diff --git a/h_transport_materials/property_database/tungsten/tungsten.py b/h_transport_materials/property_database/tungsten/tungsten.py index 32fc2e7..5f431c1 100644 --- a/h_transport_materials/property_database/tungsten/tungsten.py +++ b/h_transport_materials/property_database/tungsten/tungsten.py @@ -66,9 +66,7 @@ moore_diffusivity_tungsten_h = Diffusivity( data_T=[1783.0, 1890.0, 1960.0, 2045.0, 2175.0] * u.K, - data_y=np.array([6.45e-9, 1.26e-8, 1.81e-8, 3.01e-8, 5.15e-8]) - * u.cm**2 - * u.s**-1, + data_y=np.array([6.45e-9, 1.26e-8, 1.81e-8, 3.01e-8, 5.15e-8]) * u.cm**2 * u.s**-1, source="moore_thermal_2004", isotope="H", note="data in table IV. Units are not given but on page 2651 the equation indiquates that D is in cm2/s", @@ -77,9 +75,7 @@ zakharov_diffusivity_tungsten_h = Diffusivity( data_T=u.Quantity(np.array([400, 600, 800, 1000, 1200]), u.degC), - data_y=np.array([6.43e-8, 4.22e-6, 5.99e-5, 3.67e-4, 1.38e-3]) - * u.cm**2 - * u.s**-1, + data_y=np.array([6.43e-8, 4.22e-6, 5.99e-5, 3.67e-4, 1.38e-3]) * u.cm**2 * u.s**-1, source="zakharov_hydrogen_1975", isotope="H", note="the author gives activation energies in cal", @@ -274,11 +270,7 @@ rolled_114um_data_invT = liu_permeability_data["rolled_114umX"] * u.K**-1 rolled_114um_data_y = ( - liu_permeability_data["rolled_114umY"] - * u.mol - * u.m**-1 - * u.s**-1 - * u.Pa**-0.5 + liu_permeability_data["rolled_114umY"] * u.mol * u.m**-1 * u.s**-1 * u.Pa**-0.5 ) liu_permeability_rolled_114um = Permeability( data_T=1 / rolled_114um_data_invT, @@ -290,11 +282,7 @@ rolled_240um_data_invT = liu_permeability_data["rolled_240umX"] * u.K**-1 rolled_240um_data_y = ( - liu_permeability_data["rolled_240umY"] - * u.mol - * u.m**-1 - * u.s**-1 - * u.Pa**-0.5 + liu_permeability_data["rolled_240umY"] * u.mol * u.m**-1 * u.s**-1 * u.Pa**-0.5 ) liu_permeability_rolled_240um = Permeability( data_T=1 / rolled_240um_data_invT, @@ -306,11 +294,7 @@ annealed_50um_data_invT = liu_permeability_data["annealed_50umX"] * u.K**-1 annealed_50um_data_y = ( - liu_permeability_data["annealed_50umY"] - * u.mol - * u.m**-1 - * u.s**-1 - * u.Pa**-0.5 + liu_permeability_data["annealed_50umY"] * u.mol * u.m**-1 * u.s**-1 * u.Pa**-0.5 ) liu_permeability_annealed_50um = Permeability( data_T=1 / annealed_50um_data_invT, @@ -322,11 +306,7 @@ annealed_250um_data_invT = liu_permeability_data["annealed_250umX"] * u.K**-1 annealed_250um_data_y = ( - liu_permeability_data["annealed_250umY"] - * u.mol - * u.m**-1 - * u.s**-1 - * u.Pa**-0.5 + liu_permeability_data["annealed_250umY"] * u.mol * u.m**-1 * u.s**-1 * u.Pa**-0.5 ) liu_permeability_annealed_250um = Permeability( data_T=1 / annealed_250um_data_invT, @@ -396,9 +376,7 @@ ) -recrystallized_250um_data_invT = ( - liu_diffusivity_data["recrystallized_250umX"] * u.K**-1 -) +recrystallized_250um_data_invT = liu_diffusivity_data["recrystallized_250umX"] * u.K**-1 recrystallized_250um_data_y = ( liu_diffusivity_data["recrystallized_250umY"] * u.m**2 * u.s**-1 ) @@ -421,11 +399,7 @@ bauchenaeur_permeability_iter_grade = Permeability( data_T=1000 / (buchenauer_data["ITER_grade"]["x"] * u.K**-1), - data_y=buchenauer_data["ITER_grade"]["y"] - * u.mol - * u.m**-1 - * u.s**-1 - * u.MPa**-0.5, + data_y=buchenauer_data["ITER_grade"]["y"] * u.mol * u.m**-1 * u.s**-1 * u.MPa**-0.5, source="buchenauer_permeation_2016", isotope="D", note="ITER grade Tungsten", @@ -457,6 +431,15 @@ isotope="T", ) +shimada_permeability = Permeability( + pre_exp=2.13e-9 * u.mol * u.m**-1 * u.Pa**-0.5 * u.s**-1, + act_energy=93.32 * u.kJ * u.mol**-1, + isotope="T", + range=(573 * u.K, 873 * u.K), + note="polycristalline tungsten, pressure range 5.8e-2-6.8e-2 Pa, details in table 1", + source="shimada_tritium_2019", +) + properties = [ frauenfelder_diffusivity, liu_diffusivity_tungsten, @@ -500,6 +483,7 @@ bauchenaeur_permeability_ufg, otsuka_diffusivity, ikeda_diffusivity, + shimada_permeability, ] for prop in properties: diff --git a/h_transport_materials/references.bib b/h_transport_materials/references.bib index 825228b..68de215 100644 --- a/h_transport_materials/references.bib +++ b/h_transport_materials/references.bib @@ -2621,3 +2621,21 @@ @article{guthrie_permeation_1974 volume = {53}, year = {1974} } + +@article{shimada_tritium_2019, + series = {{SI}:{SOFT}-30}, + title = {Tritium permeability in polycrystalline tungsten}, + volume = {146}, + issn = {0920-3796}, + url = {https://www.sciencedirect.com/science/article/pii/S0920379619304041}, + doi = {10.1016/j.fusengdes.2019.03.083}, + abstract = {A flowing hydrogen-tritium permeation system was used to investigate tritium permeation behavior in polycrystalline tungsten. Tritium permeability was measured with T2 partial pressure ranging from 5.8 × 10−2 Pa to 6.8 × 10−2 Pa over the temperature range from 573 to 873 K. The obtained tritium permeability in polycrystalline tungsten was PT [mol m−1s−1 Pa−0.5] = (2.13 × 10−9)exp(−93.32 [kJ mol−1]/RT). This is one of the first tritium permeability data from any polycrystalline tungsten via a gas-driven permeation technique. The tritium permeability in polycrystalline tungsten was compared with the reported hydrogen isotope permeability in other polycrystalline tungsten.}, + urldate = {2024-03-21}, + journal = {Fusion Engineering and Design}, + author = {Shimada, M. and Pawelko, R. J.}, + month = sep, + year = {2019}, + keywords = {Permeation, Tritium permeability, Tungsten}, + pages = {1988--1992}, + file = {ScienceDirect Snapshot:C\:\\Users\\remidm\\Zotero\\storage\\K6L4T4HI\\S0920379619304041.html:text/html}, +} \ No newline at end of file