Skip to content
New issue

Have a question about this project? Sign up for a free GitHub account to open an issue and contact its maintainers and the community.

By clicking “Sign up for GitHub”, you agree to our terms of service and privacy statement. We’ll occasionally send you account related emails.

Already on GitHub? Sign in to your account

Explosives and Related Materials #22

Open
TechLord22 opened this issue Sep 11, 2022 · 0 comments
Open

Explosives and Related Materials #22

TechLord22 opened this issue Sep 11, 2022 · 0 comments
Labels
material This relates to new materials

Comments

@TechLord22
Copy link
Member

TechLord22 commented Sep 11, 2022

Details

These materials can be used for many purposes: be it combat or mining or something else altogether.

Production

Explosive Boosters

Picric Acid

Phenol (s) + Fuming Sulfuric Acid (aq) + Nitric Acid (aq) -> 10 Picric Acid (s)
C6H5OH (s) + H2SO4 (aq) + HNO3 (aq) -> C6H3N3O7 (s)
This reaction step is highly exothermic. Note that GT's phenol is liquid/aqeuous.

Tetryl

Aniline (l) + 2 Methanol (l) + Acid (catalyst) -> Dimethylaniline (l) + 2 Water (l)
C6H7N (l) + 2CH3OH (l) -> C6H5N(CH3)2 (l) + 2H2O (l)

Dimethylaniline (l) + 8 Nitration Mixture (aq) -> 10 Tetryl + 0.5 Ethylene (g) + 6 Dilute Sulfuric Acid (l)
C8H11N + 4HNO3 (aq) -> C7H5N5O8 (s) + 0.5 C2H4 (g) + 4H2O (l)

Detonators

Mercury Fulminate

Mercury (l) + 2 Nitric Acid (aq) + Ethanol (l) -> 7 Mercury (II) Fulminate (s) + 4 Water (l) + Oxygen (g)
Hg (l) + 2HNO3 (aq) + C2H5OH (l) -> Hg(CNO)2 (s) + 4H2O (l) + O (g)

TNT

Toluene (l) + 2 Nitration Mixture (aq) -> Mononitrotoluene (aka MNT) (l) + Dilute Sulfuric Acid (aq)
C7H8 (l) + HNO3 (aq) -> C7H7(NO2) (l) + H2O (l)

Mononitrotoluene (l) + Nitric Acid (aq) -> 3 Dinitrotoluene (aka DNT) (s) + Water (l)
C7H7NO2 (l) + HNO3 (aq) -> C7H6(NO2)2 (s) + H2O (l)

3 Dinitrotoluene (s) + Nitric Acid (aq) -> 4 Crude Trinitrotoluene (s) + Water (l)
C7H6(NO2)2 (s) + HNO3 (aq) -> C7H5(NO2)3 (s) + H2O (l)

Sulfur Dioxide (g) + 6 Sodium Hydroxide (s) -> 6 Sodium Sulfite (s) + Water (l)
SO2 (g) + 2NaOH (s) -> Na2SO3 (s) + H2O (l)

Sulfur Dioxide (g) + 6 Sodium Bicarbonate (soda ash) (s) -> 6 Sodium Sulfite (s) + Carbon Dioxide (g)
SO2 (g) + Na2CO3 (s) -> Na2SO3 (s) + CO2 (g)

Water (l) + 6 Sodium Sulfite (s) -> Sodium Sulfite Solution (aq)

2 Crude Trinitrotoluene (s) + Sodium Sulfite Solution (aq) -> Trinitrotoluene (aka TNT) (s) + Red Water (aq)

Red Water (aq) -> A Sodium Sulfite (s) + B Sodium Sulfate (s) + C Sodium Nitrate (s) + D Sulfonated Nitroaromatics (l)
This part of the process usually vaporizes the contained water, and then incinerates the residue for disposal.
A potential implementation of this step could be Red Water -> 5 Sodium Sulfite (loss) + Steam in a Dryer.

Nitroglycerin / Glyceryl Trinitrate

Glycerol (l) + 6 Nitration Mixture (aq) -> Nitroglycerine (l) + 4.5 Dilute Sulfuric Acid
C3H5(OH)3 (l) + 3HNO3 (aq) -> C3H5(NO3)3 (l) + 3H2O (l)

RDX - Research Department eXplosive / Hexogen

4 Ammonia (g) + 6 Formaldehyde (l) -> 12 Hexamine (s) + 6 Water (l) + 10 Hydrogen (g)
4NH3 (g) + 6CH2O (l) -> C6H2N4 (s) + 6H2O (l) + 10H (g)

12 Hexamine (s) + 4 Ammonium Nitrate (s) + 4 Nitric Acid (aq) -> 20 RDX (s) + Water (l) + 5 Oxygen (g)
C6H2N4 (s) + 2NH4NO3 (s) + 4HNO3 (aq) -> 2C3H6N6O6 (s) + H2O (l) + 5O (g)
This step is called the Brachmann Process.

HMX - Octogen / Tetrahexamine Tetranitramine

4 RDX (s) + Nitric Acid (aq) (catl) -> 3 HMX (s)
4C3H6N6O6 (s) -> 3C4H8N8O8 (s)

PETN - Pentraerythritol Tetranitrate

Acetaldehyde (l) + 3 Formaldehyde (l) + Calcium Hydroxide (s) (catl) -> Pentaerythrose (l)
CH3CHO (l) + 3CH2O (l) -> C5H10O4 (l)

Pentaerythrose (l) + Formaldehyde (l) -> 5 Pentraerythritol (s) + Carbon Monoxide (g)
C5H10O4 (l) + CH2O (l) -> C(CH2OH)4 (s) + CO (g)

5 Pentraerythritol (s) + 4 Nitric Acid (aq) -> 5 PETN (s) + 4 Water (l)
C(CH2OH)4 (s) + 4HNO3 (aq) -> C5H8(NO3)4 (s) + 4H2O (l)

Explosive D - Dunnite

10 Picric Acid (s) + Ammonia (g) -> 10 Explosive D (s)
C6H3N3O7 (s) + NH3 (g) -> C6H6N4O7 (s)

TATB - Triaminotrinitrobenzene

3 Methanol (l) + 1 Red Phosphorus Dust (s) + 3 Iodine (s) -> 3 Iodomethane (l) + Phosphorous Acid (aq)
3CH3OH (l) + 1/4 P4 (s) + 3I (s) -> 3CH3I (l) + H3PO3 (aq)

Unsymmetrical Dimethylhydrazine (UDMH, aka 1,1-dimethylhydrazine) (l) + Iodomethane (l) -> 4 1,1,1-trimethylhydrazinium Iodide (TMHI) (l)
H2NN(CH3)2 (l) + CH3I (l) -> H2NN(CH3)3I (s)

10 Explosive D (s) -> 2 Picramide (s) + Water (l)
C6H6N4O7 (s) -> C6H4N4O6 (s) + H2O (l)

4 TMHI (l) + 10 Explosive D (s) -> 10 TATB (s) + Iodomethane (l) + Ethane (g)
H2NN(CH3)3I (l) + C6H4N4O6 (s) -> C6H6N6O6 (s) + CH3I (l) + C2H6 (g)

HND - Hexanitrodiphenylamine

2-Nitrochlorobenzene + Nitric Acid (aq) -> 2,4-Dinitrochlorobenzene (l) + Water (l)
C6H4ClNO2 (l) + HNO3 (aq) -> C6H3Cl(NO2)2 (l) + H2O (l)

Chlorobenzene + 2 Nitric Acid (aq) -> 2,4-Dinitrochlorobenzene (l) + 2 Water (l)
C6H5Cl (l) + 2HNO3 (aq) -> C6H3Cl(NO2)2 (l) + 2H2O (l)

Aniline (l) + Dinitrochlorobenzene (l) + Sodium Carbonate (soda ash) (s) (catl) -> 6 Dinitrodiphenylamine (s) + Hydrochloric Acid (aq)
C6H5NH2 (l) + C6H3Cl(NO2)2 (l) + Na2CO3 (s) -> C12H9N(NO2)2 (s) + HCl (aq)

6 Dinitrodiphenylamine (s) + 4 Nitric Acid (aq) -> 10 HND (s) + 4 Water (l)
C12H9N(NO2)2 (s) + 4HNO3 -> C12H5N(NO2)6 (s) + 4H2O (l)

HND was found to be mutagenic.

Nitrocellulose - Flash Paper/String or Guncotton

Cellulose (s) + 3 Nitric Acid (aq) -> 10 Trinitrocellulose (s) + 3 Water (l)
C6H10O5 (s) + 3HNO3 (aq) -> C6H7(NO2)3O5 (s) + 3H2O (l)

TATP - Triacetone Triperoxide / APEX

Hydrogen Peroxide (l) + Acetone (l) -> TATP (s) + 3 Water (l)
3H2O2 (l) + 3C3H6O (l) -> C9H18O6 (s) + 3H2O (l)

FOX-7 - 1,1-diamino-2,2-dinitroethylene (DADNE)

Ethylene Glycol (l) + 2 Oxygen (g) + Silver (s) (catl) -> Glyoxal (l) + 2 Water (l)
C2H4(OH)2 (l) + 2O (g) -> C2H2O2 (l) + 2H2O (l)

Acetaldehyde (l) + Nitric Acid (aq) -> Glyoxal (l) + Nitrogen Dioxide (g) + 2 Hydrogen (g)
CH3CHO (l) + HNO3 (aq) -> C2H2O2 (l) + NO2 (g) + 2H (g)

Glyoxal (l) + 2 Ammonia (g) + Acetaldehyde (l) -> 12 2-Methylimidazole (s) + 3 Water (l)
C2H2O2 (l) + 2NH3 (g) + CH3CHO (l) -> C4H6N2 (s) + 3H2O (l)
This is a Radziszewski Reaction.

12 2-Methylimidazole (s) + 4 Nitration Mixture (aq) -> 2-(dinitromethylene)-4,5-imidazolidinedione (l) + 3 Dilute Sulfuric Acid
C4H6N2 (s) + 2HNO3 (aq) -> C4H2N4O6 (l) + 6H (g)

2-(dinitromethylene)-4,5-imidazolidinedione (l) + 2 Ammonia (g) -> 10 FOX-7 (s) + Ethylene (g) + 2 Nitric Oxide (g)
C4H2N4O6 (l) + 2NH3 (g) -> C2H4N4O4 (s) + C2H4 (g) + 2NO (g)

HNIW - CL-20 aka Hexanitrohexaazaisowurtzitane

Toluene (l) + 2 Chlorine (g) -> Benzyl Chloride (l) + Hydrochloric Acid (aq)
C7H8 (l) + 2Cl (g) -> C7H7Cl (l) + HCl (aq)
This step is a photochemical reaction.

Benzyl Chloride (l) + Ammonia (g) -> Benzylamine (l) + Hydrochloric Acid (aq)
C7H7Cl (l) + NH3 (g) -> C7H7NH2 (l) + HCl (aq)

6 Benzylamine (l) + 3 Glyoxal (l) + Formic Acid (aq) (catl) -> 1 Hexabenzyl Hexaazaisowurtzitane (s) + 6 Water (l)
6 C7H7NH2 (l) + 3 C2H2O2 (l) -> C48H48N6 (s) + 6H2O (l)

1 Hexabenzyl Hexaazaisowurtzitane (s) + 4 Acetic Anhydride (l) + Palladium (II) Acetate (s) (catl) -> 1 Tetraacetyl Hexaazaisowurtzitane (s) + 4 Ethylbenzene (l) + 4 Carbon Dioxide (g)
C48H48N6 (s) + 4C4H6O3 (l) -> C28H32N6O4 (s) + 4C8H10 (l) + 4CO2 (g)

Nitric Acid (aq) + Hydrofluoric Acid (aq) + 4 Boron Triflouride (s) -> 8 Nitronium Tetrafluoroborate (s) + Water (l)
HNO3 (aq) + HF (aq) + BF3 (s) -> NO2BF4 (s) + H2O (l)

Nitric Oxide (g) + Nitrogen Dioxide (g) -> Dinitrogen Trioxide (l)
NO (g) + NO2 (g) -> N2O3 (l)
This reaction is performed at 252K.

Water (l) + Dinitrogen Trioxide (l) -> 2 Nitrous Acid (aq)
H2O (l) + N2O3 (l) -> 2HNO2 (aq)

Nitrous Acid (aq) + Hydrofluoric Acid (aq) + 4 Boron Triflouride (s) -> 7 Nitrosyl Tetrafluoroborate (s) + Water (l)
HNO2 (aq) + HF (aq) + BF3 (s) -> NOBF4 (s) + H2O (l)

1 Tetraacetyl Hexaazaisowurtzitane (s) + 32 Nitronium Tetrafluoroborate (s) + 14 Nitrosyl Tetrafluoroborate (s) -> 32 HNIW (s) + 24 Boron Trifluoride (s) + 2 Ethylbenzene (l) + 2 Carbon Monoxide (g) + 4 Carbon (s)
C28H32N6O4 (s) + 4NO2BF4 (s) + 2NOBF4 (s) -> C6N12H6O12 (s) + 6HF (aq) + 6BF3 (s) + 2C8H10 (l) + 2CO (g) + 4C (s)

Flamethrowers

Fuel is usually Gasoline or Diesel, sometimes Creosote.
The fuel is propelled by compressed Nitrogen Gas.

Thermite

5 Hematite / Iron (III) Oxide + 2 Aluminium Dust -> 7 Iron Thermite (mixer)
(Fe2O3 + 2Al -> Fe + Al2O3)

6 Copper Oxide + 2 Aluminium Dust -> 8 Copper Thermite (mixer)
(3CuO + 2Al -> 3Cu + Al2O3)

9 Pyrolusite / Manganese Dioxide + 4 Aluminium Dust -> 13 Manganese Thermite (mixer)
(3MnO2 + 4Al -> 3Mn + 2Al2O3)

5 Chromium Trioxide + 2 Aluminium Dust -> 7 Chromium Thermite (mixer)
(Cr2O3 + 2Al -> 2Cr + Al2O3)

9 Silicon Dioxide + 4 Alunium Dust -> 13 Silicon Thermite (mixer)
(3SiO2 + 4Al -> 3Si + 2Al2O3)

Explosives

Any Explosive Booster + Any Detonator + TNT -> 4 TNT Sticks (forming press)
16 TNT Sticks -> 1 TNT Block (packager)

2 TNT + 3 RDX -> 5 Composition B (mixer)

9 RDX + 1 Polyisobutylene Pulp -> 10 Composition C-4 (mixer)

3 TNT + 2 Ammonium Nitrate -> 5 Amatol (mixer)

2 TNT + 3 Barium Nitrate -> 5 Baratol (mixer)

2 TNT + 2 RDX + 1 Aluminium Dust -> 5 Torpex (mixer)

4 TNT + 1 Aluminium Dust -> 5 Tritonal (mixer)

1 TNT + 4 RDX -> 5 Cyclotol (mixer)

1 TNT + 1 HMX -> 2 Octol (mixer)

1 TNT + 1 PETN -> 2 Pentolite (mixer)

1 TNT + 1 Tetryl -> 2 Tetryol (mixer)

3 TNT + 2 HND -> 5 Hexanite (mixer)

4 TNT + 4 RDX + 2 Aluminium Dust + 1 Tiny Nitrocellulose + 1 Tiny Calcium Chloride + 1 Tiny Calcium Silicate -> 10 HBX-1 (mixer)

3 PETN + 1 RDX + 1 Styrene-Butadiene Rubber Pulp -> 5 Semtex 2P (mixer)

9 Ammonium Nitrate + 100L Diesel/Kerosene -> 10 ANFO (mixer)

1 PETN -> 4 Detcord (compressor)

1 Nitrocellulose + 1 Wood Pulp + 1 Saltpeter/Potassium Nitrate/Sodium Nitrate + 100L Nitroglycerin -> 4 Gelingite aka Blasting Gelatin (mixer)

Sources

https://en.wikipedia.org/wiki/Picric_acid
https://en.wikipedia.org/wiki/Tetryl
https://en.wikipedia.org/wiki/Mercury(II)_fulminate
https://en.wikipedia.org/wiki/TNT
https://en.wikipedia.org/wiki/Nitroglycerin
https://en.wikipedia.org/wiki/Hexamethylenetetramine
https://en.wikipedia.org/wiki/RDX
https://en.wikipedia.org/wiki/HMX
https://en.wikipedia.org/wiki/Pentaerythritol_tetranitrate
https://en.wikipedia.org/wiki/Dunnite
https://en.wikipedia.org/wiki/2,4,6-Trinitroaniline
https://en.wikipedia.org/wiki/TATB
https://en.wikipedia.org/wiki/2,4-Dinitrochlorobenzene
https://en.wikipedia.org/wiki/Hexanitrodiphenylamine
https://en.wikipedia.org/wiki/Nitrocellulose
https://en.wikipedia.org/wiki/Glyoxal
https://en.wikipedia.org/wiki/2-Methylimidazole
https://www.sciencedirect.com/science/article/pii/S0040402098006735?via%3Dihub
https://en.wikipedia.org/wiki/FOX-7
https://en.wikipedia.org/wiki/Benzyl_chloride
https://en.wikipedia.org/wiki/Benzylamine
https://en.wikipedia.org/wiki/Hexanitrohexaazaisowurtzitane
https://en.wikipedia.org/wiki/Nitronium_tetrafluoroborate
https://en.wikipedia.org/wiki/Dinitrogen_trioxide
https://en.wikipedia.org/wiki/Nitrous_acid
https://en.wikipedia.org/wiki/Nitrosonium_tetrafluoroborate
https://pubs.acs.org/doi/pdf/10.1021/jo00237a043
https://en.wikipedia.org/wiki/Petroleum_Warfare_Department
https://en.wikipedia.org/wiki/Thermite
https://en.wikipedia.org/wiki/Acetone_peroxide
https://en.wikipedia.org/wiki/High_Blast_Explosive
https://en.wikipedia.org/wiki/ANFO
https://en.wikipedia.org/wiki/Gelignite

@TechLord22 TechLord22 added the material This relates to new materials label Sep 11, 2022
Sign up for free to join this conversation on GitHub. Already have an account? Sign in to comment
Labels
material This relates to new materials
Projects
None yet
Development

No branches or pull requests

1 participant