c

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-05

Wikipedia Reference: https://en.wikipedia.org/wiki/Cathodic_protection


-

CathodicReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f4a1323a_ce2b_4c1a_b89d_c80170110ed6

Elucidation: electrode reaction in which reduction occurs at the cathode

Alternative Label(s): Electroreduction, Electroreduction, ElectroreductionReaction, ElectroreductionReaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-10


-

CathodicStrippingVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_61740c42_d332_492c_8b37_90a187c7f6d9

Elucidation: stripping voltammetry in which material accumulated at the working electrode is electrochemically reduced in the stripping step

Alternative Label(s): CSV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Catholyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_15b852b5_19cc_49ab_849f_7df6175fb2be

Elucidation: electrolyte on the cathode side of an electrochemical cell that is divided into compartments.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-18


-

CatholyteTank

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9b6853e7_3412_463d_b5a9_82c14acebf7d

Elucidation: a tank for holding catholyte


-

CellBaffle

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_328c6e36_3706_4d92_abae_432fa3adb2a0

Elucidation: internal component used to reduce the amount of electrolyte loss due to electrolyte spray being carried in the gas and/or by electrolyte movement

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-13


-

CellCan

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4a5660bd_1c1a_40e5_8a41_463c720d3903

Elucidation: cell container which is usually metallic and typically, but not exclusively, cylindrical

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-13


-

CellLid

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1e33e37e_d7c9_4701_ba6d_a09456a13aaf

Elucidation: part used to close the case normally having holes for filling, topping-up, gas escape, terminals, etc.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-15


-

CelsiusTemperatureMeasurement

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bea04148_10d9_4eda_9cd5_8f609d7e9ff8

Elucidation: measurement of temperature


-

CelsiusTemperatureMeasurementResult

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2dea31c2_5061_4464_ab76_5336bef23629


-

CelsiusTemperatureVector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_efaca8db_a3e0_4188_9c9b_ed0037966725

Elucidation: vector containing at least two values for the quantity celsius temperature


-

Charge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f

Elucidation: operation during which a secondary cell or battery is supplied with electric energy from an external circuit which results in chemical changes within the cell and thus the storage of energy as chemical energy.

Alternative Label(s): ElectrochemicalCharging

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-27


-

ChargeCarrier

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d1042a12_e4be_4992_86cb_59420ef4e05c

Elucidation: a generic denomination of particles or quasiparticles responsible for electric charge transport.

Wikipedia Reference: https://en.wikipedia.org/wiki/Charge_carrier


-

ChargeTimePlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46676855_68b0_4096_ac6c_35400111d46d

Elucidation: plot of the time-dependent amount of electric charge passed through an electrochemical system due to the application of a electric potential

Alternative Label(s): ChargeTimeCurve, ElectricChargeTimeCurve, ElectricChargeTimePlot, QtCurve


-

ChemicalReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9

Elucidation: a process that results in the interconversion of chemical species

IUPAC Reference: https://doi.org/10.1351/goldbook.C01033

Wikipedia Reference: https://en.wikipedia.org/wiki/Chemical_reaction


-

ChromiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_510e4061_c4fa_49aa_a052_23ad56098eda

Elucidation: electrode in which the active material is chromium


-

Chronoamperometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_729a1064_d039_4b74_9d1d_759b18a3971c

Elucidation: amperometry in which the current is measured as a function of time after a change in the applied potential

Alternative Label(s): AmperiometricDetection, AmperometricCurrentTimeCurve

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Chronocoulometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f91c9ae3_42b8_4efa_9b67_a406d162d3b5

Elucidation: direct coulometry at controlled potential in which the electric charge passed after the application of a potential step perturbation is measured as a function of time (Q-t curve)

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Chronopotentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b

Elucidation: potentiometry in which the potential is measured with time following a change in applied current

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

CoatedElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_92147e31_d015_4889_a092_04fbab033f15

Elucidation: cell electrode consisting of a current collector and active material

Alternative Label(s): Plate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-02


-

Coating

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_09a7f560_9ddf_4c32_b067_b213eca5b0a1

Elucidation: a covering on the surface of an object

Wikipedia Reference: https://en.wikipedia.org/wiki/Coating


-

CobaltElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7b811780_7251_481b_a4d3_97d437955099

Elucidation: electrode in which the active material is cobalt


-

CoinCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37

Alternative Label(s): ButtonCase

IEC Reference: a round-type case with a height that is less than the diameter


-

ConcentrationCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8a5083b0_cd23_4f8c_99e8_b9ccd6f9f3a2

Elucidation: electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their ion concentrations

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-08

Wikipedia Reference: https://en.wikipedia.org/wiki/Concentration_cell


-

ConductiveAdditive

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82fef384_8eec_4765_b707_5397054df594

Elucidation: a material added to an electrode for the purpose of increasing its electronic conductivity.

Alternative Label(s): ElectronicallyConductiveElectrodeAdditive


-

ConductivityCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686

Elucidation: an electrochemical cell for conductivity measurements


-

ConductometricTitration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e9639083_e9c5_4d0a_97e8_be1e139c179f

Elucidation: titration in which the electric conductivity of a solution is measured as a function of the amount of titrant added

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Conductometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e

Elucidation: measurement principle in which the electric conductivity of a solution is measured

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Conductometry


-

Connector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00

Elucidation: conductor of electricity used for carrying current between components in an electric circuit

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-37


-

ConstantCurrentCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f

Elucidation: charge during which the electric current is maintained at a constant value regardless of the battery voltage or temperature

Alternative Label(s): GalvanostaticCharging

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-38


-

ConstantCurrentConstantVoltageCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0cc8f231_0ce5_467e_9c76_29b2c80349ad

Elucidation: a two-step charging process in which a constant current is applied until a set upper cutoff voltage is reached and then the cell is potentiostatically held at that voltage until the current falls below some set threshhold value

Alternative Label(s): CCCV


-

ConstantCurrentDischarging

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30

Elucidation: a discharging process in which the current is kept at a constant value

Alternative Label(s): GalvanostaticDischarging


-

ConstantPotentialPulses

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_84d37a37_88bd_47db_9425_31f73a81d38c

Elucidation: Signal consisting of successive pulses of electric potential of the same magnitude.


-

ConstantPotentialSignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0d3e8340_4229_4fd3_b6dd_763bd566551d

Elucidation: Signal consisting of a constant electric potential.


-

ConstantVoltageCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6

Elucidation: charge during which the voltage is maintained at a constant value regardless of charge current or temperature

Alternative Label(s): FloatCharging, PotentiostaticCharging

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-49


-

ConstantVoltageDischarge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9865e4f9_756d_4d94_a6fd_4102ab795f9e

Elucidation: a discharging process in which the voltage between the terminals of the electrochemical cell is kept at a constant value

Alternative Label(s): PotentiostaticDischarging


-

ContinuousServiceTest

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_25d01d13_3ca5_4619_98c1_8ebbd01ad794

Elucidation: service test with an uninterrupted discharge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-48


-

CopperElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_26b19a7c_59ca_4e1b_8fb9_ba061c22531e

Alternative Label(s): metal electrode in which the active material is copper


-

CopperOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a8edd38f_f8a5_41fb_9fc7_48f1866fd699

Elucidation: electrode in which the active material is cupric oxide (copper (II) oxide)

Alternative Label(s): CupricOxideElectrode


-

Coulometer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940

Elucidation: measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration.

Alternative Label(s): Voltameter

Wikipedia Reference: https://en.wikipedia.org/wiki/Voltameter


-

CoulometricTitration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_52501237_0c13_4bfb_aa3a_441c6a9ae3a6

Elucidation: titration in which the titrant is generated electrochemically, either by constant current or at constant potential. The titrant reacts stoichiometrically with the analyte, the amount of which is calculated using Faraday’s laws of electrolysis from the electric charge required to reach the end-point


-

Coulometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9

Elucidation: electrochemical measurement principle in which the electric charge required to carry out a known electrochemical reaction is measured. By Faraday’s laws of electrolysis, the amount of substance is proportional to the charge

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-13

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Coulometry


-

CounterElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_871bc4a4_2d17_4b88_9b0f_7ab85f14afea

Elucidation: electrode whose function is to carry the electric current flowing through the electrical circuit of an electrochemical cell, the electrochemical processes on its surface not being of interest

Alternative Label(s): AuxiliaryElectrode

IUPAC Reference: https://goldbook.iupac.org/terms/view/A00535

Wikipedia Reference: https://en.wikipedia.org/wiki/Auxiliary_electrode


-

CurrentCollector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_212af058_3bbb_419f_a9c6_90ba9ebb3706

Elucidation: A good electron conductor support designed to transfer electrons from the external circuit to the active materials of the cell.

Alternative Label(s): ElectrodeCurrentCollector

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-06-07


-

CurrentControlledProcess

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36

Elucidation: a process in which the electric current is controlled


-

CurrentPotentialPlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b9a72491_8a50_4cac_a131_1e95d72b57ee

Elucidation: plot of current versus applied potential (I-E) for a given system

Alternative Label(s): CurrentPotentialCurve, ElectricCurrentPotentialCurve


-

CurrentPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_712c791a_d593_4732_af73_493f7bc50999

Elucidation: rapid, transient change in the amplitude of an electric current, from a baseline value to a higer or lower value, followed by a rapid return to the baseline value.


-

CurrentPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9f1ffb54_4403_4541_98c1_3a821c6d060f

Elucidation: the process of applying a current pulse


-

CurrentTimePlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b99cff7f_b13f_4075_aa88_62c04f8daacc

Elucidation: plot of the dependence of instantaneous current on time

Alternative Label(s): CurrentTimeCurve


-

CycleDomainMatrix

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d2f6f1a6_4dee_4c5e_9a69_32b9fe990d2f

Elucidation: a series of data points indexed in cycle order


-

CycleNumberVector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ca48d41c_f5ea_4bf8_84ce_2d67fd9dad98

Elucidation: vector containing at least two values for the quantity cycle number


-

CyclicChronopotentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_225cb9b8_d413_451e_9e36_fb6d1344b16e

Elucidation: chronopotentiometry where the change in applied current undergoes a cyclic current reversal


-

CyclicVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2f96eb3e_4115_4236_9203_525fb27fe92d

Elucidation: voltammetry in which the electric current is recorded as the electrode potential is varied with time cycli- cally between two potential limits, normally at a constant scan rate

Alternative Label(s): CV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Cyclic_voltammetry


-

Cycling

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69

Elucidation: set of operations that is carried out on a secondary cell or battery and is repeated regularly in the same sequence.

Alternative Label(s): ChargeCycle, ElectrochemicalCycling

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-28

Wikipedia Reference: https://en.wikipedia.org/wiki/Charge_cycle


-

CylindricalCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b1cf9fee_2164_4f95_8204_90f717373a8a

IEC Reference: a round-type case with a height that is greater than or equal to the diameter


-

DCPolarography

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5a0f3b6a_10b4_43a7_b0b6_4eb5c077980e

Elucidation: linear scan voltammetry with slow scan rate in which a dropping mercury electrode is used as the working electrode

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Dendrite

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_34bc54e3_de4c_41f8_8d3a_d77c951ee23a

Elucidation: needle-like or tree-like formation of crystalline growth formed during deposition of a material

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-07

IUPAC Reference: https://doi.org/10.1351/goldbook.D01588

Wikipedia Reference: https://en.wikipedia.org/wiki/Dendrite_(crystal)


-

Dielectrometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_43ce1a7e_8056_40cb_bdbd_4ce991af1821

Elucidation: electrochemical measurement principle based on the measurement of the dielectric constant of a sample resulting from the orientation of particles (molecules or ions) that have a dipole moment in an electric field

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

DifferentialLinearPulseVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb

Elucidation: Differential Pulse Voltammetry in which small potential pulses are superimposed onto a linearly varying potential.


-

DifferentialPotentialPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b49e2355_392f_4e83_b630_7ff4581d767b

Elucidation: Small pulses of electric potential superimposed to a linear potential ramp or a staircase potential ramp.


-

DifferentialPulseVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2

Elucidation: voltammetry in which small potential pulses (constant height 10 to 100 mV, constant width 10 to 100 ms) are superimposed onto a linearly varying potential or onto a staircase potential ramp. The current is sampled just before the onset of the pulse (e.g. 10 to 20 ms) and for the same sampling time just before the end of the pulse. The difference between the two sampled currents is plotted versus the potential applied before the pulse. Thus, a differential pulse voltammogram is peak-shaped

Alternative Label(s): DPV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Differential_pulse_voltammetry


-

DifferentialStaircasePulseVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a

Elucidation: Differential Pulse Voltammetry in which small potential pulses are superimposed onto a staircase potential ramp.


-

DirectCoulometryAtControlledCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_180878b5_8de8_4dd8_b881_1d0bebe326d4

Elucidation: coulometry at an imposed, constant current in the electrochemical cell


-

DirectCoulometryAtControlledPotential

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_39536efc_22a6_4f39_b0c2_e8b845a36278

Elucidation: coulometry at a preselected constant potential of the working electrode

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

DirectCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_40ca9548_910a_48b6_9a26_f94095d349cd

Elucidation: Signal consisting of a constant electric current.

Alternative Label(s): ConstantCurrentSignal, DC

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=131-11-22

Wikipedia Reference: https://en.wikipedia.org/wiki/Constant_current


-

DirectCurrent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7

Elucidation: electric current that flows in a constant direction, i.e. a current with a constant sign

Alternative Label(s): DC

IUPAC Reference: https://goldbook.iupac.org/terms/view/D01767

Wikipedia Reference: https://en.wikipedia.org/wiki/Direct_current


-

Discharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc

Elucidation: operation during which an electrochemical cell supplies electric energy as the result of chemical changes within the cell

Alternative Label(s): ElectrochemicalDischarging

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-23


-

Dissociation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90

Elucidation: process where molecules split up into ions due to being dissolved

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-08

Wikipedia Reference: https://en.wikipedia.org/wiki/Dissociation_(chemistry)


-

Dissolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_49263a32_eca6_4644_8144_0d3b14c26d0a

Elucidation: mixing of a substance into another substance with formation of one new homogeneous substance

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-04


-

DoubleCoatedElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_56f85b19_1384_4e88_b130_cb8e7984db83

Elucidation: an electrode that is coated on both sides of the current collector


-

DoubleLayer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d

Elucidation: a double layer of charges exists at the interface between two conducting media: One side carries a positive excess charge, which is balanced by a negative excess of equal magnitude on the other side.

Alternative Label(s): DL, EDL, ElectricalDoubleLayer

Wikipedia Reference: https://en.wikipedia.org/wiki/Double_layer_(surface_science)


-

DoubleLayerModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b

Elucidation: model representing the structure of an electrolyte at an electrode-electrolyte interface by a rigid layer formed by the charge carriers on the surface of the electrode and a diffuse layer formed by mobile ions in the electrolyte.

Alternative Label(s): ElectricalDoubleLayerModel, ElectricalPolarizationLayerModel

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-19

Wikipedia Reference: https://en.wikipedia.org/wiki/Double_layer_(surface_science)


-

DroppingMercuryElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b76a778f_253f_4210_a67f_fb6444d0de26

Elucidation: mercury electrode formed by sequence of mercury drops falling from a small aperture

Alternative Label(s): DME

Wikipedia Reference: https://en.wikipedia.org/wiki/Dropping_mercury_electrode


-

EdgeInsulator

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bbc77932_643b_4603_a4e8_970ef06a76ad

Elucidation: part which insures insulation between the plate (electrode) edges and adjacent plates (electrodes) and the container side walls

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-19


-

ElectricChargeSignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_276cfa84_3cc0_40c0_9f6a_57a3b776f47c

Elucidation: Time-dependent variation of electric charge passed through a system.


-

ElectricCurrentMeasurement

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_158ae038_c64b_4cc0_aa56_650475490705

Elucidation: measurement of electric current


-

ElectricCurrentMeasurementResult

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7beef5fb_a406_4284_b85a_87d55cf46a0e


-

ElectricCurrentMeasuringSystem

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f693b744_930c_42ac_8e6f_627b22c6da3f

Elucidation: a system for measuing electric current


-

ElectricCurrentSignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_904b12e0_4a10_47b0_b7db_592aba215cb6

Elucidation: Time-dependent variation of electric current


-

ElectricCurrentVector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4920de95_3a48_4669_b762_5a0b5232b52f

Elucidation: vector containing at least two values for the quantity electric current


-

ElectricPotentialMeasuringSystem

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f9b2956_1465_4fe0_b0df_5e4784dac3b6

Elucidation: a system for measuring electric potential


-

ElectricPotentialSignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7

Elucidation: Time-dependent variation of electric potential


-

ElectricSignal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_898971cb_a9fc_4955_8abf_5d7163a9fe6c

Elucidation: Time dependent variation of an electric quantity.


-

ElectroanalyticalTechnique

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1

Elucidation: analytical methods in which electrochemical processes or phenomena are the core of the measurement principle involving electrochemical cells providing qualitative and quantitative responses.

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Electrocapillarity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1

Elucidation: change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-02

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrocapillarity


-

Electrocatalysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4d6f7f50_b343_4bd6_8612_2b8521a99c9b

Elucidation: increasing the rate of an electrode reaction by adding specific material to the electrode.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-15


-

Electrocatalyst

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841

Elucidation: material that can cause electrocatalysis.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-16

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrocatalyst


-

ElectrochemicalCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77

Elucidation: a system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-01

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemical_cell


-

ElectrochemicalConstituent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82

Elucidation: A constituent in an electrochemical system.


-

ElectrochemicalDegradationPhenomenon

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0a0de817_addc_46a5_8ba2_255d48cdf366

Elucidation: A phenomenon that causes an electrochemical system to deviate from its ideal behaviour.


-

ElectrochemicalDevice

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df

Elucidation: a device whose primary function is facilitating the conversion between chemical and electrical energy.


-

ElectrochemicalDoubleLayerCapacitor

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b91180e7_97ae_49e2_bf82_5bf720e7fa66

Elucidation: Device that stores electrical energy using a double layer in an electrochemical cell.

Alternative Label(s): DoubleLayerCapacitor, EDLC, ElectrochemicalCapacitor


-

ElectrochemicalHalfCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9da958fc_f76d_4654_8a78_99b5f98c118c

Elucidation: a system comprising one electrode in contact with an ionic conductor.

Alternative Label(s): HalfCell

Wikipedia Reference: https://en.wikipedia.org/wiki/Half-cell


-

ElectrochemicalImmunity

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e

Elucidation: situation in which a material in a given environment undergoes negligible electrochemical corrosion.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-03


-

ElectrochemicalImpedanceSpectroscopy

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d30d9de0_b9bf_4919_a022_0394df9c3672

Elucidation: electrochemical measurement method of the complex impedance of an electrochemical system as a function of the frequency of a small amplitude (normally 5 to 10 mV) sinusoidal voltage perturbation superimposed on a fixed value of applied potential or on the open circuit potential

Alternative Label(s): EIS

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

ElectrochemicalInterface

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2

Elucidation: The two-dimensional space comprising the boundary between two electrochemical constituents.


-

ElectrochemicalMaterial

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755

Elucidation: A material that undergoes electrochemical changes.


-

ElectrochemicalMethod

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4


-

ElectrochemicalMigration

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685

Elucidation: transport of ions in an electrolyte due to an electric field

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-06

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemical_migration


-

ElectrochemicalPhenomenon

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b

Elucidation: A chemical phenomenon that is accompanied by the flow of electric current


-

ElectrochemicalPiezoelectricMicrogravimetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1a7fb32a_743f_4aa6_ac5a_ff7a2ba29dce

Elucidation: Electrogravimetry using an electrochemical quartz crystal microbalance.

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

ElectrochemicalPlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ddade648_2033_47b6_bc36_b562a9af591e

Elucidation: Graphical representation of a dataset resulting from the measurement of the response of an electrochemical system.


-

ElectrochemicalPseudocapacitor

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ca0527c1_f682_4eea_aca5_f3ae66a9ddce

Elucidation: a type of supercapacitor that uses metal oxide or conducting polymer electrodes with a high amount of electrochemical pseudocapacitance additional to the double-layer capacitance

Wikipedia Reference: https://en.wikipedia.org/wiki/Pseudocapacitor


-

ElectrochemicalReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914

Elucidation: a chemical reaction in an electrolyte involving a transfer of electrons between chemical components or between chemical components and an electrode

Alternative Label(s): ChargeTransferReaction, ChargeTransferReaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-01


-

ElectrochemicalRelation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae

Elucidation: A material relation in electrochemistry.


-

Electrochemiluminescence

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_96309fa9_e157_48fe_9fda_41003860a3c0

Elucidation: chemiluminescence produced in electrode reactions

Alternative Label(s): ECL, ElectrogeneratedChemiluminescence

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-18

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemiluminescence


-

Electrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627

Elucidation: electronically conductive part in electric contact with a medium of lower electronic conductivity and intended to perform one or more of the functions of emitting charge carriers to or receiving charge carriers from that medium or to establish an electric field in that medium

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-03

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrode


-

ElectrodeElectrolyteInterface

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9c73aff8_1c82_4116_a6be_78e21982b69d

Elucidation: interface between an electrolyte and an electrode where an electrode reaction takes place.

Alternative Label(s): ActiveSurfaceOfAnElectrode, ActiveSurfaceOfAnElectrode

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-05


-

ElectrodePair

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b

Elucidation: assembly of one positive plate, one negative plate and the associated separator if any

Alternative Label(s): PlatePair

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-09


-

ElectrodePassivation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_01260656_ac32_472e_9513_a607366538ec

Elucidation: formation of compounds that reduces the conductivity at the surface of an electrode

Alternative Label(s): Passivation

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-16

Wikipedia Reference: https://en.wikipedia.org/wiki/Passivation_(chemistry)


-

ElectrodePolarisation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2e6933aa_4522_4f16_a437_37110e6cbd0d

Elucidation: accumulation or depletion of electric charges at an electrode, resulting in a difference between the electrode potential with current flow, and the potential without current flow or equilibrium electrode potential

Alternative Label(s): ElectrodePolarization, Polarisation, Polarization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-15

Wikipedia Reference: https://en.wikipedia.org/wiki/Polarization_(electrochemistry)


-

ElectrodeReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8

Elucidation: electrochemical reaction involving the transfer of electrons between electrolyte and electrode

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-04

IUPAC Reference: https://doi.org/10.1351/goldbook.E01960


-

ElectrodeStack

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_27662d03_1bcf_4393_a239_32e31b760839

Elucidation: finished assembly of the positive and negative plate (electrode) groups with interleaved separators and terminals or intercell connectors

Alternative Label(s): PlatePack

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-08


-

Electrodeposition

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f0c24970_4c14_4207_bd78_5f2181a67085

Elucidation: the process of forming a film or a bulk material using an electrochemical process where the electrons are supplied by an external power supply


-

Electrodissolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4df84ec1_8a1a_4770_963f_bf48009bd043

Elucidation: the electrochemical dissolution of a material to soluble species


-

Electrogravimetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_14d0358f_f65d_44f9_8b85_40b38f17c4ed

Elucidation: method of electroanalytical chemistry used to separate by electrolyse ions of a substance and to derive the amount of this substance from the increase in mass of an electrode.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-14

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrogravimetry


-

Electrolysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc

Elucidation: method of separating and neutralizing ions by an electric current in an electrolytic cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-09

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrolysis


-

Electrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59

Elucidation: a material in which the mobile species are ions and free movement of electrons is blocked.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-02

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrolyte


-

ElectrolyteCreep

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089

Elucidation: gradual and slow spreading of an electrolyte film on the external surface of a cell or battery

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-30


-

ElectrolyteLevelIndicator

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c05692eb_ae92_4e03_b355_f259f9089cb8

Elucidation: device used to assist in the measurement of the level of electrolyte in a cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-52


-

ElectrolyteSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de

Elucidation: a liquid electrolyte that consists of solutes dissolved in a solvent

Alternative Label(s): ElectrolyticSolution


-

ElectrolyticCapacitor

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_900d95fb_863d_4142_a96d_369fb39e2639

Elucidation: capacitor consisting of a metallic plate as first conductor, a very thin oxide film formed on the metal as the dielectric and an electrolyte as second conductor

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-04

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrolytic_capacitor


-

ElectrolyticCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4

Elucidation: electrochemical cell intended to produce chemical reactions

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-06

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrolytic_cell


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Electroosmosis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916

Elucidation: movement of a fluid through a diaphragm, produced by application of an electric field

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-01

Wikipedia Reference: https://en.wikipedia.org/wiki/Electro-osmosis


-

Electroplating

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a2b92d2e_4431_411e_8da5_a4c08bac2c0e

Elucidation: process inside an electrolytic cell used to coat a conductive object with a layer of a material

Alternative Label(s): Galvanizing

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-17

Wikipedia Reference: https://en.wikipedia.org/wiki/Electroplating


-

EqualizationCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_990d19b8_672a_4219_a2b3_0a25bfa13f69

Elucidation: extended charge to ensure an equal state of charge of all cells in a battery

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-40


-

FaradaysFirstLawOfElectrolysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1152ae6b_8b57_4d99_912e_40c6a29342fb

Elucidation: mass m of electrochemically-transformed substance is proportional to the charge Q passed, m ∝ Q.

Alternative Label(s): FaradaysLaw, FaradaysLawOfElectrolysis

Wikipedia Reference: https://en.wikipedia.org/wiki/Faraday%27s_laws_of_electrolysis#First_law


-

FaradaysSecondLawOfElectrolysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03

Elucidation: when the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i.

Wikipedia Reference: https://en.wikipedia.org/wiki/Faraday%27s_laws_of_electrolysis#Second_law


-

FlameArrestorVent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e

Elucidation: vent of special design which provides protection against the propagation of a flame front from or into the interior of a secondary cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-11


-

FlowCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d

Elucidation: an electrochemical cell in which the active materials are flowed through the cell from an external source

Alternative Label(s): ElectrochemicalFlowCell


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FluorineDopedTinOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_339e1ba1_2006_4f22_aac4_3ce75edf1088

Elucidation: electrode in which the active material is tin oxide doped with fluorine

Alternative Label(s): FTOElectrode


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Foil

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1d5377a7_9f2b_4fdf_958a_7eeadce158d6


-

FormationCycling

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cb223440_51bd_4f16_a536_96ec408e7de4

Elucidation: the cycling of a cell after manufacturing, usually for the purpose of forming interfacial layers


-

FrequencyResponseAnalyser

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_279ecc9f_bfbc_4108_ae40_3c1c0f735e60

Elucidation: analyzes the output signal of a stimulated system

Alternative Label(s): FRA, FrequencyResponseAnalyzer


-

FuelCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bd33779c_6f40_4354_ab5d_f6c17396414d

Elucidation: galvanic cell that transforms chemical energy from continuously supplied reactants to electric energy by an electrochemical process.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-05

Wikipedia Reference: https://en.wikipedia.org/wiki/Fuel_cell


-

GITT

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_11895d59_3f97_4bad_badf_1a90f2347c2a

Elucidation: electrochemical method that applies current pulses to an electrochemical cell at rest and measures the voltage response

Alternative Label(s): GalvanostaticIntermittentTitrationTechnique


-

GalvanicCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f

Elucidation: electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-02

Wikipedia Reference: https://en.wikipedia.org/wiki/Galvanic_cell


-

Galvanostat

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_22725105_c941_4b14_a4a2_fcb627958607

Elucidation: instrument which controls the electric current between the working electrode and the auxiliary electrode

Alternative Label(s): Amperostat

Wikipedia Reference: https://en.wikipedia.org/wiki/Galvanostat


-

GalvanostaticCycling

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79a8802e_8296_459a_b65d_6e5c79e1bf37

Elucidation: a cycling protocol in which an electrochemical cell is subject to alternating galvanostatic charging and discharging processes


-

GalvanostaticProcess

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5

Elucidation: a process in which the electric current is kept constant


-

GasDiffusionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215

Elucidation: a type of electrode specifically designed for gaseous reactants or products or both

Alternative Label(s): GDE

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=485-02-02

Wikipedia Reference: https://en.wikipedia.org/wiki/Gas_diffusion_electrode


-

GasDissolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0c9017b4_6efd_4e2b_8e24_48b60ebe9315

Elucidation: the dissolution of molecules from a gas into another phase


-

GasEvolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4288b145_ba79_4989_92f8_86086679b0fe

Elucidation: process through which a gas is evolved

Alternative Label(s): Gassing

Wikipedia Reference: https://en.wikipedia.org/wiki/Gas_evolution_reaction


-

GassingOfACell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0f827b54_370d_4c63_99a6_80f13b24e55e

Elucidation: evolution of gas resulting from electrolysis of the water in the electrolyte of a cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-51


-

GlassFibreSeparator

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d11b0e66_c35b_4da7_80a1_037ce89b77fb

Elucidation: a separator is composed of a mass of intermeshed glass fibers.

Alternative Label(s): FibreglassSeparator


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GlassyCarbonElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_057bb143_639c_472b_99ed_ffa1867f6e63

Elucidation: electrode made of glassy carbon material with an intertwined graphitic ribbon structure, formed by pyrolysis of a resol precursor at temperatures up to 3000 °C

Alternative Label(s): GCE


-

GoldElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185

Elucidation: foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries

Alternative Label(s): AuElectrode


-

GouyChapmanModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa54f95d_b49e_43b5_84c3_35520d0fb2f6

Elucidation: an extension of the Helmholtz model that describes the distribution of ions as a function of distance from the electrode surface to the bulk of the electroylte


-

GrahameModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f168ebc_4c78_459c_9a39_bddaa57e214c

Elucidation: a modification of the Stern model that considers the double layer as three regions separated by the inner Helmholtz plane and the outer Helmholtz plane


-

GraphiteElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c831d963_629a_41ab_850f_97fb6841b739

Elucidation: electrode in which the active material is graphite


-

GravimetricAnalysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_32ab2ea8_6263_42a8_8682_2fe0343f8bea

Elucidation: quantitative determination of a chemical species based on its mass

Alternative Label(s): GravimetricMethod

IUPAC Reference: https://goldbook.iupac.org/terms/view/G02694

Wikipedia Reference: https://en.wikipedia.org/wiki/Gravimetric_analysis


-

HPPC

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_99bdbd45_c3ea_4fb9_ae50_ed1ab6bb1dff

Elucidation: electrochemical method that measures the voltage drop of a cell resulting from a square wave current load

Alternative Label(s): HybridPulsePowerCharacterisation, HybridPulsePowerCharacterization


-

HardCarbonElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6235cc7c_2eee_432a_93af_47d7e05db007

Elucidation: electrode in which the active material is hard carbon


-

HelmholtzModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9bc02662_9799_4593_906d_638a841d7352

Elucidation: a structural representation of the double layer that states that the accumulation of electric charge on the surface of the electrode is balanced by a layer of ions in the electrolyte


-

HermeticallySealedCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c14ae9b3_e4ba_4129_a7b6_afd2d4571de6

Elucidation: permanently sealed gas tight cell without pressure release device

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-01


-

HybridFlowCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f54474fc_5d07_474b_97ae_f5d0349363b4

Elucidation: a flow cell that uses one or more electroactive components deposited as a solid layer


-

HydrodynamicVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166

Elucidation: voltammetry with forced flow of the solution towards the electrode surface

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Hydrodynamic_voltammetry


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HydrogenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff

Elucidation: platinized platinum electrode saturated by a stream of pure gaseous hydrogen

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-16


-

ICI

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0838f0b6_ca9a_4f76_9770_ca964617bf1b

Elucidation: electrochemical method that measures the voltage response of an electrochemical cell under galvanostatic conditions to short interruptions in the current

Alternative Label(s): IntermittentCurrentInterruptionMethod


-

Impedimetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_07ad0aff_ab59_442d_9c0a_7f8c5cba8982

Elucidation: measurement principle in which the complex electric impedance of a system is measured, usually as a function of a small amplitude sinusoidal electrode potential

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


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IncreasingPotentialPulses

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_77be01ef_49bd_4f2e_bec8_eec0894b8562

Elucidation: Pulses of electric potential, of amplitude increasing by a constant increment and with a pulse width of 2 to 200 ms, which are superimposed on a constant initial potential.


-

IndicatorElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6fcd255_248d_4603_b128_04dab960a676

Elucidation: electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement

IUPAC Reference: https://goldbook.iupac.org/terms/view/I03006


-

IndiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7b9db6b3_36f0_4b5d_acbb_9284a9054a09

Elucidation: electrode in which the active material is indium


-

IndiumTinOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c63baed9_48dd_4b5c_9e8c_03011010ffb6

Elucidation: electrode in which the active material is indium tin oxide

Alternative Label(s): ITO


-

InertElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543

Elucidation: electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-08


-

InsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c

Elucidation: an electrode at which the predominant electrochemical reaction is an intercalation

Alternative Label(s): IntercalationElectrode


-

Interphase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec

Elucidation: a spatial region at the interface between two bulk phases in contact, which is different chemically and physically from both phases in contact

Alternative Label(s): InterfacialLayer

IUPAC Reference: https://goldbook.iupac.org/terms/view/I03085


-

InterphaseGrowth

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_402598d9_0eea_405d_b0d0_3b8b79deba6f


-

IonExchangeMembrane

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_15325775_6d4c_4192_82f1_e4feca9de426

Elucidation: A membrane having ion-exchange groups:

IUPAC Reference: https://doi.org/10.1351/goldbook.IT07155

Wikipedia Reference: https://en.wikipedia.org/wiki/Ion-exchange_membrane


-

IonicLiquidElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c3f4b34a_0e2c_46f3_baab_4ebd2682d26f

Elucidation: An ionic liquid is an electrolyte composed of a salt that is liquid below 100 °C. Ionic liquids have found uses in electrochemical analysis, because their unconventional properties include a negligible vapor pressure, a high thermal and electrochemical stability, and exceptional dissolution properties for both organic and inorganic chemical species.

Alternative Label(s): IonicLiquid

Wikipedia Reference: https://en.wikipedia.org/wiki/Ionic_liquid


-

IridiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e6a7d5f_3700_46b3_b1b8_f34e37e6f931

Elucidation: electrode in which the active material is iridium


-

IridiumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cba03815_eaa8_493d_b9e4_52856b57fde6

Elucidation: electrode in which the active material is iridium oxide

Alternative Label(s): IrO2Electrode


-

IronDisulfideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d2726dd5_69f0_4cb1_bd3c_4c48813e57e7

Elucidation: an electrode in which the active material is iron disulfide


-

IronElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cc4e178c_bc1f_4502_b6c2_33f304ef6bab

Elucidation: electrode in which the active material is iron


-

Jacket

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069

Elucidation: partial or complete external covering of a cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-20


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KohlrauschsLaw

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_598ae3d0_76e9_429c_a0e1_8694525cb574

Elucidation: For any electrolyte A_xB_y, the limiting molar conductivity is expressed as x times the limiting molar conductivity of A^{y+} and y times the limiting molar conductivity of B^{x-}.

Wikipedia Reference: https://en.wikipedia.org/wiki/Molar_conductivity#Kohlrausch's_law_of_independent_migration_of_ions


-

LawOfMassAction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5a7a3028_db9e_4045_ab68_054c6afc91fc

Elucidation: the rate of the chemical reaction is directly proportional to the product of the activities or concentrations of the reactants

Wikipedia Reference: https://en.wikipedia.org/wiki/Law_of_mass_action


-

LeadElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_610f0bc8_557d_455b_a8ed_272d5d1813c9


-

LeadOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6223121_7df5_42f8_902c_d26fa2fc4f04

Elucidation: electrode in which the active material is lead oxide

Alternative Label(s): PbOElectrode


-

Leakage

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c55ec02c_b727_4df1_97ce_91d7bb5d5e91

Elucidation: unplanned escape of electrolyte, gas or other material from a cell or battery

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-32


-

LeclancheElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_23b30468_be7b_45a9_bc11_a8219bc3ab8b

Elucidation: an aqueous mixture of ammonium chloride and zinc chloride


-

LidSealingCompound

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0

Elucidation: material used to seal the cell lid to the case or to the terminals of a cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-16


-

LinearChronopotentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_618538fa_6607_45a3_ad06_6a5f98febcbd

Elucidation: chronopotentiometry where the applied current is changed linearly


-

LinearCurrentRamp

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa774456_718a_4a28_ba6a_6f828887c510

Elucidation: signal where an electric current is varied linearly from an initial current, typically 0 A


-

LinearPotentialRamp

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_29f2a35a_8c09_429d_b9e8_33f3e1fc3671

Elucidation: Signal where the electric potential is varied linearly from an initial potential.


-

LinearScanVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a9f19bb0_55bc_4908_b0e4_7888077b0019

Elucidation: Voltammetry in which the current is recorded as the electrode potential is varied linearly with time.

Alternative Label(s): LSV, LinearPolarization, LinearSweepVoltammetry

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Linear_sweep_voltammetry


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LiquidElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89

Elucidation: an electrolyte in the liquid phase.


-

LiquidGalliumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_80fdbd63_9b7a_462b_a8cb_b50f5f6ab182

Elucidation: a liquid electrode with an active material of gallium


-

LiquidJunction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_634467ad_feed_4979_adb2_877d98fe1768

Elucidation: any junction between two electrolyte solutions of different composition.

IUPAC Reference: https://goldbook.iupac.org/terms/view/L03584


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LiquidMetalElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29

Elucidation: an electrode that uses a liquid metal

Wikipedia Reference: https://en.wikipedia.org/wiki/Liquid_metal_electrode


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LithiumCobaltOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fd7caf39_0a43_4fbf_958e_a62067aa9007

Elucidation: electrode in which the active material is lithium cobalt oxide

Alternative Label(s): LCOElectrode


-

LithiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_47346d85_b9be_4480_8993_6307b1c58fcd

Elucidation: metal electrode in which the active material is lithium


-

LithiumHydroxideSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e84e691a_df58_465c_9771_7a7fe2212ed5

Elucidation: a solution of lithium hydroxide (LiOH) dissolved in water (H2O)

Alternative Label(s): AqueousLithiumHydroxideSolution, LiOHSolution


-

LithiumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4c3ee364_829b_41a4_b895_ca4a041efb2a

Elucidation: an insertion electrode in which the guest molecule is lithium


-

LithiumIronPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1d0f15cb_d6b5_4c27_89ca_fe78adc1ce5b

Elucidation: electrode in which the active material is lithium iron phosphate

Alternative Label(s): LFPElectrode


-

LithiumManganeseIronPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9109b3f6_112b_456d_ae45_b82c271c656b

Elucidation: electrode in which the active material is lithium manganese iron phosphate

Alternative Label(s): LMFPElectrode


-

LithiumManganeseOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c231227b_f318_4e59_ad90_6e91072903ed

Elucidation: electrode in which the active material is lithium manganese oxide

Alternative Label(s): LMOElectrode


-

LithiumManganeseOxideLithiumIronPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fffc3dad_6946_4c32_a9d3_f5f311339881

Elucidation: an electrode with blended lithium manganese oxide (LMO) and lithium iron phosphate (LFP) active materials

Alternative Label(s): LMOLFPElectrode


-

LithiumManganesePhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_713200a1_952b_49e2_90b7_deba229f6bbe

Elucidation: electrode in which the active material is lithium manganese phosphate

Alternative Label(s): LMPElectrode


-

LithiumNickelCobaltAluminumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f19d3b4f_d59b_4a92_a547_54a6f59cc9b4

Elucidation: electrode in which the active material is lithium nickel cobalt aluminium oxide

Alternative Label(s): NCAElectrode


-

LithiumNickelMananeseCobaltOxideLithiumManganeseOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_48e380c3_0441_4761_a80f_3e448cb2f0ba

Elucidation: an electrode with blended lithium nickel manganese cobalt oxide (NMC) and lithium manganese oxide (LMO) active materials

Alternative Label(s): NMCLMOElectrode


-

LithiumNickelManganeseCobaltOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3eb8c65_5644_45e3_9e17_0be6277c7962

Elucidation: electrode in which the active material is lithium nickel manganese cobalt

Alternative Label(s): NMCElectrode


-

LithiumNickelManganeseCobaltOxideLithiumCobaltOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_098690e3_9010_437e_8042_cee1656efa9b

Elucidation: an electrode with blended lithium nickel manganese cobalt oxide (NMC) and lithium cobalt oxide (LCO) active materials

Alternative Label(s): NMCLCOElectrode


-

LithiumNickelManganeseOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_41ddf723_245f_4ce8_b9b1_7d9b3b9eea7d

Elucidation: electrode in which the active material is lithium nickel manganese oxide

Alternative Label(s): LNMOElectrode


-

LithiumNickelManganeseOxideLithiumIronPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bb710d71_98fa_48a1_85bc_d8f1ef2200da

Elucidation: an electrode with blended lithium nickel manganese oxide (LNMO) and lithium iron phosphate (LFP) active materials

Alternative Label(s): LNMOLFPElectrode


-

LithiumNickelOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cab66388_3feb_4101_82bc_f4441f0b60e3

Elucidation: electrode in which the active material is lithium nickel oxide

Alternative Label(s): LNOElectrode


-

LithiumTitanateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6d0fe07e_a629_479c_ab24_2846f209bb0b

Elucidation: electrode in which the active material is lithium titanate

Alternative Label(s): LTOElectrode


-

LithiumVanadiumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5e91259_cd97_4ed6_9ab2_4b18ef68a35a

Elucidation: electrode in which the active material is lithium vanadium oxide


-

MagnesiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2a177462_ff01_4b83_ab9f_032e93c9ec69


-

MagnesiumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d9888f1f_2226_4ce3_9cb3_91fd9bd1bf22

Elucidation: an insertion electrode in which the guest molecule is magnesium


-

ManganeseDioxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ca4d9efc_70be_441e_b358_d927aa4c36c4

Elucidation: electrode in which the active material is manganese dioxide

Alternative Label(s): MnO2Electrode


-

MeasurementPrinciple

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65

Elucidation: phenomenon serving as the basis of a measurement

Alternative Label(s): PrincipleOfMeasurement

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=112-04-03


-

MercuryElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff

Elucidation: liquid metal electrode used in polarography

Alternative Label(s): HgElectrode


-

MetalElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e

Elucidation: an electrode in which the actve electrochemical material is a metal


-

MetalOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5

Elucidation: electrode in which the active material is a metal oxide


-

ModifiedConstantVoltageCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_acdeaa89_0e99_4941_8821_d5dea3d34912

Elucidation: constant voltage charge where the electric current is limited to a predetermined value

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-50


-

MonoblocContainer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e94f6d42_35e4_4f9f_bb74_5e0628bbd454

Elucidation: case with multiple separate cell compartments

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-18


-

Mudrib

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1a2eb6db_c927_4039_aea0_8dfab060fd27

Elucidation: ridges in the bottom of the case which support the plate pack (electrode stack) and thus create a space which allows the active material detached from the plates (electrodes) to settle without causing a short-circuit between the plates (electrodes)

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-18


-

NearNeutralElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c

Elucidation: an aqueous electrolyte with a nominal pH value between 4 and 10.

Alternative Label(s): NearNeutralAqueousElectrolyte, NearNeutralSolution


-

NegativeElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c94c041b_8ea6_43e7_85cc_d2bce7785b4c

Elucidation: for a device having two electrodes, that electrode having the lower electric potential

Alternative Label(s): NegativePlate, NegativePlate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=151-13-04


-

NegativeTerminal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b851c7e9_60bf_4d3d_abe1_8d08d3d85124

Elucidation: accessible conductive part provided for the connection of an external electric circuit to the negative electrode of the cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-24


-

NernstEinsteinEquation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9d7e5fea_a49a_4a19_a8de_8e24c60e420c

Elucidation: an equation relating the limiting molar conductivity Λ_m^0 to the ionic diffusion coefficients.

Wikipedia Reference: https://en.wikipedia.org/wiki/Einstein_relation_(kinetic_theory)#Nernst%E2%80%93Einstein_equation


-

NernstEquation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e

Elucidation: An equation that relates the reduction potential of an electrochemical reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation.

Wikipedia Reference: https://en.wikipedia.org/wiki/Nernst_equation


-

Neutralisation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0471ec77_91bc_4a78_be31_b6af613e5966

Elucidation: insertion or removal of electrons into or from ions to obtain particles having zero electric charge

Alternative Label(s): Neutralization

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-11


-

NickelElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b8dc138f_8024_4f15_8350_192425d23a4d

Alternative Label(s): metal electrode in which the active material is nickel


-

NickelOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76e461aa_5948_4a68_8337_284d11e0fd7d

Elucidation: electrode in which the active material is nickel oxide

Alternative Label(s): NiOElectrode


-

NickelOxideHydroxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_344ed3a6_481a_499f_afef_631f1cece9ef

Elucidation: electrode in which the active material is nickel oxyhydroxide

Alternative Label(s): NiOOHElectrode, NickelOxyhydroxideElectrode


-

NonAqueousElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98

Elucidation: an ion-transport medium that does not contain water.

Alternative Label(s): NonAqueousElectrolyticSolution, NonAqueousSolution


-

NonPolarizableElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275

Elucidation: an electrode that holds its potential essentially constant by efficiently allowing electric current to pass


-

NonSpillableCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c610d869_cc03_44f0_b40d_ca86e945b9c9

Elucidation: cell from which electrolyte cannot escape regardless of its orientation

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-16


-

NormalHydrogenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83ee23b3_2f5c_4afa_b972_ac85e91d7306

Elucidation: potential of a platinum electrode in 1 M acid solution.

Alternative Label(s): NHE


-

NormalPulseVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3c3972f6_8e1d_454b_a198_48173ba2232b

Elucidation: voltammetry in which potential pulses of amplitude increasing by a constant increment and with a pulse width of 2 to 200 ms are superimposed on a constant initial potential

Alternative Label(s): NPV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

NyquistPlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a2b01d05_b472_4cf5_b388_e0914db56324

Elucidation: plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested in an impedimetry measurement

Alternative Label(s): ComplexPlanePlot, NyquistDiagram

Wikipedia Reference: https://en.wikipedia.org/wiki/Nyquist_stability_criterion#Nyquist_plot


-

OpenCircuitHold

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cb3c0663_5962_4b79_8e72_1e8242af3977

Elucidation: a process in which the electric current is kept constant at 0 (i.e., open-circuit conditions)

Alternative Label(s): OCVHold


-

OrganicElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_564d31be_91cb_4a8f_8369_2a55f1180499

Elucidation: an electrolyte solution with an organic solvent


-

OutputCable

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c

Elucidation: cable used for the electrical connection of the battery terminals and the load and/or the charger

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-36


-

Overcharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9ee6e728_e8f5_4b36_a045_d63da69dfc85

Elucidation: continued charging of a fully charged secondary cell or battery

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-44


-

OxygenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e2c91edd_dd01_4309_9735_6fe5280261d4

Elucidation: a gas diffusion electrode in which the active material is oxygen (O2)


-

PalladiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9f056bb_a38b_43bd_a6bd_99d618431f4d

Elucidation: electrode in which the active material is palladium


-

ParallelConnection

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_efc4f7ab_850d_443c_a17f_184983021f96

Elucidation: arrangement of cells or batteries wherein all the positive terminals and all the negative terminals, respectively, are connected together.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-39


-

ParallelSeriesConnection

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5da9948_e95b_4f12_a2d2_10a48f390c52

Elucidation: arrangement of cells or batteries wherein parallel connected cells or batteries are connected in series.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-40


-

ParasiticReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b79d4f9e_5727_4895_8d7f_5fc18d83eb90

Elucidation: an unwanted side reaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-07


-

PassivationLayer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d16eec87_c646_4566_bda6_7d3357cda061

Elucidation: an interfacial layer of an electrode surface, that causes the electrode to become passivated


-

PastedPlate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c

Elucidation: plate in which the active material is applied as a paste to a conductive current collector

Alternative Label(s): PastedElectrode

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-03


-

PhosphoricAcidSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_78f75a64_55b6_4243_a35e_3d279c83209b

Elucidation: a solution of phosphoric acid (H3PO4) dissolved in water (H2O)


-

PhotoelectrolyticCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2

Elucidation: electrolytic cell in which a chemical reaction is influenced by the absorption of light.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-19


-

PlateGroup

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_457a8f92_0a19_4773_8114_a42edff32248

Elucidation: assembly of plates of the same polarity electrically connected together

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-04


-

PlatinumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2d32a81a_2148_41bd_84fb_467aa8de4a8f

Elucidation: foil, wire, disc, or mesh electrode made of platinum, which is the most commonly used metallic working electrode in electrochemistry

Alternative Label(s): PtElectrode


-

PolarityReversal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83d2c2d4_ffa9_42f4_9264_a0c59c657607

Elucidation: reversing of the polarities of the electrodes of a cell, generally due to over-discharge of a low-capacity cell in a series arrangement

Alternative Label(s): CellReversal

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-03


-

PolarizableElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c2024587_3237_474e_8df9_91d10db2df47

Elucidation: electrode whose potential changes with an applied potential


-

PolymerElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c6d6c0a1_a06b_437a_978f_a469d3071ca9

Elucidation: a polymer matrix capable of ion conduction

Wikipedia Reference: https://en.wikipedia.org/wiki/Polymer_electrolytes


-

PorousElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3663991d_9319_4f7a_922b_f0e428b58801

Elucidation: porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix.


-

PorousElectrodeCoating

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_403c300e_09b9_400b_943b_04e82a3cfb56

Elucidation: a porous electrode which is coated onto a non-porous substrate, typically a metallic foil current collector.


-

PorousSeparator

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91

Elucidation: a separator with a porosity greater than 0


-

PositiveElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aff732a9_238a_4734_977c_b2ba202af126

Elucidation: for a device having two electrodes, that electrode having the higher electric potential

Alternative Label(s): PositivePlate, PositivePlate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=151-13-05


-

PositiveTerminal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_522f0c0b_cf33_4328_af71_12e38dae6798

Elucidation: accessible conductive part provided for the connection of an external electric circuit to the positive electrode of the cell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-25


-

PotassiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0afe79ed_dc0d_4b3e_88fa_ae0c7b1e88b5


-

PotassiumHydroxideSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_26a0dc36_8171_4a84_88dd_0f5dd7cb2d20

Elucidation: a solution of potassium hydroxide (LiOH) dissolved in water (H2O)

Alternative Label(s): AqueousPotassiumHydroxideSolution, KOHSolution


-

PotassiumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c183f697_8995_477c_9ccd_5c12d98e3633

Elucidation: an insertion electrode in which the guest molecule is potassium


-

PotentialPulse

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2dd44ff6_425a_4377_b86e_fa2bd567819f

Elucidation: Rapid, transient change in the amplitude of an electric potential, from a baseline value to a higer or lower value, followed by a rapid return to the baseline value.


-

PotentialTimePlot

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cd7d24a5_db31_4d76_97d9_367c809f099e

Elucidation: plot of the time-dependence of instantaneous electric potential following a change in applied current

Alternative Label(s): ElectricPotentialTimeCurve, ElectricPotentialTimePlot, PotentialTimeCurve


-

PotentiometricStrippingAnalysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5

Elucidation: two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential

Alternative Label(s): PSA


-

PotentiometricStrippingAnalysis

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5039bc8_f595_4797_908a_7e86131fbde4

Elucidation: two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential. The time between changes in potential in step 2 is related to the concentration of analyte in the solution

Alternative Label(s): PSA

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Potentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6

Elucidation: techniques based on the measurement of potential at controlled current (constant or equal to zero)

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-12

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Potentiostat

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a9fc3f77_e48e_4bce_b118_044d608722f6

Elucidation: Measuring instrument for electric current that controls the potential difference between a working electrode and a reference electrode and measures the electric current between a working electrode and an auxiliary electrode.

Wikipedia Reference: https://en.wikipedia.org/wiki/Potentiostat


-

PotentiostaticProcess

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f07be701_9d6a_415b_ac6d_63202297a7a1

Elucidation: a process in which the voltage is kept constant


-

PouchCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_74459386_875c_4303_b774_60125b599d06

Elucidation: a soft pouch case that is described by its length, width, and height


-

Powder

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ee479886_6805_4018_95e1_500185e44215


-

PressureReliefVent

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f330680b_347e_45b3_9113_5ce09d18d60b

Elucidation: vent of special design which allows to release gas from a cell in order to avoid excessive internal pressure and thereby to preclude rupture or explosion of the cell container

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-41


-

PrismaticCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603

Elucidation: a rigid prismatic case that is described by characteristic length, width, and height


-

ProtonInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_11a774f3_d20a_4741_bd81_cae53230bd0c

Elucidation: an insertion electrode in which the guest molecule is a proton (hydrogen)


-

R1025

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e73cb0b7_e2af_4c1a_b05b_503df25a8bf5

Elucidation: a coin case with a nominal diameter of 10.0 mm and a height of 2.5 mm


-

R11108

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dac5067c_e6f2_4fca_a915_5b7b918ca1c4

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 10.8 mm


-

R1121

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_31b7ac6a_b1eb_45e7_a075_b6063080c949

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 2.1 mm

Alternative Label(s): R55


-

R1126

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cf6eebea_24f6_48d2_8389_65eba0393762

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 2.6 mm

Alternative Label(s): R56


-

R1130

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_39c6f5a0_5dc8_4112_b432_b9fece568ca2

Elucidation: a coin case with a nominal diameter of 11.5 mm and a height of 3.0 mm


-

R1131

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b442217f_02f6_4991_aadf_22d81369223c

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 3.1 mm

Alternative Label(s): R54


-

R1136

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_21eef598_0799_4cb1_b2d5_6e072a8579a3

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 3.6 mm

Alternative Label(s): R42


-

R1142

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_abffe8cd_14d3_4437_84e6_5dfc61b057e8

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 4.2 mm

Alternative Label(s): R43


-

R1154

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fe054d02_41c7_40e9_8206_3440ab6a67b2

Elucidation: a coin case with a nominal diameter of 11.6 mm and a height of 5.4 mm

Alternative Label(s): R44


-

R1216

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_36e05f2f_d279_4816_b5ae_6bb4cef02736

Elucidation: a coin case with a nominal diameter of 12.5 mm and a height of 1.6 mm


-

R1220

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_296b95b0_c4cb_45db_a8ca_f638379870c4

Elucidation: a coin case with a nominal diameter of 12.5 mm and a height of 2.0 mm


-

R1225

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f7e253da_b12e_40b0_ba51_8cb039839ab6

Elucidation: a coin case with a nominal diameter of 12.05 mm and a height of 2.5 mm


-

R1511

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ce4352a7_f0b1_4f27_9184_6deebf8bbe96

Elucidation: a coin case with a nominal diameter of 15.8 mm and a height of 11.1 mm

Alternative Label(s): R52


-

R1616

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5f67a0c_ed56_479d_9b68_6003142f98b0

Elucidation: a coin case with a nominal diameter of 16.0 mm and a height of 1.6 mm


-

R1632

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f2cf71c1_f2d7_4131_82e0_2701cdecea55

Elucidation: a coin case with a nominal diameter of 16.0 mm and a height of 3.2 mm


-

R2012

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9c0e683b_40d7_4786_b31f_910dd68b2ea8

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 1.2 mm


-

R2016

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_30c8fb1b_3c75_49f5_9395_c15dfaf71b12

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 1.6 mm


-

R2020

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9017b8b9_e21e_4961_a3c1_c0aeef3fe795

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 2.0 mm


-

R2025

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9ceffffd_b918_48c2_aad9_5db16fa6149d

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 2.5 mm


-

R2032

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_94497aca_52a0_48e3_9b76_157b050e35b3

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 3.2 mm


-

R2040

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fab4bd12_c4ed_417a_92a3_bcb109000d82

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 4.0 mm


-

R2050

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_400cb3e0_27b5_4d9a_be80_f86ad2757763

Elucidation: a coin case with a nominal diameter of 20.0 mm and a height of 5.0 mm


-

R2320

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fbf40756_3265_4468_bcdb_88d162afc539

Elucidation: a coin case with a nominal diameter of 23.0 mm and a height of 2.0 mm


-

R2325

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0689e6fc_cda7_4e04_b1eb_41459a0a4736

Elucidation: a coin case with a nominal diameter of 23.0 mm and a height of 2.5 mm

Alternative Label(s): R23/3


-

R2330

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_11579b47_cbf8_45ac_aed3_343ea533b346

Elucidation: a coin case with a nominal diameter of 23.0 mm and a height of 3.0 mm


-

R2335

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_885ffc4d_2b29_42d6_8597_6fc879c21d60

Elucidation: a coin case with a nominal diameter of 23.0 mm and a height of 3.5 mm


-

R2354

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_af92a3ae_e870_4676_9ae7_cda277b1e6e1

Elucidation: a coin case with a nominal diameter of 23.0 mm and a height of 5.4 mm


-

R2412

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a4e7c3d6_45bd_402a_962f_5d4b88af84ff

Elucidation: a coin case with a nominal diameter of 24.5 mm and a height of 1.2 mm


-

R2430

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_11e9f765_4fea_456b_bd8e_4624b9c752ae

Elucidation: a coin case with a nominal diameter of 24.5 mm and a height of 3.0 mm


-

R2450

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aaafc5d6_050a_4c51_b1ca_db5839aad4de

Elucidation: a coin case with a nominal diameter of 24.5 mm and a height of 5.0 mm


-

R2477

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a87d4b9d_ba91_4549_aed4_508d1160c0c0

Elucidation: a coin case with a nominal diameter of 24.5 mm and a height of 7.7 mm


-

R3032

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_99475d6c_304c_4d6b_9eca_fbc42f768be5

Elucidation: a coin case with a nominal diameter of 30.0 mm and a height of 3.2 mm


-

R416

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_027d437e_3bbf_4eda_940b_e509f8d2b993

Elucidation: a coin case with a nominal diameter of 4.8 mm and a height of 1.6 mm


-

R512

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_94209cd8_f68f_40e6_ac70_cfb97a16e593

Elucidation: a coin case with a nominal diameter of 5.8 mm and a height of 1.3 mm


-

R516

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76318e8e_c1ba_49ac_8029_a951bd9dc955

Elucidation: a coin case with a nominal diameter of 5.8 mm and a height of 1.6 mm

Alternative Label(s): R62


-

R521

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0a5038d4_24af_4ea8_8d56_a156faeb98e2

Elucidation: a coin case with a nominal diameter of 5.8 mm and a height of 2.1 mm

Alternative Label(s): R63


-

R527

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b56a95e6_eea5_4a58_99aa_045fd28e75d3

Elucidation: a coin case with a nominal diameter of 5.8 mm and a height of 2.7 mm

Alternative Label(s): R64


-

R616

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dc019f3f_e5f3_4eeb_bab9_a845a02223a0

Elucidation: a coin case with a nominal diameter of 6.8 mm and a height of 1.65 mm

Alternative Label(s): R65


-

R621

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_15ec346a_6d3c_4161_95e1_9cf889965f85

Elucidation: a coin case with a nominal diameter of 6.8 mm and a height of 2.1 mm

Alternative Label(s): R60


-

R626

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_68c1c36e_1548_4247_bae2_fe7102a2c4ff

Elucidation: a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm

Alternative Label(s): R66


-

R626

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6b275583_433f_46f7_aafd_ebc9409257cc

Elucidation: a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm

Alternative Label(s): R66


-

R712

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bb2faf17_b819_4876_b17f_fa82917cf85d

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 1.3 mm


-

R716

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_34cb7ea7_2436_46e0_806e_a3c7835ae228

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 1.65 mm

Alternative Label(s): R67


-

R721

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3279f575_1c62_4bf2_a6e8_de4c7ff36f8e

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 2.1 mm

Alternative Label(s): R58


-

R726

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_06db7d9e_d224_4360_b926_734f0349d396

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 2.6 mm

Alternative Label(s): R59


-

R731

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_88100e2c_0f6e_4483_afbf_30029a6702c6

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 3.1 mm


-

R736

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0c09df01_b251_4f75_b6e3_2578ba1a10c9

Alternative Label(s): R41, a coin case with a nominal diameter of 7.9 mm and a height of 3.6 mm


-

R754

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_028069a2_4e03_409e_8af2_4c8df32b5c5e

Elucidation: a coin case with a nominal diameter of 7.9 mm and a height of 5.4 mm

Alternative Label(s): R48


-

R9

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e0869e7a_36fe_4e33_9843_a5dc19fcb488

Elucidation: a coin case with a nominal diameter of 15.5 mm and a height of 6.0 mm


-

R916

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ebf314c7_81ad_4d77_9da4_b454520fda0e

Elucidation: a coin case with a nominal diameter of 9.5 mm and a height of 1.6 mm

Alternative Label(s): R68


-

R921

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_eb1c9aa3_ad4f_4f2a_80f6_d6c8a8bc0d9a

Elucidation: a coin case with a nominal diameter of 9.5 mm and a height of 2.1 mm

Alternative Label(s): R69


-

R926

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a277e420_2483_44d5_a2bc_4e421dea231a

Elucidation: a coin case with a nominal diameter of 9.5 mm and a height of 2.6 mm

Alternative Label(s): R57


-

R927

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_387e1e59_e511_4acb_b5ec_fa7360ec7557

Alternative Label(s): a coin case with a nominal diameter of 9.5 mm and a height of 2.7 mm


-

R932

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9a23f61b_fef0_40f8_84f9_2057f90f6a95

Elucidation: a coin case with a nominal diameter of 9.3 mm and a height of 3.2 mm


-

R936

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d67a0921_15e4_4c73_804e_97b2d66452b8

Elucidation: a coin case with a nominal diameter of 9.5 mm and a height of 3.6 mm

Alternative Label(s): R45


-

Record

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_59c041fc_eaa1_40fc_9b3e_1a6aca6119fd

Elucidation: a measurement of one or more quantities, usually at a given time


-

RectangularElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_14377ecb_5ead_431e_831e_159d622bd0ea

Elucidation: an electrode in the shapre of a rectangle


-

ReferenceElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-15

IUPAC Reference: https://goldbook.iupac.org/terms/view/R05229

Wikipedia Reference: https://en.wikipedia.org/wiki/Reference_electrode


-

ReversibleHydrogenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0d9ba00d_04bc_4bdc_85af_3380694f6f68

Elucidation: a practical hydrogen electrode whose potential depends on the pH of the solution

Wikipedia Reference: https://en.wikipedia.org/wiki/Reversible_hydrogen_electrode


-

RhodiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_399b10cd_8a2e_47be_96b8_295890bd2460

Elucidation: electrode in which the active material is rhodium


-

RotatingDiskElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5

Elucidation: A disc electrode that is embedded in the centre of a cylinder which rotates in solution around the longitudinal cylinder axis.

Alternative Label(s): RDE

Wikipedia Reference: https://en.wikipedia.org/wiki/Rotating_disk_electrode


-

RotatingRingDiskElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917

Elucidation: a second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)

Alternative Label(s): RRDE

Wikipedia Reference: https://en.wikipedia.org/wiki/Rotating_ring-disk_electrode


-

RoundCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82

Elucidation: a case that is described by its diameter and height


-

RoundElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614

Elucidation: an electrode in the shape of a circle


-

RutheniumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7ffe1cb6_f87e_4b4a_8ce7_c98e2a584cb1

Elucidation: electrode in which the active material is ruthenium


-

RutheniumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_10a91aba_da41_4309_a926_ddc0f285c2c1

Elucidation: electrode in which the active material is ruthenium oxide

Alternative Label(s): RuO2Electrode


-

SaltBridge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f

Elucidation: means of making electrolytic connection between two half cells without introducing a significant liquid junction potential.

Wikipedia Reference: https://en.wikipedia.org/wiki/Salt_bridge


-

SampledDCPolarography

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6f0dc7c0_ba12_4390_9564_f10f85a1779a

Elucidation: DC polarography with current sampling at the end of each drop life mechanically enforced by a knocker at a preset drop time value. The current sampling and mechanical drop dislodge are synchronized.

Alternative Label(s): TASTPolarography

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

SaturatedCalomelElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82b66bfe_ec25_417b_ba65_b631ddaaca0e

Elucidation: A reference electrode based on the reaction between elemental mercury and mercury(I) chloride.

Wikipedia Reference: https://en.wikipedia.org/wiki/Saturated_calomel_electrode


-

SaturatedSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_27a81a51_e8d7_42fb_834f_0d068fa45d89

Elucidation: solution which has the same concentration of a solute as one that is in equilibrium with undissolved solute at specified values of the temperature and pressure

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-14

IUPAC Reference: https://doi.org/10.1351/goldbook.S05471


-

SealedCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8d3bf304_78e4_4e99_abe1_6ab429e44ed1

Elucidation: cell which remains closed and does not release either gas or liquid when operated within the limits specified by the manufacturer

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-17


-

Seawater

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1c0c8f43_7349_4646_94e3_c36727c5c2e3

Elucidation: a combination of salts (mostly NaCl) dissolved in water


-

SelfDischarge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330

Elucidation: phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-27

Wikipedia Reference: https://en.wikipedia.org/wiki/Self-discharge


-

Separator

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0

Elucidation: in an electrochemical cell, device made of insulating material permeable to the ions of the electrolyte and prohibiting totally or partially the mixing of the substances on both sides.

Alternative Label(s): ElectrochemicalSeparator, ElectrochemicalSeparator

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-17

Wikipedia Reference: https://en.wikipedia.org/wiki/Separator_(electricity)


-

SeriesConnection

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8c71739c_27c1_4d19_a0ff_02545296af43

Elucidation: arrangement of cells or batteries wherein the positive terminal of each cell or battery is connected to the negative terminal of the next cell or battery in sequence.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-41


-

SeriesParallelConnection

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bed5b5f9_b89d_45e3_a8c2_81b70ae21847

Elucidation: arrangement of cells or batteries wherein in series connected cells or batteries are connected in parallel.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-42


-

SideReaction

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f47611a2_e081_47f0_b287_3fda5f706154

Elucidation: chemical reaction which occurs in addition to the main process

Alternative Label(s): SecondaryReaction, SecondaryReaction

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-06

Wikipedia Reference: https://en.wikipedia.org/wiki/Side_reaction


-

SiliconElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79e12290_d1e5_4c41_916c_18f1e4d7fb51

Elucidation: electrode in which the active material is silicon


-

SiliconGraphiteElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e8c39ecc_29d1_4172_996e_d5b05dc88015

Elucidation: an electrode with blended silicon and graphite active materials


-

SiliconOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4143b1c2_2d21_419e_af45_247d4c78ce7e

Elucidation: electrode in which the active material is silicon oxide


-

SiliconOxideGraphiteElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2fd5964b_0c65_4413_8b8c_849639e6d1e7

Elucidation: an electrode with blended silicon oxide and graphite active materials


-

SilverChlorideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6ec59f99_5f26_4a7d_9b90_b52e0f8ad190

Elucidation: A type of reference electrode based on the reaction between sliver and silver chloride.

Wikipedia Reference: https://en.wikipedia.org/wiki/Silver_chloride_electrode


-

SilverElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e

Elucidation: electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver

Alternative Label(s): AgElectrode


-

SilverOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a3745142_b97a_4e19_b7ed_03599f56e81d

Elucidation: electrode in which the active material is silver oxide


-

SingleCoatedElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_418c59bd_dc9d_438b_bc7c_494fbd1bb4f8

Elucidation: an electrode that is coated on only one side of the current collector


-

SinusoidalCurrentWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d61deb36_b397_4811_bf7a_66d8e4578c6e

Elucidation: alternating current consistent with a sinusoidal waveform


-

SinusoidalPotentialWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c74bb11c_e875_4112_b9cf_00d0890ef1f5

Elucidation: Sinusoidal alternating potential of small amplitude (10 to 50 mV) of constant frequency (10 Hz to 100 kHz).


-

SodiumChromiumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f8f81b27_1d6c_42d8_a7e9_5a2534102562

Elucidation: electrode in which the active material is sodium chromium oxide


-

SodiumCobaltOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ee0278fb_932d_48cd_a20a_c1b89b29d68b

Elucidation: electrode in which the active material is sodium cobalt oxide


-

SodiumCobaltPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9e24d403_8531_416e_a9ec_d1ec5508bcb1

Elucidation: electrode in which the active material is sodium cobalt phosphate


-

SodiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_df4dd678_9642_47c9_84dd_4bb09f369f53


-

SodiumHydroxideSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ebd01982_6b0c_48e7_90ef_7b7342009449

Elucidation: a solution of sodium hydroxide (LiOH) dissolved in water (H2O)

Alternative Label(s): AqueousSodiumHydroxideSolution, NaOHSolution


-

SodiumInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d936c767_1530_419c_93f4_59e08f0d702c

Elucidation: an insertion electrode in which the guest molecule is sodium


-

SodiumIronHexacyanoferrateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8968eb7a_9a65_4286_a596_c31b998df329

Elucidation: electrode in which the active material is sodium iron hexacyanoferrate


-

SodiumIronPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_502a98a3_ce47_421f_8e0a_016ed171c900

Elucidation: electrode in which the active material is sodium iron phosphate


-

SodiumManganeseHexacyanoferrateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4edb47d6_107c_40a2_be7c_6b26e9d296da

Elucidation: electrode in which the active material is sodium manganese hexacyanoferrate


-

SodiumManganeseOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e8d9e091_a56d_4a24_a305_d1bac55cfce3

Elucidation: electrode in which the active material is sodium manganese oxide


-

SodiumManganesePhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cc0468a2_1851_4d3d_92a6_b4059db0c056

Elucidation: electrode in which the active material is sodium manganese phosphate


-

SodiumMetatitanateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_103c9e6c_9c26_430a_9fb9_f4f041e970b0

Elucidation: electrode in which the active material is sodium metatitanate


-

SodiumNickelPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4a13e538_4c08_4ba9_8ebc_98a866208e01

Elucidation: electrode in which the active material is sodium nickel phosphate


-

SodiumTitaniumOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c5f51531_1452_4654_82e5_0505491c2c7d

Elucidation: electrode in which the active material is sodium titanium oxide


-

SodiumTitaniumPhosphateElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cff80dd5_19a9_4357_8fb9_410a978153e2

Elucidation: electrode in which the active material is sodium titanium phosphate


-

SolidAmalgamElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc

Elucidation: electrode made of a solid amalgam of an appropriate metal

Alternative Label(s): SAE


-

SolidElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0508a114_544a_4f54_a7de_9b947fb4b618

Alternative Label(s): FastIonConductor, SolidStateElectrolyte

Wikipedia Reference: https://en.wikipedia.org/wiki/Fast_ion_conductor


-

SolidElectrolyteInterphase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ecf136cb_2584_4cb1_98b7_2d2b3d22e40d

Elucidation: an interfacial layer that forms between an electrode phase and and electrolyte phase, due to the decomposition of the electrolyte

Alternative Label(s): SEI


-

SpaceChargeLayer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e3f6eacc_f661_404e_ac16_45d2fa1f5d89

Elucidation: an interphase formed when two materials with different chemical potentials are brought in contact with each other, and the atoms or electrons are unable to migrate to establish local charge neutrality

Alternative Label(s): DepletionLayer, DepletionRegion, DepletionZone, JunctionRegion, SpaceChargeRegion

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=521-02-82

Wikipedia Reference: https://en.wikipedia.org/wiki/Depletion_region


-

Spacer

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_49909cd1_44f4_41b4_877a_82a52845a5cb

Elucidation: component of a cell made of insulating material intended to maintain the spacing between plates of opposite polarity or between the plate pack and the case

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-10


-

Spring

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e

Elucidation: an elastic device

Wikipedia Reference: https://en.wikipedia.org/wiki/Spring_(device)


-

SquareWavePotentialWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0e33278b_639f_412d_9abd_64c3790026ef

Elucidation: Periodic potential where the amplitude alternates at a steady frequency between fixed minimum and maximum values, with the same duration at minimum and maximum.


-

SquareWaveVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_042d2282_bd2d_4874_b896_2d9dd06b54dd

Elucidation: voltammetry in which a square-wave potential waveform is superimposed on an underlying linearly varying potential ramp or staircase ramp

Alternative Label(s): OSWV, OsteryoungSquareWaveVoltammetry, SWV

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Squarewave_voltammetry


-

SquareWaveVoltammetryWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_210f3520_1ea3_4c86_aa89_4cd9a3bc5a5a

Elucidation: Square wave potential waveform superimposed to a linear potential ramp or a staircase potential ramp.


-

StaircaseCurrentRamp

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_626f81db_ae4e_410a_96b8_0582aa2a9434

Elucidation: Successive current steps that form a signal with a staircase waveform.


-

StaircasePotentialRamp

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d359386f_ae2d_4ad4_9616_464e2111b67d

Elucidation: Successive steps of electric potential that form a staircase waveform.


-

StandardHydrogenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2a40b878_7d09_49db_91b2_d0ee30192284

Elucidation: for solutions in protic solvents, the universal reference electrode for which, under standard conditions, the standard electrode potential (H+ / H2) is zero at all temperatures

Alternative Label(s): SHE

IUPAC Reference: https://goldbook.iupac.org/terms/view/S05917

Wikipedia Reference: https://en.wikipedia.org/wiki/Standard_hydrogen_electrode


-

StepChronopotentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37

Elucidation: chronopotentiometry where the applied current is changed in steps


-

SternModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aa5ed981_c11b_4c4f_b1fd_8c432e009484

Elucidation: describes the double layer as divided into two parts separated by the Stern plane, located about one hydrated ion radius from the electrode surface


-

StoichiometricEquation

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1e72986e_e19f_4c24_8663_cadd4318bd72

Elucidation: the symbolic representation of a chemical reaction in the form of symbols and formulae, wherein the reactant entities are given on the left-hand side and the product entities on the right-hand side

Alternative Label(s): ChemicalEquation, ChemicalReactionEquation

IUPAC Reference: https://doi.org/10.1351/goldbook.C01034

Wikipedia Reference: https://en.wikipedia.org/wiki/Chemical_equation


-

StorageTest

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c91164b8_5e56_4c94_bad1_d7ada576b0e7

Elucidation: test carried out to measure the loss of capacity, open-circuit voltage, short-circuit current or other quantities after storage under specified conditions

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-45


-

StrippingChronopotentiometry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bfbefff0_4df5_47c2_9943_5f42cf268e9e


-

StrippingVoltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3b35e843_3132_41e3_b6df_541cd45ba880

Elucidation: two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the amount of an accumulated species is measured by voltammetry. The measured electric current in step 2 is related to the concentration of analyte in the solution by calibration.

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Electrochemical_stripping_analysis


-

StrontiumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46ac0fd3_2b8e_40aa_bf5d_19cf1dd39052

Elucidation: electrode in which the active material is strontium


-

SulfurElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_88d2d4bc_4244_4419_a260_ad099a62d580

Elucidation: electrode in which the active material is sulfur


-

SulfuricAcidSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_334b3acd_e35d_4d5a_b8b5_6d13cbebbc57

Elucidation: a solution of sulfuric acid (H2SO4) dissolved in water (H2O)


-

Supercapacitor

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dc6abae7_39b0_4d22_b52e_14d088a4bd5f

Elucidation: type of capacitor characterized by high capacitance, high specific and volumetric energy density, and low voltage limits

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-03

Wikipedia Reference: https://en.wikipedia.org/wiki/Supercapacitor


-

SupportingElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1fc5642c_b7b2_43bf_ad20_f96001db8800

Elucidation: electrolyte solution, the ions of which are electroinactive in the range of applied potential being studied, and whose ionic strength (and, therefore, contribution to the overall conductivity) is usually much greater than the concentration of an electroactive substance to be dissolved in it.

Alternative Label(s): BaseElectrolyte, IndifferentElectrolyte, InertElectrolyte

IUPAC Reference: https://goldbook.iupac.org/terms/view/S06149

Wikipedia Reference: https://en.wikipedia.org/wiki/Supporting_electrolyte


-

SwagelokCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cd1b7943_42ce_46bd_8588_1c3161268270

Elucidation: a container for an electrochemical cell manufactured by the company Swagelok


-

Terminal

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc

Elucidation: conductive part of a device, electric circuit or electric network, provided for connecting that device, electric circuit or electric network to one or more external conductors

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-22


-

TerminalProtector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7

Elucidation: cover of insulating material used to avoid electric contact with the cell or battery terminal

Alternative Label(s): TerminalCover

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-23


-

ThermalRunaway

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_04f28ce3_251d_429e_aa85_ab3eb45bbcd2

Elucidation: unstable condition arising during constant voltage charge in which the rate of heat dissipation capability, causing a continuous temperature increase with resulting further charge current increase, which can lead to the destruction of the battery

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-54


-

ThermogalvanicCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_113e0469_8ae0_407f_892d_4b988f8d8a08

Elucidation: electrochemical cell that has two half-cells separated by a wall permeable to ions, both containing the same electrolyte differing only in their temperatures.

Alternative Label(s): Thermocell

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-09

Wikipedia Reference: https://en.wikipedia.org/wiki/Thermogalvanic_cell


-

ThionylChlorideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4977521c_0438_4659_bc81_1c77fae836bb

Elucidation: electrode in which the active material is thionyl chloride


-

ThreeElectrodeCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b9bece97_a511_4cb9_88a2_b5bd5c5e5d74

Elucidation: electrochemical cell with a working electrode, reference electrode, and auxiliary electrode

Alternative Label(s): ThreeElectrodeElectrochemicalCell


-

TimeMeasurement

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e

Elucidation: measurement of time


-

TimeMeasurementResult

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb


-

TimeSeries

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77

Elucidation: a series of data points indexed in time order

Wikipedia Reference: https://en.wikipedia.org/wiki/Time_series


-

TimeVector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a

Elucidation: a vector of discrete times


-

TimeseriesElectricalDataset

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_31e8052d_bede_43c6_8b41_d51bb24c9489

Elucidation: a time series of electrical quantities


-

TinElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a10ede13_c895_4f56_a728_b1aab512b31b


-

TitaniumDioxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76fe8fb2_868e_48eb_95ca_fc6acd6f5fc9

Elucidation: electrode in which the active material is titanium dioxide

Alternative Label(s): TiO2Electrode


-

TitaniumElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d90221a0_0da7_4876_9cac_0e943e445f6f

Elucidation: electrode in which the active material is titanium


-

TrasattiBuzzancaModel

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f57a7dac_2ec2_4d51_b697_01a844c4467f

Elucidation: considers the effects of specific adsorbed ions in the double layer


-

TriangularCurrentWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_09b9a369_2228_44bd_9b63_8abecfec8650

Elucidation: Linear ramp of electric current followed by a reversal to the initial current (typically I=0), both at the same current change rate.


-

TriangularPotentialWaveform

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9af8440_3629_4558_a944_9dfaf3dfd7ec

Elucidation: Linear ramp of electric potential, followed by a reversal to the initial potential. Both forward and reversed signal ramps are applied at the same scan rate.


-

TubularPlate

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e

Elucidation: positive plate (electrode) which is either composed of an assembly of porous tube of perforated metal or tissue either a gauntlet with or without a central current collector spine, the active material being placed within the tubes

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-07


-

TungstenElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c5fd7b61_40f1_4225_a173_5caa3c5f4773

Elucidation: electrode in which the active material is tungsten


-

TungstenOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3fdc81d5_eef3_4408_a6e4_3c51c5b1c8dc

Elucidation: electrode in which the active material is tungsten oxide

Alternative Label(s): WO3Electrode


-

TwoStepCharge

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69

Elucidation: charging method applied to a secondary battery using two levels of charge rate with feedback control to initiate the changeover from a high to a low charge rate

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-48


-

Valve

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a

Elucidation: component of a cell which permits the flow of gas in one direction only

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-12


-

VentCap

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_cc1f854a_ba6c_436e_bd18_c8b9159bbf52

Elucidation: component fitted into the filling hole of a cell with a provision of allowing the venting of electrolysis gas from the cell¨

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-23


-

VentedCell

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ec1dce8b_bb46_41a9_b532_6bed381aa557

Elucidation: secondary cell having a cover provided with an opening through which products of electrolysis and evaporation are allowed to escape freely from the cell to the atmosphere

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-14


-

VoltageControlledProcess

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1

Elucidation: a process in which the voltage is controlled


-

VoltageMeasurement

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_825a749f_dd07_46fb_947c_db286440911e

Elucidation: measurement of the electric potential between the terminals of an electrochemical cell

Alternative Label(s): ElectrochemicalCellVoltageMeasurement


-

VoltageMeasurementResult

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a76072fe_ca6e_48ad_8b4a_ab98a2bc9abb


-

VoltageVector

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4d09ddc4_7e71_4712_afab_b33d8df38983

Elucidation: vector containing at least two values for the quantity voltage


-

Voltammetry

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62

Elucidation: techniques based on the measurement of current as a function of controlled time-dependent applied potential

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-11

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109

Wikipedia Reference: https://en.wikipedia.org/wiki/Voltammetry


-

VoltammetryAtARotatingDiskElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_183a2337_c35f_4b74_8d9a_08c74d89bedc

Elucidation: hydrodynamic voltammetry using a a rotating disc electrode, where the limiting current is described by the Levich equation

IUPAC Reference: https://doi.org/10.1515/pac-2018-0109


-

Voltammogram

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_bbae1ef4_0a95_4e7d_9932_1bf939129eef

Elucidation: current-potential curve in a voltammetry experiment

Wikipedia Reference: https://en.wikipedia.org/wiki/Voltammetry#Voltammograms


-

Voltmeter

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_1355816f_a2b5_4800_8001_fc888f5d6b1b

Elucidation: instrument intended to measure the value of a voltage.

IEC Reference: https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=313-01-03


-

WaveSpring

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6385e07f_f40d_46b2_b998_c439950d75cb

Elucidation: a spring made of pre-hardened flat wire, formed into a wavy washer shape

Wikipedia Reference: https://en.wikipedia.org/wiki/Wave_spring


-

WorkingElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35

Elucidation: electrode at which one or more electroactive substances undergo reaction in the solution being investigated

IUPAC Reference: https://goldbook.iupac.org/terms/view/W06686

Wikipedia Reference: https://en.wikipedia.org/wiki/Working_electrode


-

ZincChlorideSolution

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7393f12f_e3b9_42d6_bffb_e5613f53108f

Elucidation: a solution of zinc chloride (ZnCl) dissolved in water (H2O)

Alternative Label(s): AqueousZincChlorideSolution


-

ZincElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d0a26dc2_fde9_4a11_ac26_7c18499d28a5

Elucidation: metal electrode in which the active material is zinc


-

ZincInsertionElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_245c9442_ca1d_4070_a624_182b92d30b10

Elucidation: an insertion electrode in which the guest molecule is zinc


-

ZincOxideElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82c70935_0aea_454b_92bf_17fb0b488012

Elucidation: electrode in which the active material is zinc oxide

Alternative Label(s): ZnOElectrode


-

hasActiveMaterial

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee


-

hasAnolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0ac306fd_e98b_4af9_8cd6_5ed34f7f7d8a


-

hasCase

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3dcfe33d_6825_43c0_a798_68e871a68d39


-

hasCatholyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b62a6b15_236a_48bf_a323_ccbfc295f934


-

hasElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_578c41e9_ee01_4840_9c8c_04ab6e4e6241


-

hasElectrolyte

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315


-

hasNegativeElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5d299271_3f68_494f_ab96_3db9acdd3138


-

hasPositiveElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8e9cf965_9f92_46e8_b678_b50410ce3616


-

hasReferenceElectrode

https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5eb197ea_0c3e_4ea2_8392_81152ee91515


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This ontology serves as a foundational resource for harmonizing electrochemical knowledge representation, enhancing data interoperability, and accelerating progress in electrochemical research and development."@en ; - dcterms:contributor "Casper Welzel Andersen" , - "Francesca Lonstad Bleken" , - "Jesper Friis" ; - dcterms:creator "Eibar Flores" , - "Simon Clark" ; - dcterms:license "https://creativecommons.org/licenses/by/4.0/legalcode" ; - rdfs:comment """Contacts: -Simon Clark -SINTEF Industry -email: simon.clark@sintef.no - -Jesper Friis -SINTEF Industry -email: jesper.friis@sintef.no"""@en ; - owl:versionInfo "0.7.0-alpha" . - -################################################################# -# Object Properties -################################################################# - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0ac306fd_e98b_4af9_8cd6_5ed34f7f7d8a -:electrochemistry_0ac306fd_e98b_4af9_8cd6_5ed34f7f7d8a rdf:type owl:ObjectProperty ; - rdfs:subPropertyOf :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ; 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M. 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- rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A phenomenon that causes an electrochemical system to deviate from its ideal behaviour."@en ; - skos:prefLabel "ElectrochemicalDegradationPhenomenon"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0a5038d4_24af_4ea8_8d56_a156faeb98e2 -:electrochemistry_0a5038d4_24af_4ea8_8d56_a156faeb98e2 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 2.1 mm"@en ; - skos:altLabel "R63" ; - skos:prefLabel "R521"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df -:electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_494b372c_cfdf_47d3_a4de_5e037c540de8 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_ccdfed06_6d24_47e4_98af_ce3ffe7bd09e - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ; - owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_3dcfe33d_6825_43c0_a798_68e871a68d39 ; - owl:someValuesFrom :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_5d299271_3f68_494f_ab96_3db9acdd3138 ; - owl:someValuesFrom :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_8e9cf965_9f92_46e8_b678_b50410ce3616 ; - owl:someValuesFrom :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a device whose primary function is facilitating the conversion between chemical and electrical energy."@en ; - rdfs:comment "an electrochemical device contains at least one electrochemical cell plus the apparati required to make it work as a practical device (e.g. terminals, container, etc.)"@en ; - skos:prefLabel "ElectrochemicalDevice"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0afe79ed_dc0d_4b3e_88fa_ae0c7b1e88b5 -:electrochemistry_0afe79ed_dc0d_4b3e_88fa_ae0c7b1e88b5 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_88b6445a_0445_483f_88f4_6b910e901c08 - ] ; - rdfs:comment "electrode in which the active material is potassium"@en ; - skos:prefLabel "PotassiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f -:electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ; - owl:someValuesFrom :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve"@en ; - skos:prefLabel "AbrasiveStrippingVoltammetry"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_0b1f77b8_2349_4433_b440_43dc84a2210f ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrochemical method where traces of solid particles are abrasively transferred onto the surface of an electrode, followed by an electrochemical dissolution (anodic or cathodic dissolution) that is recorded as a current–voltage curve"@en ; 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- skos:prefLabel "GasDissolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0cc8f231_0ce5_467e_9c76_29b2c80349ad -:electrochemistry_0cc8f231_0ce5_467e_9c76_29b2c80349ad rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_aac51107_dbe5_4e63_b08a_9d6cf88f4b69 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a two-step charging process in which a constant current is applied until a set upper cutoff voltage is reached and then the cell is potentiostatically held at that voltage until the current falls below some set threshhold value"@en ; - skos:altLabel "CCCV"@en ; - skos:prefLabel "ConstantCurrentConstantVoltageCharge"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_0d3e8340_4229_4fd3_b6dd_763bd566551d -:electrochemistry_0d3e8340_4229_4fd3_b6dd_763bd566551d rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Signal consisting of a constant electric potential."@en ; 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- emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrode"@en ; - rdfs:comment "Alternative definition: Half-cell consisting of at least one electron conductor and at least one ionic conductor (electrolyte). - Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019)"@en , - "Electron conductor in an electrochemical cell connected to the external circuit."@en , - "In some electroanalytical techniques (conductometry and differential potentiometry), two indicator electrodes are used. 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Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook." - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d -:electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q904857" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a double layer of charges exists at the interface between two conducting media: One side carries a positive excess charge, which is balanced by a negative excess of equal magnitude on the other side."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Double_layer_(surface_science)"@en ; - skos:altLabel "DL"@en , - "EDL"@en , - "ElectricalDoubleLayer"@en ; - skos:prefLabel "DoubleLayer"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_2b50cdac_581f_48b9_87ca_bad5138ab58d ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "a double layer of charges exists at the interface between two conducting media: One side carries a positive excess charge, which is balanced by a negative excess of equal magnitude on the other side."@en ; - dcterms:source "A. 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- skos:altLabel "R67" ; - skos:prefLabel "R716"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 -:electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 ; - owl:disjointWith :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q175233" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Cathode"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "by convention, cell electrode at which, a reduction reaction occurs"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Cathode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/C00905"@en ; - rdfs:comment "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction"@en , - "the cathode is the positive electrode during discharge and the negative electrode during charge"@en , - "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ; - skos:prefLabel "Cathode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "by convention, cell electrode at which, a reduction reaction occurs"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is a reduction"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the cathode is the positive electrode during discharge and the negative electrode during charge"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_35c650ab_3b23_4938_b312_1b0dede2e6d5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3663991d_9319_4f7a_922b_f0e428b58801 -:electrochemistry_3663991d_9319_4f7a_922b_f0e428b58801 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_3a6578ac_aee0_43b9_9bc6_1eb208c8c9a9 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix."@en ; - skos:prefLabel "PorousElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_3663991d_9319_4f7a_922b_f0e428b58801 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "porous electrodes consist of porous matrices of a single reactive electronic conductor or a mixture of solids that include essentially non-conducting, reactive materials in addition to electronic conductors. An electrolytic solution fills the void spaces of the porous matrix."@en ; - dcterms:references "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004." - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_36e05f2f_d279_4816_b5ae_6bb4cef02736 -:electrochemistry_36e05f2f_d279_4816_b5ae_6bb4cef02736 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 12.5 mm and a height of 1.6 mm"@en ; - skos:prefLabel "R1216"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_38755e67_9d3b_4a82_bd8d_ef40a70379c1 -:electrochemistry_38755e67_9d3b_4a82_bd8d_ef40a70379c1 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - owl:disjointWith :electrochemistry_9b6853e7_3412_463d_b5a9_82c14acebf7d ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a tank for holding anolyte"@en ; - rdfs:comment "usually used in a flow cell system"@en ; - skos:prefLabel "AnolyteTank"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_387e1e59_e511_4acb_b5ec_fa7360ec7557 -:electrochemistry_387e1e59_e511_4acb_b5ec_fa7360ec7557 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - skos:altLabel "a coin case with a nominal diameter of 9.5 mm and a height of 2.7 mm"@en ; - skos:prefLabel "R927"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_39536efc_22a6_4f39_b0c2_e8b845a36278 -:electrochemistry_39536efc_22a6_4f39_b0c2_e8b845a36278 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "coulometry at a preselected constant potential of the working electrode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Direct coulometry at controlled potential is usually carried out in convective mass trans- fer mode using a large surface working electrode. 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A pulse is applied just before the mechanically enforced end of the drop. The pulse width is usually 10 to 20 % of the drop time. The drop dislodgment is synchro- nized with current sampling, which is carried out just before the end of the pulse, as in NPV."@en , - "Sigmoidal wave-shaped voltammograms are obtained."@en , - "The current is sampled at the end of the pulse and then plotted versus the potential of the pulse."@en , - "The current is sampled just before the end of the pulse, when the charging current is greatly diminished. In this way, the ratio of faradaic current to charging current is enhanced and the negative influence of charging current is partially eliminated. Due to the improved signal (faradaic current) to noise (charging current) ratio, the limit of detec- tion is lowered."@en , - "The sensitivity of NPV is not affected by the reversibility of the electrode reaction of the analyte."@en ; - skos:altLabel "NPV"@en ; - skos:prefLabel "NormalPulseVoltammetry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 -:electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c -:electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae -:electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_e5438930_04e7_4d42_ade5_3700d4a52ab7 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A material relation in electrochemistry."@en ; - skos:prefLabel "ElectrochemicalRelation"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e6a7d5f_3700_46b3_b1b8_f34e37e6f931 -:electrochemistry_3e6a7d5f_3700_46b3_b1b8_f34e37e6f931 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_bbfa82dc_68a0_4d0b_a3f0_735cbbc19cf2 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is iridium"@en ; - skos:prefLabel "IridiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 -:electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_a9873d3d_945b_40ba_b9cd_8dfb64cec88f , - :electrochemistry_f07be701_9d6a_415b_ac6d_63202297a7a1 ; - owl:disjointWith :electrochemistry_83f2b1e9_cb67_4dbf_977f_ba54bbae374f ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-49" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "charge during which the voltage is maintained at a constant value regardless of charge current or temperature"@en ; - skos:altLabel "FloatCharging"@en , - "PotentiostaticCharging"@en ; - skos:prefLabel "ConstantVoltageCharge"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_3e7fe02d_c888_4c49_8e05_ccd9785607a6 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "charge during which the voltage is maintained at a constant value regardless of charge current or temperature"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f67016b_32b9_4419_a3f8_a5ffb5e92538 -:electrochemistry_3f67016b_32b9_4419_a3f8_a5ffb5e92538 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of ammonium chloride (NH4Cl) dissolved in water (H2O)"@en ; - skos:altLabel "AqueousAmmoniumChlorideSolution"@en ; - skos:prefLabel "AmmoniumChlorideSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 -:electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-30" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "gradual and slow spreading of an electrolyte film on the external surface of a cell or battery"@en ; - rdfs:comment "electrolyte creep is sometimes indicated by the presence of a visible solid deposit or wet spots"@en ; - skos:prefLabel "ElectrolyteCreep"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "gradual and slow spreading of an electrolyte film on the external surface of a cell or battery"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_3f6c9e09_5f23_41cc_9f85_7de365cef089 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "electrolyte creep is sometimes indicated by the presence of a visible solid deposit or wet spots"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc -:electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-22" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "conductive part of a device, electric circuit or electric network, provided for connecting that device, electric circuit or electric network to one or more external conductors"@en ; - skos:prefLabel "Terminal"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_3f70e5c5_67f0_483e_998b_b83b7739c4bc ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "conductive part of a device, electric circuit or electric network, provided for connecting that device, electric circuit or electric network to one or more external conductors"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_3f9b2956_1465_4fe0_b0df_5e4784dac3b6 -:electrochemistry_3f9b2956_1465_4fe0_b0df_5e4784dac3b6 rdf:type owl:Class ; 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- rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "techniques based on measurement of current at a constant controlled potential"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Amperometry can be distinguished from voltammetry by the parameter being controlled (electrode potential E) and the parameter being measured (electrode current I which is usually a function of time – see chronoamperometry)."@en , - "In a non-stirred solution, a diffusion-limited current is usually measured, which is propor-tional to the concentration of an electroactive analyte."@en , - "The current is usually faradaic and the applied potential is usually constant."@en , - "The integral of current with time is the electric charge, which may be related to the amount of substance reacted by Faraday’s laws of electrolysis."@en ; - skos:prefLabel "Amperometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_400cb3e0_27b5_4d9a_be80_f86ad2757763 -:electrochemistry_400cb3e0_27b5_4d9a_be80_f86ad2757763 rdf:type owl:Class ; 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- owl:someValuesFrom chemsub:substance_f3e7979a_e3ef_450a_8762_7d8778afe478 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium nickel manganese oxide"@en ; - skos:altLabel "LNMOElectrode"@en ; - skos:prefLabel "LithiumNickelManganeseOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4288b145_ba79_4989_92f8_86086679b0fe -:electrochemistry_4288b145_ba79_4989_92f8_86086679b0fe rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5526337" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "process through which a gas is evolved"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Gas_evolution_reaction"@en ; - skos:altLabel "Gassing"@en ; - skos:prefLabel "GasEvolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603 -:electrochemistry_43cd6e14_dd43_41b5_b5b4_344d53841603 rdf:type owl:Class ; 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- skos:prefLabel "PrismaticCase"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_43ce1a7e_8056_40cb_bdbd_4ce991af1821 -:electrochemistry_43ce1a7e_8056_40cb_bdbd_4ce991af1821 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 , - :electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical measurement principle based on the measurement of the dielectric constant of a sample resulting from the orientation of particles (molecules or ions) that have a dipole moment in an electric field"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Dielectrometric titrations use dielectrometry for the end-point detection."@en , - "The method is used to monitor the purity of dielectrics, for example to detect small amounts of moisture."@en ; - skos:prefLabel "Dielectrometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330 -:electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e3d3d21c_cb9a_498c_bdb0_63c964f0d3c6 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1418367" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-27" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Self-discharge"@en ; - rdfs:seeAlso "ChargeRetention"@en ; - skos:prefLabel "SelfDischarge"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_444992e5_43f8_44a1_9767_b408dbe54330 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "phenomenon by which a cell or battery loses energy in other ways than by discharge into an external circuit"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_457a8f92_0a19_4773_8114_a42edff32248 -:electrochemistry_457a8f92_0a19_4773_8114_a42edff32248 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 - ] ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-04" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "assembly of plates of the same polarity electrically connected together"@en ; - skos:prefLabel "PlateGroup"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_457a8f92_0a19_4773_8114_a42edff32248 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "assembly of plates of the same polarity electrically connected together"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46676855_68b0_4096_ac6c_35400111d46d -:electrochemistry_46676855_68b0_4096_ac6c_35400111d46d rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ddade648_2033_47b6_bc36_b562a9af591e ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plot of the time-dependent amount of electric charge passed through an electrochemical system due to the application of a electric potential"@en ; - skos:altLabel "ChargeTimeCurve"@en , - "ElectricChargeTimeCurve"@en , - "ElectricChargeTimePlot"@en , - "QtCurve"@en ; - skos:prefLabel "ChargeTimePlot"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1 -:electrochemistry_46957d35_0f8b_4d92_acb3_aded6ce774a1 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a process in which the voltage is controlled"@en ; - skos:prefLabel "VoltageControlledProcess"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_46ac0fd3_2b8e_40aa_bf5d_19cf1dd39052 -:electrochemistry_46ac0fd3_2b8e_40aa_bf5d_19cf1dd39052 rdf:type owl:Class ; 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- dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b -:electrochemistry_4aa1b96e_44a0_4b1a_a0ac_723d0223d80b rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e -:electrochemistry_4bc38e99_1978_4143_a766_fbb57f2cf46e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-03" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "situation in which a material in a given environment undergoes negligible electrochemical corrosion."@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "cathodic protection"@en ; - skos:prefLabel "ElectrochemicalImmunity"@en . - -[ rdf:type owl:Axiom ; 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- owl:annotatedTarget "accessible conductive part provided for the connection of an external electric circuit to the positive electrode of the cell"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_52501237_0c13_4bfb_aa3a_441c6a9ae3a6 -:electrochemistry_52501237_0c13_4bfb_aa3a_441c6a9ae3a6 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "titration in which the titrant is generated electrochemically, either by constant current or at constant potential. The titrant reacts stoichiometrically with the analyte, the amount of which is calculated using Faraday’s laws of electrolysis from the electric charge required to reach the end-point"@en ; - rdfs:comment "Coulometric titrations are usually carried out in convective mass transfer mode using a large surface working electrode. The reference and auxiliary electrodes are located in sepa- rate compartments. A basic requirement is a 100 % current efficiency of titrant generation at the working electrode. End-point detection can be accomplished with potentiometry, amperometry, biamperometry, bipotentiometry, photometry, or by using a visual indicator."@en , - "The main advantages are that titration is possible with less stable titrants, the standardi- zation of titrant is not necessary, the volume of the test solution is not changed, and the method is easily automated."@en ; - skos:prefLabel "CoulometricTitration"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 -:electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30 -:electrochemistry_53fe3f58_0802_41cf_af69_4784fc42cc30 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_06d8e1ee_924a_4915_998d_33a69f41dadc , - :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ; - owl:disjointWith :electrochemistry_9865e4f9_756d_4d94_a6fd_4102ab795f9e ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a discharging process in which the current is kept at a constant value"@en ; - skos:altLabel "GalvanostaticDischarging"@en ; - skos:prefLabel "ConstantCurrentDischarging"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec -:electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_4f226cf3_6d02_4d35_8566_a9e641bc6ff3 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a spatial region at the interface between two bulk phases in contact, which is different chemically and physically from both phases in contact"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "SEI, double layer"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/I03085" ; - skos:altLabel "InterfacialLayer"@en ; - skos:prefLabel "Interphase"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_54e0c2bd_1bb2_4f9c_9b55_5b6cc34651ec ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "a spatial region at the interface between two bulk phases in contact, which is different chemically and physically from both phases in contact"@en ; - dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36 -:electrochemistry_5548f188_df00_4c05_ae98_7846e92efe36 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a process in which the electric current is controlled"@en ; - skos:prefLabel "CurrentControlledProcess"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916 -:electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q241065" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-01"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "movement of a fluid through a diaphragm, produced by application of an electric field"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electro-osmosis"@en ; - skos:prefLabel "Electroosmosis"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_5641910f_6e69_4ce4_be84_4b1bf14b8916 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "movement of a fluid through a diaphragm, produced by application of an electric field"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_564d31be_91cb_4a8f_8369_2a55f1180499 -:electrochemistry_564d31be_91cb_4a8f_8369_2a55f1180499 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrolyte solution with an organic solvent"@en ; - skos:prefLabel "OrganicElectrolyte"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a -:electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_85e39686_9658_4c74_bb91_a935704c174a - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Differential Pulse Voltammetry in which small potential pulses are superimposed onto a staircase potential ramp."@en ; - skos:prefLabel "DifferentialStaircasePulseVoltammetry"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_56da3bb3_a0ce_40ed_b152_d3c14329d31a ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "Differential Pulse Voltammetry in which small potential pulses are superimposed onto a staircase potential ramp."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_56f85b19_1384_4e88_b130_cb8e7984db83 -:electrochemistry_56f85b19_1384_4e88_b130_cb8e7984db83 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that is coated on both sides of the current collector"@en ; - skos:prefLabel "DoubleCoatedElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_573be62a_5aae_4984_9a51_7c50845493df -:electrochemistry_573be62a_5aae_4984_9a51_7c50845493df rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_bbb1d95b_72d1_44f6_b07e_a3d7d41ac215 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a gas diffusion electrode in which the active material is carbon dioxide (CO2)"@en ; - skos:prefLabel "CardonDioxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8 -:electrochemistry_5766a819_c319_48ba_ab9a_ce3bd8fedee8 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91 -:electrochemistry_58413d4e_2885_459e_ac06_8d45e661cf91 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_331e6cca_f260_4bf8_af55_35304fe1bbe0 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a separator with a porosity greater than 0"@en ; - skos:prefLabel "PorousSeparator"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58a20764_c339_4856_983a_05092b5282e8 -:electrochemistry_58a20764_c339_4856_983a_05092b5282e8 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Sinusoidal potential waveform superimposed to a linear potential ramp."@en ; - skos:prefLabel "ACVoltammetrySignal"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a -:electrochemistry_58ad1d22_3803_4c95_a137_207cfebe242a rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_06658d8d_dcde_4fc9_aae1_17f71c0bcdec , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom emmo:EMMO_d4f7d378_5e3b_468a_baa1_a7e98358cda7 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a vector of discrete times"@en ; - skos:prefLabel "TimeVector"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_598ae3d0_76e9_429c_a0e1_8694525cb574 -:electrochemistry_598ae3d0_76e9_429c_a0e1_8694525cb574 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f19ff3b4_6bfe_4c41_a2b2_9affd39c140b ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3258329" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "For any electrolyte A_xB_y, the limiting molar conductivity is expressed as x times the limiting molar conductivity of A^{y+} and y times the limiting molar conductivity of B^{x-}."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Molar_conductivity#Kohlrausch's_law_of_independent_migration_of_ions"@en ; - rdfs:comment "proposed by Friedrich Kohlrausch between 1875-1879"@en , - "valid for dilute solutions"@en ; - skos:prefLabel "KohlrauschsLaw"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_59c041fc_eaa1_40fc_9b3e_1a6aca6119fd -:electrochemistry_59c041fc_eaa1_40fc_9b3e_1a6aca6119fd rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_194e367c_9783_4bf5_96d0_9ad597d48d9a ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a measurement of one or more quantities, usually at a given time"@en ; - skos:prefLabel "Record"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5a0f3b6a_10b4_43a7_b0b6_4eb5c077980e -:electrochemistry_5a0f3b6a_10b4_43a7_b0b6_4eb5c077980e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ; - owl:someValuesFrom :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "linear scan voltammetry with slow scan rate in which a dropping mercury electrode is used as the working electrode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "If the whole scan is performed on a single growing drop, the technique should be called single drop scan voltammetry. The term polarography in this context is discouraged."@en , - "This is the oldest variant of polarographic techniques, introduced by Jaroslav Heyrovský (1890 – 1967)."@en , - "Usually the drop time is between 1 and 5 s and the pseudo-steady-state wave-shaped dependence on potential is called a polarogram. 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- emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode in which the actve electrochemical material is a metal"@en ; - rdfs:comment "the term metal is meant to loosely cover alkali metals, alkaline earth metals, transition metals, post-transition metals, and metalloids"@en ; - skos:prefLabel "MetalElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5c0fdc09_166e_40a6_ad74_be66f0db51bc -:electrochemistry_5c0fdc09_166e_40a6_ad74_be66f0db51bc rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_9da78aea_d436_40e2_a68f_c3dee32b825e - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is carbon monofluoride"@en ; - skos:prefLabel "CarbonMonofluorideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1 -:electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q9252431"@en ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-02"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrocapillarity"@en ; - skos:prefLabel "Electrocapillarity"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_5cb5548f_f774_4668_ad02_f0742581f2f1 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "change of the mechanical stress at the surface separating two bodies due to the presence of electric charges at the interface"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5ce6a328_713c_4383_ad63_26c902c30e34 -:electrochemistry_5ce6a328_713c_4383_ad63_26c902c30e34 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98 -:electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - owl:disjointWith :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an ion-transport medium that does not contain water."@en ; - skos:altLabel "NonAqueousElectrolyticSolution"@en , - "NonAqueousSolution"@en ; - skos:prefLabel "NonAqueousElectrolyte"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_5f9a9411_05f9_4576_acd3_81d7d41cfe98 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "an ion-transport medium that does not contain water."@en ; - dcterms:source "IEEE Standard Glossary of Stationary Battery Terminology (2016), https://doi.org/10.1109/IEEESTD.2016.7552407" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 -:electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrolyte in the liquid phase."@en ; - skos:prefLabel "LiquidElectrolyte"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7 -:electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-23" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cover of insulating material used to avoid electric contact with the cell or battery terminal"@en ; - skos:altLabel "TerminalCover"@en ; - skos:prefLabel "TerminalProtector"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_60bc27f0_8290_4113_8c3b_011433a733c7 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "cover of insulating material used to avoid electric contact with the cell or battery terminal"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03 -:electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_9c32fd69_f480_4130_83b3_fb25d9face14 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "when the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Faraday%27s_laws_of_electrolysis#Second_law"@en ; - rdfs:comment "m_1/m_2 = (M_1/z_1) / (M_2/z_2)" ; - skos:prefLabel "FaradaysSecondLawOfElectrolysis"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_60c5b2e5_164a_4ce6_8409_f386f5e50c03 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "when the same electric charge (quantity of electricity) Q is passed through several electrolytes, the mass, m_i, of the substances deposited are proportional to their respective chemical equivalent molar mass, M_i/z_i."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_610f0bc8_557d_455b_a8ed_272d5d1813c9 -:electrochemistry_610f0bc8_557d_455b_a8ed_272d5d1813c9 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_ff5b9c8c_3fb0_4575_9ab8_23ebd9116294 - ] ; - rdfs:comment "metal electrode in which the active material is lead"@en ; - skos:prefLabel "LeadElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 -:electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ; - owl:disjointWith :electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH greater than 7"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "KOH-H2O"@en ; - rdfs:comment "typical alkaline electrolytes have a pH in the range 13 < x < 15"@en ; - skos:altLabel "AlkalineAqueousElectrolyte"@en , - "AlkalineSolution"@en ; - skos:prefLabel "AlkalineElectrolyte"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_61740c42_d332_492c_8b37_90a187c7f6d9 -:electrochemistry_61740c42_d332_492c_8b37_90a187c7f6d9 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3b35e843_3132_41e3_b6df_541cd45ba880 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q4016325" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "stripping voltammetry in which material accumulated at the working electrode is electrochemically reduced in the stripping step"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "A peak-shaped cathodic stripping voltammogram is obtained. Peak current depends on time of accumulation, mass transport of analyte (stirring), scan rate and mode (linear or pulse), and analyte concentration in solution."@en ; - skos:altLabel "CSV"@en ; - skos:prefLabel "CathodicStrippingVoltammetry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_618538fa_6607_45a3_ad06_6a5f98febcbd -:electrochemistry_618538fa_6607_45a3_ad06_6a5f98febcbd rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_f046d602_22ea_4f9b_9101_319f510d39f0 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "chronopotentiometry where the applied current is changed linearly"@en ; - skos:prefLabel "LinearChronopotentiometry"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_618538fa_6607_45a3_ad06_6a5f98febcbd ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "chronopotentiometry where the applied current is changed linearly"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109." - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6235cc7c_2eee_432a_93af_47d7e05db007 -:electrochemistry_6235cc7c_2eee_432a_93af_47d7e05db007 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_5cee19d2_f916_4264_a8ed_efed13a808d2 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is hard carbon"@en ; - skos:prefLabel "HardCarbonElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_626f81db_ae4e_410a_96b8_0582aa2a9434 -:electrochemistry_626f81db_ae4e_410a_96b8_0582aa2a9434 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_904b12e0_4a10_47b0_b7db_592aba215cb6 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Successive current steps that form a signal with a staircase waveform."@en ; - skos:prefLabel "StaircaseCurrentRamp"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_634467ad_feed_4979_adb2_877d98fe1768 -:electrochemistry_634467ad_feed_4979_adb2_877d98fe1768 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_50044b99_b858_433b_a32d_23d1e1cf88b2 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "any junction between two electrolyte solutions of different composition."@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/L03584"@en ; - rdfs:comment "Across such a junction there arises a potential difference, called the liquid junction potential."@en , - "In the operational pH cell the junction is between the test, or pH standard, solution and the filling solution or the bridge solution of the reference electrode."@en ; - skos:prefLabel "LiquidJunction"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f -:electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q899119" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Salt_bridge"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Salt_bridge"@en ; - rdfs:comment "A typical construction is a tube of an inert material (e.g. agar agar) filled with a solution containing an electrolyte with approximately equal ion mobilities of the cation and the anion (e.g., KNO3, KCl), with the ends of the tube immersed in the electrolyte solution of the half cells."@en ; - skos:prefLabel "SaltBridge"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_637c576e_a50e_47ae_8c74_2024ce4c6d0f ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "means of making electrolytic connection between two half cells without introducing a significant liquid junction potential."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6385e07f_f40d_46b2_b998_c439950d75cb -:electrochemistry_6385e07f_f40d_46b2_b998_c439950d75cb rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_872b11e1_8bb3_4a2a_af90_bbaa0055d01e ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q11288626" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a spring made of pre-hardened flat wire, formed into a wavy washer shape"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Wave_spring"@en ; - skos:prefLabel "WaveSpring"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b -:electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e8cedede_5685_4625_9abe_64f62b5ddcb6 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "potentiometry in which the potential is measured with time following a change in applied current"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "The change in applied current is usually a step, but cyclic current reversals or linearly increasing currents are also used."@en ; - skos:prefLabel "Chronopotentiometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685 -:electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q30587730"@en ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-06"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "transport of ions in an electrolyte due to an electric field"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_migration"@en ; - skos:prefLabel "ElectrochemicalMigration"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_63ea1c9b_0bda_4a69_9745_efb08e6be685 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "transport of ions in an electrolyte due to an electric field"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 -:electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_314d0bd5_67ed_437e_a609_36d46147cea7 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1530469" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=112-04-03"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "phenomenon serving as the basis of a measurement"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Energy absorption applied to the measurement of amount-of-substance concentration."@en , - "Hall effect applied to the measurement of magnetic flux density."@en , - "Thermoelectric effect applied to the measurement of temperature."@en ; - rdfs:comment "The phenomenon can be of a physical, chemical, or biological nature."@en ; - skos:altLabel "PrincipleOfMeasurement"@en ; - skos:prefLabel "MeasurementPrinciple"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0 -:electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0 rdf:type owl:Class ; - rdfs:subClassOf ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-16" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material used to seal the cell lid to the case or to the terminals of a cell"@en ; - skos:prefLabel "LidSealingCompound"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6559c04d_75bc_41ea_8ed8_8d3c09dae6b0 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "material used to seal the cell lid to the case or to the terminals of a cell"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 -:electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH values less than 7"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "HCl-H2O"@en ; - rdfs:comment "typical alkaline electrolytes have a pH in the range 0 < x < 4"@en ; - skos:altLabel "AcidicAqueousElectrolyte"@en , - "AcidicSolution"@en ; - skos:prefLabel "AcidicElectrolyte"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc -:electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_dc5fb846_1824_40f8_9834_81f118aa1c2d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode made of a solid amalgam of an appropriate metal"@en ; - rdfs:comment "Liquid and paste amalgams can also be used."@en , - "Solid amalgam electrodes are electrochemically similar to the hanging mercury drop electrode. Their main advantages are high hydrogen overpotential (similar to liquid mercury); a wide working potential range; the simple mechanical, chemical, and electrochemical regeneration of the surface; a long lifetime; low toxicity of material (comparable with that of dental amalgams); applicability for field measurements; compatibility with flow-through systems; simple construction, without mobile parts; and easy miniaturization."@en ; - skos:altLabel "SAE"@en ; - skos:prefLabel "SolidAmalgamElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_65c90d8d_9712_4f3f_b830_d8163ec4cfcc ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode made of a solid amalgam of an appropriate metal"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8 -:electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_68c1c36e_1548_4247_bae2_fe7102a2c4ff -:electrochemistry_68c1c36e_1548_4247_bae2_fe7102a2c4ff rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm"@en ; - skos:altLabel "R66"@en ; - skos:prefLabel "R626"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_68eb5e35_5bd8_47b1_9b7f_f67224fa291e -:electrochemistry_68eb5e35_5bd8_47b1_9b7f_f67224fa291e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_06448f64_8db6_4304_8b2c_e785dba82044 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q863583" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material or substance that holds or draws other materials together to form a cohesive whole"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "CMC, PVDF"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Binder_(material)"@en ; - skos:altLabel "ElectrodeBinder"@en ; - skos:prefLabel "Binder"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e -:electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_aff732a9_238a_4734_977c_b2ba202af126 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-07" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "positive plate (electrode) which is either composed of an assembly of porous tube of perforated metal or tissue either a gauntlet with or without a central current collector spine, the active material being placed within the tubes"@en ; - skos:prefLabel "TubularPlate"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6b1f594f_2c0a_46a0_8805_d6ab08baa75e ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "positive plate (electrode) which is either composed of an assembly of porous tube of perforated metal or tissue either a gauntlet with or without a central current collector spine, the active material being placed within the tubes"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6b275583_433f_46f7_aafd_ebc9409257cc -:electrochemistry_6b275583_433f_46f7_aafd_ebc9409257cc rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 2.6 mm"@en ; - rdfs:comment "often used in wrist watches"@en ; - skos:altLabel "R66" ; - skos:prefLabel "R626"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 -:electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_a8bfac4f_3f30_4e6d_8d8e_34b1eeecb614 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q3587619" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A disc electrode that is embedded in the centre of a cylinder which rotates in solution around the longitudinal cylinder axis."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Rotating_disk_electrode"@en ; - rdfs:comment "The current is directly proportional to the electrode area and the electrode is uniformly accessible."@en , - "The limiting current is given by the Levich equation."@en ; - skos:altLabel "RDE"@en ; - skos:prefLabel "RotatingDiskElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "A disc electrode that is embedded in the centre of a cylinder which rotates in solution around the longitudinal cylinder axis."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6d0fe07e_a629_479c_ab24_2846f209bb0b -:electrochemistry_6d0fe07e_a629_479c_ab24_2846f209bb0b rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_acdb232f_8041_4e11_8a11_5db2d2baae4d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium titanate"@en ; - skos:altLabel "LTOElectrode"@en ; - skos:prefLabel "LithiumTitanateElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 -:electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 -:electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 , - :electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q1136979" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-13" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical measurement principle in which the electric charge required to carry out a known electrochemical reaction is measured. By Faraday’s laws of electrolysis, the amount of substance is proportional to the charge"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Coulometry"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Coulometry used to measure the amount of substance is a primary reference measurement procedure [VIM 2.8] not requiring calibration with a standard for a quantity of the same kind (i.e. amount of substance)."@en , - "The coulometric experiment can be carried out at controlled (constant) potential (see direct coulometry at controlled potential) or controlled (constant) current (see direct coulometry at controlled current)."@en ; - skos:prefLabel "Coulometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6ec59f99_5f26_4a7d_9b90_b52e0f8ad190 -:electrochemistry_6ec59f99_5f26_4a7d_9b90_b52e0f8ad190 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q900939" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A type of reference electrode based on the reaction between sliver and silver chloride."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Silver_chloride_electrode"@en ; - skos:prefLabel "SilverChlorideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6f0dc7c0_ba12_4390_9564_f10f85a1779a -:electrochemistry_6f0dc7c0_ba12_4390_9564_f10f85a1779a rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5a0f3b6a_10b4_43a7_b0b6_4eb5c077980e ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "DC polarography with current sampling at the end of each drop life mechanically enforced by a knocker at a preset drop time value. The current sampling and mechanical drop dislodge are synchronized."@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "In this way, the ratio of faradaic current to double layer charging current is enhanced and the negative influence of charging current is partially eliminated. Due to the improved signal (faradaic current) to noise (charging current) ratio, the limit of detection is lowered."@en ; - skos:altLabel "TASTPolarography"@en ; - skos:prefLabel "SampledDCPolarography"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 -:electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_b9522e56_1fac_4766_97e6_428605fabd3e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_3bd08946_4e81_455d_9fca_dc7a5ead9315 ; - owl:someValuesFrom :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_5d299271_3f68_494f_ab96_3db9acdd3138 ; - owl:someValuesFrom :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_8e9cf965_9f92_46e8_b678_b50410ce3616 ; - owl:someValuesFrom :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q80097" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-01"@en ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "http://dbpedia.org:8891/page/Electrochemical_cell" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrochemical_cell"@en ; - rdfs:comment "If processes of interest occur at both the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or two working electrodes."@en , - "In electrochemistry the term “cell” is commonly qualified to describe the particular device on which electrochemical reactions take place. It is important to distinguish between the concept of an electrochemical cell (two electrodes separated by electrolyte) and an electrochemical device (a manufactured object for making practical use of an electrochemical cell, e.g. for measurement or energy storage purposes)."@en , - "composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy"@en , - "system that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)"@en ; - skos:prefLabel "ElectrochemicalCell"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "a system containing two electrodes that allow transport of electrons, separated by an electrolyte that allows movement of ions but blocks movement of electrons."@en ; - dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004." - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "composite system in which the supplied electric energy mainly produces chemical reactions or, conversely, in which the energy released by chemical reactions is mainly delivered by the system as electric energy"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "system that consists of at least two electron conductors (electrodes) in contact with ionic conductors (electrolytes)"@en ; - rdfs:comment "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185 -:electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_b3815a7f_f64a_48f6_b0ce_d0032578c699 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries"@en ; - rdfs:comment "At positive potentials, Au forms an oxide and/or chemisorbed oxygen layer, while in the presence of complexing anions, such as chloride or cyanide, it readily undergoes oxidation and dissolution, limiting its working potential range and its applications."@en ; - skos:altLabel "AuElectrode"@en ; - skos:prefLabel "GoldElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_6fec8cc1_4e6c_428e_8343_6cf3c286a185 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "foil, wire or disc electrode made of gold which is easily fabricated into a variety of electrode geometries"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_712c791a_d593_4732_af73_493f7bc50999 -:electrochemistry_712c791a_d593_4732_af73_493f7bc50999 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_904b12e0_4a10_47b0_b7db_592aba215cb6 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q114979515" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "rapid, transient change in the amplitude of an electric current, from a baseline value to a higer or lower value, followed by a rapid return to the baseline value."@en ; - skos:prefLabel "CurrentPulse"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_713200a1_952b_49e2_90b7_deba229f6bbe -:electrochemistry_713200a1_952b_49e2_90b7_deba229f6bbe rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium manganese phosphate"@en ; - skos:altLabel "LMPElectrode"@en ; - skos:prefLabel "LithiumManganesePhosphateElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_729a1064_d039_4b74_9d1d_759b18a3971c -:electrochemistry_729a1064_d039_4b74_9d1d_759b18a3971c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3fe63496_6d87_427a_b2aa_4555bc31ee1a , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom emmo:EMMO_90e59882_4592_4036_a75d_5fbefb22dc80 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "amperometry in which the current is measured as a function of time after a change in the applied potential"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "If the potential step is from a potential at which no current flows (i.e., at which the oxidation or reduction of the electrochemically active species does not take place) to one at which the current is limited by diffusion (see diffusion-limited current), the current obeys the Cottrell equation."@en ; - skos:altLabel "AmperiometricDetection"@en , - "AmperometricCurrentTimeCurve"@en ; - skos:prefLabel "Chronoamperometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7393f12f_e3b9_42d6_bffb_e5613f53108f -:electrochemistry_7393f12f_e3b9_42d6_bffb_e5613f53108f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of zinc chloride (ZnCl) dissolved in water (H2O)"@en ; - skos:altLabel "AqueousZincChlorideSolution"@en ; - skos:prefLabel "ZincChlorideSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37 -:electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_63dec5af_f3e9_46c9_8b0c_82516231d96b , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_85e39686_9658_4c74_bb91_a935704c174a - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "chronopotentiometry where the applied current is changed in steps"@en ; - skos:prefLabel "StepChronopotentiometry"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_7416a831_ba72_447c_bf83_3989ba2dfe37 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "chronopotentiometry where the applied current is changed in steps"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109." - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_74459386_875c_4303_b774_60125b599d06 -:electrochemistry_74459386_875c_4303_b774_60125b599d06 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_1aec4cc0_82d5_4042_a657_ed7fe291c3d8 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_43003c86_9d15_433b_9789_ee2940920656 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_cd2cd0de_e0cc_4ef1_b27e_2e88db027bac - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_e4de48b1_dabb_4490_ac2b_040f926c64f0 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a soft pouch case that is described by its length, width, and height"@en ; - skos:prefLabel "PouchCase"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c -:electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_9a823d64_9d10_4a29_9cbd_9bbdad7985bc ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode at which the predominant electrochemical reaction is an intercalation"@en ; - skos:altLabel "IntercalationElectrode"@en ; - skos:prefLabel "InsertionElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76318e8e_c1ba_49ac_8029_a951bd9dc955 -:electrochemistry_76318e8e_c1ba_49ac_8029_a951bd9dc955 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 1.6 mm"@en ; - skos:altLabel "R62" ; - skos:prefLabel "R516"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c -:electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-36"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cable used for the electrical connection of the battery terminals and the load and/or the charger"@en ; - skos:prefLabel "OutputCable"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_76df6e7b_fc3b_4a1f_98b1_0ca9c0539e4c ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "cable used for the electrical connection of the battery terminals and the load and/or the charger"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_76e461aa_5948_4a68_8337_284d11e0fd7d -:electrochemistry_76e461aa_5948_4a68_8337_284d11e0fd7d rdf:type owl:Class ; 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- skos:altLabel "TiO2Electrode"@en ; - skos:prefLabel "TitaniumDioxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 -:electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q653954" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-15"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a """The standard hydrogen electrode represents the primary standard in electrochemistry. Elec- trodes of the 2nd kind, such as Ag | AgCl, Hg | Hg2 -Cl2, Hg | Hg2SO4, and Hg | HgO, can be used as reference electrodes in aqueous solutions containing ions Cl^{−}, SO_4^{2−}, and OH^{−}, respectively."""@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Reference_electrode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/R05229"@en ; - rdfs:comment "Electrode that maintains an essentially constant potential under the conditions prevailing in an electrochemical measurement, and that serves for observation, measurement, or control of the potential of the indicator or working electrode."@en , - "Electrode with a well-defined and constant equilibrium potential with respect to which it is possible to measure or calculate electrode potentials of other electrodes by including them in an appropriate electrochemical cell."@en , - "In potentiometry, under zero current condition, the essentially constant potential is achieved by ensuring a constant composition of solution in contact with the electrode forming a half-cell. Practical reference half-cells are generally non-polarizable electrodes of the 2nd kind (metal | insoluble salt | ion), constructed so that their electrolyte solutions serve as salt bridges to the solutions under investigation."@en , - "“Double” junction reference electrodes are recommended when the reference electrolyte contains interfering components."@en ; - skos:prefLabel "ReferenceElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "Electrode that maintains an essentially constant potential under the conditions prevailing in an electrochemical measurement, and that serves for observation, measurement, or control of the potential of the indicator or working electrode."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "Electrode with a well-defined and constant equilibrium potential with respect to which it is possible to measure or calculate electrode potentials of other electrodes by including them in an appropriate electrochemical cell."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2 -:electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e931087f_7681_4096_b200_5223bcc47eb4 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-19"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ; - skos:prefLabel "PhotoelectrolyticCell"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_7760b241_775f_4be1_b827_59f9bde9e5b2 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrolytic cell in which a chemical reaction is influenced by the absorption of light."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_77be01ef_49bd_4f2e_bec8_eec0894b8562 -:electrochemistry_77be01ef_49bd_4f2e_bec8_eec0894b8562 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 ; 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- rdfs:subClassOf :electrochemistry_6592d8cc_4ce4_42ca_b010_6bfc4a8444d2 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of phosphoric acid (H3PO4) dissolved in water (H2O)"@en ; - skos:prefLabel "PhosphoricAcidSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 -:electrochemistry_791c1915_a791_4450_acd8_7f94764743b5 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600 -:electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79a8802e_8296_459a_b65d_6e5c79e1bf37 -:electrochemistry_79a8802e_8296_459a_b65d_6e5c79e1bf37 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a cycling protocol in which an electrochemical cell is subject to alternating galvanostatic charging and discharging processes"@en ; - skos:prefLabel "GalvanostaticCycling"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 -:electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 , - :electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom emmo:EMMO_06448f64_8db6_4304_8b2c_e785dba82044 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_3cfdfc10_a5cb_4e3e_b1a1_281010d1465c - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_5ce6a328_713c_4383_ad63_26c902c30e34 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907375" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-14"@en , - "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-33" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material that is oxidized or reduced at an electrode in an electrochemical cell"@en ; - rdfs:comment "in secondary cells, the active material is restored to its original state during charge"@en , - "material which reacts chemically to produce electric energy when the cell discharges" ; - skos:altLabel "ActiveElectrochemicalMaterial"@en , - "ElectrochemicallyActiveMaterial"@en ; - skos:prefLabel "ActiveMaterial"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "material that is oxidized or reduced at an electrode in an electrochemical cell"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "in secondary cells, the active material is restored to its original state during charge"@en ; - rdfs:comment "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "material which reacts chemically to produce electric energy when the cell discharges" ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_79e12290_d1e5_4c41_916c_18f1e4d7fb51 -:electrochemistry_79e12290_d1e5_4c41_916c_18f1e4d7fb51 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_68c0876b_cb62_41cd_846d_95cc9d9a8733 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is silicon"@en ; - skos:prefLabel "SiliconElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7b811780_7251_481b_a4d3_97d437955099 -:electrochemistry_7b811780_7251_481b_a4d3_97d437955099 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_8f857eb2_7cc8_4294_954d_e69f2842c084 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is cobalt"@en ; - skos:prefLabel "CobaltElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7b9db6b3_36f0_4b5d_acbb_9284a9054a09 -:electrochemistry_7b9db6b3_36f0_4b5d_acbb_9284a9054a09 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_9b92f5b9_a477_4267_bf68_769c995e6e83 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is indium"@en ; - skos:prefLabel "IndiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7beef5fb_a406_4284_b85a_87d55cf46a0e -:electrochemistry_7beef5fb_a406_4284_b85a_87d55cf46a0e rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ; - skos:prefLabel "ElectricCurrentMeasurementResult"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7cc8b738_3462_4592_ba83_951a8d50fef7 -:electrochemistry_7cc8b738_3462_4592_ba83_951a8d50fef7 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_8522bd08_3855_4e4b_bca0_30923a40de88 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is caesium"@en ; - skos:prefLabel "CaesiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f168ebc_4c78_459c_9a39_bddaa57e214c -:electrochemistry_7f168ebc_4c78_459c_9a39_bddaa57e214c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a modification of the Stern model that considers the double layer as three regions separated by the inner Helmholtz plane and the outer Helmholtz plane"@en ; - rdfs:comment "proposed by D. C. Grahame in 1947"@en ; - skos:prefLabel "GrahameModel"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917 -:electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_6c421175_477f_45e0_8b6c_c3464f5351c5 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_3a77b5e7_9646_4154_bf8f_5f798989e5f3 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5829908"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Rotating_ring-disk_electrode"@en ; - rdfs:comment "This arrangement is largely used in mechanistic studies."@en ; - skos:altLabel "RRDE"@en ; - skos:prefLabel "RotatingRingDiskElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_7f4d74cd_d0a5_4908_9da9_7629fe419917 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "a second annular working electrode positioned concentric with a rotating disc electrode to make a rotating ring-disc electrode (RRDE)"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77 -:electrochemistry_7fa74f69_047f_4c86_a02c_e7805d6f5b77 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_194e367c_9783_4bf5_96d0_9ad597d48d9a , - emmo:EMMO_1cba0b27_15d0_4326_933f_379d0b3565b6 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_496c8f31_9732_42c1_8eae_dd73979c06eb - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q186588" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a series of data points indexed in time order"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Time_series"@en ; - skos:prefLabel "TimeSeries"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e -:electrochemistry_7fdf65c1_b86a_4cbe_8c06_56321b425d4e rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of time"@en ; - skos:prefLabel "TimeMeasurement"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_7ffe1cb6_f87e_4b4a_8ce7_c98e2a584cb1 -:electrochemistry_7ffe1cb6_f87e_4b4a_8ce7_c98e2a584cb1 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_99e61c41_9038_418a_b98c_ab225bd6bec1 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is ruthenium"@en ; - skos:prefLabel "RutheniumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_80fdbd63_9b7a_462b_a8cb_b50f5f6ab182 -:electrochemistry_80fdbd63_9b7a_462b_a8cb_b50f5f6ab182 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_73d4606c_7460_4a5c_9413_793bdf35753e - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a liquid electrode with an active material of gallium"@en ; - skos:prefLabel "LiquidGalliumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_81833d8a_b03d_4250_be84_6385415beb01 -:electrochemistry_81833d8a_b03d_4250_be84_6385415beb01 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 - ] ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-34" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "blend containing a material which reacts chemically to produce electrical energy with other constituents and additives"@en ; - skos:prefLabel "ActiveMaterialMix"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_81833d8a_b03d_4250_be84_6385415beb01 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "blend containing a material which reacts chemically to produce electrical energy with other constituents and additives"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb -:electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom emmo:EMMO_90e59882_4592_4036_a75d_5fbefb22dc80 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Differential Pulse Voltammetry in which small potential pulses are superimposed onto a linearly varying potential."@en ; - skos:prefLabel "DifferentialLinearPulseVoltammetry"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_81b7c95b_8671_4ba7_b4f8_ec19a25096eb ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "Differential Pulse Voltammetry in which small potential pulses are superimposed onto a linearly varying potential."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_825a749f_dd07_46fb_947c_db286440911e -:electrochemistry_825a749f_dd07_46fb_947c_db286440911e rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_463bcfda_867b_41d9_a967_211d4d437cfb , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ; - owl:someValuesFrom :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement of the electric potential between the terminals of an electrochemical cell"@en ; - skos:altLabel "ElectrochemicalCellVoltageMeasurement"@en ; - skos:prefLabel "VoltageMeasurement"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82b66bfe_ec25_417b_ba65_b631ddaaca0e -:electrochemistry_82b66bfe_ec25_417b_ba65_b631ddaaca0e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q898591" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A reference electrode based on the reaction between elemental mercury and mercury(I) chloride."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Saturated_calomel_electrode"@en ; - skos:prefLabel "SaturatedCalomelElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82c70935_0aea_454b_92bf_17fb0b488012 -:electrochemistry_82c70935_0aea_454b_92bf_17fb0b488012 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_848003a2_71ee_4967_8039_354c907ec7f4 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is zinc oxide"@en ; - skos:altLabel "ZnOElectrode"@en ; - skos:prefLabel "ZincOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_82fef384_8eec_4765_b707_5397054df594 -:electrochemistry_82fef384_8eec_4765_b707_5397054df594 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a material added to an electrode for the purpose of increasing its electronic conductivity."@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "carbon black"@en ; - skos:altLabel "ElectronicallyConductiveElectrodeAdditive"@en ; - skos:prefLabel "ConductiveAdditive"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83d2c2d4_ffa9_42f4_9264_a0c59c657607 -:electrochemistry_83d2c2d4_ffa9_42f4_9264_a0c59c657607 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_f49b84d4_e1f9_424c_bb22_8cea23c0a7d4 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-03"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "reversing of the polarities of the electrodes of a cell, generally due to over-discharge of a low-capacity cell in a series arrangement"@en ; - skos:altLabel "CellReversal"@en ; - skos:prefLabel "PolarityReversal"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_83d2c2d4_ffa9_42f4_9264_a0c59c657607 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "reversing of the polarities of the electrodes of a cell, generally due to over-discharge of a low-capacity cell in a series arrangement"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_83ee23b3_2f5c_4afa_b972_ac85e91d7306 -:electrochemistry_83ee23b3_2f5c_4afa_b972_ac85e91d7306 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_7729c34e_1ae9_403d_b933_1765885e7f29 ; 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- owl:annotatedSource :electrochemistry_865a40fc_2187_4549_a7e1_37aa2458448f ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "Electrolyte solution in the anodic compartment of an electrolysis cell or galvanic cell, i.e., in that part of the cell where the anode is placed."@en ; - dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. 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Peak current depends on time of accumulation, mass transport of analyte (stirring), scan rate and mode (linear or pulse), and analyte concentration in solution."@en , - "A solid electrode, carbon paste or composite electrode, bismuth film electrode, mercury film electrode, or static mercury drop electrode may be used."@en ; - skos:prefLabel "AnodicStrippingVoltammetry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8c71739c_27c1_4d19_a0ff_02545296af43 -:electrochemistry_8c71739c_27c1_4d19_a0ff_02545296af43 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-41" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "arrangement of cells or batteries wherein the positive terminal of each cell or battery is connected to the negative terminal of the next cell or battery in sequence."@en ; - skos:prefLabel "SeriesConnection"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_8c71739c_27c1_4d19_a0ff_02545296af43 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "arrangement of cells or batteries wherein the positive terminal of each cell or battery is connected to the negative terminal of the next cell or battery in sequence."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_8ca00b45_5ba6_48a0_aaf6_abd959a7238b -:electrochemistry_8ca00b45_5ba6_48a0_aaf6_abd959a7238b rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom emmo:EMMO_852b4ab8_fc29_4749_a8c7_b92d4fca7d5a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_f591a444_89d6_4093_836d_7d53895edce4 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120895154" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which a sinusoidal alternating potential of small amplitude (10 to 50 mV) of constant frequency (10 Hz to 100 kHz) is superimposed on a slowly and linearly varying potential ramp"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "The resulting alternating current is plotted versus imposed DC potential. 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- rdfs:comment "historically for the analysis of metal ions, mercury ions were added to the test solution to form a mercury amalgam when reduced. Alternatively, an HMDE or MFE was used and the oxidizing agent added after amalgam formation. However, the toxicity of mercury and its compounds have all but precluded the present-day use of mercury"@en , - "the accumulation is similar to that used in stripping voltammetry"@en , - "the stripping potentiogram shows staircase curves of potential as a function of time. Frequently, the first derivative is displayed (dE/dt=f(t)), as this produces peak-shaped signals. The time between transitions (peaks) is proportional to the concentration of analyte in the test solution"@en , - "the time between changes in potential in step 2 is related to the concentration of analyte in the solution"@en ; - skos:altLabel "PSA"@en ; - skos:prefLabel "PotentiometricStrippingAnalysis"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "historically for the analysis of metal ions, mercury ions were added to the test solution to form a mercury amalgam when reduced. Alternatively, an HMDE or MFE was used and the oxidizing agent added after amalgam formation. However, the toxicity of mercury and its compounds have all but precluded the present-day use of mercury"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the accumulation is similar to that used in stripping voltammetry"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the stripping potentiogram shows staircase curves of potential as a function of time. Frequently, the first derivative is displayed (dE/dt=f(t)), as this produces peak-shaped signals. The time between transitions (peaks) is proportional to the concentration of analyte in the test solution"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_916b1863_f417_4b94_9407_9d749ada9ed5 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the time between changes in potential in step 2 is related to the concentration of analyte in the solution"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_92147e31_d015_4889_a092_04fbab033f15 -:electrochemistry_92147e31_d015_4889_a092_04fbab033f15 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_212af058_3bbb_419f_a9c6_90ba9ebb3706 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_403c300e_09b9_400b_943b_04e82a3cfb56 - ] ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-02"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "cell electrode consisting of a current collector and active material"@en ; - skos:altLabel "Plate"@en ; - skos:prefLabel "CoatedElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "cell electrode consisting of a current collector and active material"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_94209cd8_f68f_40e6_ac70_cfb97a16e593 -:electrochemistry_94209cd8_f68f_40e6_ac70_cfb97a16e593 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 1.3 mm"@en ; - skos:prefLabel "R512"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_94497aca_52a0_48e3_9b76_157b050e35b3 -:electrochemistry_94497aca_52a0_48e3_9b76_157b050e35b3 rdf:type owl:Class ; 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- rdfs:subClassOf :electrochemistry_78a8f60b_10c2_41ee_9946_d35437e1edb5 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "the process of applying a current pulse"@en ; - skos:prefLabel "CurrentPulse"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 -:electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that holds its potential essentially constant by efficiently allowing electric current to pass"@en ; - rdfs:comment "this is a desirable characteristic for a reference electrode" ; - skos:prefLabel "NonPolarizableElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_9f466223_e20a_474d_ac4d_6d4b6131c275 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "an electrode that holds its potential essentially constant by efficiently allowing electric current to pass"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 -:electrochemistry_9fd49892_cf6d_482e_a6c3_5f763948ec29 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q6557456" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode that uses a liquid metal"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Liquid_metal_electrode"@en ; - rdfs:comment "they can be used in electrocapillarity, voltammetry, and impedance measurements"@en ; - skos:prefLabel "LiquidMetalElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 -:electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_2e3e14f9_4cb8_45b2_908e_47eec893dec8 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-09"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode reaction in which oxidation occurs at the anode"@en ; - rdfs:comment "an electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate"@en , - "electrode reaction involving an electrochemical oxidation"@en ; - skos:altLabel "Electrooxidation"@en , - "ElectrooxidationReaction"@en ; - skos:prefLabel "AnodicReaction"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode reaction in which oxidation occurs at the anode"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "an electrode reaction, when the energy of electrons in the working electrode is lower than the HOMO orbital of the substrate"@en ; - dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0580fa9_5073_44af_b33e_7adbc83892d0 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "electrode reaction involving an electrochemical oxidation"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a05e7945_c942_45cf_812c_c9a595d15888 -:electrochemistry_a05e7945_c942_45cf_812c_c9a595d15888 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3b35e843_3132_41e3_b6df_541cd45ba880 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Stripping voltammetry involving pre-concentration by adsorption of the analyte (in contrast to electro- chemical accumulation)."@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "A peak-shaped adsorptive stripping voltammogram is obtained. Peak current depends on time of accumulation, mass transport of analyte (stirring), scan rate and mode (linear or pulse), and analyte concentration in solution."@en , - "AdSV is usually employed for analysis of organic compounds or metal complexes with organic ligands. 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- skos:prefLabel "InertElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode that serves only as a source or sink for electrons without playing a chemical role in the electrode reaction"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 -:electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-20"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "partial or complete external covering of a cell"@en ; - rdfs:comment "a jacket may be made of metal (insulated from the cell terminals), plastic, paper or other suitable material"@en ; - skos:prefLabel "Jacket"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "partial or complete external covering of a cell"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a0fcb105_587f_45d8_a89a_46dc8f745069 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "a jacket may be made of metal (insulated from the cell terminals), plastic, paper or other suitable material"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a10ede13_c895_4f56_a728_b1aab512b31b -:electrochemistry_a10ede13_c895_4f56_a728_b1aab512b31b rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_9c9ceee7_2470_4d05_89e7_28fb93108e38 - ] ; - rdfs:comment "metal electrode in which the active material is tin"@en ; - skos:prefLabel "TinElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c -:electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_92147e31_d015_4889_a092_04fbab033f15 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-03"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plate in which the active material is applied as a paste to a conductive current collector"@en ; - skos:altLabel "PastedElectrode"@en ; - skos:prefLabel "PastedPlate"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a1ec9e3c_c624_4848_af13_89a6bc54d77c ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "plate in which the active material is applied as a paste to a conductive current collector"@en ; - rdfs:comment "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a277e420_2483_44d5_a2bc_4e421dea231a -:electrochemistry_a277e420_2483_44d5_a2bc_4e421dea231a rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 2.6 mm"@en ; - skos:altLabel "R57" ; - skos:prefLabel "R926"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a2b01d05_b472_4cf5_b388_e0914db56324 -:electrochemistry_a2b01d05_b472_4cf5_b388_e0914db56324 rdf:type owl:Class ; 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J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a -:electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-12" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "component of a cell which permits the flow of gas in one direction only"@en ; - rdfs:comment "a valve has a characteristic venting or opening and closing pressure"@en ; - skos:prefLabel "Valve"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "component of a cell which permits the flow of gas in one direction only"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a2f4dca3_829f_412b_9025_bd7581aad82a ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "a valve has a characteristic venting or opening and closing pressure"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a3745142_b97a_4e19_b7ed_03599f56e81d -:electrochemistry_a3745142_b97a_4e19_b7ed_03599f56e81d rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_2a540939_3908_4f85_92f9_c46da7d4e9cb - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is silver oxide"@en ; - skos:prefLabel "SilverOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841 -:electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_8ab1e656_38ff_48e6_ab09_293d76bc9044 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5357962" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-16" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrocatalyst"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "material that can cause electrocatalysis."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrocatalyst"@en ; - skos:prefLabel "Electrocatalyst"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a3b53904_22b1_42a9_a515_c8a3aed7e841 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "material that can cause electrocatalysis."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e -:electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_e1e6ff98_0725_4d27_ab21_2ca5a95371f0 - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q20851418" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver"@en ; - rdfs:comment "Ag electrodes were first used in potentiometry for the determination of Cl−, Br−, I−, as well as for Ag+ ions, to which they are sensitive."@en ; - skos:altLabel "AgElectrode"@en ; - skos:prefLabel "SilverElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a462859d_d8bd_48ea_8bde_1576f1248a1e ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode in the form of foil, mesh, wire, rod, tube, powder, pellets, or single crystal of silver"@en ; - dcterms:source "J. M. 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O'M. and Despić, . Aleksandar R. (2011, December 15). Electrochemical reaction. Encyclopedia Britannica. https://www.britannica.com/science/electrochemical-reaction" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_a6a69e90_06b5_45b1_83cf_7c0bf39b2914 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the electrode reaction can also involve other chemical reactions including subreactions on a cell electrode"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a76072fe_ca6e_48ad_8b4a_ab98a2bc9abb -:electrochemistry_a76072fe_ca6e_48ad_8b4a_ab98a2bc9abb rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_0f6f0120_c079_4d95_bb11_4ddee05e530e ; - skos:prefLabel "VoltageMeasurementResult"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_a87d4b9d_ba91_4549_aed4_508d1160c0c0 -:electrochemistry_a87d4b9d_ba91_4549_aed4_508d1160c0c0 rdf:type owl:Class ; 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- rdfs:comment "this flame front may originate from a spark or an external naked flame igniting combustible electrolysis gas"@en ; - skos:prefLabel "FlameArrestorVent"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "vent of special design which provides protection against the propagation of a flame front from or into the interior of a secondary cell"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_ae56cce3_7a7c_4e53_bb58_31e0d642d47e ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "this flame front may originate from a spark or an external naked flame igniting combustible electrolysis gas"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 -:electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_af92a3ae_e870_4676_9ae7_cda277b1e6e1 -:electrochemistry_af92a3ae_e870_4676_9ae7_cda277b1e6e1 rdf:type owl:Class ; 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- skos:altLabel "PositivePlate"@en ; - skos:prefLabel "PositiveElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_aff732a9_238a_4734_977c_b2ba202af126 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "by convention, a reduction reaction occurs during discharge"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1 -:electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5037987" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Electrode of a composite of carbon powder and a pasting liquid (including mineral oil, Nujol, bromoform, bromonaphthalene)."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Carbon_paste_electrode"@en ; - rdfs:comment "The CPE was first described by Adams in 1958. A CPE is typically housed in a Teflon holder, contacted by a conductive wire (occasionally a piston is used to renew the surface by extrusion of the used paste). Problems are long-term stability of the paste and that the binder can influence its properties."@en , - "These electrodes can easily be chemically modified by the incorporation of reagents (electrocatalysts, redox mediators, complexation agents, enzymes, etc.) and by the attachment of micro- or nanoparticles to prepare electrochemical sensors for analytical applications."@en ; - skos:altLabel "CPE"@en ; - skos:prefLabel "CarbonPasteElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b0a0dddb_d942_4af2_b6a7_d7165f4253f1 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "Electrode of a composite of carbon powder and a pasting liquid (including mineral oil, Nujol, bromoform, bromonaphthalene)."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b1cf9fee_2164_4f95_8204_90f717373a8a -:electrochemistry_b1cf9fee_2164_4f95_8204_90f717373a8a rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_eacb141f_6ab4_491f_8603_a3e025cefc82 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "a round-type case with a height that is greater than or equal to the diameter"@en ; - skos:prefLabel "CylindricalCase"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f -:electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120965018" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "membrane constituted of two or more structural planes of non-identical morphologies"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1351/goldbook.AT06862" ; - skos:prefLabel "AsymmetricMembrane"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b2d11f0d_c1b0_4476_8d17_03b73d31e01f ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "membrane constituted of two or more structural planes of non-identical morphologies"@en ; - dcterms:source "IUPAC. Compendium of Chemical Terminology, 2nd ed. (the \"Gold Book\"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). Online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook." - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e -:electrochemistry_b3a6d552_b38e_47ad_9d48_e8b77035d63e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_10359c79_cdf2_401a_83ee_d22e7fbb2ad1 , - :electrochemistry_64bf0969_37a1_4aaf_82e9_68462847ac65 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q901180" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measurement principle in which the electric conductivity of a solution is measured"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "Monitoring of the purity of deionized water."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Conductometry"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "The conductivity of a solution depends on the concentration and nature of ions present."@en ; - skos:prefLabel "Conductometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90 -:electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_8a1c9a7b_978c_4421_a9c1_d0b07b42aab9 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q189673" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-08" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "process where molecules split up into ions due to being dissolved"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Dissociation_(chemistry)"@en ; - skos:prefLabel "Dissociation"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b3b3868f_6edd_4ce8_a984_08f9cf391f90 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "process where molecules split up into ions due to being dissolved"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 -:electrochemistry_b3e56313_417c_42b7_a934_0018ce2dffc2 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ; - owl:someValuesFrom :electrochemistry_b49e2355_392f_4e83_b630_7ff4581d767b - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5275361" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "voltammetry in which small potential pulses (constant height 10 to 100 mV, constant width 10 to 100 ms) are superimposed onto a linearly varying potential or onto a staircase potential ramp. The current is sampled just before the onset of the pulse (e.g. 10 to 20 ms) and for the same sampling time just before the end of the pulse. The difference between the two sampled currents is plotted versus the potential applied before the pulse. Thus, a differential pulse voltammogram is peak-shaped"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Differential_pulse_voltammetry"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Differential pulse polarography is differential pulse voltammetry in which a dropping mercury electrode is used as the working electrode. A pulse is applied before the mechani- cally enforced end of the drop and the current is sampled twice: just before the onset of the pulse and just before its end. The pulse width is usually 10 to 20 % of the drop life. The drop dislodgement is synchronized with current sampling, which is carried out as in DPV."@en , - "The ratio of faradaic current to charging current is enhanced and the negative influence of charging current is partially eliminated in the same way as in normal pulse voltammetry (NPV). Moreover, subtraction of the charging current sampled before the application of the pulse further decreases its negative influence. Due to the more enhanced signal (faradaic current) to noise (charging current) ratio, the limit of detection is lower than with NPV."@en , - "The sensitivity of DPV depends on the reversibility of the electrode reaction of the analyte."@en ; - skos:altLabel "DPV"@en ; - skos:prefLabel "DifferentialPulseVoltammetry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b3eb8c65_5644_45e3_9e17_0be6277c7962 -:electrochemistry_b3eb8c65_5644_45e3_9e17_0be6277c7962 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_3ac62305_acd6_4312_9e31_4f824bd2530d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium nickel manganese cobalt"@en ; - skos:altLabel "NMCElectrode"@en ; - skos:prefLabel "LithiumNickelManganeseCobaltOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b442217f_02f6_4991_aadf_22d81369223c -:electrochemistry_b442217f_02f6_4991_aadf_22d81369223c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 3.1 mm"@en ; - skos:altLabel "R54" ; - skos:prefLabel "R1131"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b49e2355_392f_4e83_b630_7ff4581d767b -:electrochemistry_b49e2355_392f_4e83_b630_7ff4581d767b rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Small pulses of electric potential superimposed to a linear potential ramp or a staircase potential ramp."@en ; - rdfs:comment "The pulses are usually of constant height 10 to 100 mV and constant width 10 to 100 ms."@en ; - skos:prefLabel "DifferentialPotentialPulse"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5039bc8_f595_4797_908a_7e86131fbde4 -:electrochemistry_b5039bc8_f595_4797_908a_7e86131fbde4 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_270f239e_33cb_4c6d_a41c_875ec1262d62 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "two-step electrochemical measurement in which 1) material is accumulated at an electrode and 2) the material is removed by chemical reaction or electrochemically at constant current with measurement of electrode potential. The time between changes in potential in step 2 is related to the concentration of analyte in the solution"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Historically for the analysis of metal ions, mercury ions were added to the test solution to form a mercury amalgam when reduced. Alternatively, an HMDE or MFE was used and the oxidizing agent added after amalgam formation. However, the toxicity of mercury and its compounds have all but precluded the present-day use of mercury."@en , - "The accumulation is similar to that used in stripping voltammetry."@en , - "The stripping potentiogram shows staircase curves of potential as a function of time. Fre- quently, the first derivative is displayed (dE/dt = f(t)), as this produces peak-shaped signals. The time between transitions (peaks) is proportional to the concentration of analyte in the test solution."@en ; - skos:altLabel "PSA"@en ; - skos:prefLabel "PotentiometricStrippingAnalysis"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686 -:electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0acd0fc2_1048_4604_8e90_bf4e84bd87df ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrochemical cell for conductivity measurements"@en ; - rdfs:comment """Formed, in theory, by two 1 cm2 reversible electrodes spaced 1 cm apart, providing a uniform distribution of electrical field. In practice, however, a number -of other configurations are used."""@en ; - skos:prefLabel "ConductivityCell"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b525a629_a679_464f_bc5b_b49d2fc82686 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "an electrochemical cell for conductivity measurements"@en ; - dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: http://doi.org/10.1007/978-3-642-29551-5" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b56a95e6_eea5_4a58_99aa_045fd28e75d3 -:electrochemistry_b56a95e6_eea5_4a58_99aa_045fd28e75d3 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 5.8 mm and a height of 2.7 mm"@en ; - skos:altLabel "R64" ; - skos:prefLabel "R527"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5e91259_cd97_4ed6_9ab2_4b18ef68a35a -:electrochemistry_b5e91259_cd97_4ed6_9ab2_4b18ef68a35a rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium vanadium oxide"@en ; - skos:prefLabel "LithiumVanadiumOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 -:electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_ceaaf9f7_fd11_424b_8fda_9afa186af186 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "A constituent in an electrochemical system."@en ; - rdfs:comment "a constituent is essential to the functioning of the system and cannot be replaced by a comparable thing without altering the behaviour of the system" ; - skos:prefLabel "ElectrochemicalConstituent"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 -:electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q181232"@en ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-27" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Anode"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "by convention, cell electrode at which an oxidation reaction occurs"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Anode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/A00370"@en ; - rdfs:comment "at an anode, electrons are produced in a galvanic cell or extracted in an electrolytic cell"@en , - "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation"@en , - "the anode is the negative electrode during discharge and the positive electrode during charge"@en , - "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ; - skos:prefLabel "Anode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "by convention, cell electrode at which an oxidation reaction occurs"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "at an anode, electrons are produced in a galvanic cell or extracted in an electrolytic cell"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "electrode of an electrochemical cell through which net electric current flows and at which the predominating electrochemical reaction is an oxidation"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the anode is the negative electrode during discharge and the positive electrode during charge"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_b6319c74_d2ce_48c0_a75a_63156776b302 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "the concepts of “anode” and “cathode” are related only to the direction of electron flow, not to the polarity of the electrodes"@en ; - dcterms:source "J. M. 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Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff -:electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_a0a619d7_da95_41f0_8bc3_9c19d636d543 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-16"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "platinized platinum electrode saturated by a stream of pure gaseous hydrogen"@en ; - rdfs:comment "A platinized platinum electrode consists of a platinum rod covered by compact platinum powder called platinum black."@en ; - skos:prefLabel "HydrogenElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_c4a778c7_33da_4e1a_960e_402a210bfeff ; 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Resistances (e.g. to charge transfer) give a response in phase with the voltage perturbation; capacitances (e.g. double layer) give a response 90° out of phase; combinations of resistances and capacitances give phase angles between 0 and 90°. Plots of the out of phase vs. the in phase component of the impedance for all the frequencies tested are called complex plane (or Nyquist) plots. Plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency are called Bode diagrams. 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- emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q5074261" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-28" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "set of operations that is carried out on a secondary cell or battery and is repeated regularly in the same sequence."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Charge_cycle"@en ; - rdfs:comment "in a secondary battery these operations may consist of a sequence of a discharge followed by a charge or a charge followed by a discharge under specified conditions"@en , - "this sequence may include rest periods"@en ; - skos:altLabel "ChargeCycle"@en , - "ElectrochemicalCycling"@en ; - skos:prefLabel "Cycling"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "set of operations that is carried out on a secondary cell or battery and is repeated regularly in the same sequence."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "in a secondary battery these operations may consist of a sequence of a discharge followed by a charge or a charge followed by a discharge under specified conditions"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_d3e2d213_d078_4b9a_8beb_62f063e57d69 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "this sequence may include rest periods"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d48ea516_5cac_4f86_bc88_21b6276c0938 -:electrochemistry_d48ea516_5cac_4f86_bc88_21b6276c0938 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q903846" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Butler%E2%80%93Volmer_equation"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a phenomenological model for electrode kinetics, describing the relation between the electrode current from an electrochemical charge-transfer reaction and the surface overpotential of the electrode"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Butler%E2%80%93Volmer_equation"@en ; - rdfs:comment "i = i0 * (exp(alpha*n*F*eta/(R*T)) – exp(-(1-alpha)*n*F*eta/(R*T)))" ; - skos:altLabel "ButlerVolmerApproximation"@en , - "ErdeyGruzVolmerEquation"@en ; - skos:prefLabel "ButlerVolmerEquation"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5da9948_e95b_4f12_a2d2_10a48f390c52 -:electrochemistry_d5da9948_e95b_4f12_a2d2_10a48f390c52 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-40" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "arrangement of cells or batteries wherein parallel connected cells or batteries are connected in series."@en ; - skos:prefLabel "ParallelSeriesConnection"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_d5da9948_e95b_4f12_a2d2_10a48f390c52 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "arrangement of cells or batteries wherein parallel connected cells or batteries are connected in series."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d5f67a0c_ed56_479d_9b68_6003142f98b0 -:electrochemistry_d5f67a0c_ed56_479d_9b68_6003142f98b0 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 16.0 mm and a height of 1.6 mm"@en ; - skos:prefLabel "R1616"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d61deb36_b397_4811_bf7a_66d8e4578c6e -:electrochemistry_d61deb36_b397_4811_bf7a_66d8e4578c6e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_a53d6dee_1547_4854_a311_805b4d557298 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "alternating current consistent with a sinusoidal waveform"@en ; - skos:prefLabel "SinusoidalCurrentWaveform"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d67a0921_15e4_4c73_804e_97b2d66452b8 -:electrochemistry_d67a0921_15e4_4c73_804e_97b2d66452b8 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 3.6 mm"@en ; - skos:altLabel "R45" ; - skos:prefLabel "R936"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00 -:electrochemistry_d8a78cd2_8107_46dd_a198_0b64676efc00 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f76884f7_964e_488e_9bb7_1b2453e9e817 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-37" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "conductor of electricity used for carrying current between components in an electric circuit"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "a connector electrically joins two cells, or a terminal of a cell to a terminal of the battery, or a terminal of the battery to an exterior circuit and also to auxiliary devices"@en ; 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- rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_f8d50782_11fa_4188_ba55_d043d2eb597d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is titanium"@en ; - skos:prefLabel "TitaniumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b -:electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_52bbaaee_1145_4be3_8a5c_b366851ea1b9 ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-09" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "assembly of one positive plate, one negative plate and the associated separator if any"@en ; - skos:altLabel "PlatePair"@en ; - skos:prefLabel "ElectrodePair"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_d907805f_678b_4ab6_8b56_59631684f84b ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "assembly of one positive plate, one negative plate and the associated separator if any"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d936c767_1530_419c_93f4_59e08f0d702c -:electrochemistry_d936c767_1530_419c_93f4_59e08f0d702c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an insertion electrode in which the guest molecule is sodium"@en ; - skos:prefLabel "SodiumInsertionElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166 -:electrochemistry_d95fdd2e_38bf_4065_a857_78eb201ee166 rdf:type owl:Class ; 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Convective mass transfer occurs up to the diffusion-limiting layer, within which the mass transfer is controlled by diffusion. Electroactive substance depletion outside the diffusion layer is annulled by convective mass transfer, which results in steady- state sigmoidal wave-shaped current-potential curves."@en , - "The forced flow can be accomplished by movement either of the solution (solution stirring, or channel flow), or of the electrode (electrode rotation or vibration)."@en ; - skos:prefLabel "HydrodynamicVoltammetry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_d9888f1f_2226_4ce3_9cb3_91fd9bd1bf22 -:electrochemistry_d9888f1f_2226_4ce3_9cb3_91fd9bd1bf22 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_757eae08_4d43_42d4_8b4e_8a0bfd2f9a1c ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an insertion electrode in which the guest molecule is magnesium"@en ; - skos:prefLabel "MagnesiumInsertionElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dac5067c_e6f2_4fca_a915_5b7b918ca1c4 -:electrochemistry_dac5067c_e6f2_4fca_a915_5b7b918ca1c4 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 10.8 mm"@en ; - skos:prefLabel "R11108"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dc019f3f_e5f3_4eeb_bab9_a845a02223a0 -:electrochemistry_dc019f3f_e5f3_4eeb_bab9_a845a02223a0 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 6.8 mm and a height of 1.65 mm"@en ; - skos:altLabel "R65" ; - skos:prefLabel "R616"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c -:electrochemistry_dc205ac2_314e_415c_a2b6_b12e8359d54c rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b812e9d0_7c58_4455_b3e7_6847f10c8e8a ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an aqueous electrolyte with a nominal pH value between 4 and 10."@en ; 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- skos:prefLabel "Supercapacitor"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_dd4c5ffa_6228_41d8_8a44_a40a2b22723e -:electrochemistry_dd4c5ffa_6228_41d8_8a44_a40a2b22723e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_90f71119_f476_4033_b6ee_6342680322e5 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is cadmium"@en ; - skos:prefLabel "CadmiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ddade648_2033_47b6_bc36_b562a9af591e -:electrochemistry_ddade648_2033_47b6_bc36_b562a9af591e rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_eb7de1a1_c30e_4f0d_94c6_fe70414d7e61 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Graphical representation of a dataset resulting from the measurement of the response of an electrochemical system."@en ; 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- owl:someValuesFrom chemsub:substance_dc5fb846_1824_40f8_9834_81f118aa1c2d - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "liquid metal electrode used in polarography"@en ; - rdfs:comment "A mercury film electrode (MFE) or thin mercury film electrode (TMFE) is formed by coating a conducting substrate, usually glassy carbon, with a layer of mercury (thin film, amalgam, or array of microdrops), often by electrodeposition from a solution containing Hg(II). The electrode area is normally in the range of 0.1 to 0.5 cm2 and mercury film thickness typically ranges from 10 to 1000 nm, producing a film of large surface area-to-volume ratio that results in a high analyte pre-concentration during the deposition step of anodic stripping voltammetry. Compared to an HMDE, the MFE provides high sensitivity and resolution; however, it is somewhat less reproducible and more prone to interferences from intermetallic formation and surface-active substances."@en , - "Liquid mercury is an ideal electrode material for negative potentials because of its high overpotential for hydrogen evolution (electrochemical reduction of hydroxonium cations from solution). However, mercury is readily oxidized, particularly in the presence of anions that form complexes or that pre- cipitate with Hg(I) or Hg(II) ions, and thus it is not suitable for use at positive potentials. The use of liquid mercury has largely been discontinued because of concerns about the toxicity of the element and its compounds."@en ; - skos:altLabel "HgElectrode"@en ; - skos:prefLabel "MercuryElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_df78745e_f9db_4830_88f0_8ce074fcb8ff ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "liquid metal electrode used in polarography"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e0869e7a_36fe_4e33_9843_a5dc19fcb488 -:electrochemistry_e0869e7a_36fe_4e33_9843_a5dc19fcb488 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 15.5 mm and a height of 6.0 mm"@en ; - skos:prefLabel "R9"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e0b57b09_68ee_4687_a901_bfb599421972 -:electrochemistry_e0b57b09_68ee_4687_a901_bfb599421972 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ddade648_2033_47b6_bc36_b562a9af591e ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q245627" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "plots of the phase angle and the magnitude of the impedance vs. the logarithm of perturbation frequency at all the frequencies tested in an impedimetry measurement"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Bode_plot"@en ; - skos:altLabel "BodeDiagram"@en ; - skos:prefLabel "BodePlot"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f -:electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_6f2c88c9_5c04_4953_a298_032cc3ab9b77 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q209440" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-02"@en ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Galvanic_cell"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Galvanic_cell"@en ; - rdfs:comment "An electrochemical cell that spontaneously produces work."@en , - "Electrochemical cell intended to produce electric energy."@en ; - skos:prefLabel "GalvanicCell"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrochemical cell in which chemical reactions occur spontaneously and chemical energy is converted into electrical energy."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "An electrochemical cell that spontaneously produces work."@en ; - dcterms:references "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004." - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_e248373f_294f_4ca4_9edf_0ad6653bb64f ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "Electrochemical cell intended to produce electric energy."@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc -:electrochemistry_e2a1dae1_05e4_4bd1_a39d_0eb10db482bc rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q64403" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-04-09" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrolysis"@en ; 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- skos:prefLabel "R1025"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e84e691a_df58_465c_9771_7a7fe2212ed5 -:electrochemistry_e84e691a_df58_465c_9771_7a7fe2212ed5 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of lithium hydroxide (LiOH) dissolved in water (H2O)"@en ; - skos:altLabel "AqueousLithiumHydroxideSolution"@en , - "LiOHSolution"@en ; - skos:prefLabel "LithiumHydroxideSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_e8c39ecc_29d1_4172_996e_d5b05dc88015 -:electrochemistry_e8c39ecc_29d1_4172_996e_d5b05dc88015 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5186239a_2af7_4dbf_92ca_22e8e583c528 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_68c0876b_cb62_41cd_846d_95cc9d9a8733 - ] , - [ rdf:type owl:Restriction ; 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The indicator electrode is in direct contact with the analyte solution, whereas the reference electrode is usually separated from the analyte solution by a salt bridge. The potential difference between the indicator and reference electrodes is normally directly proportional to the logarithm of the activity (concentration) of the analyte in the solution (Nernst equation). 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- rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 9.5 mm and a height of 2.1 mm"@en ; - skos:altLabel "R69" ; - skos:prefLabel "R921"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ebd01982_6b0c_48e7_90ef_7b7342009449 -:electrochemistry_ebd01982_6b0c_48e7_90ef_7b7342009449 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of sodium hydroxide (LiOH) dissolved in water (H2O)"@en ; - skos:altLabel "AqueousSodiumHydroxideSolution"@en , - "NaOHSolution"@en ; - skos:prefLabel "SodiumHydroxideSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 -:electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_68390bfb_e307_479d_8f78_d66d8773cb1d ; 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- dcterms:source "A. J. Bard, G. Inzelt, and F. Scholz, Eds., Electrochemical Dictionary, 2nd Edition. Berlin: Springer-Verlag, 2012. DOI: https://doi.org/10.1007/978-3-642-29551-5" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f54474fc_5d07_474b_97ae_f5d0349363b4 -:electrochemistry_f54474fc_5d07_474b_97ae_f5d0349363b4 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_95e4aa95_b7e9_40d7_b78e_4d7dcc31093d ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a flow cell that uses one or more electroactive components deposited as a solid layer"@en ; - skos:prefLabel "HybridFlowCell"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f57a7dac_2ec2_4d51_b697_01a844c4467f -:electrochemistry_f57a7dac_2ec2_4d51_b697_01a844c4467f rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "considers the effects of specific adsorbed ions in the double layer"@en ; - rdfs:comment "proposed by Sergio Trasatti and Giovanni Buzzanca in 1971"@en ; - skos:prefLabel "TrasattiBuzzancaModel"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f591a444_89d6_4093_836d_7d53895edce4 -:electrochemistry_f591a444_89d6_4093_836d_7d53895edce4 rdf:type owl:Class . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6223121_7df5_42f8_902c_d26fa2fc4f04 -:electrochemistry_f6223121_7df5_42f8_902c_d26fa2fc4f04 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_4126ee09_b9c6_4694_bf33_0d8970e05f72 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lead oxide"@en ; - skos:altLabel "PbOElectrode"@en ; - skos:prefLabel "LeadOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6341d7d_7620_48f5_97b2_99b55c349169 -:electrochemistry_f6341d7d_7620_48f5_97b2_99b55c349169 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_19abaccd_43be_4048_965c_e4fb63c5951b , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_ae2d1a96_bfa1_409a_a7d2_03d69e8a125a ; - owl:someValuesFrom :electrochemistry_79d1b273_58cd_4be6_a250_434817f7c261 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a degradation mechanism in electrochemical cells in which fractures in the active material particles increase cell resistance."@en ; - skos:prefLabel "ActiveMaterialParticleCracking"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f693b744_930c_42ac_8e6f_627b22c6da3f -:electrochemistry_f693b744_930c_42ac_8e6f_627b22c6da3f rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_7dea2572_ab42_45bd_9fd7_92448cec762a , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_dba27ca1_33c9_4443_a912_1519ce4c39ec ; - owl:someValuesFrom :electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a system for measuing electric current"@en ; - emmo:EMMO_b432d2d5_25f4_4165_99c5_5935a7763c1a "a digital coulometer connected to a computer"@en ; - skos:prefLabel "ElectricCurrentMeasuringSystem"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f6fcd255_248d_4603_b128_04dab960a676 -:electrochemistry_f6fcd255_248d_4603_b128_04dab960a676 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q120907462" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/I03006"@en ; - rdfs:comment "If processes of interest occur both at the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or working electrodes."@en , - "This term is typically used in potentiometry."@en ; - skos:prefLabel "IndicatorElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_f6fcd255_248d_4603_b128_04dab960a676 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode that responds to one, or more than one, species in the solution being investigated, with no appreciable change of bulk solution composition during the measurement"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f7e253da_b12e_40b0_ba51_8cb039839ab6 -:electrochemistry_f7e253da_b12e_40b0_ba51_8cb039839ab6 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 12.05 mm and a height of 2.5 mm"@en ; - skos:prefLabel "R1225"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f8e0d532_cf44_403c_9188_e00ee161a3c1 -:electrochemistry_f8e0d532_cf44_403c_9188_e00ee161a3c1 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ecf136cb_2584_4cb1_98b7_2d2b3d22e40d ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a type of solid electrolyte interface that forms on the surface of the electrode designated as the \"cathode\" or positive electrode"@en ; - rdfs:comment "used to distinguish the interphase on the cathode surface from that on the anode, which is typically called the solid electrolyte interphase (SEI)"@en ; - skos:prefLabel "CathodeElectrolyteInterphase"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f8f81b27_1d6c_42d8_a7e9_5a2534102562 -:electrochemistry_f8f81b27_1d6c_42d8_a7e9_5a2534102562 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_68f9b85e_340f_46ec_96da_ebb6bd62f5fd - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is sodium chromium oxide"@en ; - skos:prefLabel "SodiumChromiumOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f91c9ae3_42b8_4efa_9b67_a406d162d3b5 -:electrochemistry_f91c9ae3_42b8_4efa_9b67_a406d162d3b5 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_6e439f86_3d00_4b0b_82ab_1fa25241d4e9 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a - ] , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_36e69413_8c59_4799_946c_10b05d266e22 ; - owl:someValuesFrom :electrochemistry_85e39686_9658_4c74_bb91_a935704c174a - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "direct coulometry at controlled potential in which the electric charge passed after the application of a potential step perturbation is measured as a function of time (Q-t curve)"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://doi.org/10.1515/pac-2018-0109"@en ; - rdfs:comment "Chronocoulometry provides the same information that is provided by chronoamperometry, since it is based on the integration of the I-t curve. Nevertheless, chronocoulometry offers important experimental advantages, such as (i) the measured signal usually increases with time and hence the later parts of the transient can be detected more accurately, (ii) a better signal-to-noise ratio can be achieved, and (iii) other contributions to overall charge passed as a function of time can be discriminated from those due to the diffusion of electroactive substances."@en ; - skos:prefLabel "Chronocoulometry"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9af8440_3629_4558_a944_9dfaf3dfd7ec -:electrochemistry_f9af8440_3629_4558_a944_9dfaf3dfd7ec rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0a03ce7e_d79f_412e_a103_b5d74de9f4d7 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "Linear ramp of electric potential, followed by a reversal to the initial potential. Both forward and reversed signal ramps are applied at the same scan rate."@en ; - skos:prefLabel "TriangularPotentialWaveform"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9e2e676_5cd1_4e22_a776_af45838d4027 -:electrochemistry_f9e2e676_5cd1_4e22_a776_af45838d4027 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_615cff2a_be95_4e65_9471_98db23f4c878 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a solution of ammonia (NH3) dissolved in water (H2O)"@en ; - rdfs:comment "the solution can also be made by dissolving ammonium hydroxide (NH4OH) in water"@en ; - skos:altLabel "AqueousAmmoniaSolution"@en ; - skos:prefLabel "AmmoniaSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_f9f056bb_a38b_43bd_a6bd_99d618431f4d -:electrochemistry_f9f056bb_a38b_43bd_a6bd_99d618431f4d rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_5adb91e0_ffe1_41f3_b779_c6966f65fb0e , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_f96ceacb_2808_4c4d_925c_d28086c8a2e1 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is palladium"@en ; - skos:prefLabel "PalladiumElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de -:electrochemistry_fa22874b_76a9_4043_8b8f_6086c88746de rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_4b3e2374_52a1_4420_8e3f_3ae6b9bf7dff , - :electrochemistry_609b340f_3450_4a10_95c2_c457e3eb8a89 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a liquid electrolyte that consists of solutes dissolved in a solvent"@en ; - skos:altLabel "ElectrolyticSolution"@en ; - skos:prefLabel "ElectrolyteSolution"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa54f95d_b49e_43b5_84c3_35520d0fb2f6 -:electrochemistry_fa54f95d_b49e_43b5_84c3_35520d0fb2f6 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_ac9723d1_bac0_4109_874e_32849de9299b ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an extension of the Helmholtz model that describes the distribution of ions as a function of distance from the electrode surface to the bulk of the electroylte"@en ; - rdfs:comment "this model fails for highly charged double layers"@en ; - skos:prefLabel "GouyChapmanModel"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fa774456_718a_4a28_ba6a_6f828887c510 -:electrochemistry_fa774456_718a_4a28_ba6a_6f828887c510 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_904b12e0_4a10_47b0_b7db_592aba215cb6 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "signal where an electric current is varied linearly from an initial current, typically 0 A"@en ; - skos:prefLabel "LinearCurrentRamp"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fab4bd12_c4ed_417a_92a3_bcb109000d82 -:electrochemistry_fab4bd12_c4ed_417a_92a3_bcb109000d82 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 20.0 mm and a height of 4.0 mm"@en ; - skos:prefLabel "R2040"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 -:electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_b5ea31c9_bb10_4276_980e_c3eceb1efc82 , - :electrochemistry_ebdb68e9_c4b5_4d57_a042_c0f51d446755 , - [ rdf:type owl:Restriction ; - owl:onProperty emmo:EMMO_0aa934ee_1ad4_4345_8a7f_bc73ec67c7e5 ; - owl:someValuesFrom :electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc - ] ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q162908" ; - emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-01-02" , - "https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-02-29" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Electrolyte"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a material in which the mobile species are ions and free movement of electrons is blocked."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Electrolyte"@en ; - rdfs:comment "A solid electrolyte is a solid material where the predominant charge carriers are ions. For example: NASICON (Na Super Ionic Conductor), which has the general formula Na1+xZr2P3-xSix O12 , 0 < x < 3."@en , - "An ionic liquid is an electrolyte composed of a salt that is liquid below 100 °C. Ionic liquids have found uses in electrochemical analysis, because their unconventional properties include a negligible vapor pressure, a high thermal and electrochemical stability, and exceptional dissolution properties for both organic and inorganic chemical species."@en , - "conducting medium in which the flow of electric current is accompanied by the movement of ions"@en , - "liquid or solid substance containing mobile ions that render it conductive"@en , - "substance that provides ions on dissolution in a solvent or on melting"@en ; - skos:prefLabel "Electrolyte"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "a material in which the mobile species are ions and free movement of electrons is blocked."@en ; - dcterms:source "J. Newman and K. E. Thmoas-Alyea, Electrochemical Systems, 3rd ed. Hoboken, New Jersey: John Wiley & Sons, 2004." - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "conducting medium in which the flow of electric current is accompanied by the movement of ions"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "liquid or solid substance containing mobile ions that render it conductive"@en ; - dcterms:source "International Electrotechnical Commission (IEC), IEC 60050 - International Electrotechnical Vocabulary, retrieved from: https://www.electropedia.org" - ] . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb0d9eef_92af_4628_8814_e065ca255d59 ; - owl:annotatedProperty rdfs:comment ; - owl:annotatedTarget "substance that provides ions on dissolution in a solvent or on melting"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 -:electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_0f007072_a8dd_4798_b865_1bf9363be627 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q477099" ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode at which one or more electroactive substances undergo reaction in the solution being investigated"@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Working_electrode"@en ; - emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 "https://goldbook.iupac.org/terms/view/W06686"@en ; - rdfs:comment "If processes of interest occur both at the anode and the cathode of a cell (as in differential amperometry or controlled-current potentiometric titration with two indicator electrodes), the cell should be said to comprise two indicator or working electrodes."@en , - "Te potential of a working electrode is controlled with respect to the reference electrode."@en , - "This term is typically used in voltammetry, polarography, amperometry, and coulometry."@en ; - skos:prefLabel "WorkingElectrode"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb988878_ee54_4350_9ee9_228c00c3ad35 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "electrode at which one or more electroactive substances undergo reaction in the solution being investigated"@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 -:electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 rdf:type owl:Class ; - rdfs:subClassOf emmo:EMMO_f2d5d3ad_2e00_417f_8849_686f3988d929 ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q905539" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Voltmeter"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Voltameter"@en ; - rdfs:comment "Modern instruments for measuring trace water by Karl Fischer titration use the passage of a measured charge to produce iodine from iodide solution. They are known as Karl Fischer coulometers"@en , - "The silver coulometer is a primary reference measurement procedure [VIM 2.8] for charge and current. By weighing the mass of silver deposited in a known time at constant current, the charge and current are calculated from Faraday’s laws of electrolysis"@en ; - skos:altLabel "Voltameter"@en ; - skos:prefLabel "Coulometer"@en . - -[ rdf:type owl:Axiom ; - owl:annotatedSource :electrochemistry_fb9bf7cb_dd4b_4391_99a1_628263dd6940 ; - owl:annotatedProperty emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ; - owl:annotatedTarget "measuring instrument to obtain the electrical charge passed in an experiment, or to produce a known amount of substance in a titration."@en ; - dcterms:source "J. M. Pingarrón et al., Terminology of electrochemical methods of analysis (IUPAC Recommendations 2019), Pure and Applied Chemistry, 4, 92, 2020, 641-694. https://doi.org/10.1515/pac-2018-0109" - ] . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fbf40756_3265_4468_bcdb_88d162afc539 -:electrochemistry_fbf40756_3265_4468_bcdb_88d162afc539 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 23.0 mm and a height of 2.0 mm"@en ; - skos:prefLabel "R2320"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fd7caf39_0a43_4fbf_958e_a62067aa9007 -:electrochemistry_fd7caf39_0a43_4fbf_958e_a62067aa9007 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_e4b6cb36_4dac_49e3_871d_40bcfca943a5 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_4c62d334_a124_40b3_9fd1_fe713d01a6af - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "electrode in which the active material is lithium cobalt oxide"@en ; - skos:altLabel "LCOElectrode"@en ; - skos:prefLabel "LithiumCobaltOxideElectrode"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fe054d02_41c7_40e9_8206_3440ab6a67b2 -:electrochemistry_fe054d02_41c7_40e9_8206_3440ab6a67b2 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3979cd56_6256_414d_966c_7f723bf71e37 ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "a coin case with a nominal diameter of 11.6 mm and a height of 5.4 mm"@en ; - skos:altLabel "R44" ; - skos:prefLabel "R1154"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e -:electrochemistry_fe3a6c9a_85b8_4da6_aa4f_71c8de74939e rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_3d805c2a_4801_440e_9e4d_0fa5585c76ae ; - emmo:EMMO_26bf1bef_d192_4da6_b0eb_d2209698fb54 "https://www.wikidata.org/wiki/Q751124" ; - emmo:EMMO_6dd685dd_1895_46e4_b227_be9f7d643c25 "https://dbpedia.org/page/Nernst_equation"@en ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "An equation that relates the reduction potential of an electrochemical reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation."@en ; - emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d "https://en.wikipedia.org/wiki/Nernst_equation" ; - rdfs:comment "An expression of the Law of Mass Action."@en , - "E_{eq} = E^0 - (R*T/(z*F))*ln(Q)" ; - skos:prefLabel "NernstEquation"@en . - - -### https://w3id.org/emmo/domain/electrochemistry#electrochemistry_fffc3dad_6946_4c32_a9d3_f5f311339881 -:electrochemistry_fffc3dad_6946_4c32_a9d3_f5f311339881 rdf:type owl:Class ; - rdfs:subClassOf :electrochemistry_4839708a_3864_47eb_b719_373ff8874c61 , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_aa8e9cc4_5f66_4307_b1c8_26fac7653a90 - ] , - [ rdf:type owl:Restriction ; - owl:onProperty :electrochemistry_860aa941_5ff9_4452_8a16_7856fad07bee ; - owl:someValuesFrom chemsub:substance_e8fafdc8_6cd3_4dd0_9630_10ca8e3f1827 - ] ; - emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 "an electrode with blended lithium manganese oxide (LMO) and lithium iron phosphate (LFP) active materials"@en ; - skos:altLabel "LMOLFPElectrode"@en ; - skos:prefLabel "LithiumManganeseOxideLithiumIronPhosphateElectrode"@en . - - -### Generated by the OWL API (version 4.5.9.2019-02-01T07:24:44Z) https://github.com/owlcs/owlapi diff --git a/_deprecate/docs/index.html b/_deprecate/docs/index.html deleted file mode 100644 index ed2b450..0000000 --- a/_deprecate/docs/index.html +++ /dev/null @@ -1,26 +0,0 @@ - - - - - - BattINFO - - - - - - -

| About | Contribute | BattINFO Github

-

An electrochemistry domain ontology developed in the BIG-MAP project. -The ontology is a part of the Battery Interface Domain Ontology (BattINFO).

-

The ontology is based on EMMO.

-

The Electrochemistry Domain ontology is a digital resource to support interoperability of electrochemical data.

-

This ontology consists of a list of entities representing concepts used in electrochemistry. Each entity has a unique identifier (IRI) and is annotated with additional information, such as its preferred name ("prefLabel"), alternative names, definition, references, etc. As users link their research resources to ontology entities, they are effectively describing their resource using a common vocabulary. Resources can be datasets, documents, persons, organizations, equipment, samples... anything linked to the common vocabulary described in this ontology, becomes part of an ecosystem of Findable resources.

-

See list of entities

- - - \ No newline at end of file diff --git a/_deprecate/docs/scripts/__pycache__/html_styling.cpython-310.pyc b/_deprecate/docs/scripts/__pycache__/html_styling.cpython-310.pyc deleted file mode 100644 index 56e3b85..0000000 Binary files a/_deprecate/docs/scripts/__pycache__/html_styling.cpython-310.pyc and /dev/null differ diff --git a/_deprecate/docs/scripts/__pycache__/md_to_html.cpython-310.pyc b/_deprecate/docs/scripts/__pycache__/md_to_html.cpython-310.pyc deleted file mode 100644 index 626e2fa..0000000 Binary files a/_deprecate/docs/scripts/__pycache__/md_to_html.cpython-310.pyc and /dev/null differ diff --git a/_deprecate/docs/scripts/__pycache__/ttl_to_html.cpython-310.pyc b/_deprecate/docs/scripts/__pycache__/ttl_to_html.cpython-310.pyc deleted file mode 100644 index 351b88b..0000000 Binary files a/_deprecate/docs/scripts/__pycache__/ttl_to_html.cpython-310.pyc and /dev/null differ diff --git a/_deprecate/docs/scripts/__pycache__/ttl_to_md.cpython-310.pyc b/_deprecate/docs/scripts/__pycache__/ttl_to_md.cpython-310.pyc deleted file mode 100644 index 7bf56e7..0000000 Binary files a/_deprecate/docs/scripts/__pycache__/ttl_to_md.cpython-310.pyc and /dev/null differ diff --git a/_deprecate/docs/scripts/md_to_html.py b/_deprecate/docs/scripts/md_to_html.py deleted file mode 100644 index 6b45138..0000000 --- a/_deprecate/docs/scripts/md_to_html.py +++ /dev/null @@ -1,84 +0,0 @@ -import markdown - - -########## RENDER HTML TOP ################ - -def render_html_top() -> str: - - top_html = """ - - - - - BattINFO - - - - - """ - - banner = ''' - - ''' - - return top_html + banner - -########## RENDER HTML BOTTOM ################ - -def render_html_bottom() -> str: - return """ - - - """ - - -########## LOAD MD INTO HTML ################ - -def load_md_into_html(path:str)-> str: - - with open(path, 'r', encoding="utf-8") as file: - markdown_text = file.read() - - # Convert Markdown to HTML - html = markdown.markdown(markdown_text) - return html - - - -########### RUN THE RENDERING WORKFLOW ############## - -def rendering_workflow(): - - # PAGES - pages = [ - {"filename":"about.html", - "path":"./docs/assets/about.md"}, - - {"filename":"index.html", - "path":"./docs/assets/index.md"}, - - {"filename":"contribute.html", - "path":"./docs/assets/contribute.md"}, - ] - - # GENERATE PAGES - - for page in pages: - - - html = render_html_top() - html += load_md_into_html(page["path"]) - html += render_html_bottom() - - with open("./docs/"+page["filename"], "w", encoding="utf-8") as f: - f.write(html) - - - -if __name__ == "__main__": - - rendering_workflow() diff --git a/_deprecate/docs/scripts/prototyping.ipynb b/_deprecate/docs/scripts/prototyping.ipynb deleted file mode 100644 index f753dac..0000000 --- a/_deprecate/docs/scripts/prototyping.ipynb +++ /dev/null @@ -1,1131 +0,0 @@ -{ - "cells": [ - { - "cell_type": "code", - "execution_count": 1, - "metadata": {}, - "outputs": [], - "source": [ - "from ttl_to_html import load_ttl_from_url" - ] - }, - { - "cell_type": "code", - "execution_count": 2, - "metadata": {}, - "outputs": [], - "source": [ - "path = \"https://raw.githubusercontent.com/emmo-repo/domain-electrochemistry/master/electrochemicalquantities.ttl\"\n", - "g = load_ttl_from_url(path)" - ] - }, - { - "cell_type": "code", - "execution_count": 14, - "metadata": {}, - "outputs": [ - { - "data": { - "text/plain": [ - "[{'IRI': 'http://emmo.info/electrochemistry#electrochemistry_7fa406b0_512a_4d59_9e0c_5d8aba0103ae',\n", - " 'prefLabel': 'ActivationOverpotential',\n", - " 'Elucidation': 'Part of the electrode polarization arising from a charge-transfer step of the electrode reaction.',\n", - " 'Alternative Label(s)': 'ActivationPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-05',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_c955c089_6ee1_41a2_95fc_d534c5cfd3d5',\n", - " 'prefLabel': 'ActiveMaterialLoading',\n", - " 'Elucidation': 'Mass of active material in an electrode per unit electrode area.',\n", - " 'Alternative Label(s)': 'ActiveElectrochemicalMaterialLoading',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_214d925c_76c4_4f69_9afc_056a1ea82fc6',\n", - " 'prefLabel': 'AdsorptionCurrent',\n", - " 'Elucidation': 'Electric current that accompanies the adsorption of a species.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/A00159',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_26c84165_e6e3_47f6_8433_e04e755a4751',\n", - " 'prefLabel': 'AlternatingCurrent',\n", - " 'Elucidation': 'Electric current having a sinusoidal wave form that changes direction during a cycle.',\n", - " 'Alternative Label(s)': 'AC',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/A00252',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_39a44af0_0e1a_4859_b550_bdabad64386e',\n", - " 'prefLabel': 'AmbientThermodynamicTemperature',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_6e7c2081_284f_48f5_88fb_7d517243d4fa',\n", - " 'prefLabel': 'AmountPerAreaDimension',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_10eb778d_da60_4832_a355_4ee74baea650',\n", - " 'prefLabel': 'AmplitudeOfAlternatingCurrent',\n", - " 'Elucidation': 'Half the peak-to-peak amplitude of a sinusoidal alternating current.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.A00310',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'https://emmo.info/electrochemistry#electrochemistry_f591a444_89d6_4093_836d_7d53895edce4',\n", - " 'prefLabel': 'AmplitudeOfAlternatingVoltage',\n", - " 'Elucidation': 'Half of the peak-to-peak amplitude of a periodic voltage perturbation within a single time period, with respect to a reference potential value.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.A00311',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_565c0b10_70fe_441a_b76a_b9a8e08ca7b7',\n", - " 'prefLabel': 'AnodicOverpotential',\n", - " 'Elucidation': 'electrode polarization associated with an electrochemical oxidation reaction.',\n", - " 'Alternative Label(s)': 'AnodicPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-06',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_fa01b7ce_c398_45f7_be8b_31a6f6533767',\n", - " 'prefLabel': 'AppliedPotential',\n", - " 'Elucidation': 'Difference of electric potentials measured between identical metallic leads to two electrodes of an electrochemical cell.',\n", - " 'Alternative Label(s)': 'Voltage',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_bcb33f7e_5573_4bc2_b636_4ea313a9dd3a',\n", - " 'prefLabel': 'AreicCapacity',\n", - " 'Elucidation': 'Quotient of the capacity of a battery cell or battery by its plane area.',\n", - " 'Alternative Label(s)': 'ArealCapacity',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-20',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_269ddd97_1437_4545_b272_0df75a12c68a',\n", - " 'prefLabel': 'BaselineCellVoltage',\n", - " 'Elucidation': 'In electrochemical measurements, the voltage of an electrochemical cell to which a voltage signal is superimposed.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_c55bcb85_b7b8_4e67_8a78_9a42fe25b6cf',\n", - " 'prefLabel': 'CatalyticCurrent',\n", - " 'Elucidation': 'Faradaic current measured in a solution containing two electroactive substances, A and B, that exceeds the sum of the faradaic currents that would be obtained for A and B separately under the same experimental conditions.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_0853b072_3b80_4864_8147_24ce35407ade',\n", - " 'prefLabel': 'CathodicOverpotential',\n", - " 'Elucidation': 'electrode polarization associated with an electrochemical reduction reaction.',\n", - " 'Alternative Label(s)': 'CathodicPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-07',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_637ee9c4_4b3f_4d3a_975b_c0572dfe53ce',\n", - " 'prefLabel': 'CellCurrent',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_4ebe2ef1_eea8_4b10_822d_7a68215bd24d',\n", - " 'prefLabel': 'CellVoltage',\n", - " 'Elucidation': 'Voltage between the terminals of an electrochemical cell.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-10',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ce4126c1_a7a8_41ce_aff0_5bfb91d2ecea',\n", - " 'prefLabel': 'CellVolume',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_49efb72a_f8e6_4f50_acac_975302200d47',\n", - " 'prefLabel': 'ChargeRetention',\n", - " 'Elucidation': 'ability of a cell or battery to retain capacity on open circuit under specified conditions.',\n", - " 'Alternative Label(s)': 'CapacityRetention',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-35',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_a4dfa5c1_55a9_4285_b71d_90cf6613ca31',\n", - " 'prefLabel': 'ChargeTransferCoefficient',\n", - " 'Elucidation': 'The fraction of the electrostatic potential energy affecting the reduction rate in an electrode reaction, with the remaining fraction affecting the corresponding oxidation rate.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_79551e01_4bc6_4292_916e_08fe28a84600',\n", - " 'prefLabel': 'ChargingCurrent',\n", - " 'Elucidation': 'Electric current applied to a battery during its charge.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_9ed7210c_c4fa_467b_822d_ba12f885bdf4',\n", - " 'prefLabel': 'ConcentrationOverpotential',\n", - " 'Elucidation': 'The concentration overpotential of an electrode reaction at a given electrode current density (c.d.) is basically the difference in equilibrium potentials across the diffusion layer. More precisely, it is the potential of a reference electrode (of the same electrode reaction as the working electrode ) with the interfacial concentrations which establish themselves at c.d., relative to the potential of a similar reference electrode with the concentrations of the bulk solution. From such a measured potential difference, with c.d. flowing, one needs to subtract the ohmic potential drop prevailing between the two electrodes.',\n", - " 'Alternative Label(s)': 'ConcentrationPolarization, MassTransferOverpotential, MassTransferPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-08',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/C01230',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_8de9735b_374a_4a0f_b29f_71a50794cf94',\n", - " 'prefLabel': 'CrystalizationOverpotential',\n", - " 'Elucidation': 'part of the electrode polarization arising from crystal nucleation and growth phenomena.',\n", - " 'Alternative Label(s)': 'CrystalizationPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-04',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_71f10616_15eb_4dc4_bc8d_ffaac3838af2',\n", - " 'prefLabel': 'CurrentChangeLimit',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_76e7e556_f47e_47e2_b2ef_67aeed09c63e',\n", - " 'prefLabel': 'CurrentDensityLimit',\n", - " 'Elucidation': 'Maximum electric current density that can be achieved for an electrode reaction at a given concentration of a electrochemically active material in the presence of a large excess of supporting electrolyte.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-13',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_5696453c_9da7_41e2_bbda_603c1b90a8fc',\n", - " 'prefLabel': 'CurrentEfficiency',\n", - " 'Elucidation': 'Fraction of the electric current passing through an electrochemical cell which accomplishes the desired chemical reaction.',\n", - " 'Alternative Label(s)': 'CoulombicEfficiency, FaradayEfficiency',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-03-07',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_f046d602_22ea_4f9b_9101_319f510d39f0',\n", - " 'prefLabel': 'CurrentScanRate',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ae782b14_88ce_4cdd_9418_12aca00be937',\n", - " 'prefLabel': 'CycleLife',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': 'ElectrochemicalCycleLife',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e38f11d0_a16f_4fe8_8ec5_3fe4493b7759',\n", - " 'prefLabel': 'DiffuseLayerPotential',\n", - " 'Elucidation': 'Electric potential difference between the rigid layer and the diffuse layer of a double layer.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-20',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_17626b8e_dfce_4d3a_ae6c_5a7215d43a90',\n", - " 'prefLabel': 'DiffusionCurrent',\n", - " 'Elucidation': 'Faradaic current that is controlled by the rate at which electroactive species diffuse toward (or away from) and electrode-solution interface.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/D01722',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_5fb7a03f_d6dd_47ee_9317_0629681c7d00',\n", - " 'prefLabel': 'DiffusionLimitedCurrent',\n", - " 'Elucidation': 'Diffusion current of the potential-independent value that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion.',\n", - " 'Alternative Label(s)': 'LimitingDiffusionCurrent',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/L03534',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_37b24a94_cae0_4d7a_9519_9f7692dec607',\n", - " 'prefLabel': 'Diffusivity',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_885b462e_f6bc_412d_8b94_9425e13af0c7',\n", - " 'prefLabel': 'DirectCurrent',\n", - " 'Elucidation': 'ElectricCurrent that flows in a constant direction, i.e. a current with a constant sign.',\n", - " 'Alternative Label(s)': 'DC',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/D01767',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e4d666ee_d637_45cd_a904_dc33941ead4f',\n", - " 'prefLabel': 'DischargeCurrent',\n", - " 'Elucidation': 'Electric current delivered by a battery during its discharge.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-24',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_a56fc557_9dea_42e6_b936_e9d62dcaf84f',\n", - " 'prefLabel': 'DoubleLayerCurrent',\n", - " 'Elucidation': 'Non-faradaic current associated with the charging of the electrical double layer at the electrode-solution interface.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/D01847',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_4b18c3f9_df10_4259_adb4_cd10842ff0be',\n", - " 'prefLabel': 'DropTimeInPolarography',\n", - " 'Elucidation': 'The time that elapses between the instants at which two successive drops of liquid metal are detached from the tip of the capillary.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.D01862',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_791c1915_a791_4450_acd8_7f94764743b5',\n", - " 'prefLabel': 'ElectricChargeCapacity',\n", - " 'Elucidation': 'Amount of electric charge that can be stored.',\n", - " 'Alternative Label(s)': 'Capacity, ChargeCapacity',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_578dca29_729c_4131_8e37_a187472b1c37',\n", - " 'prefLabel': 'ElectricChargeCapacityDimension',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_061fd188_0552_4a53_8eb3_845aacc1bb5d',\n", - " 'prefLabel': 'ElectricChargeCapacityPerAreaDimension',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_38ee287e_ff33_49b7_8841_bfac8eff5d49',\n", - " 'prefLabel': 'ElectricPotentialPerTimeDimension',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_c5047d29_4e68_43ee_8355_3e8f05dc70a5',\n", - " 'prefLabel': 'ElectrochemicalControlQuantity',\n", - " 'Elucidation': 'Quantities that control electroanalytical measurements.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_21745019_2830_4395_bca7_15ddfd266673',\n", - " 'prefLabel': 'ElectrochemicalKineticQuantity',\n", - " 'Elucidation': 'An ElectrochemicalQuantity that relates to the kinetics of a reaction.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_02eb0465_4f94_453c_8c1f_5ddf80134634',\n", - " 'prefLabel': 'ElectrochemicalPerformanceQuantity',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_1422cde1_929e_46b6_b0dc_1010eebc5dfd',\n", - " 'prefLabel': 'ElectrochemicalPotential',\n", - " 'Elucidation': 'The electrochemical potential is the chemical potential of an ion in the presence of an electric potential.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/E01945',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_900e357f_2ee3_425a_a0b6_322661117787',\n", - " 'prefLabel': 'ElectrochemicalProperty',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_aecc6094_c6a5_4a36_a825_8a497a2ae112',\n", - " 'prefLabel': 'ElectrochemicalQuantity',\n", - " 'Elucidation': 'Physical quantities defined within the domain of electrochemistry.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_8f4b90ef_fea4_47c9_99f5_a9b3290a505d',\n", - " 'prefLabel': 'ElectrochemicalStabilityLimit',\n", - " 'Elucidation': 'Electric potential at which a material undergoes an oxidation or reduction decomposition.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_2d896559_eee3_447c_9759_87c854a4266a',\n", - " 'prefLabel': 'ElectrochemicalThermodynamicQuantity',\n", - " 'Elucidation': 'A thermodynamically derived ElectrochemicalQuantity.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_4a450a27_b84a_4c70_a3a9_15ec30e2f30b',\n", - " 'prefLabel': 'ElectrochemicalTransportQuantity',\n", - " 'Elucidation': 'An ElectrochemicalQuantity related to the transport of mass, charge, or energy.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_129926b6_fc30_441d_b359_29b44c988514',\n", - " 'prefLabel': 'ElectrochemicalWindow',\n", - " 'Elucidation': 'The electrode electric potential range between which the substance is neither oxidized nor reduced.',\n", - " 'Alternative Label(s)': 'ElectrochemicalStabilityWindow',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_bad1b6f4_1b26_40e2_b552_6d53873e3973',\n", - " 'prefLabel': 'ElectrochemicallyActiveSurfaceArea',\n", - " 'Elucidation': 'The area of the electrode material that is accessible to the electrolyte that is used for charge transfer and/or storage.',\n", - " 'Alternative Label(s)': 'EASA, ECSA',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_63a8f9d2_0cf6_484d_b996_2e5c3f0a3c73',\n", - " 'prefLabel': 'ElectrodeCoverageDensity',\n", - " 'Elucidation': 'Amount of a chemical modifier at an electrode surface per unit area.',\n", - " 'Alternative Label(s)': 'ElectrodeCoverage',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_fa7790d6_07bb_4b0f_9965_55966828f5f3',\n", - " 'prefLabel': 'ElectrodeGeometricSurfaceArea',\n", - " 'Elucidation': 'The interfacial area, determined on the assumption that the interface is truly flat (2-dimensional) and calculated using the geometric data of the involved surfaces.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_f509645f_eb27_470e_9112_7ab828ed40d3',\n", - " 'prefLabel': 'ElectrodePotential',\n", - " 'Elucidation': 'Electric potential at an electrode, reported as the difference in potential relative to a reference electrode.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-11',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/E01956',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_a82e16c3_b766_482f_be94_b8e9af37f6fc',\n", - " 'prefLabel': 'ElectrodeRealSurfaceArea',\n", - " 'Elucidation': 'Surface area of an electrode that takes into account non-idealities of the interface (roughness, porosity, etc.) and can be measured by a variety of electrochemical methods. The electroactive area is the area calculated from experiments with model electroactive species and may be different from the real surface area in cases where not all of the surface is electrochemically active or accessible.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_47ab1dad_cc09_4fd8_af23_acb36fb680dd',\n", - " 'prefLabel': 'ElectrodeSurfaceArea',\n", - " 'Elucidation': 'Area of electrode - solution interface.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_54e8cef6_b4cb_4560_947a_50811fa0f177',\n", - " 'prefLabel': 'ElectrolyteVolume',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_abfadc99_6e43_4d37_9b04_7fc5b0f327ae',\n", - " 'prefLabel': 'ElectronNumberOfAnElectrochemicalReaction',\n", - " 'Elucidation': 'Number of electrons transferred in a charge transfer reaction between an electrode and a single entity (ion, radical-ion, or molecule) of an electroactive substance, whose identity must be specified.',\n", - " 'Alternative Label(s)': 'ChargeNumber, NumberOfElectronsTransferred',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/C00995',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ce74d2dc_d496_4116_b2fb_3e83d88bc744',\n", - " 'prefLabel': 'ElectronicConductivity',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_d91940f0_c8b6_4505_9b68_6bf6cfc5c544',\n", - " 'prefLabel': 'EquilibriumElectrodePotential',\n", - " 'Elucidation': 'Potential of an electrode when no electric current flows through the cell and all local charge transfer equilibria across phase boundaries that are represented in the cell diagram (except at possible electrolyte-electrolyte junctions) and local chemical equilibria are established.',\n", - " 'Alternative Label(s)': 'EquilibriumPotential, NernstPotential, ReversiblePotential',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-12',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ccde24bb_790a_40ca_a06e_cea156a61031',\n", - " 'prefLabel': 'ExchangeCurrent',\n", - " 'Elucidation': 'The common value (i0) of the anodic and cathodic partial currents when the reaction is at equilibrium.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/E02238',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e9fd9ef9_adfe_46cb_b2f9_4558468a25e7',\n", - " 'prefLabel': 'ExchangeCurrentDensity',\n", - " 'Elucidation': 'Defined by j0 = i0/A, where i0 is the exchange current of the electrode reaction and A is usually taken as the geometric area of the electrode.',\n", - " 'Alternative Label(s)': 'MeanExchangeCurrentDensity',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/M03777',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_05cf26ef_782a_4f66_a196_7004dd973f8e',\n", - " 'prefLabel': 'ExternalSurfaceArea',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_2a2f59b7_aa16_40aa_9c8b_0de8a2720456',\n", - " 'prefLabel': 'FaradaicCurrent',\n", - " 'Elucidation': 'Electric current that results from the electrooxidation or electroreduction of an electroactive substance.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/F02321',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_77f9d496_555e_4ae2_ae80_f297ef8335ca',\n", - " 'prefLabel': 'FaradayConstant',\n", - " 'Elucidation': 'Fundamental physical constant representing molar elementary charge.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.F02325',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_b21de1ef_6c15_4d63_b320_c9b96fbf186f',\n", - " 'prefLabel': 'FormalElectrodePotential',\n", - " 'Elucidation': 'Equilibrium electrode potential under conditions of unit concentration of species involved in the electrode reaction.',\n", - " 'Alternative Label(s)': 'FormalPotential',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_c4d551db_db17_4c33_92e6_aec71638afbc',\n", - " 'prefLabel': 'HalfPeakPotential',\n", - " 'Elucidation': 'For dynamic voltammetric techniques, the electric potential of the working electrode at which the current is equal to one-half of the peak current.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.H02720',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_2ae53fc6_d44d_41c9_acaf_c5606e6a981d',\n", - " 'prefLabel': 'HalfWavePotential',\n", - " 'Elucidation': 'Electric potential of a steady-state voltammetric working electrode at the point, on the rising part of the voltammetric wave, where the current is equal to one-half of the limiting current.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_74861991_7da2_4e0f_b6c1_b16713f538bf',\n", - " 'prefLabel': 'InitialDischargeVoltage',\n", - " 'Elucidation': 'Discharge voltage of a cell or battery at the beginning of the discharge immediately after any transients have subsided.',\n", - " 'Alternative Label(s)': 'InitialClosedCircuitVoltage',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-29',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_9c9b80a4_a00b_4b91_8e17_3a7831f2bf2f',\n", - " 'prefLabel': 'InititalThermodynamicTemperature',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_a24f8581_a5a4_41a4_bb45_d0fdd5c0d810',\n", - " 'prefLabel': 'InstantaneousCurrent',\n", - " 'Elucidation': 'Value of an electric current at an instant in time, t.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/I03062',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_f94678d6_1386_48fc_8e54_024921924401',\n", - " 'prefLabel': 'InternalApparentResistance',\n", - " 'Elucidation': 'quotient of change of voltage of a battery by the corresponding change in discharge current under specified conditions.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-36',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_0c9655c6_6b0b_4819_a219_f286ad196fa9',\n", - " 'prefLabel': 'InternalConductance',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_9bf40017_3f58_4030_ada7_cb37a3dfda2d',\n", - " 'prefLabel': 'InternalResistance',\n", - " 'Elucidation': 'Impetance associated with a power source.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_25dabdc2_68bf_4a38_8cbe_11be017358bc',\n", - " 'prefLabel': 'IonicConductivity',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ff7797ed_9ef7_40d0_872b_2c215cd54578',\n", - " 'prefLabel': 'IsopotentialPoint',\n", - " 'Elucidation': 'Electric potential of an ion-selective electrode (ISE) and activity of an analyte ion at which the potential of the ISE is independent of temperature.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.I03304',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_98b6e9d7_d5df_46a5_87dd_79642b8b2e4b',\n", - " 'prefLabel': 'KineticCurrent',\n", - " 'Elucidation': 'Faradaic current of an electroactive substance B formed by a prior chemical reaction from another substance Y that is no electroactive at the potential at which B is electrochemically transformed.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/K03399',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_d5ac8868_d318_4065_aa23_72140ae888ae',\n", - " 'prefLabel': 'LimitingCurrent',\n", - " 'Elucidation': 'Faradaic current that is approached as the rate of the charge-transfer process is increased by varying the applied potential, being greater than the rate of mass transport controlled by diffusion.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/L03532',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_a17ee4e0_c81a_4a64_9ecb_9c6fa022cf4d',\n", - " 'prefLabel': 'LimitingMolarConductivity',\n", - " 'Elucidation': 'Molar conductivity at infinite dilution',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_534dd59c_904c_45d9_8550_ae9d2eb6bbc9',\n", - " 'prefLabel': 'LowerCutoffVoltage',\n", - " 'Elucidation': 'Specified voltage of a battery at which the battery discharge is terminated.',\n", - " 'Alternative Label(s)': 'CutOffVoltage, DischargeCutoffVoltage, EndOfDischargeVoltage, EndPointVoltage, FinalVoltage, LowerVoltageLimit',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-30',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_b66d6553_6136_4754_902a_707e414210c2',\n", - " 'prefLabel': 'LowerFrequencyLimit',\n", - " 'Elucidation': 'The lower end of the interval of frequencies tested in impedimetry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_7e53fa42_cf93_4d6e_b753_6f0ef3034648',\n", - " 'prefLabel': 'LowerVoltageLimit',\n", - " 'Elucidation': 'Minimum cell voltage limit at which an applied signal is reversed or terminated.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ba7ac581_0e13_4815_b888_013c378932f5',\n", - " 'prefLabel': 'MaxContinuousDischargeCurrent',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_3e54f9e3_a31d_4821_9bfb_ef953a42c35b',\n", - " 'prefLabel': 'MaxPulseDischargeCurrent',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_d5dc0c1d_0926_4268_89f0_4519a326eabc',\n", - " 'prefLabel': 'MaxPulseDischargeTime',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_47287d09_6108_45ca_ac65_8b9451b1065e',\n", - " 'prefLabel': 'MaximumConcentration',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_95ef8c3c_62fe_467f_b5d4_dd0cd18a7ea8',\n", - " 'prefLabel': 'MaximumStoichiometry',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e8e41092_cc75_4952_bc54_af1a72d19fcd',\n", - " 'prefLabel': 'MeasuredCapacity',\n", - " 'Elucidation': 'An electric charge capacity measured under a given set of experimental conditions.',\n", - " 'Alternative Label(s)': 'MeasuredElectricChargeCapacity',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_601ff226_59b9_460b_90f5_2593450d96fa',\n", - " 'prefLabel': 'MembranePotential',\n", - " 'Elucidation': 'Electric potential difference between two solutions separated by an ion-selective membrane in the absence of any electric current flowing through the membrane.',\n", - " 'Alternative Label(s)': 'Donnan potential, Membrane electromotive force',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.M03825',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_22cec04f_c7f3_4ff8_a34b_e512379c9dcb',\n", - " 'prefLabel': 'MigrationCurrent',\n", - " 'Elucidation': 'Component of electric current due to transport of ions in the electric field between the electrodes.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/M03921',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_86324806_4263_4d80_b5af_1a7be844ab5b',\n", - " 'prefLabel': 'MinimumStoichiometry',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_7fe804b8_6126_4132_be8f_b4985d61b1f6',\n", - " 'prefLabel': 'MolarElectrochemicalPotential',\n", - " 'Elucidation': 'ElectrochemicalPotential per mole.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/E01945',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_14577b99_a8a9_4358_9bc5_ab8c401dd34b',\n", - " 'prefLabel': 'NetFaradaicCurrent',\n", - " 'Elucidation': 'Algebraic sum of faradaic currents flowing through an electrode.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_870c5c54_0764_454b_b43c_35cefd00d42c',\n", - " 'prefLabel': 'NominalConcentration',\n", - " 'Elucidation': 'The set concentration.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_482173dc_7779_4f12_982c_b19f2cda2dac',\n", - " 'prefLabel': 'NumberOfCellsConnectedInParallel',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_9d6a52ed_a53d_4327_a391_f173677a4b1d',\n", - " 'prefLabel': 'NumberOfCellsConnectedInSeries',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_03a6ce70_5085_4683_bb4e_fc3c18f7143a',\n", - " 'prefLabel': 'OhmicOverpotential',\n", - " 'Elucidation': 'part of the electrode polarization arising from an electric current through an ohmic resistance within the electrode or the electrolyte.',\n", - " 'Alternative Label(s)': 'OhmicOvervoltage, OhmicPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-09',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_9c657fdc_b9d3_4964_907c_f9a6e8c5f52b',\n", - " 'prefLabel': 'OpenCircuitVoltage',\n", - " 'Elucidation': 'Electrode potential of working electrode relative to the reference electrode when no potential or electric current is being applied to the electrochemical cell.',\n", - " 'Alternative Label(s)': 'OpenCircuitPotential',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-32',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_1cd1d777_e67b_47eb_81f1_edac35d9f2c6',\n", - " 'prefLabel': 'Overpotential',\n", - " 'Elucidation': 'Electrode potential (E) minus the equilibrium electrode potential (Eeq) of an electrochemical reaction.',\n", - " 'Alternative Label(s)': 'ElectrodePolarization, Overvoltage, PolarizationPotential',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-02',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/O04358',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_b92e382f_5109_4f60_ab5e_c89d340419a9',\n", - " 'prefLabel': 'ParticleRadius',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_382b10dc_83aa_4e77_a1d5_1edd06fd1e05',\n", - " 'prefLabel': 'PeakCurrent',\n", - " 'Elucidation': 'In dynamic voltammetric techniques, the maximum value of the faradaic current attained by varying the applied potential in the current-potential or I-E curve.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/P04457',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e4a221e0_afc9_4464_91d4_e0c8ecdf79e8',\n", - " 'prefLabel': 'PeakPotential',\n", - " 'Elucidation': 'Electrode potential of the working electrode at which the peak current is attained.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.P04464',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_16a5de33_a2ca_4563_80d4_6caeb08d97ca',\n", - " 'prefLabel': 'Polarity',\n", - " 'Elucidation': 'nominal property of an electrode, having values negative or positive according to the sign of the electrode potential, or neutral when the electrode potential is zero.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-14',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_264f40d1_17c9_4bc7_9c47_5cfb18132278',\n", - " 'prefLabel': 'PotentialScanRate',\n", - " 'Elucidation': 'The rate of change of applied potential with time.',\n", - " 'Alternative Label(s)': 'PotentialSweepRate, ScanRate, SweepRate',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_136744ff_0563_4df7_aa03_4219d70392a0',\n", - " 'prefLabel': 'PotentiometricSelectivityCoefficient',\n", - " 'Elucidation': 'Parameter defining the ability of an ion-selective electrode to distinguish a particular ion, i.e., a primary ion A from an interfering ion B.',\n", - " 'Alternative Label(s)': 'SelectivityCoefficient, SelectivityConstant, SelectivityFactor',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.P04791',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_3cd0e74e_292c_48ed_a831_4cb8753d9a56',\n", - " 'prefLabel': 'PulseDuration',\n", - " 'Elucidation': 'Time interval during which the excitation signal deviates from the base line in normal pulse voltamme- try, differential pulse voltammetry, and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.P04947',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_762ba55f_9b56_4c31_865f_cff2e7d0a94b',\n", - " 'prefLabel': 'PulseMagnitude',\n", - " 'Elucidation': 'A single value, for instance a mean, root mean square or peak value characterizing the aggregate instantaneous values of a unidirectional pulse with respect to the common initial and final value.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=702-03-03',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_346519a4_006c_496d_8f36_74e38814ed2d',\n", - " 'prefLabel': 'PulseMagnitudeCurrent',\n", - " 'Elucidation': 'The magnitude of a current pulse applied to an electrochemical cell during pulsed potentiometry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'https://emmo.info/electrochemistry#electrochemistry_4d2b102b_3515_4591_b079_69232c44f9dc',\n", - " 'prefLabel': 'PulseMagnitudePotential',\n", - " 'Elucidation': 'The magnitude of a voltage pulse applied to an electrochemical cell during pulsed amperometry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_2705525b_7512_48bf_825b_f2d0409bede4',\n", - " 'prefLabel': 'QuarterTransitionTimePotential',\n", - " 'Elucidation': 'Electric potential of the indicator electrode, in chronopotentiometry at constant current, at the instant when the time that has elapsed since the application of current is equal to one-fourth of the transition time.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_f4fadc4e_ca7d_4e4e_89cf_eacf45b4041e',\n", - " 'prefLabel': 'ReactionOverpotential',\n", - " 'Elucidation': 'part of the electrode polarization arising from a chemical reaction impeding the electrode reaction.',\n", - " 'Alternative Label(s)': 'ReactionOvervoltage, ReactionPolarization',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-10',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_0335e3f6_d1d8_4daa_8376_a9285f1bc9f1',\n", - " 'prefLabel': 'ReactionRateConstant',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_db40df7e_1aa5_49a7_85cb_2aa2c1c70489',\n", - " 'prefLabel': 'ReferenceThermodynamicTemperature',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_526bf81a_0572_49ff_a8cc_85efc343c1c2',\n", - " 'prefLabel': 'ResidualActiveMass',\n", - " 'Elucidation': 'charged active material remaining in a cell following a discharge to a specified end-of-discharge voltage.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-37',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_d47985f1_6bd7_4c4f_894f_13a6cab38bb5',\n", - " 'prefLabel': 'ResidualCapacity',\n", - " 'Elucidation': 'Electric charge capacity remaining in a cell or battery following a discharge, operation or storage under specific test conditions.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-16',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_07e219c3_890f_488f_bd96_bee8e445d764',\n", - " 'prefLabel': 'ResidualCurrent',\n", - " 'Elucidation': 'Electric current that flows, at a particular value of the applied potential, in the absence of the substance whose electrode behaviour is being investigated, i.e. a \"blank\" solution.',\n", - " 'Alternative Label(s)': 'BackgroundCurrent',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/R05311',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_1a104474_c326_4a29_ac26_26a05ac8f72c',\n", - " 'prefLabel': 'ResponseTimeAtAnISE',\n", - " 'Elucidation': 'Duration between the time when an ion-selective electrode and an external reference electrode (the two completing the ion-selective electrode cell) are brought into contact with a sample solution (or the time at which the activity of the ion of interest in solution is changed) and the first time at which the slope of the cell potential vs. time plot (ΔE/Δt) becomes equal to a limiting value selected on the basis of the experimental conditions and/or requirements concerning accuracy.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_2678a656_4a27_4706_8dde_b0a93e9b92fa',\n", - " 'prefLabel': 'RestingTime',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_1900143f_cbc0_415f_9057_9382022a7bfe',\n", - " 'prefLabel': 'RotatingDiskSpeed',\n", - " 'Elucidation': 'Rotational frequency of a rotating component in a rotating disk electrode.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_52ac73c7_763c_4fda_93cd_a2db9dfc2dab',\n", - " 'prefLabel': 'SamplingInterval',\n", - " 'Elucidation': 'Time interval during which the current is measured in pulse voltammetry.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.S05465',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ecb6dfdf_bd3d_4339_8a1c_d32abbef30ba',\n", - " 'prefLabel': 'SamplingTime',\n", - " 'Elucidation': 'Duration of the sampling interval in pulse voltammetry.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.S05467',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_4b62d40a_8e17_47cb_b169_32e7c48233fc',\n", - " 'prefLabel': 'SetCurrent',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_8427071b_3a01_44b8_9090_5ae0d98675b5',\n", - " 'prefLabel': 'SetVoltage',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'https://emmo.info/electrochemistry#electrochemistry_68059d94_4c21_4065_b329_07faeebc7e87',\n", - " 'prefLabel': 'SignalReferencePotential',\n", - " 'Elucidation': 'Potential to which the magnitude of an excitation signal is compared to.',\n", - " 'Alternative Label(s)': 'BaselinePotential',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_1e3dc60d_dd6b_47d6_8161_70004fc5ee30',\n", - " 'prefLabel': 'SpecificCapacity',\n", - " 'Elucidation': 'quotient of the capacity of a battery, cell, electrode, or active material by its mass.',\n", - " 'Alternative Label(s)': 'GravimetricCapacity, SpecificChargeCapacity, SpecificElectricChargeCapacity',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-19',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_327eb3e1_f74a_4076_96de_5a2e3f63cb65',\n", - " 'prefLabel': 'SquareWaveCurrent',\n", - " 'Elucidation': 'Component of an electric current that is associated with the presence of an analyate in square-wave voltammetry.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/S05897',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_7fc10197_41d9_4c1e_a107_928f03eb2d36',\n", - " 'prefLabel': 'StandardElectrodePotential',\n", - " 'Elucidation': 'Equilibrium electrode potential of an electrode under standard conditions.',\n", - " 'Alternative Label(s)': 'StandardPotential',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=114-02-13',\n", - " 'IUPAC Reference': 'https://goldbook.iupac.org/terms/view/S05912',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_85e39686_9658_4c74_bb91_a935704c174a',\n", - " 'prefLabel': 'StepDuration',\n", - " 'Elucidation': 'The duration between two consecutive steps in a staircase signal.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_d78b696d_9832_4352_a264_28a2ea7d82e4',\n", - " 'prefLabel': 'StepIndex',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_6769536b_5320_4b48_a2d8_ac285ec635a8',\n", - " 'prefLabel': 'StepSignalCurrent',\n", - " 'Elucidation': 'The magnitude of the current step in chronopotentiometry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_0bf1ed19_2fc9_4e6d_87ec_62015985a9a6',\n", - " 'prefLabel': 'StepSignalVoltage',\n", - " 'Elucidation': 'The magnitude of the voltage step in step voltammetry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_f0667139_6428_4e3d_ac0d_08c1dd7f36ea',\n", - " 'prefLabel': 'Stoichiometry',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_7f381c19_cf07_47a8_ab10_0b14d46901e8',\n", - " 'prefLabel': 'SurfaceAreaPerVolume',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_60741c58_a10d_4aa6_bb68_0066a6ff8e30',\n", - " 'prefLabel': 'SurfaceOverpotential',\n", - " 'Elucidation': 'The potential of a working electrode relative to a reference electrode of the same kinds placed in the solution adjacent to the surface of the working electrode (just outside the double layer).',\n", - " 'Alternative Label(s)': 'SurfacePolarization',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_8f3ab19f_ce22_424e_a9bf_d5cedb815374',\n", - " 'prefLabel': 'TemperatureCoefficientOfTheCapacity',\n", - " 'Elucidation': 'quotient of the change in capacity of a cell by the corresponding change in temperature.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-18',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_3bb5ae23_59fa_4bc7_9495_803eb6719f28',\n", - " 'prefLabel': 'TemperatureCoefficientOfTheOpenCircuitVoltage',\n", - " 'Elucidation': 'quotient of change in open-circuit voltage of a cell or battery by the corresponding change in temperature.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-33',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_27b3799c_250c_4332_8b71_7992c4a7bb05',\n", - " 'prefLabel': 'TestTime',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_b7781ebc_90a7_4f19_997f_aed28dee1b01',\n", - " 'prefLabel': 'TheoreticalCapacity',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': 'TheoreticalChargeCapacity',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_ae9882de_d6a2_4525_a84f_80947c10f1cb',\n", - " 'prefLabel': 'TransitionTime',\n", - " 'Elucidation': 'In chronopotentiometry and related techniques, the duration between the application of current and when the concentration of an electroactive substance at the electrode-solution interface becomes indistinguishable from zero.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'https://doi.org/10.1351/goldbook.T06472',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_0ffa4bda_8a52_471a_a59d_f27cf8caecbb',\n", - " 'prefLabel': 'TransportEfficiency',\n", - " 'Elucidation': 'None',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_6dcd5baf_58cd_43f5_a692_51508e036c88',\n", - " 'prefLabel': 'UpperCutoffVoltage',\n", - " 'Elucidation': 'voltage attained at the end of a charging step, at a specified constant current .',\n", - " 'Alternative Label(s)': 'EndOfChargeVoltage',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-05-55',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_666f0b69_9c74_49a3_80b3_96a188332462',\n", - " 'prefLabel': 'UpperFrequencyLimit',\n", - " 'Elucidation': 'The higher end of the interval of frequencies tested in impedimetry and related techniques.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_88d6d177_4b76_4b0a_9a65_aef6592cdb8f',\n", - " 'prefLabel': 'UpperVoltageLimit',\n", - " 'Elucidation': 'Maximum cell voltage limit at which an applied signal is reversed or terminated.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_09e64707_a17d_4405_84cc_ee9d91ed32ef',\n", - " 'prefLabel': 'VoltageChangeLimit',\n", - " 'Elucidation': 'In CCCV methods, the cell voltage at which the constant current mode switches to constant voltage mode.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_e6b63190_acac_4e78_9cba_fb2b10bbe910',\n", - " 'prefLabel': 'VolumetricCapacity',\n", - " 'Elucidation': 'quotient of the capacity of a cell or battery by its volume.',\n", - " 'Alternative Label(s)': 'VolumetricChargeCapacity, VolumetricElectricChargeCapacity',\n", - " 'IEC Reference': 'https://www.electropedia.org/iev/iev.nsf/display?openform&ievref=482-03-17',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'},\n", - " {'IRI': 'http://emmo.info/electrochemistry#electrochemistry_c39b2498_783e_48e1_9814_6164bd99823c',\n", - " 'prefLabel': 'WorkingPotentialRange',\n", - " 'Elucidation': 'Range of electrode potentials of a given working electrode in a given electrolyte, where the electric current from reactions of the electrode or electrolyte is negligible compared with the current from reactions of the system under investigation.',\n", - " 'Alternative Label(s)': '',\n", - " 'IEC Reference': 'None',\n", - " 'IUPAC Reference': 'None',\n", - " 'Wikipedia Reference': 'None'}]" - ] - }, - "execution_count": 14, - "metadata": {}, - "output_type": "execute_result" - } - ], - "source": [ - "PREFIXES = \"\"\"\n", - " PREFIX emmo: \n", - " PREFIX skos: \n", - " \"\"\"\n", - "\n", - "\n", - "query = PREFIXES + \"\"\"\n", - " SELECT ?iri ?prefLabel ?elucidation (GROUP_CONCAT(?altLabel; SEPARATOR=\", \") AS ?altLabels) ?iecref ?iupacref ?wikipediaref\n", - " WHERE {\n", - " ?iri skos:prefLabel ?prefLabel.\n", - "\n", - " OPTIONAL { ?iri emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ?elucidation . }\n", - " OPTIONAL { ?iri skos:altLabel ?altLabel . }\n", - " OPTIONAL { ?iri emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f ?iecref . }\n", - " OPTIONAL { ?iri emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 ?iupacref . }\n", - " }\n", - "\n", - " GROUP BY ?iri ?prefLabel ?elucidation\n", - "\n", - " \"\"\"\n", - "\n", - "list_entity_types = [\"IRI\", \"prefLabel\", \"Elucidation\", \"Alternative Label(s)\", \"IEC Reference\", \"IUPAC Reference\", \"Wikipedia Reference\"]\n", - "text_entities = []\n", - "\n", - "qres = g.query(query)\n", - "\n", - "for hit in qres: \n", - " hit_dict = {entity_type:str(entity) for entity_type, entity in zip(list_entity_types, hit)}\n", - " text_entities.append(hit_dict)\n", - "\n", - " text_entities.sort(key=lambda e: e[\"prefLabel\"])\n", - "text_entities" - ] - }, - { - "cell_type": "code", - "execution_count": 12, - "metadata": {}, - "outputs": [ - { - "data": { - "text/plain": [ - "'OhmicOvervoltage, OhmicPolarization'" - ] - }, - "execution_count": 12, - "metadata": {}, - "output_type": "execute_result" - } - ], - "source": [ - "tata = list(qres)[2]\n", - "str(tata[3])" - ] - } - ], - "metadata": { - "kernelspec": { - "display_name": "venv-ontoapps", - "language": "python", - "name": "python3" - }, - "language_info": { - "codemirror_mode": { - "name": "ipython", - "version": 3 - }, - "file_extension": ".py", - "mimetype": "text/x-python", - "name": "python", - "nbconvert_exporter": "python", - "pygments_lexer": "ipython3", - "version": "3.10.6" - }, - "orig_nbformat": 4 - }, - "nbformat": 4, - "nbformat_minor": 2 -} diff --git a/_deprecate/docs/scripts/todo.md b/_deprecate/docs/scripts/todo.md deleted file mode 100644 index ea66198..0000000 --- a/_deprecate/docs/scripts/todo.md +++ /dev/null @@ -1,7 +0,0 @@ -# To do -* Anchors are in place, but the redirection system needs to be defined. - * What to use as anchor: the full IRI, or just the suffix? This implementation assumes that the document has a common prefix, so that anchors are the IRI suffixes. - -* Test github pages deployment - -* Set up github workflows \ No newline at end of file diff --git a/_deprecate/docs/scripts/ttl_to_context.py b/_deprecate/docs/scripts/ttl_to_context.py deleted file mode 100644 index f7956d6..0000000 --- a/_deprecate/docs/scripts/ttl_to_context.py +++ /dev/null @@ -1,96 +0,0 @@ -import rdflib -from rdflib.namespace import RDF, OWL, SKOS -import json -import os -from urllib.parse import urljoin -from urllib.request import pathname2url -import warnings - - -def generate_jsonld_context(ttl_file, predicate_uri, label_uri='http://www.w3.org/2000/01/rdf-schema#label'): - """ - Generate a JSON-LD context file from a Turtle file. - - Args: - - ttl_file: Path to the Turtle (.ttl) file. - - predicate_uri: The URI of the predicate to map to JSON-LD. - - label_uri: The URI for the label (default is rdfs:label). - - Returns: - - A Python dictionary representing the JSON-LD context. - """ - g = rdflib.Graph() - g.parse(ttl_file, format='ttl') - - CHAMEO = rdflib.Namespace("https://w3id.org/emmo/domain/chameo#") - g.bind('chameo', CHAMEO) - - context = {} - object_properties = {} - other_entries = {} - namespace_prefixes= {} - predicate = rdflib.URIRef(predicate_uri) - label = rdflib.URIRef(label_uri) - existing_keys = set() - - for s, p, o in g: - if (s, RDF.type, OWL.ObjectProperty) in g: - # If the subject is an OWL.ObjectProperty - label_value = g.value(s, SKOS.prefLabel) - if label_value: - object_properties[str(label_value)] = { - "@id": str(s), - "@type": "@id" - } - - - elif p == predicate: - # Normal context entry - # Use the label as key if it exists - #label_value = g.value(s, label) if g.value(s, label) else str(s) - label_value = str(s) - other_entries[str(o)] = str(label_value) - - - # Add namespace prefixes to the context - for prefix, uri in g.namespace_manager.namespaces(): - if len(prefix) >= 2: - namespace_prefixes[prefix] = str(uri) - - # Sort the entries alphabetically - sorted_object_properties = dict(sorted(object_properties.items())) - sorted_other_entries = dict(sorted(other_entries.items())) - sorted_namespace_prefixes = dict(sorted(namespace_prefixes.items())) - - # Merge the sorted entries - context = { - "@context": { - **sorted_namespace_prefixes, - **sorted_object_properties, - **sorted_other_entries - } - } - - print("Namespaces:") - for prefix, uri in g.namespace_manager.namespaces(): - print(f"{prefix}: {uri}") - - - return context - - -# Example usage -filename = 'electrochemistry-inferred.ttl' -script_dir = os.path.dirname(os.path.abspath(__file__)) -file_path = os.path.join(script_dir, filename) - -# Convert the file path to a file URI -file_uri = urljoin('file:', pathname2url(file_path)) - -predicate_uri = 'http://www.w3.org/2004/02/skos/core#prefLabel' -context = generate_jsonld_context(file_uri, predicate_uri) - -# Save to JSON file -with open('context.json', 'w') as f: - json.dump(context, f, indent=4) - diff --git a/_deprecate/docs/scripts/ttl_to_html.py b/_deprecate/docs/scripts/ttl_to_html.py deleted file mode 100644 index 78f79e1..0000000 --- a/_deprecate/docs/scripts/ttl_to_html.py +++ /dev/null @@ -1,169 +0,0 @@ -from rdflib import Graph - - - -########## LOAD TTL ################ - - -def load_ttl_from_url(url:str)->Graph: - g = Graph() - g.parse(url, format="turtle") - return g - - - - -########## QUERY TLL ################ - -def extract_terms_info_sparql(g: Graph)-> list: - - text_entities = [] - - # SPARQL QUERY # - PREFIXES = """ - PREFIX emmo: - PREFIX skos: - """ - - list_entity_types = ["IRI", "prefLabel", "Elucidation", "Alternative Label(s)", "IEC Reference", "IUPAC Reference", "Wikipedia Reference"] - - query = PREFIXES + """ - SELECT ?iri ?prefLabel ?elucidation (GROUP_CONCAT(?altLabel; SEPARATOR=", ") AS ?altLabels) ?iecref ?iupacref ?wikipediaref - WHERE { - ?iri skos:prefLabel ?prefLabel. - - OPTIONAL { ?iri emmo:EMMO_967080e5_2f42_4eb2_a3a9_c58143e835f9 ?elucidation . } - OPTIONAL { ?iri skos:altLabel ?altLabel . } - OPTIONAL { ?iri emmo:EMMO_50c298c2_55a2_4068_b3ac_4e948c33181f ?iecref . } - OPTIONAL { ?iri emmo:EMMO_fe015383_afb3_44a6_ae86_043628697aa2 ?iupacref . } - OPTIONAL { ?iri emmo:EMMO_c84c6752_6d64_48cc_9500_e54a3c34898d ?wikipediaref . } - } - - GROUP BY ?iri ?prefLabel ?elucidation - - """ - - qres = g.query(query) - - for hit in qres: - hit_dict = {entity_type:str(entity) for entity_type, entity in zip(list_entity_types, hit)} - text_entities.append(hit_dict) - - text_entities.sort(key=lambda e: e["prefLabel"]) - - return text_entities - - - - - -########## RENDER HTML TOP ################ - -def render_html_top() -> str: - - top_html = """ - - - - - BattINFO - - - - - """ - - banner = ''' - - ''' - - return top_html + banner - - - - -########## RENDER ENTITIES ################ - -def entities_to_html(entities: list[dict]) -> str: - - html = "" - - for item in entities: - - iri_prefix, iri_suffix = item['IRI'].split("#") - - html += f"""

{item['prefLabel']}

""" - #html += f"""

{item['IRI']}

""" - html += f"""

{item['IRI']}

""" - - for key, value in item.items(): - - if (key not in ['IRI', 'prefLabel']) & (value != "None") & (value != ""): - - if value.startswith("http"): - html += f"""

{key}: {value}

""" - else: - html += f"""

{key}: {value}

""" - - html += "
\n" - - return html - - - - -########## RENDER HTML BOTTOM ################ - -def render_html_bottom() -> str: - return """ - - - """ - - - -########### RUN THE RENDERING WORKFLOW ############## - -def rendering_workflow(): - - # PAGES - - ttl_modules = [ - {"section title":"Quantities used in Electrochemistry", - "path":"./electrochemicalquantities.ttl"}, - - {"section title":"Electrochemistry Concepts", - "path":"./electrochemistry.ttl"} - ] - - - - # GENERATE PAGES - html_filename = "electrochemistry.html" - - html = render_html_top() - - for module in ttl_modules: - - g = load_ttl_from_url(module["path"]) - - entities_list = extract_terms_info_sparql(g) - - page_title = module["section title"] - html += f"

{page_title}

\n" - html += entities_to_html(entities_list) - - html += render_html_bottom() - - with open("./docs/"+ html_filename, "w", encoding="utf-8") as f: - f.write(html) - - - -if __name__ == "__main__": - - rendering_workflow() \ No newline at end of file diff --git a/sphinx/.gitignore b/docs/.gitignore similarity index 100% rename from sphinx/.gitignore rename to docs/.gitignore diff --git a/sphinx/Makefile b/docs/Makefile similarity index 100% rename from sphinx/Makefile rename to docs/Makefile diff --git a/sphinx/README.org b/docs/README.org similarity index 100% rename from sphinx/README.org rename to docs/README.org diff --git a/sphinx/_static/css/custom.css b/docs/_static/css/custom.css similarity index 100% rename from sphinx/_static/css/custom.css rename to docs/_static/css/custom.css diff --git a/sphinx/about.rst b/docs/about.rst similarity index 100% rename from sphinx/about.rst rename to docs/about.rst diff --git a/sphinx/assets/data/example-cyclic-voltammetry.csv b/docs/assets/data/example-cyclic-voltammetry.csv similarity index 100% rename from sphinx/assets/data/example-cyclic-voltammetry.csv rename to docs/assets/data/example-cyclic-voltammetry.csv diff --git a/sphinx/assets/data/example-eis-nyquist.csv b/docs/assets/data/example-eis-nyquist.csv similarity index 100% rename from sphinx/assets/data/example-eis-nyquist.csv rename to docs/assets/data/example-eis-nyquist.csv diff --git a/sphinx/assets/jsonld/example_electrochemical_cell.json b/docs/assets/jsonld/example_electrochemical_cell.json similarity index 100% rename from sphinx/assets/jsonld/example_electrochemical_cell.json rename to docs/assets/jsonld/example_electrochemical_cell.json diff --git a/sphinx/conf.py b/docs/conf.py similarity index 100% rename from sphinx/conf.py rename to docs/conf.py diff --git a/sphinx/contribute.rst b/docs/contribute.rst similarity index 100% rename from sphinx/contribute.rst rename to docs/contribute.rst diff --git a/sphinx/electrochemistry.rst b/docs/electrochemistry.rst similarity index 100% rename from sphinx/electrochemistry.rst rename to docs/electrochemistry.rst diff --git a/sphinx/example_alkaline_electrochemical_cell.rst b/docs/example_alkaline_electrochemical_cell.rst similarity index 100% rename from sphinx/example_alkaline_electrochemical_cell.rst rename to docs/example_alkaline_electrochemical_cell.rst diff --git a/sphinx/example_aqueous_electrolyte_KOH.rst b/docs/example_aqueous_electrolyte_KOH.rst similarity index 100% rename from sphinx/example_aqueous_electrolyte_KOH.rst rename to docs/example_aqueous_electrolyte_KOH.rst diff --git a/sphinx/example_cyclic_voltammetry.rst b/docs/example_cyclic_voltammetry.rst similarity index 100% rename from sphinx/example_cyclic_voltammetry.rst rename to docs/example_cyclic_voltammetry.rst diff --git a/sphinx/example_eis_nyquist.rst b/docs/example_eis_nyquist.rst similarity index 100% rename from sphinx/example_eis_nyquist.rst rename to docs/example_eis_nyquist.rst diff --git a/sphinx/example_linked_data_zinc_powder.ipynb b/docs/example_linked_data_zinc_powder.ipynb similarity index 100% rename from sphinx/example_linked_data_zinc_powder.ipynb rename to docs/example_linked_data_zinc_powder.ipynb diff --git a/sphinx/example_person_jsonld_nb.ipynb b/docs/example_person_jsonld_nb.ipynb similarity index 100% rename from sphinx/example_person_jsonld_nb.ipynb rename to docs/example_person_jsonld_nb.ipynb diff --git a/sphinx/example_zinc_electrode.rst b/docs/example_zinc_electrode.rst similarity index 100% rename from sphinx/example_zinc_electrode.rst rename to docs/example_zinc_electrode.rst diff --git a/sphinx/example_zinc_powder.rst b/docs/example_zinc_powder.rst similarity index 100% rename from sphinx/example_zinc_powder.rst rename to docs/example_zinc_powder.rst diff --git a/sphinx/examples.rst b/docs/examples.rst similarity index 100% rename from sphinx/examples.rst rename to docs/examples.rst diff --git a/sphinx/faq.rst b/docs/faq.rst similarity index 100% rename from sphinx/faq.rst rename to docs/faq.rst diff --git a/sphinx/getstarted.rst b/docs/getstarted.rst similarity index 100% rename from sphinx/getstarted.rst rename to docs/getstarted.rst diff --git a/sphinx/img/ElectrochemicalCell.svg b/docs/img/ElectrochemicalCell.svg similarity index 100% rename from sphinx/img/ElectrochemicalCell.svg rename to docs/img/ElectrochemicalCell.svg diff --git a/sphinx/img/battinfologo.ico b/docs/img/battinfologo.ico similarity index 100% rename from sphinx/img/battinfologo.ico rename to docs/img/battinfologo.ico diff --git a/sphinx/img/battinfologo.jpg b/docs/img/battinfologo.jpg similarity index 100% rename from sphinx/img/battinfologo.jpg rename to docs/img/battinfologo.jpg diff --git a/sphinx/index.rst b/docs/index.rst similarity index 100% rename from sphinx/index.rst rename to docs/index.rst diff --git a/sphinx/make.bat b/docs/make.bat similarity index 95% rename from sphinx/make.bat rename to docs/make.bat index 153be5e..8084272 100644 --- a/sphinx/make.bat +++ b/docs/make.bat @@ -1,35 +1,35 @@ -@ECHO OFF - -pushd %~dp0 - -REM Command file for Sphinx documentation - -if "%SPHINXBUILD%" == "" ( - set SPHINXBUILD=sphinx-build -) -set SOURCEDIR=. -set BUILDDIR=_build - -if "%1" == "" goto help - -%SPHINXBUILD% >NUL 2>NUL -if errorlevel 9009 ( - echo. - echo.The 'sphinx-build' command was not found. Make sure you have Sphinx - echo.installed, then set the SPHINXBUILD environment variable to point - echo.to the full path of the 'sphinx-build' executable. Alternatively you - echo.may add the Sphinx directory to PATH. - echo. - echo.If you don't have Sphinx installed, grab it from - echo.https://www.sphinx-doc.org/ - exit /b 1 -) - -%SPHINXBUILD% -M %1 %SOURCEDIR% %BUILDDIR% %SPHINXOPTS% %O% -goto end - -:help -%SPHINXBUILD% -M help %SOURCEDIR% %BUILDDIR% %SPHINXOPTS% %O% - -:end -popd +@ECHO OFF + +pushd %~dp0 + +REM Command file for Sphinx documentation + +if "%SPHINXBUILD%" == "" ( + set SPHINXBUILD=sphinx-build +) +set SOURCEDIR=. +set BUILDDIR=_build + +if "%1" == "" goto help + +%SPHINXBUILD% >NUL 2>NUL +if errorlevel 9009 ( + echo. + echo.The 'sphinx-build' command was not found. Make sure you have Sphinx + echo.installed, then set the SPHINXBUILD environment variable to point + echo.to the full path of the 'sphinx-build' executable. Alternatively you + echo.may add the Sphinx directory to PATH. + echo. + echo.If you don't have Sphinx installed, grab it from + echo.https://www.sphinx-doc.org/ + exit /b 1 +) + +%SPHINXBUILD% -M %1 %SOURCEDIR% %BUILDDIR% %SPHINXOPTS% %O% +goto end + +:help +%SPHINXBUILD% -M help %SOURCEDIR% %BUILDDIR% %SPHINXOPTS% %O% + +:end +popd diff --git a/sphinx/requirements.txt b/docs/requirements.txt similarity index 100% rename from sphinx/requirements.txt rename to docs/requirements.txt diff --git a/sphinx/resources.rst b/docs/resources.rst similarity index 100% rename from sphinx/resources.rst rename to docs/resources.rst diff --git a/sphinx/tools.rst b/docs/tools.rst similarity index 100% rename from sphinx/tools.rst rename to docs/tools.rst diff --git a/sphinx/ttl_to_context.py b/docs/ttl_to_context.py similarity index 100% rename from sphinx/ttl_to_context.py rename to docs/ttl_to_context.py diff --git a/sphinx/ttl_to_rst.py b/docs/ttl_to_rst.py similarity index 98% rename from sphinx/ttl_to_rst.py rename to docs/ttl_to_rst.py index 6a44fc8..3a6f020 100644 --- a/sphinx/ttl_to_rst.py +++ b/docs/ttl_to_rst.py @@ -166,7 +166,7 @@ def rendering_workflow(): rst += render_rst_bottom() - with open("./sphinx/"+ rst_filename, "w+", encoding="utf-8") as f: + with open("./docs/"+ rst_filename, "w+", encoding="utf-8") as f: f.write(rst) diff --git a/sphinx/util.el b/docs/util.el similarity index 100% rename from sphinx/util.el rename to docs/util.el